• Title/Summary/Keyword: 기계화학법

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Simulation Model of Membrane Gas Separator Using Aspen Custom Modeler (ACM을 이용한 가스 투과막 특성 해석 모델)

  • Song, Dong-keun;Shin, Gahui;Yun, Jinwon;Yu, Sangseok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.12
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    • pp.761-768
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    • 2016
  • Membranes are used to separate pure gas from gas mixtures. In this study, three different types of mass transport through a membrane were developed in order to investigate the gas separation capabilities of a membrane. The three different models typically used are a lumped model, a multi-cell model, and a discretization model. Despite the multi-cell model producing similar results to a discretization model, the discretization model was selected for this investigation, due to the cell number dependence of a multi-cell model. The mass transport model was then used to investigate the effects of pressure difference, flow rate, total exposed area, and permeability. The results showed that the pressure difference increased with the stage cut, but the selectivity was a trade-off for the increasing pressure difference. Additionally, even though permeability is an important parameter, the selectivity and stage cut of the membrane converged as permeability increased.

Nano-bending method for the measurement of the Poisson's ratio of MEMS thin films (MEMS 박막의 푸와송 비 측정을 위한 미소굽힘기법)

  • 김종훈;김정길;연순창;전윤광;한준희;이호영;김용협
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.2
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    • pp.57-62
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    • 2003
  • Nano-bending method is presented to measure the Poisson's ratio of thinfilms for MEMS (Micro-Electro-Mechanical Systems) applicaiton. The douvle-ring specimen is designed and fabricated based on the surface micromachining process to facilitate the measurement of the Poisson's ratio. The Poisson's ratio can be obtained through analyzing the linear load-displacement relationship of the double ring specimen subjected to nano-indenter loading. The Present nano-bending mehod is an in-situ measurement approach due to the compatibility to the surface micromachining process. The Poisson's ratio is locally obtained at the location of the double ring specimen with micro dimension. To validate the nano-bending method, the Poisson's ratio of LPCVD (Low Pressure Chemical Vapor Deposition) poly-silicon with thickness of 2.3㎛ is investigated. Experimental results reveal that the Poisson's ratio of the poly-silicon film is 0.2569. The standard deviation of the nano-bending measurement for the stiffness of double ring specimens is 2.66%.

Phase Analysis of Mechanically Alloyed $\sigma$-VFe Alloy Powders by Neutron and X-ray Diffraction (기계적 합금화한 $\sigma$-VFe합금의 중성자 및 X선 회절에 의한 상분석)

  • 이충효;조재문;이상진;심해섭;이창희
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.664-664
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    • 2001
  • The mechanical alloying (MA) effect in $\sigma$-VFe intermetallic compound was studied by neutron and X-ray diffraction. The structure of MA $\sigma$-VFe powders were characterized by the X- ray diffraction with Cu- $K\alpha$ radiation and neutron diffraction with monochromatic neutrons of $1.835\AA$ using a high resolution powder diffractometer (HRPD). Mechanical alloying of $\sigma$-VFe compound gives rise to a dramatic structural change. After 60 hours of MA, the Fe-Fe distribution of the $\sigma$- phase VFe tetragonal structure with 30 atoms in a unit cell is found to change into that of the $\sigma$-(V,Fe) solid solution with bcc structure, which is a stable phase at elevated temperature above $1200^{\circ}C$. A comparison of X-ray diffraction data for the $\alpha$-phase has been also made with the corresponding neutron diffraction data. The (101) and (111) diffraction peaks of the $\sigma$-phase was clearly observed only in neutron diffraction pattern, which is believed to be a characteristic feature due to the chemical atomic ordering of $\sigma$- VFe phase.

Studies on the Preparation of Conducting Composite Film by a Vapor Phase in situ Polymerization (전도성 복합필름의 기상중합과 특성에 대한 연구)

  • Park, Jun-Seo;Park, Jang-Woo
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.902-906
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    • 1999
  • Electrically conducting composite films were prepared by a vapor phase in situ polymerization of pyrrole in the methyl cellulose film containing a copper(II) perchlorate. Methylcellulose had high affinity to pyrrole and was used as a matrix polymer. Conducting polypyrrole was embedded in the methylcellulose film forming a conducting network and the conductivity of the composite films ranged $10^{-1}$ to $10^{-7}S/cm$. The conductivities of conducting composite films were dependent on the nature of the matrix polymers, concentration of oxidant and polymerization time. In situ polymerization of pyrrole was observed in the matrix polymer and confirmed by UV-vis spectra. From the results of the thermogravimetric analysis, the chemical oxidative polymerization of pyrrole in the matrix polymers did not give any negative effects on the thermal stability of the composite films. Electron micrograph of composites indicated good penetration of PPy in the matrix polymer. DMA suggested a certain degree of incompatibility of the polypyrrole in the composites.

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A Study of $NO_x$ Reduction in Stage Combustion (단계적 연소의 $NO_x$ 저감에 대한 연구)

  • 채재우;전영남;이운영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1556-1571
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    • 1993
  • Nitrogen oxides ($NO_x$) are air pollutants which are generated from the combustion of fossil fuels. Stage combustion is an effective method to reduce $NO_x$ emissions. The effects of $NO_x$ reduction by stage combustion in a pilot scale combustor(6.6kW) have been investigated using propane gas flames laden with NH$_{3}$ as Fuel-N. The results in this study are follows; (1) $NO_x$ emissions are dependent on the reducing environment of fuel-rich zone regardless of total air ratio. The maximum $NO_x$ reduction is at the stoichiometric ratio of 0.8 to 0.9 in the reducing zone. (2) $NO_x$ reduction is maximum when burnout air is injected at the point where the oxygen in reducing zone is almost consumed. (3) $NO_x$ reduction is dependent upon the temperature of reducing zone with best effect above 950.deg. C in the reducing zone. (4) The fuel stage combustion is more effective to reduce $NO_x$ formation in the wide range of stoichiometric ratio than two stage combustion. (5) The results of this study could be utilized mainly in a design strategy for low $NO_x$ emission from the combustion of high fuel-nitrogen in energy sources ratio than as an indication of the absolute levels of $NO_x$ which can be achieved by stage combustion techniques in large scale facilities.

Physical and Chemical Effects of Extracellular Matrix on the Growth of Cardiomyocytes (HL-1) (세포외 기질 물질의 물리·화학적 영향에 따른 심근세포(HL-1)의 성장 연구)

  • Hong, Yoon-Mi;Choi, Seong-Kyun;Kim, Sun-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1229-1235
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    • 2011
  • The extracellular matrix (ECM) is a key factor affecting cell growth and adhesion to the culture surface, and it is also important for maintaining the innate characteristics of cells. Here, we describe the effects of the ECM on cardiomyocyte (HL-1 cell line) growth, viability, phenotype, and contractile ability. Five different ECM materials were investigated to analyze their effects on the cell growth. The physical morphology of the ECM-coated surfaces was scanned with an atomic force microscope (AFM), and the attachment, growth, proliferation, viability, and phenotype of the cells were analyzed using fluorescence immunostaining and an inverted phase contrast microscope.

Removal of Polymer residue on Graphene by Plasma treatment

  • Yun, Hye-Ju;Jeong, Dae-Seong;Lee, Geon-Hui;Sim, Ji-Ni;Lee, Jeong-O;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.375.2-375.2
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    • 2016
  • 그래핀(Graphene)은 원자 한 층 두께의 얇은 특성에 기인하여 우수한 투과도(~97.3%)를 나타내며, 높은 전자 이동도($200,000cm^2V^{-1}s^{-1}$)로 인하여 전기 전도도가 우수한 2차원 전자소재이다. 또한 유연하고 우수한 기계적 물성을 가지고 있어 실제로 다양한 소자에서 활용되고 있다. 그래핀을 이용하여 다양한 소자로 응용하기 위한 과정 중 하나인 포토리소그래피 공정(Photolithography process)은 원하는 패턴을 만들기 위해 제작하고자 하는 기판 위에 포토레지스트(Photoresist)를 코팅하는 과정을 거치게 된다. 하지만 이러한 과정은 소자 제작에 있어서 포토레지스트 잔여물을 남기게 된다. 그래핀 위에 남은 포토레지스트 잔여물은 그래핀의 우수한 전기적 특성을 저하시켜 소자특성에 불이익을 주게 된다. 본 연구에서는 수소 플라즈마를 이용하여 그래핀 위에 남은 중합체(Polymer) 잔여물을 제거한다. 사용한 그래핀은 화학 기상 증착법(Chemical vapor deposition)을 이용하여 성장시켰으며, PMMA(Poly(methyl methacrylate))를 이용하여 이산화규소(silicon dioxide) 기판에 전사하였다. 그래핀의 손상 없이 중합체 잔여물을 제거하기 위해 플라즈마 처리시간을 15초부터 1분까지 늘려가며 연구를 진행하였으며, 플라즈마 처리 시간에 따른 중합체 잔여물의 제거 정도와 그래핀의 보존 여부를 확인하기 위해 라만 분광법(Raman spectroscopy)과 원자간력현미경(Atomic force microscopy)을 사용하였다. 본 연구 결과를 통해 간단한 플라즈마 처리로 보다 나은 특성의 그래핀 소자를 얻게 됨으로써, 향상된 특성을 가진 그래핀 소자로 산업적 응용 가능성을 높일 수 있을 것이라 생각된다.

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A Study on Weathering Processes of Tafoni in Mt. Cheonsaeng, Gumi, the Republic of Korea: Interpretation of Water Content Data using GIS Interpolation Analysis (구미 천생산 타포니의 풍화과정에 관한 연구: GIS 보간법을 활용한 함수율 측정 자료의 해석)

  • Shin, Jae-Ryul;Lee, Jin-Kook;Choo, Chang-Oh;Park, Kyung-Gun
    • Journal of the Korean earth science society
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    • v.36 no.6
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    • pp.543-552
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    • 2015
  • This study examines the processes of rock weathering and tafoni formation targeting tafoni at Mt. Cheonsaeng, Gumi-si, Gyeongsangbuk-do. In the study area, a frequency of tafoni is high in conglomerate and conglomeratic sandstone among regional sedimentary rocks, which means that an initial stage of the formation begins a breakaway of gravel from bedrock and also exfoliation from rock surface. Geomorphologically tafoni have intensively been developed at the southfacing slope with exposed rocks, which means that its formation was favorably controlled by environmental conditions including strong influences of mechanical weathering in winter and chemical weathering in summer times. The results of measuring water content at a tafoni-bearing rock surface using GIS interpolation analysis indicate that moisture rate in/around tafoni is higher than the periphery. Thus, it is considered that moisture distribution at a rock surface plays a role in its formation. Analysis of percipitation and secondary minerals induced by chemical weathering is in progress.

A Wave Propagation Analysis in the Layered Systems (적층계(積層係)를 통과하는 소성응력파(塑性應力波)의 전파(傳波))

  • Lee, Sang Ho;Ahn, Byoung Ki;Kang, Young Goo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.2
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    • pp.61-71
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    • 1993
  • The stress waves generated by the mechanical energies by impact or the chemical energies by the explosions are transmitted through medium. The wave propagation process through medium is a very complicated procedure due to the reflections and refractions of the waves at the free surfaces and interfaces. In this study the pressure independent Von-Mises model is employed for the wave propagation analysis in the layered systems. Governing equations of this study are conservation equations of momentum and mass in Lagrangian coordinate system which is fixed to the material. Due to the shock-front which violates the continuity assumptions inherent in the differential equations numerical artificial viscosity is used to spread the shock front over several computational zones. These equations are solved by Finite Difference Method with discretized time and space coordinates. The associate normality flow rule as a plastic theory is implemented to find the plastic strains.

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Effects of PEO Conditions on Surface Properties of AZ91 Mg Alloy (PEO 처리조건에 따른 마그네슘 합금 AZ91의 표면특성변화에 관한 연구)

  • Park, Kyeong-Jin;Jung, Myung-Won;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.3
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    • pp.71-77
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    • 2010
  • Mg alloys have been used in automobile industry, aerospace, mobile phone and computer parts owing to low density. However, they have a restricted application because of low mechanical and poor corrosion properties. Thus, improved surface treatments are required to produce protective films. Environmental friendly Plasma Electrolytic Oxidation(PEO) was used to produce protective films on magnesium alloys. PEO process is combined electrochemical oxidation with plasma treatment in the aqueous solution. In this study, the effects of applied voltage and applied current on the surface morphologies were investigated. Also, the effects of Direct Current(DC) and Pulse Current(PC) were compared. PC and constant current control gave the dense coating on the Mg alloy. The potentiodynamic polarization tests were carried out for the analysis of corrosion properties of specimens. The surface hardness was 5 times higher than that of untreated AZ91D.