• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.1
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• pp.58-63
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• 2005

PTFE (polytetrafluoroethylene) thin films were prepared from the pellets of the graphite doped PTFE via pulsed laser ablation with 1064 nm Nd:YAG laser. The graphite powder converts the absorbed photon energy into thermal energy which is transmitted to nearby PTFE. The PTFE is decomposed by thermal process. The deposited films were transparent and crystalline. SEM (scanning electron microscopy) and AFM (atomic force microscopy) analyses indicated that the film surface morphology changed to fibrous structure with increasing thickness. The fluorine to carbon ratios of the film were 1.7 and molecular axis was parallel with (100) Si-wafer substrate. These results obtained by XPS (X-ray photoelectron spectroscopy), FTIR (fourier transform infrared spectroscopy) and XRD (X-ray diffraction).

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.466-473
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• 2020

Fabric current collector can be a promising electrode material for Capacitive Deionization (CDI) system that can achieve energy-efficient desalination of water. The one of the most attractive feature of the fabric current collector is its high tensile strength, which can be an alternative to the low mechanical strength of the graphite foil electrode. Another advantage is that the textile properties can easily make shapes by simple cutting, and the porosity and inter-fiber space which can assist facile flow of the aqueous medium. The fibers used in this study were made of woven structures using a spinning yarn using conductive LM fiber and carbon fiber, with tensile strength of 319 MPa, about 60 times stronger than graphite foil. The results were analyzed by measuring the salt removal efficiency by changing the viscosity of electrode slurry, adsorption voltage, flow rate of the aqueous medium, and concentration of the aqueous medium. Under the conditions of NaCl 200 mg/L, 20ml/min and adsorption voltage 1.5 V, salt removal efficiency of 43.9% in unit cells and 59.8% in modules stacked with 100 cells were shown, respectively. In unit cells, salt removal efficiency increases as the adsorption voltage increase to 1.3, 1.4 and 1.5 V. However, increasing to 1.6 and 1.7 V reduced salt removal efficiency. However, the 100-cell-stacked module showed a moderate increase in salt removal efficiency even at voltages above 1.5 V. The salt removal rate decreased when the flow rate of the feed was increased, and the salt removal rate decreased when the concentration of the feed was increased. This work shows that fabric current collector can be an alternative of a graphite foil.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.225-225
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• 2012

DLC (Diamind-Like Carbon) 코팅은 1970년대 이온주입기술을 통하여 개발된 것이 처음으로 알려져 있으며, 다이아몬드 구조인 SP3 구조와 그라파이트 구조인 SP2 구조가 혼재되어 있으면서 제조 방법에 따라 수소와 Si 및 다양한 금속을 내재시킬 수 있는 코팅 물질이다. DLC는 높은 경도, 내마모성, 윤활성, 표면조도 등 뛰어난 기계적 특성과 전기절연성, 화학적 안정성 그리고 높은 광학적 투과성을 가져 산업적 활용 잠재력이 높은 재료로 평가되고 있으며, 이외에도 낮은 공정 온도에서 증착할 수 있고, 고경도와 낮은 마찰계수를 가지고 있는 장점이 있다. 그러나, DLC가 열적으로 불안정하기 때문에 사용되는 환경이 $500^{\circ}C$ 이상이 되면 DLC는 자체의 성질을 잃고 거의 흑연에 가까운 물질이 되어버리는 문제가 있고, 또한 높은 압축응력과 기재와의 낮은 밀착력이 단점으로 나타나고 있다. 이에 본 연구는 그런 단점을 보완하고자 PECVD (Plasmas Enhanced Chemical Vapor Deposition) 방법으로 DLC박막에 여러 가지 첨가원소(F,Si,0)를 사용하여 증착시킨 후 400, 500, $600^{\circ}C$에서 1시간동안 열처리를 진행하였으며, 그에 따른 내열 특성을 평가하였다. 또한 염수분무 테스트를 통한 박막의 내식 특성을 평가하였다. DLC박막의 구조는 Raman Spectra을 통해, Sp3 (like diamond) peak와 Sp2 (like graphite) peak 의 혼재 여부를 분석하였고, FE-SEM을 이용하여 막의 표면 및 단면을 관찰하였다. 스크래치 테스트를 통해 DLC박막의 밀착력을 측정하였으며, 볼 온 디스크 타입의 Tribo-meter을 이용하여 마찰계수 변화를 관찰하였다. 또한 나노인덴터를 이용하여 미소경도를 측정하였다. 그 결과 일반 DLC 막에 비해 첨가원소가 함유된 DLC 박막에서 내식성 및 내열특성이 향상되었다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2000.04a
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• pp.32-32
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• 2000

잠입노즐은 로케트 추진기관의 길이 및 중량을 감소시켜 체계설계의 관점에서 볼 때 많은 이점을 제공한다. 본 연구에서는 3단형 과학로케트 원지점 차넣기 모타(apogee kick motor)에 적용하기위한 잠입노즐의 기초기술 개발에 주안점을 두었다. 고고도에서 저속으로 회전하며 비행하는 원지점 차넣기 모타를 제작하기위해서 체계 요구성능에 의해 예상된 실물형의 50% 크기에 해당하는 축소형 잠입노즐을 제작하였다. 잠입노즐은 잠입부의 내외부가 고온의 추진제 연소가스에 노출된 상태에서 노즐 내부 압력 외에 연소실압에 의한 외부압력이 작용하므로 이를 고려한 열 및 구조설계가 중요하다. 본 연구에서는 노즐 수렴부와 목부에 일체형 그라파이트 소재를 적용하고 확장부 내열재 및 잠입부 배면내열재에 탄소/페놀 복합재를 노즐 내열재로 사용하였다. 그리고 이들의 구조적 지지를 위해 스틸구조물을 적용하였다. 적용된 스틸구조물에는 K형 열전쌍을 이용해 내열재와 구조물 온도를 측정할 수 있는 관통구멍 및 나사부를 구조물 외변에 가공하였다. 열전쌍은 노즐 목직경의 2, 4배 되는 확장부 내열재 단면위치의 2mm와 4mm 깊이와 구조물 내면 및 외면의 4개소에 열전쌍을 부착하여 지상연소시험시 노즐 내열재와 구조물의 온도분포를 관찰한다. 그리고 노즐 조립시 확장부 내열재와 구조물에 각 각 반원형 홈을 내어 여분의 접착제가 원형 홈에 밀려들어가 경화되어 노즐 기밀유지와 체결력을 향상시킬 수 있는 원형공간 접착제 충전 공법을 적용하여 실제모타에 대한 적용가능성을 지상연소시험을 통해 확인한다.

• Composites Research
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• v.14 no.6
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• pp.32-37
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• 2001

It is known that recoating or protection with glass-tube can prevent FBG sensor from being affected by birefringence. However, the effect on the strain transfer of such treatment has not been verified yet. Three types (uncoated, recoated and glass-tube protection) of FBG sensors are fabricated to verify the effect on the strain transfer of each treatment. The strain from each sensor embedded into a graphite/epoxy composite specimen was compared with that of ESG attached on the surface through the tensile test. And the signal characteristics of each sensor were also compared using the tensile test of a tapered aluminum specimen which was under the state of strain gradient.

• Journal of the Korean Society for Precision Engineering
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• v.20 no.7
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• pp.26-35
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• 2003

This study explains the effects of lubricant and surface treatment on hot forging die life. The mechanical and thermal load, and thermal softening which is happened by the high temperature of die, in hot and warm forging, cause die wear, heat checking and plastic deformation, etc. This study is fur the effects of solid lubricants and surface treatment condition for hot forging die. Because cooling effect and low friction are essential to the long life of dies, optimal surface treatment and lubricant are very important to improve die life for hot forging process. The main factors, which affect die hardness and heat transfer, are surface treatments and lubricants, which are related to thermal diffusion coefficient and heat transfer coefficient, etc. For verifying these effects, experiments are performed for hot ring compression test and heat transfer coefficient in various conditions as like different initial billet temperatures and different loads. The effects of lubricant and surface treatment for hot forging die life are explained by their thermal characteristics. The new developed technique in this study for predicting tool life can give more feasible means to improve the tool life in hot forging process.

• Elastomers and Composites
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• v.49 no.1
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• pp.66-72
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• 2014

Carbon coating on silica particles is done by grafting expanded graphite on the silica aggregates. Successful coating of carbon is corroborated using FT-IR, TGA, XPS and TEM. Crystalline nature of coated graphite is corroborated using XRD. Influence of carbon coated silica particles on rheometric and mechanical properties of SBR composites are investigated. Carbon coated silica particles showed significant improvement in rheometric and mechanical properties, when compared to pristine silica filled system corroborating higher polymer-filler adhesion. This fact was further supported by bound rubber content and equilibrium swelling ratios of unvulcanized and vulcanized SBR composites.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.05a
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• pp.833-836
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• 2000

The mechanical and thermal load. and thermal softening which is happened by the high temperature of die, in hot and warm forging, cause wear. heat checking and plastic deformation, etc. This study is for the effects of solid lubricants and surface treatments for warm forging die Because cooling effect and low friction are essential to the long lift of dies. optimal surface treatments and lubricants are very important to hot and warm forging Process. The heat that is generated by repeated forging processes. and its transfer are important factors to affect die life. The main factors, which affect die hardness and heat transfer, are surface treatments and lubricants, which are related to thermal diffusion coefficient and heat transfer coefficient, etc. For verifying these. experiments art performed for diffusion coefficient and heat transfer coefficient in various conditions - different initial billet temperatures and different loads. Carbonitriding and ionitriding are used as surface treatments. and oil- base and water-base graphite lubrirants are used. The effects of lubricant and surface treatment for warm forging die lift are explained by their thermal characteristics.

• Journal of the Korean Ceramic Society
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• v.44 no.11
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• pp.622-626
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• 2007

Graphite is widely used in electronic industry due to its excellent electrical and thermal properties. However, graphite starts to oxidize around $400^{\circ}C$ that seriously degrades its properties. SiC coating can be applied to graphite foam to improve its high temperature oxidation resistance. In this research, SiC coating on graphite foam was made via preceramic polymer using a polyphenylcarbosilane. 20% of polyphenylcarbosilane in hexane solution was coated onto graphite by dip coating method. Thermal oxidation was carried out at $200^{\circ}C$ for crosslink of the preceramic polymer and the sample were pyrolysized at $800^{\circ}C{\sim}1200^{\circ}C$ under nitrogen to convert the preceramic polymer to SiC film. The microstructure of the SiC coating after pyrolysis was investigated using FESEM and oxidation resistance up to $800^{\circ}C$ was evaluated.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.397-402
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• 2012

The objective of this study is the estimation of the two unknown thermal conductivity and thermal diffusivity by an inverse heat conduction analysis using the Levenberg-Marguardt method. One dimensional formulation of heat conduction problem in the model was applied. Two point transient temperature of test pieces and heat flux of inflow were measured under the high enthalpy flow environment. Estimated thermal conductivity and thermal diffusivity by an inverse analysis were compared with the known values of graphite test piece. It showed the effectiveness of proposed experimental inverse analysis.