• Polymer(Korea)
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• v.25 no.5
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• pp.744-753
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• 2001

One of the most important factors which affect the impact strength of high impact polystyrene (HIPS) is the rubber-phase particle size and size distribution. In this study, HIPS was prepared from a batch reactor to observe the influence of reaction conditions such as rubber content, agitation speed and prepolymerization time on the particle size and size distribution. Measurements concerning the particle size distribution were conducted using a particle size analyzer. Due to swelling, the particle suspended in toluene increases in size with lower heat-treatment temperature and shorter heat-treatment time, while the particle in methyl ethyl ketone shows quite reasonable size without any effort of heat-treatment. As rubber content increases, the average particle size increases substantially, but the increase in agitation speed at lower rubber contents does not have much influence on the size. However, the polystyrene-phase particles occluded in rubber-phase become more uniform as agitation speed increases. Longer prepolymerization time produces rubber-phase particles with narrower particle size distribution.

• Polymer(Korea)
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• v.34 no.2
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• pp.144-149
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• 2010

Ag/polystyrene(PS) nanocomposites were prepared by in situ reduction of silver 2-ethylhexylcarbamate (Ag-CB) complex and follwing radical polymerization only by heating at 110 $^{\circ}C$. In contrast to this conventional heating method, the microwave irradiation afforded well-dispersed silver nanoparticles(NPs) in styrene monomer without polymerization. The synthesis of Ag NPs proceeded uniformly throughout the reaction vessel only under microwave irradiation, completing the reaction simultaneously in the whole reaction solution. Successive polymerization of the monomer containing the resultant NPs has successfully produced a hybrid of the silver NPs dispersed in PS matrix. Ag/PS (0.1/100) nanocomposites were prepared successfully by melt-mixing process using Ag/PS(4.0/100) as a master-batch. UV-VIS spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the process of formation of Ag/PS nanocomposites.

• 대한공업교육학회지
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• v.32 no.2
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• pp.188-198
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• 2007

Platinum nanoparticles loading on carbon nanotube was carried out by impregnation of hexachloro platinate(IV) from hydrogen hexachloro platinate(IV) hydrate dissolved solution without using reduction agents, and heating the hexachloro platinate(IV) impregnated carbon nanotube up to $400^{\circ}C$. The amounts of impregnated hexachloro platinate(IV) on to carbon nanotube were measured with UV-visible spectrophotometer. The TG, XRD, and TEM analysis were performed to confirm the platinum particles loading and distribution on carbon nanotube. The average platinum particles size on carbon nanotube was under 2 nm by heating the hexachloro platinate(IV) up to $400^{\circ}C$ in spite of non-using reduction agents, while the average size increased due to the agglomeration of some particles by heating them up to $800^{\circ}C$. Therefore, uniformly distributed platinum nanoparticles loading on carbon nanotube can be obtained from simple impregnation of hexachloro platinate(IV) from solution and heating it up to $400^{\circ}C$.

• The Journal of the Acoustical Society of Korea
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• v.22 no.7
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• pp.545-553
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• 2003

This paper is concerned with protecting piezoelectric transducers used in an ultrasonic flowmeter from the high temperature of hot fluid in a pipe by using a waveguide and with improving the propagation of ultrasonic longitudinal vibration in the waveguide. Waveguide material has been chosen for efficient insulation of heat transferred in the waveguide, and the minimum length of the waveguide for protecting piezoelectric transducer has been estimated. Forced response of the longitudinal vibration in a uniform circular rod has been obtained and the length of the waveguide has been selected for maximum amplitude. Longitudinal vibration response of a conically-tapered rod excited at a natural frequency has been obtained to confirm that wave motion is amplified as the cross-sectional size of the waveguide decreases along the axial direction. The fact that dispersion of a pulse wave in a waveguide is reduced as the cross-sectional radius is decreased has been examined theoretically and confirmed experimentally by using a single-rod waveguide. A bundle-type waveguide has proven to be a practical one through the evaluation of the wave propagation performance.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.470-474
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• 2010

In this study, we presents a simple microfluidic approach for generating uniform Poly(ethylene glycol)(PEG) microfiber. Elongated flow pattern of monomer induced by sheath flow of immiscible oil as continuous phase is generated in Y-shape junction and in situ polymerization by UV exposure. For uniform microfiber, we investigate the optimized flow condition and draw phase diagram as function of Ca and Qd. At the region for stable elongated flow pattern, the microfiber generated in microfluidic chip is very uniform and highly reproducible. Importantly, the thickness of microfibers can be easily controlled by flow rate of continuous and disperse phase. We also demonstrate the feasibility for biological application as encapsulating FITC-BSA in PEG microfiber.

• Applied Chemistry for Engineering
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• v.2 no.2
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• pp.119-126
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• 1991

This investigation was undertaken to study the synthesis of Boehmite by the hydrothermal homogeneous precipitation reaction of alum with urea. The reactions were carried out at a temperature of 100 to $250^{\circ}C$, 1 : 2 to 1 : 5 in a mole ratio of alum to urea and a reaction time of 0.5 to 20 hrs. The reaction precipitates were examined by X-ray diffraction analysis, scanning electron microscope, and chemical analysis. Under the condition of mole ratio 1 : 4 of alum to urea, the spherical and monodispersed amorphous aluminum sulfate hydrate was formed at $100^{\circ}C$, the mixture of spherical amorphous aluminum sulfate hydrate and Boehmite was formed at $150^{\circ}C$, Boehmite was formed at above $200^{\circ}C$, respectively. The reaction precipitates were dense, superior precipitable and filterable particle of average $2-4{\mu}m$.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.10 no.6
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• pp.847-854
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• 1999

In this paper, we have analysed frequency-dispersion characteristics of higher-order modes for uniform planar transmission lines, using the 2-dimensional finite-difference time-domain method. The method presented in this paper uses both informations of amplitude and phase of the electromagnetic spectrum to determine resonant frequencies, while methods previously reported use the magnitude only. This algorithm is very useful when a resonant mode has a relatively small magnitude, where the identification of the resonant mode is quite difficult. Numerical results show that a strip line supports few higher-order modes within the frequency range of 20 GHz, but there occur many higher-order modes in the structure of grounded coplanar waveguide, where resonant frequencies of the first higher-order mode is very close to those of the fundamental mode and there occur lots of very adjacent higher-order modes. As in this example, for the analysis of planar transmission lines which support many resonant modes very close each other, the method presented in this paper can be applied very efficiently.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.3
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• pp.581-593
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• 1990

A semi-solid alloy in which solid and liquid phase are co-existing is obtained by strirring of Al7075 molten metal. A semi-solid alloy is dependent on the corresponding temperature within the solid-liquid range, and the process parameters should be controlled accurately to obtain the homogeneous semi-solid alloy. The possibility o homogeneous fiber-reinforce aluminum alloy by addition of $Al_{2}$O$_{3}$ short fibers with vigorous agitation was investigated. The billet of composite materials was fabricated by squeeze casting, and homogeneous dipersion state of fibers in billet of fabricated metal matrix composites was observed. A slurry of semi-solid short fiber metal matrix composites is used in the direct rolling process, and this process showed the fabrication possibility of metal matrix composite sheets. The fabricated sheet was tested regarding vickers hardness, elongation and micro-structure. It has become clear that mashy state processing and working are very useful to obtain parts of composites material closed to near net shape.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.27 no.11
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• pp.1019-1022
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• 2016

In this paper, a 2~16 GHz GaN wideband power amplifier MMIC s designed and fabricated using the nonuniform power amplifier design technique that utilizes drain shunt capacitors to simultaneously provide each transistor with the optimum load impedance and phase balance between input and output transmission lines. The power amplifier MMIC chip that is fabricated using the $0.25{\mu}m$ GaN HEMT foundry process of Win Semiconductors occupies an area of $3.9mm{\times}3.1mm$ and shows a linear gain of larger than 12 dB and an input return loss of greater than 10 dB. Under a continuous-wave mode, it has a saturated output power of 36.2~38.5 dBm and a power-added efficiency of about 8~16 % in 2 to 16 GHz.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.9 no.3
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• pp.291-297
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• 2016

In this paper, we are comparative analysis of exit algorithm and proposal algorithm for desired target direction of arrival estimation in correlation signal system. Proposed algorithm in this paper is to decrease target direction of arrival an estimation error probability using bayesian, maximum posterior, and MUSIC algorithm in order to decrease direction of arrival error probability as optimize and use linear constrained minimum variance to update weight value. Through simulation, we were comparative analysis proposed algorithm and exit MUSIC algorithm. In case SNR is 10dB and antenna element arrays are 9 and 12, We show the superior performance of the proposed method relative to the class method to decrease of signal estimation error probability about 11% and 13%, respectively.