• Title/Summary/Keyword: 규소의 편석

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Surface-energy -induced Selective Growth and Magnetic Induction in 3%Si-Fe Strip (극박 3%규소강에서 표면에너지 유기 선택적 결정성장 현상과 자성특성)

  • 조성수
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.4
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    • pp.57-61
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    • 2001
  • The {111}<112> deformation torture, which originated from the {110}<00l> texture near the surface of hot bands, is not prerequisite for the recrystallized {110}<001> Goss texture. During final annealing, surface-energy-induced selective growth of grains urn at the strip surface of 3%Si-Fe alloys containing 6ppm bulk content of sulfur. With decreasing final reduction, the probability that Goss grains survive under the highly segregated sulfur atmosphere and have a chance for later surface-energy-induced selective growth becomes higher, resulting in high magnetic induction.

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Estimation of the impurity segregation in the multi-crystalline silicon ingot grown with UMG (Upgraded Metallurgical Grade) silicon (UMG(Upgraded Metallurgical Grade) 규소 이용한 다결정 잉곳의 불순물 편석 예측)

  • Jeong, Kwang-Pil;Kim, Young-Kwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.5
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    • pp.195-199
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    • 2008
  • Production of the silicon feedstock for the semiconductor industry cannot meet the requirement for the solar cell industry because the production volume is too small and production cost is too high. This situation stimulates the solar cell industry to try the lower grade silicon feedstock like UMG (Upgraded Metallurgical Grade) silicon of 5$\sim$6 N in purity. However, this material contains around 1 ppma of dopant atoms like boron or phosphorous. Calculation of the composition profile of these impurities using segregation coefficient during crystal growth makes us expect the change of the type from p to n : boron rich area in the early solidified part and phosphorous rich area in the later solidified part of the silicon ingot. It was expected that the change of the growth speed during the silicon crystal growth is effective in controlling the amount of the metal impurities but not effective in reducing the amount of dopants.

The effect of carbon content on hot cracking of low carbon steel weld (저탄소성 용접금속의 응고균열에 미치는 탄소함량의 영향)

  • ;;Masumoto, I.
    • Journal of Welding and Joining
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    • v.6 no.4
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    • pp.16-26
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    • 1988
  • The effect of carbon content on hot cracking of welded carbon steel was investigated Eight steel plates whose carbon content range from 0.02 to 0.23 percent were welded by autogeous gas tungsten are process. Constant strain was applied to the hot crack test specimen under the strain rate of 0.15 mm per second during welding. The hot cracking susceptibility ws high in the rnage of 0.02-0.05 and 0.12-0.23 percent carbon contents. The critical carbon content immune to hot cracking is in the range from 0.07 to 0.12 percent carbon. By electron probe microanalyser, amanganese segregation was not seen significantly in the whole carbon range. But segregation of silicon was higher in the region of low carbon contents. However, sulphur was segregated remarkably in the region betwen 0.18 and 0.23 percent carbon by peritectic reaction. Very smal lamount of dnedritic structure was observed in the region from 0.02 to 0.05 percent carbon by peritectic reaction. Very small amount of dendritic structure was observed in the region from 0.02 to 0.05 percent carbon but the predominant solidification structure was smooth by cellular growth. The higher the carbon content is, the more the columnar dendritic structure was observed.

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Effects of Mn on Sulfur Segregation and Magnetic Induction in Thin-gauged 3%Si-Fe Strip (극박 3%규소강에서 Mn이 황의 편석 거동 및 자성특성에 미치는 효과)

  • 조성수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.917-920
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    • 2001
  • Effects of addition of manganese and final reduction on segregation behavior of sulfur and final mangetic induction during final annealing have been investigated in the 300 ppm sulfur-contained 3% silicon-iron alloy strips with or without manganese. At the same concentration of sulfur, lower final reduction is favorable for final Goss texture. This is because the probability that the initial Goss grains survive under the highly segregated sulfur atmosphere and grow selectively within the segregated sulfur-free time range becomes higher. In the case of 3% silicon-iron with manganese, much lower magnetic induction was obtained, although the weak final reduction of 30% is given to the alloy, comparative to the 40%. This is because MnS particles acted as an reducer in the primary grain size.

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