• Title/Summary/Keyword: 규사코팅

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Sorption of Arsenite Using Nanosized Mackinawite (FeS)-Coated Silica Sand (나노 크기 매킨나와이트로 코팅된 규사를 이용한 아비산염의 흡착)

  • Lee, Seungyeol;Kang, Jung Chun;Park, Minji;Yang, Kyounghee;Jeong, Hoon Young
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.185-195
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    • 2012
  • Due to the high reduction and sorption capacity as well as the large specific surface area, nanosized mackinawite (FeS) is useful in reductively transforming chlorinated organic pollutants and sequestering toxic metals and metalloids. Due to the dynamic nature in its colloid stability, however, nanosized FeS may be washed out with the groundwater flow or result in aquifer clogging via particle aggregation. Thus, these nanoparticles should be modified such as to be built into permeable reactive barriers. This study employed coating methods in efforts to facilitate the installation of permeable reactive barriers of nanosized mackinawite. In applying the methods, nanosized mackinawite was coated on non-treated silica sand (NTS) and chemically treated silica sand (CTS). For both silica sands, the maximum coating of mackinawite occurred around pH 5.4, the condition of which was governed by (1) the solubility of mackinawite and (2) the surface charge of both silica and mackinawite. Under this pH condition, the maximum coating by NTS and CTS were found to be 0.101 mmol FeS/g and 0.043 mmol FeS/g respectively, with such elevated coatings by NTS likely linked with impurities (e.g., iron oxides) on its surface. Arsenite sorption experiments were performed under anoxic conditions using uncoated silica sands and those coated with mackinawite at the optimal pH to compare their reactivity. At pH 7, the relative sorption efficiency between uncoated NTS and coated NTS changed with the initial concentration of arsenite. At the lower initial concentration, uncoated NTS showed the higher sorption efficiency, whereas at the higher concentration, coated NTS exhibited the higher sorption efficiency. This could be attributed to different sorption mechanisms as a function of arsenite concentration: the surface complexation of arsenite with the iron oxide impurity on silica sand at the low concentration and the precipitation as arsenic sulfides by reaction with mackinawite coating at the high concentration. Compared to coated NTS, coated CTS showed the lower arsenite removal at pH 7 due to its relatively lower mackinawite coating. Taken together, our results indicate that NTS is a more effective material than CTS for the coating of nanosized mackinawite.

A study on the optimum condition of FRP coarse-sand coating by using a new testing method for shear bearing capacity of FRP-concrete interface (새로운 FRP-콘크리트 전단부착성능 평가법을 활용한 최적 FRP 규사코팅 조건에 관한 연구)

  • Lee, Gyu-Phil;Shin, Hyu-Soung;Kim, Seung-Han
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.3
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    • pp.277-289
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    • 2011
  • This study proposes a new testing method for shear bearing capacity of FRP-concrete interface, which could well consider a loading condition corresponding to a tunnel lining undergoing axial compression and could be easily carried out with a simply specified specimen. A parametric study is carried out for capturing an optimized condition of coarse-sand coating of FRP, which governs shear bearing capacity of FRP-concrete interface, by using the proposed testing manner in this study. From the parametric study, it is shown that the proposed testing method is reasonably feasible in comparison with the existing testing methods. An optimum condition of coated sand size and sand density is given for the shearing capacity of FRP-concrete interface.

Behavior of FRP-Concrete Composite Decks with the Mechanical Connection (기계적 합성이 적용된 FRP-콘크리트 합성 바닥판의 거동 분석)

  • Kim, Sung-Tae;Park, Sung-Yong;Cho, Jeong-Rae;Kim, Byung-Suk;Cho, Keun-Hee
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.609-616
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    • 2010
  • FRP-concrete composite deck, an innovative system, is composed of concrete in the top and FRP panel in the bottom. Bottom FRP panel can reduce self weight and improve workability. This system requires strong connection between FRP and concrete. Therefore coarse sand coating was previously applied on FRP to improve the bonding. In this study, concrete wedge method is newly introduced to enhance both vertical bond and fatigue performance. Three FRP-concrete composite deck specimens with the concrete wedges were manufactured, and static and fatigue tests were carried out. The results showed that the new FRP-concrete composite deck satisfied deflection and crack width limits set by the design codes. And the fatigue test showed that the composite deck was capable of two million load cycles under 50% of its static strength. Based on the results, it can be concluded that that this new system has outstanding mechanical and durability performance, and therefore, satisfactorily be used in designing FRP-concrete composite deck.

Effect of Freezing and Thawing on Adhesion of Cement Concrete with Coarse-sand Coated FRP (규사코팅 FRP와 콘크리트 부착특성에 동결융해가 미치는 영향)

  • Lee, Gyu Phil;Park, Kwang Phil;Hwang, Jae Hong;Kim, Dong Gyou
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.2
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    • pp.117-123
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    • 2013
  • As fiber reinforced polymer (FRP) material is appled for a curved structure such as tunnel, FRP material must has a curved shape. Until now, the curved FRP material has been producted by hand-lay-up or filament winding work. It is impossible for mass production of the curved FRP material by these methods. Also, the quality of product by these methods is lower than that by pultrusion method. New pultrusion method and equipment had been developed for production of FRP material with steady curvature. The objective of this study is to evaluate the effect of freezing and thawing on adhesion of cement concrete with coarse-sand coated FRP in repair and reinforcement of cement-concrete structure using curved FRP material.

Post-Thermal Exposure Bond Strength Properties of CFRP and GFRP in Concrete (콘크리트 고온 가열 이후 CFRP와 GFRP의 부착강도 특성)

  • Kim, Ju-Sung;Jeong, Su-Mi;Kim, Young-Jin;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.5
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    • pp.509-517
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    • 2023
  • The surge in FRP(Fiber Reinforced Plastic) research signifies the industry's pursuit to counteract the longstanding issue of rebar corrosion. Notably, Carbon Fiber Reinforced Plastic(CFRP) emerges as a commendable alternative, given its superior resistance to both corrosion and chemical interactions, thus positing itself as a potential replacement for traditional steel rebars. However, the layered composition of fibers and resin in CFRP flags a notable susceptibility to elevated temperatures. Despite its promise, comprehensive studies elucidating the full spectrum of CFRP properties remain ongoing. In this investigative study, we meticulously assessed the bond strength of CFRP post-exposure to high thermal conditions. Our findings underscored a parity in bond strength amongst silica sand-coated CFRP, rib-type CFRP, and Glass Fiber Reinforced Plastic(GFRP).

Improvement of Low-quality Local Aggregates Using Coating Materials (코팅재료를 이용한 비쇄석골재의 성능향상)

  • Park Dae-Wook;Kim Min-Gu
    • International Journal of Highway Engineering
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    • v.8 no.3 s.29
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    • pp.39-48
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    • 2006
  • A laboratory investigation was conducted wherein smooth, rounded, siliceous river gravel aggregates were coated with fine-grained polyethylene, carpet co-product, or cement + styrene butadiene rubber latex and used to prepare hot mix asphalt concrete specimens. Only the coarse (+ No.4) aggregates were coated. The concept was that the coatings would enhance surface roughness of the aggregates and, thus, produce asphalt mixtures with superior engineering properties. Hot mix asphalt specimens were prepared and evaluated using several standard and non-standard test procedures. Based on experiences during the coating processes and analyses of these limited test results, the following was concluded: All three aggregate coating materials increased Hveem and Marshall stability, tensile strength, and resilient modulus(stiffness). These findings are indicative of improved resistance to rutting and cracking in hot mix asphalt pavements prepared using coated gravel aggregates in comparison to similar uncoated gravel aggregates.

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Resistance to Chloride Attack of FRP Hybrid Bar After Freezing and Thawing Action (동결융해 이후의 FRP Hybrid Bar의 부식 저항성)

  • Ryu, Hwa-Sung;Park, Ki-Tae;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.59-65
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    • 2018
  • RC(Reinforced Concrete) structures are exposed to various exterior conditions, and the performances of both chloride resistance and freezing/thawing action are evaluated for those exposed to corrosive environment-sea shore. Recently developed FRP Hybrid Bars which is coated with glass fiber and epoxy with core steel has an engineering advantage of higher Elasticity than FRP rod. In this work, corrosion resistance, weight loss, and bond strength are evaluated for the FRP Hybrid Bar tested through freezing/thawing action for 300cycles. The double coated FRP Hybrid Bar shows the least weight loss without defection due to freezing/thawing action. Bond strength in FRP Hybrid Bar increases to 120% of normal steel through torturity effect with Si-coating. Bond strength in normal steel shows 0.86~0.89times in 3-day corrosion acceleration and 0.35~0.38times in 5-day corrosion acceleration, however, that in FRP Hybrid Bar shows little changes in bond strength before and after freezing/thawing action.

Evaluation of Bond Strength in FRP Hybrid Bar Affected by Freezing/thawing Test and UV Rays (동결융해 및 UV 폭로시험을 거친 FRP Hybrid Bar의 인발거동특성 평가)

  • Park, Jae-Sung;Yoon, Yong-Sik;Park, Ki-Tae;Kwon, Sung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.53-58
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    • 2017
  • FRP Hybrid Bar, composed of an embedded steel and the coated composites with epoxy and glass fiber, is an effective construction material with tension-hardening performance and lightweight. The epoxy exposed to UV(Ultra Violet Rays) and FT(Freezing and Thawing) action easily shows a surface deterioration, which can cause degradation of bonding strength between inside-steel and outside-concrete. In the present work, surface inspection for 3 different samples of normal steel, FRP Hybrid Bar before UV, and FRP Hybrid Bar after UV test was performed, then concrete samples with 3 reinforcement types were prepared for accelerated FT test. Through visual inspection on 3 typed reinforcement, no significant deterioration like chalking was evaluated. The results from FT test to 120 and 180 cycles showed FRP Hybrid Bar exposed to UV test has higher bonding strength than normal steel by 106.3% due to enlarged bond area by silica coating. The 3 cases showed a similar bond strength tendency with increasing FT cycles, however a relatively big deviations of bond strength were evaluated in FRP Hybrid Bar after UV test due to loss of silica coating.

Study on mechanical behavioral characteristics of FRP-concrete composit member considering interface element between FRP and concrete (계면특성을 고려한 FRP와 콘크리트 복합부재의 역학적 거동특성 분석 연구)

  • Lee, Gyu-Phil;Park, Young-Taek;Hwang, Jae-Hong;Kim, Dong-Gyou
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.14 no.6
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    • pp.595-606
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    • 2012
  • Utilization of fiber reinforced polymer(FRP) material has been increased to solve construction material problems such as corrosion, etc. However, there are still many problems in using a linear-shaped FRP material for a tunnel structure with curved section. In this study, the loading tests were performed on the curved FRP-concrete composite material to evaluate its behavior as tunnel support. These tests were based on the result from preliminary numerical analysis on FRP-concrete composite material. Also, additional numerical analysis considering interface characteristics between FRP and cement-concrete was conducted to compare the result of loading test on FRP-concrete composite material. From the results of the loading test and numerical analysis, the analysis method suggested from this study is reasonable to evaluate the mechanical behavior of FRP-concrete composite material.

Study on mechanical behavioral characteristics of the curved FRP-concrete composite member for utilization as a tunnel lining structure (터널 라이닝 구조체로서 활용을 위한 곡면 FRP-콘크리트 복합부재의 역학적 거동특성 분석 연구)

  • Lee, Gyu-Phil;Shin, Hyu-Soung;Kim, Seung-Han
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.2
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    • pp.149-158
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    • 2011
  • Utilization of the fiber reinforced polymer (FRP) material has been increased as an alternative in a bid to supplement the problems with general construction materials such as long-term problems corrosion, etc. However, there are still many problems in using a linear-shaped FRP material for a tunnel lining structure which has arch-shape in general. In this study, the loading tests for the FRP-concrete composite member was carried out to evaluate their applicability as a tunnel reinforcement material, which are based on the results from preliminary numerical studies for identifying the behavioral characteristics of FRP-concrete composite member. Moreover, numerical analysis under the same condition as applied in the loading tests was again conducted for analysis of mechanical behavior of the composite member. As a result of the load test and numerical analysis, it appears that the FRP-concrete composite member is greatly subject to shear movement caused by bending tension acting on the interface between two constituent members.