• Title/Summary/Keyword: 구조적 안정도

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Improvement of Structure and Electrochemical Properties of LiNi0.5Mn1.5O4 for High Voltage Class Cathode Material by Cr Substitution (Cr 치환을 이용한 고전압용 양극 활물질 LiNi0.5Mn1.5O4의 구조와 전기화학적 성능의 개선)

  • Eom, Won-Sob;Kim, Yool-Koo;Cho, Won-Il;Jang, Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.82-87
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    • 2005
  • The cathode material, $LiNi_{0.5}Mn_{1.5}O_4$, for high voltage applications of Li-ion batteries exhibits impurity phases due to oxygen deficiency during the high temperature heat treatment. The impurity phase reduces the electrochemical properties of the electrode since the deficiency spinel structure disturbs the lithium ion intercalation and deintercalation. In this study, Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4(0{\leq}x{\leq}0.05)$ powders are synthesized by a sol-gel method in order to reduce the amount of the impurity phases in the $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4$. Thermal analysis of the cathode material shows that the $LiNi_{0.5}Mn_{1.5}O_4$ without Cr substitution looses $2\%$ of its weight due to oxygen deficiency but the amount of weight loss is diminished when Cr is substituted. XRD analysis also supports the reduction of the impurity phases in the cathode after chromium substitution, suggesting that the improvement of the electrochemical properties such as the capacity retention and electrochemical stability are attributed to the low content of impurity phases in the Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4.$

A Study On Structural Stability Of Blast Door by Blast Pressure (폭압에 의한 방폭문의 구조적 안정성에 대한 연구)

  • Kim, Nam Hyuk;Park, Kwan Jin;Lee, Keun-Oh
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.8-15
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    • 2016
  • The purpose of this study is to design a model with the structural stability so as not to lose the operational function due to structural plastic or fail of a sliding blast door by blast pressure to this aim, a numerical simulation was performed using full-size experiments and M&S (Modeling & Simulation) of the sliding blast door. The sliding blast door ($W3,000{\times}H2,500mm$) under the blast load is in the form of a sliding type 2-way metal grill, which was applied by a design blast pressure (reflected pressure $P_r$) of 17 bar. According to the experimental results of a real sliding blast door under blast load, the blast pressure reached the sliding blast door approximately 4.3 ms after the explosion and lasted about 4.0 ms thereafter. The maximum blast pressure($P_r$) was 347.7 psi (2,397.3 kPa), it is similar to the UFC 3-340-02 of Parameter(91 %). In addition, operation inspection that was conducted for the sliding blast door after real test showed a problem of losing the door opening function, which was because of the fail of the Reversal Bolt that was installed to prevent the shock due to rebound of the blast door from the blast pressure. According to the reproduction of the experiment through M&S by applying the blast pressure measurement value of the full-size experiments, the sliding blast door showed a similar result to the full-size experiment in that the reversal bolt part failed to lose the function. In addition, as the pressure is concentrated on the failed reversal bolt, the Principal Tensile Failure Stress was exceeded in only 1.25 ms after the explosion, and the reversal bolt completely failed after 5.4 ms. Based on the result of the failed reversal bolt through the full-size experiment and M&S, the shape and size of the bolts were changed to re-design the M&S and re-analyze the sliding blast door. According to the M&S re-analysis result when the reversal bolt was designed in a square of 25 mm ($625mm^2$), the maximum pressure that the reversal bolt receives showed 81% of the principal tensile failure stress of the material, in plastic stage before fail.

A Study on Viscous Damping System of a Ship with Anti-Rolling Pendulum (안티롤링 진자를 장치한 선박의 점성감쇠계 해석에 대한 연구)

  • Park, Sok-Chu;Jang, Kwang-Ho;Yi, Geum-Joo
    • Journal of Navigation and Port Research
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    • v.41 no.6
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    • pp.365-372
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    • 2017
  • The rolling motion of a floating body makes crews and passengers exhausted and/or applies forces to the structure to cause damage; it might even upset the body. Therefore, almost all ships are equipped with bilge keels for anti-rolling; in special cases, an anti-rolling tank(ART) or fin stabilizer or gyroscope could be installed. But an ART requires a large capacity to install it, and a fin stabilizer and gyroscope need great costs to install and also many expenses to operate. The authors suggest the use of an anti-rolling pendulum(ARP), and they showed that the ARP is effective to reduce rolling by experiments and via a Runge-Kutta analysis. This paper introduces the linearized 2 degrees of freedom with a viscous damping system for a ship equipped with ARP; it also shows the validation of the linearized analysis for the ship's roll motion. The paper proposes an optimum ARP on the basis of the justified model. The case of the 7.7kg model with ship 20g ARP of a mass ratio of 0.26%, is the most effective for reducing roll motion. The paper shows the ARPs with various mass ratios are effective for reducing the roll motion of a ship by free decaying roll experiments.

Characteristics of Large-Scale Fault Zone and Quaternary Fault Movement in Maegok-dong, Ulsan (울산 매곡동 일대의 대규모 단층대 특성과 제4기 단층운동)

  • Cho, Jin-Hyuck;Kim, Young-Seog;Gwon, Sehyeon;Edwards, Paul;Rezaei, Sowreh;Kim, Taehyung;Lim, Soon-Bok
    • The Journal of Engineering Geology
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    • v.25 no.4
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    • pp.485-498
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    • 2015
  • Structural analysis for a large-scale fault in Maegok-dong, Ulsan, was carried out based on filed-works to investigate the geometric and kinematic characteristics of the fault as well as its Quaternary slip. As results, a series of repeated stratigraphy, minor faults, fracture zones, and deformation band clusters are observed over a distance of about 100 m in the first studied site consisting of sedimentary rocks, which may indicate the damage zone of a large-scale fault in this site. In the second site, mainly composed of granitic clastic rocks, a large-scale thrust fault is expected based on low-angle dipping faults showing branched and/or merged patterns. Age of the last slip on this fault was restrained as after 33,275 ± 355 yr BP based on radiocarbon dating for organic material included in the gouge zone. Dimension of fault damage zone, dominant sense of slip, and age of the slip event associated with the fault suggest that these structures have a close relationship with the Ulsan Fault and/or Yeonil Tectonic Line, which are well-known large-scale neotectonic structural features around the study area. Therefore, it is necessary to study the characteristics of the faults in detail based on structural geology and paleoseismology in order to ensure seismic and geologic stability of the buildings under construction, and to prevent geologic hazards in this area.

Magnetoresistance Properties of Spin Valves Using MoN Underlayer (MoN 하지층을 이용한 스핀밸브의 자기저항 특성)

  • Kim, Ji-Won;Jo, Soon-Chul;Kim, Sang-Yoon;Ko, Hoon;Lee, Chang-Woo
    • Journal of the Korean Magnetics Society
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    • v.16 no.5
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    • pp.240-244
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    • 2006
  • In this paper, magnetic properties and annealing behavior of spin valve structures using Mo(MoN) layers as underlayers were studied varying the thickness of the underlayers. The spin valve structure was consisted of Si substrate/$SiO_2(2,000{\AA})/Mo(MoN)(t{\AA})/NiFe(21\;{\AA})/CoFe(28\;{\AA})/Cu(22\;{\AA})/CoFe(18\;{\AA})/IrMn(65\;{\AA})/Ta(25\;{\AA})$. Also, MoN films were deposited on Si substrates and their thermal annealing behavior was analyzed. The resistivity of the MoN film increased as the $N_2$ gas flow rate was increased. After annealing at $600^{\circ}C$, XRD results did not show peaks of silicides. XPS results indicated MoN film deposited with 5 sccm of $N_2$ gas flow rate was more stable than the film deposited with 1 sccm of $N_2$ gas flow rate. The variations of MR ratio and magnetic exchange coupling fold were small for the spin valve structures using Mo(MoN) underlayers up to thickness of45 ${\AA}$. MR ratio of spin valves using MoN underlayers deposited with various $N_2$ gas flow rate was about 7.0% at RT and increased to about 7.5% after annealing at $220^{\circ}C$. Upon annealing at $300^{\circ}C$, the MR ratio decreased to about 3.5%. Variation of $N_2$ gas flow rate up to 5 sccm did not change the MR ratio and $H_{ex}$ appreciably.

Thermal and Optical Properties of Poly{1-(Cholesteryloxycarbonylalkanoyloxy)ethylene}s (폴리{1-(콜레스테릴옥시카보닐알카노일옥시)에틸렌}들의 열 및 광학 특성)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.144-152
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    • 2009
  • The thermal and optical properties of poly {1-(cholesteryloxycarbonylalkanoyloxy) ethylene}s (PCALEn, n=2$\sim$8,10, the number of methylene units in the spacer) were investigated. All of the homologues formed monotropic cholesteric phases with left-handed helical structures. PCALEn with n=2 or 10, in constrast with PCALEn with $3{\leq}n{\leq}8$, did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cholesteryl group highly depends on the length of the spacer connecting the cholesteryl group to the polyethylene chain. The glass transition temperatures decreased with increasing n. The isotropic-cholesteric phase transition temperatures decreased with increasing n up to 7 and showed an odd-even effect. However it became almost constant when n is more than 7. This behavior is rationalized in terms of the change in the average shape of the side chain on varing the parity of the spacer. This rationalization also accounts for the observed variation of the entropy gain for the clearing transition. The thermal stability and degree of order in the mesophase and the temperature dependence of the optical pitch observed for PCALEn were significantly different from those reported for cellulose tri(cholesteryloxycarbonyl)alkanoates. The results were discussed in terms of the differences in the chemical structure and flexibility of main chain and the number of the mesogenic units per repeating unit.

The Effects of Bail-in System on SME's Loans (채권자 손실분담제도(Bail-in 제도)가 중소기업대출에 미치는 영향)

  • Kim, Sung Woo;Lee, Ki Hwan
    • International Area Studies Review
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    • v.22 no.2
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    • pp.41-59
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    • 2018
  • After global financial crisis, policy makers in major countries tried to find a new bank recovery and resolution policy. The new policy intends to normalize the market not by bail-out approach in which public funds should be provided bankrupt banks, but by market discipline approach in which unsecured creditors take part in liquidation process. Bail-in system is a new and dominant financial policy after crisis period in resolution regimes led by the government administration. This study tries to analyze the relationship between bail-in system and pro-cyclicality. Empirical analysis has been done by taking the basis of the 8 year data from 2008 to 2015, which is selected from financial statistics information system of Korea Financial Supervisory Service. Accounting and financial data are collected from the dataguide 5.0 between 2008 and 2015. Through the analysis, the effect of bail-out system and bail-in system on pro-cyclicality of total loans did not show the statistically significant relationship. However the effect of bail-out system on pro-cyclicality of SME loans showed the statistically significant relationship, meanwhile the effect of bail-in system on pro-cyclicality of SME loans did not show the statistically significant relationship. In conclusion, bail-in system can be useful policy which improves the support and promotion of SMEs.

Determination of Volume Porosity and Permeability of Drainage Layer in Rainwater Drainage System Using 3-D Numerical Method (3차원 수치해석기법을 이용한 우수배수시스템 배수층의 체적공극과 투수도 결정)

  • Yeom, Seong Il;Park, Sung Won;Ahn, Jungkyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.8
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    • pp.449-455
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    • 2019
  • The increase in impermeable pavement from recent urbanization has resulted in an increase in surface runoff. The surface runoff has also increased the burden of the existing drainage system. This drainage system has structural limitations in that the catchment area is reduced by the waste particles transported with the surface runoff. In addition, the efficiency of the drainage system is decreased. To overcome these limitations, a new type of drainage system with a drainage layer was developed and applied. In this study, various volume porosity and permeability of the lower drainage layer were simulated using ANSYS CFX, which is a three dimensional computational fluid dynamics program. The results showed that the outlet velocity of the 35% volume porosity was faster than that of the 20% and 50% cases, and there was no relationship between the volume porosity and drainage performance. The permeability of the drainage layer can be determined from the particle size of the material, and a simulation of five conditions showed that 2 mm sand grains are most suitable for workability and usability. This study suggests appropriate values of the volume porosity and particle size of the drainage layer. This consideration can be advantageous for reducing and preventing flood damage.

Dispersion Effects of Wave Force on Interlocking Caisson Breakwater with Shear-Key (전단키형 인터로킹 케이슨 방파제의 파력분산효과)

  • Song, Sung Hoon;Park, Min Su;Jeong, Youn Ju;Hwang, Yoon Koog
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.39 no.1
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    • pp.195-201
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    • 2019
  • Long caisson breakwaters can improve the structural safety of a caisson due to the wave dispersion effect which reduces the average wave force acting on one caisson. However, in order to make long caissons, there are many manufacturing and construction limitations. Recently, interlocking caisson systems, which are to form a long caisson by interlocking individual caissons with adjacent caissons, have been much attention. In the present study, a interlocking caisson system with shear-keys was proposed and the wave dispersion effect according to the shear-key was evaluated analytically. As a result, (1) Because of the asymmetric shape of the interlocking caisson, the structure behavior and the wave dispersion effect of one are also asymmetric. (2) The wave dispersion effect is more influenced by the distribution and characteristics of wave acting on each caisson rather than the shape of the shear-key such as shear angle, height, shear length ratio. (3) The interlocking caisson breakwater is almost the same behavior and wave dispersion effect as a fully integrated breakwater.

Community Structure of Fish and Distribution Characteristics of Phoxinus phoxinus and Rhynchocypris kumgangensis in the Gihwacheon Stream of Namhangang River, Korea (남한강 지류 기화천의 어류 군집 구조 및 연준모치와 금강모치의 분포 특성)

  • Jeon, Hyoung-Joo;Baek, Jeong-Ik;Kim, Kyung-Hwan;Kim, Seung-Yong;Lee, Wan-Ok;Kwak, Ihn-Sil;Song, Mi-Young
    • Korean Journal of Ichthyology
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    • v.31 no.2
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    • pp.90-100
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    • 2019
  • This study was carried out from March to November, 2013 to investigate the fish community structure and distribution characteristics of Phoxinus phoxinus and Rhynchocypris kumgangensis appearing in Gihwacheon Stream, Pyeongchang. A total of 6 families and 19 species of fish emerged during the survey period. The dominant species were R. kumgangensis (Individuals 44.7%, Biomass 30.2%) and P. phoxinus (Individuals 27.7%, Biomass 15.9%). Endemic species were 10 species including Pseudopungtungia tenuicorpus, Coreoleuciscus splendidus, Hemibarbus mylodon, Gobiobotia brevibarba, Microphysogobio longidorsalis, R. kumgangensis, Zacco koreanus, Korecobitis rotundicaudata, Iksookimis koreensis and Coreoperca herzi. Endogenous species were P. tenuicorpus, G. brevibarba and P. phoxinus. Hemibarbus mylodon was a natural monument. Oncherhynchus mykiss was exotic species and translocated species was Oncorhynchus masou masou. The dominant species, R. kumgangensis, appeared at all survey sites. Except for St.6, the b value was more than 3.0 and the slope of K value showed positive correlation. P. phoxinus appeared in St. 3~St. 6 and St. 3 and St. 4 only showed stable populations.