• Title/Summary/Keyword: 구조광

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Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields (축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략)

  • Sangyeop Chae;Kwangmin Ryu;Sang-hun Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.45-53
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    • 2023
  • This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites. Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

Development of Functional Halogenated Phenylpyrrole Derivatives (기능성 할로겐화 페닐피롤 )

  • Min-Hee Jung;Hee Jeong Kong;Young-Ok Kim;Jin-Ho Lee
    • Journal of Life Science
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    • v.33 no.10
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    • pp.842-850
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    • 2023
  • Pyrrolnitrin, pyrrolomycin, and pyoluteorin are functional halogenated phenylpyrrole derivatives (HPDs) derived from microorganisms with diverse antimicrobial activities. Pyrrolnitrin is a secondary metabolite produced from L-tryptophan through four-step reactions in Pseudomonas fluorescens, Burkholderia cepacia, Serratia plymuthica, etc. It is currently used for the treatment of superficial dermatophytic fungal infections, has high antagonistic activities against soil-borne and foliar fungal infections, and has many industrial applications. Since pyrrolnitrin is easily decomposed by light, it is difficult to widely use it outdoors. As an alternative, fludioxonil, a synthetically produced non-systemic surface fungicide that is structurally similar and has excellent light stability, has been commercialized for seed and foliar treatment of plants. However, due to its high toxicity to aquatic organisms and adverse effects in human cell lines, many countries have established maximum residue levels and strictly control its levels. Pyrrolomycin and pyoluteorin, which have antibiotic/antibiofilm activity against Gram-positive bacteria and high anti-oomycete activity against the plant pathogen Pythium ultimum, respectively, were isolated and identified from microorganisms. This review summarizes the biosynthesis and production of natural pyrrolnitrin derived from bacteria and the characteristics of synthetic fludioxonil and other natural phenylpyrrole derivatives among the HPDs. We expect that a plethora of highly effective, novel HPDs that are safe for humans and environments will be developed through the generation of an HPD library by microbial biosynthesis and chemical synthesis.

Design a Four Layer Depth-Encoding Detector Using Quasi-Block Scintillator for High Resolution and Sensitivity (고분해능 및 고민감도를 위한 준 블록 섬광체를 사용한 네 층의 반응 깊이 측정 검출기 설계)

  • Seung-Jae Lee;Byungdu Jo
    • Journal of the Korean Society of Radiology
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    • v.18 no.2
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    • pp.65-71
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    • 2024
  • To achieve high resolution and sensitivity of positron emission tomography (PET) for small animals, the detector is constructed using very thin and long scintillation pixels. Due to the structure of these scintillation pixels, spatial resolution deterioration occurs outside the system's field of view. To solve this problem, we designed a detector that could improve spatial resolution by measuring the interaction depth and improve sensitivity by using a quasi-block scintillator. A quasi-block scintillator size of 12.6 mm x 12.6 mm x 3 mm was arranged in four layers, and optical sensors were placed on all sides to collect light generated by the interaction between gamma rays and the scintillator. DETECT2000 simulation was performed to evaluate the performance of the designed detector. Flood images were acquired by generating gamma-ray events at 1 mm intervals from 1.3 mm to 11.3 mm within the scintillator of each layer. The spatial resolution and peak-to-peak distance for each location were measured in an 11 x 11 array of flood images. The average measured spatial resolution was 0.25 mm, and the average distance between peaks was 1.0 mm. Through this, it was confirmed that all locations were separated from each other. In addition, because the light signals of all layers were measured separately from each other, the layer of the scintillator that interacted with the gamma rays could be completely separated. When the designed detector is used as a detector in a PET system for small animals, it is considered that excellent spatial resolution and sensitivity can be achieved and image quality can be improved.

Analysis of Plants Social Network on Island Area in the Korean Peninsula (한반도 도서지역의 식물사회네트워크 분석)

  • Sang-Cheol Lee;Hyun-Mi Kang;Seok-Gon Park
    • Korean Journal of Environment and Ecology
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    • v.38 no.2
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    • pp.127-142
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    • 2024
  • This study aimed to understand the interrelationships between tree species in plant communities through Plant Social Network (PSN) analysis using a large amount of vegetation data surveyed in an island area belonging to a warm-temperate boreal forest. The Machilus thunbergii, Castanopsis sieboldii, and Ligustrum japonicum, which belong to the canopy layer, Pittosporum tobira and Ardisia japonica, which belong to the shrub layer and Trachelospermum asiaticum and Stauntonia hexaphylla, which belong to the vines, appearing in evergreen broad-leaved climax forest community, showed strong positive association(+) with each other. These tree species had a negative association or no friendly relationship with deciduous broad-leaved species due to the large difference in location environments. Divided into 4 group modularizations in the PSN sociogram, evergreen broad-leaved tree species in Group I and deciduous broad-leaved tree species in Group II showed high centrality and connectivity. It was analyzed that the arrangement of tree species (nodes) and the degree of connection (grouping) of the sociogram can indirectly estimate environmental factors and characteristics of plant communities like DCA. Tree species with high centrality and influence in the PSN included T. asiaticum, Eurya japonica, Lindera obtusiloba, and Styrax japonicus. These tree species are common with a wide range of ecological niches and appear to have the characteristics and survival strategies of opportunistic species that commonly appear in forest gaps and damaged areas. They will play a major role in inter-species interactions and structural and functional changes in plant communities. In the future, long-term research and in-depth discussions are needed to determine how these species actually influence plant community changes through interactions

Modeling Study on The Structure of Entrepreneurship and Entrepreneurial Intention (기업가정신과 창업의지의 구조에 관한 모델링 연구)

  • Jae-hun Jang;Miri Choi;Sung-gwang Jung
    • Journal of Platform Technology
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    • v.12 no.3
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    • pp.41-54
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    • 2024
  • Recently, support for various types of entrepreneurship has been increasing. At the same time, interest in entrepreneurship education is increasing to expand support for entrepreneurship and improve entrepreneurship performance. Therefore, the scope and interest of entrepreneurship education and support is expanding beyond college students and the general public to include high school students. Accordingly, this study seeks to investigate in more depth the relationship between entrepreneurship competency, entrepreneurship attitude, and intention to start a business in order to increase the intention to start a business. As a result of the analysis, entrepreneurship capabilities (creativity, risk-taking, and innovation) had a positive effect on attitude toward entrepreneurship, and attitude toward entrepreneurship had a positive effect on the will to start a business. In addition, the results of the analysis of the mediating effect of entrepreneurship attitude in the relationship between entrepreneurship capabilities (creativity, risk-taking, and innovation) and entrepreneurship will are as follows. First, in the relationship between creativity and entrepreneurial will, entrepreneurial attitude played a partial mediating role. Additionally, in the relationship between risk tolerance and entrepreneurial intention, entrepreneurial attitude played a partial mediating role. Lastly, in the relationship between innovation and entrepreneurial will, entrepreneurial attitude played a complete mediating role. The research conclusion summarizes the results of this study, suggests implications for entrepreneurs and start-ups, as well as limitations of this study and directions for future research..

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Seismic wave propagation through surface basalts - implications for coal seismic surveys (지표 현무암을 통해 전파하는 탄성파의 거동 - 석탄 탄성파탐사에 적용)

  • Sun, Weijia;Zhou, Binzhong;Hatherly, Peter;Fu, Li-Yun
    • Geophysics and Geophysical Exploration
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    • v.13 no.1
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    • pp.1-8
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    • 2010
  • Seismic reflection surveying is one of the most widely used and effective techniques for coal seam structure delineation and risk mitigation for underground longwall mining. However, the ability of the method can be compromised by the presence of volcanic cover. This problem arises within parts of the Bowen and Sydney Basins of Australia and seismic surveying can be unsuccessful. As a consequence, such areas are less attractive for coal mining. Techniques to improve the success of seismic surveying over basalt flows are needed. In this paper, we use elastic wave-equation-based forward modelling techniques to investigate the effects and characteristics of seismic wave propagation under different settings involving changes in basalt properties, its thickness, lateral extent, relative position to the shot position and various forms of inhomogeneity. The modelling results suggests that: 1) basalts with high impedance contrasts and multiple flows generate strong multiples and weak reflectors; 2) thin basalts have less effect than thick basalts; 3) partial basalt cover has less effect than full basalt cover; 4) low frequency seismic waves (especially at large offsets) have better penetration through the basalt than high frequency waves; and 5) the deeper the coal seams are below basalts of limited extent, the less influence the basalts will have on the wave propagation. In addition to providing insights into the issues that arise when seismic surveying under basalts, these observations suggest that careful management of seismic noise and the acquisition of long-offset seismic data with low-frequency geophones have the potential to improve the seismic results.

Vegetation Structure of Hongdo Island (홍도의 식생구조)

  • Lee, Ji-Hye;Do, Mi-Sol;Song, Ho-Kyung
    • Korean Journal of Environment and Ecology
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    • v.27 no.5
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    • pp.592-613
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    • 2013
  • This study was carried out to analyze the vegetation properties, soil characteristic, and ordination of forest in Hongdo island and the results are as follows: Castanopsis cuspidata var. sieboldii community, Quercus acuta community, Machilus thunbergii community, Pinus densiflora community and Carpinus coreana community. The results of importance value on the vegetation of Hongdo island consisted of the following in order: 75.56% of Castanopsis cuspidata var. sieboldii, the highest, 34.84% of Pinus densiflora, 29.11% of Machilus thunbergii, 26.88% of Camellia japonica, 17.79% of Quercus acuta, 15.23% of Dendropanax morbifera, 13.41% of Ligustrum japonicum, 12.67% of Carpinus coreana. Due to the high organic matter, total nitrogen and low pH, the soil properties of Hongdo island are different from those of other forest in Korea. The composition of soil properties in the same areas are as follows: organic matter, total nitrogen, available phosphorous, exchangeable $K^+$, exchangeable $Ca^{2+}$, exchangeable $Mg^{2+}$ contained, and soil pH. The capacities of these chemical properties of the soil ranged from 14.48~25.45%, 0.49~0.90%, 26.00~58.68 mg/kg, $0.64{\sim}1.64cmol^+/kg$, $6.22{\sim}21.5cmol^+/kg$, $2.92{\sim}6.95cmol^+/kg$, and 4.42~5.44 respectively. The results of the correlation between communities and soil conditions of vegetation of Hongdo island by DCCA ordination method are as follows: Castanopsis cuspidata var. sieboldii community was found in the highest soil moisture and followed in order Machilus thunbergii community, Quercus acuta community. The Machilus thunbergii community was found in the highest pH, exchangeable $Ca^{2+}$, exchangeable $Mg^{2+}$, exchangeable $K^+$ and cation exchange capacity. The Carpinus coreana community was found in the highest elevation, total nitrogen, cation exchange capacity, exchangeable $Mg^{2+}$ and followed in order Pinus densiflora community.

Forest Structure in Relation to Altitude and Part of Slope in the Mansugol Valley at Woraksan National Park (월악산국립공원 만수골 계곡부의 해발고와 사면부위에 따른 산림구조)

  • Park In-Hyeop;Jang Jeong-Jae;Kim Kye-Seon
    • Korean Journal of Environment and Ecology
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    • v.19 no.2
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    • pp.99-105
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    • 2005
  • The Mansugol valley forest in Woraksan National Park was studied to investigate forest structure in relation to altitude and part of the slope. Forty eight quadrats were set up in the valley forest along altitude of 380m to 915m and part of the slope, and vegetation analysis for the woody species in the tree and subtree layers were carried out. With increasing elevation belt, tree density and basal area of the tree layer decreased while basal area of the subtree layer increased. As elevation increased, the importance percentages of Quercus mongolica, Fraxinus rhynchophylla, Lindera obtusiloba and Acer mono increased while those of Pinus densiflora, Quercus variablias Quercus serrata and Styrax obassia decreased. Species diversities of the elevation belts including the top of the valley ranged from 0.351 to 0.903, and those of the parts of the slope ranged from 0.780 to 1.064. The range of similarity indices between elevation belts were $36.0\~67.3\%$, and the range of similarity indices between parts of the slope were $66.8\~75.1\%$. According to importance percentage and cluster analysis, the studied valley forest was classified into three forest communities of Pinus densiflora-Quecus species community in the low elevation belt and the middle part of the slope at the middle elevation belt, Quercus mongolica-broad-leaved tree species community in the high elevation belt and the lower and upper parts at the middle elevation belt, and Quercus mongolica community in the top area of the valley. The importace percentage of Quercus mongolica was significantly and negatively correlated with those of Pinus desiflora and Quercus serrata. There were significantly positive correlation among Pinus densiflora, Quercuss serata and Rhus trichocarpa.

Beneficial Effect of an Agar Mask against Skin Damage Induced by UV Exposure in SKH-1 Hairless Mice (UV조사에 의해 유발된 SKH-1 hairless 마우스의 피부노화에 미치는 한천마스크의 개선효과)

  • Song, Bo Ram;Kim, Ji Eun;Yun, Woo Bin;Lee, Mi Rim;Choi, Jun Young;Park, Jin Ju;Kim, Dong Seob;Lee, Chung Yeoul;Lee, Hee Seob;Lim, Yong;Jung, Min Wook;Kim, Bae Hwan;Hwang, Dae Youn
    • Journal of Life Science
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    • v.27 no.9
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    • pp.975-985
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    • 2017
  • To investigate the beneficial effects of an agar gel mask (AGM) on UV-induced photoaging, SKH-1 hairless mice were treated with a topical application of AGM and an AGM dipped in essence (AGMdE). The mice were divided into an no radiation group, UV + AGM, UV + AGMdE, and UV + vehicle (PBS) treatment groups. Alterations in skin wrinkles, skin phenotype, histological structures, oxidative status, and toxicity were then evaluated during 4 weeks of exposure. The topical application of AGM and AGMdE inhibited wrinkle formation, suppressed the erythema index, prevented transepidermal water loss, and enhanced skin hydration. In addition, epidermal thickness recovered to a similar level as that in the no irradiation group in the UV + AGM and UV + AGMdE treatment groups compared with the UV + vehicle (distilled water) group. Furthermore, the expression levels of matrix metalloproteinase-1 (MMP-1) and tyrosinase were reduced in the UV + AGM and UV + AGMdE treatment groups, although the highest level varied. Moreover, superoxide dismutase (SOD) activity was significantly lower in the UV + AGM and UV + AGMdE treatment groups as compared with the UV + vehicle group. No significant alterations induced by most toxic compounds were measured in serum biochemical markers and liver and kidney histological features of the UV + AGM and UV + AGMdE treatment groups. These results suggest that AGM may protect against skin aging by regulating skin morphology, histopathological structures, and oxidative conditions.

Comparative Compressional Behavior of Zeolite-W in Different Pressure-transmitting Media (제올라이트-W의 압력전달매개체에 따른 체적탄성률 비교 연구)

  • Seoung, Donghoon;Kim, Hyeonsu;Kim, Pyosang;Lee, Yongmoon
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.3
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    • pp.169-176
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    • 2021
  • This study aimed to fundamentally understand structural changes of zeolite under pressure and in the presence of different pressure-transmitting media (PTM) for application studies such as immobilization of heavy metal cation or CO2 storage using pressure. High-pressure X-ray powder diffraction study was conducted on the zeolite-W (K6.4Al6.5Si25.8O64× 15.3H2O, K-MER) to understand linear compressibility and the bulk moduli in different PTM conditions. Zeolite-w is a synthetic material having the same framework as natural zeolite merlinoite ((K, Ca0.5, Ba0.5, Na)10 Al10Si22O64× 22H2O). The space group of the sample was identified as I4/mmm belonging to the tetragonal crystal system. Water, carbon dioxide, and silicone-oil were used as pressure-transmitting media. The mixture of sample and each PTM was mounted in a diamond anvil cell (DAC) and then pressurized up to 3 GPa with an increment of ca. 0.5 GPa. Pressure-induced changes of powder diffraction patterns were measured using a synchrotron X-ray light source. Lattice constants, and bulk moduli were calculated using the Le-Bail method and the Birch-Murnaghan equation. In all PTM conditions, linear compressibility of c-axis (𝛽c) was 0.006(1) GPa-1 or 0.007(1) GPa-1. On the other hand, the linear compressibility of a(b)-axis (𝛽a) was 0.013(1) GPa-1 in silicone-oil run, which is twice more compressible than the a(b)-axis in water and carbon dioxide runs, 𝛽a = 0.006(1) GPa-1. The bulk moduli were measured as 50(3) GPa, 52(3) GPa, and 29(2) GPa in water, carbon dioxide, and silicone-oil run, respectively. The orthorhombicities of ac-plane in the water, and carbon dioxide runs were comparatively constant, near 0.350~0.353, whereas the value decreased abruptly in the silicone-oil run following formula, y = -0.005(1)x + 0.351(1) by non-penetrating pressure fluid condition.