• Title/Summary/Keyword: 구조격자계

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유리반도체

  • 박창엽
    • 전기의세계
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    • v.24 no.4
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    • pp.6-10
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    • 1975
  • 반도체와 그의 응용소자는 지난 20여년간 눈부식 발전을 이룩하였다. 이는 주로 단결정의 제작기술 진보에 의한 것으로 본다. 그러나 최근 단결정과는 전연 다른 유리질반도체가 국제회의에서도 그 우수성을 의논하기에 이르렀다. 유리질 반도체가 주목을 끌게 된겻은 1968년 Ovshinsky가 "무질서 구조에 있어서 가역적 스위칭현상"이라는 논문이 발표되고 유리질 반도체를 사용한 Ovonic 스위칭 소자의 출현에 기인된다. 유리질 반도체가 전기스위칭 작용, 기억작용을 나타낸다고 하는 Ovshinsky의 발표는 전자제치로서의 응용에 대해 찬반되는 의견이 있었지만 물성적 연구의 교량적인 역할을했다고 할 수 있다. 이런 반도체에 속하는 재료는 호칭도 여러가지로 유리질반도체, 비정질반도체 무정형반도체등으로 불리어진다. 단결정체가 각 격자간에 장거리질서를 갖는 반면 유리질 반도체는 무질서한 구조로 각 격자간에 단거리 질서를 갖는 것이 단결정과는 본질적으로 다른 점이라 본다. 유리 반도체의 종류는 첫째, 원소성 유리반도체로서 Ge, Si, Se, Te 들과 같이 단일원소로 된 겻과, 둘째 IV, V, VI족 원소로 된 공유결합 합금인 As$_{2}$Se$_{3}$-As$_{2}$Te$_{3}$ 계 Ge Si As Te계등의 칼코게나이드 유리등으로 금지대는 어느 것이나 2eV이하이다. 셋째 이론결합인 SiO $Al_{2}$O$_{3}$ Ta$_{2}$O$_{3}$Si$_{3}$N$_{4}$등의 산화물 및 질화물로 대표되는 분자성 비정질 물질로서 금지대는 2eV보다 큰 세종류로 크게 분류할 수 있다. 분류할 수 있다. 한다. 단 개개의 문제에 관한 구체적인 해석 또는 검토에 관하여는 다음 기회에 미루기로하고, 우선 여기서는 당면문제로서 대처하지 않으면 안될 자동주파수제어문제및 계통의 경제운용문제만에 한정하여, 이것을 우리나라의 현상과 관련시켜 개설하고, 이들의 자동화에 관한 기본적인 문제를 간단히 적어 보겠다. 가능하다. 제작완료된 ASIC은 기능시험을 완료했으며 실제 line-of-sight(LOS) 시스템 구현에 적용중이다. 시대를 살아 갈 회원들이다. '컨텐츠의 시대'가 개막되는 것이며, 신세기통신과 SK텔레콤은 선의의 경쟁 과 협력을 통해 이동인터넷 서비스의 컨텐츠를 개발해 나가게 될 것이다. 3배가 높았다. 효소 활성에 필수적인 물의 양에 따른 DIAION WA30의 라세미화 효율에 관하여 실험한 결과, 물의 양이 증가할수록 그 효율은 감소하였다. DIAION WA30을 라세미화 촉매로 사용하여 아이소옥탄 내에서 라세믹 나프록센 2,2,2-트리플로로에틸 씨오에스터의 효소적 DKR 반응을 수행해 보았다. 그 결과 DIAION WA30을 사용하지 않은 경우에 비해 반응 전환율과 생성물의 광학 순도는 급격히 향상되었다. 전통적 광학분할 반응의 최대 50%라는 전환율의 제한이 본 연구에서 찾은 DIAION WA30을 첨가함으로써 성공적으로 극복되었다. 또한 고체 염기촉매인 DIAION WA30의 사용은 라세미화 촉매의 회수 및 재사용이 가능하게 해준다.해준다.다. TN5 세포주를 0.2 L 규모 (1 L spinner flask)oJl에서 세포간의 응집현상 없이 부유배양에 적응,배양시킨 후 세포성장 시기에 따른 발현을 조사한 결과 1 MOI의 감염조건 하에서는 $0.6\times10^6$cell/mL의 early exponential시기의 세포밀도에서 72시간 배양하였을 대 최대 발현양을

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Analysis of Electromagnetic Scattering by a Perfectly Conducting Strip Grating on Dielectric Multilayers (다층 유전체 위의 조기적인 도체 스트립 구조에 의한 전자파산란 해석)

  • 윤의중;양승인
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.8 no.2
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    • pp.161-172
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    • 1997
  • In this paper, electromagnetic scattering by a perfectly conducting strip grating on dielectric multilayers is analyzed for the normalized reflected and transmitted power by applying the Fourier-Galeakin moment method. The induced current density is expanded in a series of multiplication of chebyshev polynomials of the first kind and functions with appropriate edge boundary condition, the continuous condition of electromagnetic field is applied in the boundary planes. The confirm the validity of the proposed method, the nor- malized reflected and transmitted power obtained by varying the relative permittivity and thickness of each dielectric layers are evaluated and compared with those of the existing numerical method and a paper, and then the numerical results in this paper are in good agreement with those of the existing numerical method and the paper. The sharp variation position in the geometrically normalized reflected and transmitted power can be moved by the incident angle, grating period, and the relative permittivity and thickness of the dielectric multilayers, these sharp variation points which are called the Wood's anomaly of the Geome- trically normalized reflected power are observed as a main factor when the reflected powers of the higher order mode are transitted between propagating and evanescent modes, and the local minimum positions are slightly moved to the left hand direction in which grating period is getting small according to the increase of the relative permittivity of dielectric layers.

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Synthesis and Defect-Structure Analysis of $ThO_2-Tm_2O_3$ Solid Solutions ($ThO_2-Tm_2O_3$ 고용체의 합성 및 결함구조해석)

  • Don Kim;Chang Kwon Kang;Keu Hong Kim;Jae Shi Choi
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.491-497
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    • 1987
  • $ThO_2-Tm_2O_3$ (TDT) solid solutions containing 1,3,5,8,10, and 15 mol% $Tm_2O_3$ were synthesized from spectroscopically pure $ThO_2$ and $Tm_2O_3$ polycrystalline powders. The TDT solid solutions were indentified to the fluorite structure by the X-ray powder technique. The values of the lattice parameter were decreased with increasing amount of $Tm_2O_3$ incorporated. But, there was no linearity for the samples containing 8, 10, and 15 mol% $Tm_2O_3$. It was concluded that these samples became incomplete solid solutions. From the intensity analyses of X-ray diffraction patterns, the residual factor was found below 0.13 even for the 15 mol% TDT system. lt was confirmed from the DTA and TGA analyses that any phase transitions did not occur under the experimental condition executed. Comparing the pycnometric density with the lattice parameter obtained from XRD, it was suggested that the predominant defect model be an oxygen vacancy.

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Scheduling and Load Balancing Methods of Multithread Parallel Linear Solver of Finite Element Structural Analysis (유한요소 구조해석 다중쓰레드 병렬 선형해법의 스케쥴링 및 부하 조절 기법 연구)

  • Kim, Min Ki;Kim, Seung Jo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.5
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    • pp.361-367
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    • 2014
  • In this paper, task scheduling and load balancing methods of multifrontal solution methods of finite element structural analysis in a modern multicore machine are introduced. Many structural analysis problems have generally irregular grid and many kinds of properties and materials. These irregularities and heterogeneities lead to bottleneck of parallelization and cause idle time to analysis. Therefore, task scheduling and load balancing are desired to reduce inefficiency. Several kinds of multithreaded parallelization methods are presented and comparison between static and dynamic task scheduling are shown. To reduce the idle time caused by irregular partitioned subdomains, computational load balancing methods, Balancing all tasks and minmax task pairing balancing, are invented. Theoretical and actual elapsed time are shown and the reason of their performance gap are discussed.

The Limit of the Continuum Assumption Based on Compressible Flow Structures in an Axisymmetric Micro-Thruster Used for a Satellite (인공위성용 축대칭 소형 추력기의 압축성 유동 구조 계산에 의한 연속체 가정의 적용 한계)

  • Kwon, Soon-Duk;Kim, Sung-Cho;Kim, Jeong-Soo;Choi, Jong-Wook;Lee, Kee-Man
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.281-285
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    • 2007
  • The flow characteristics in the thruster should be analyzed considering its geometry and the pressure ratio to estimate its performance and etc. This paper suggests the computational result of an axisymmetric real nozzle for the altitude control of a satellite to find out the application limit that the assumption of continuum mechanics holds. The steady non-reacted compressible flow field in the unstructured grid system is computed and analyzed with varying the environmental pressure (or the degree of vacuum) under the fixed pressure ratio in a real thruster of which the area ratio of exit to throat is 56. The assumption of the continuum mechanics is not approved when the environmental pressure is reduced less than $10^{-3}$ atm.

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Rocket Plume Analysis with DSMC Method (DSMC 방법을 이용한 로켓 플룸의 해석)

  • Jeon, Woojin;Baek, Seungwook;Park, Jaehyun;Ha, Dongsung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.5
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    • pp.54-61
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    • 2014
  • In this study, a plume exhausted from rocket nozzle is investigated by using an unstructured 2-dimensional axisymmetirc DSMC code at various altitude. The small back-pressure to total-pressure ratio($P_b/P_o$) and large $P_b/P_o$ represent low and high altitude condition, respectively. At low altitude, the plume shows a typical complicated structure (e.g. Mach disk) of underexpanded jet while the high altitude plume experiences plain expansion. The various features of exhaust plume is discussed including density, translational/rotational temperature, Mach number and Knudsen number. The results shows that even at 20 km altitude where the freestream Knudsen number is small as $1.5{\times}10^{-5}$, the transitional and rarefied flow regimes can occur locally within the plume. It confirms the necessity of DSMC computation at low altitude.

Prediction of Seabed Topography Change Due to Construction of Offshore Wind Power Structures in the West-Southern Sea of Korea (서남해에서 해상풍력구조물의 건설에 의한 해저지형의 변화예측)

  • Jeong, Seung Myung;Kwon, Kyung Hwan;Lee, Jong Sup;Park, Il Heum
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.31 no.6
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    • pp.423-433
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    • 2019
  • In order to predict the seabed topography change due to the construction of offshore wind power structures in the west-southern sea of Korea, field observations for tides, tidal currents, suspended sediment concentrations and seabed sediments were carried out at the same time. These data could be used for numerical simulation. In numerical experiments, the empirical constants for the suspended sediment flux were determined by the trial and error method. When a concentration distribution factor was 0.1 and a proportional constant was 0.05 in the suspended sediment equilibrium concentration formulae, the calculated suspended sediment concentrations were reasonably similar with the observed ones. Also, it was appropriate for the open boundary conditions of the suspended sediment when the south-east boundary corner was 11.0 times, the south-west was 0.5 times, the westnorth 1.0 times, the north-west was 1.0 times and the north-east was 1.0 times, respectively, using the time series of the observed suspended sediment concentrations. In this case, the depth change was smooth and not intermittent around the open boundaries. From these calibrations, the annual water depth change before and after construction of the offshore wind power structures was shown under 1 cm. The reason was that the used numerical model for the large scale grid could not reproduce a local scour phenomenon and they showed almost no significant velocity change over ± 2 cm/s because the jacket structures with small size diameter, about 1 m, were a water-permeable. Therefore, it was natural that there was a slight change on seabed topography in the study area.

Crystal structure refinement and microwave dielectric characteristic of $(1-x)CaTiO_3-x(La_{1/3}Nd_{1/3})TiO_3$ ($(1-x)CaTiO_3-x(La_{1/3}Nd_{1/3})TiO_3$계의 결정구조 해석 및 마이크로파 유전 특성)

  • 조남웅;성경필;문종하;최주현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.478-486
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    • 1998
  • $CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm x\le0.8)$ system was prepared by reaction of $CaCO_3,\;LaO_3,\;Nd_2CO_3$ and ,TEX>$TiO_2$ mixture at 1673 K, which can be applied for microwave dielectric ceramic materials. The lattice parameters of(1-x))$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm x\le0.8)$ system increased with the increase of x. Its structure was investigated by Rietveld profile-analysis of XRD in detail. Cations $ La^{3+}$ and Nd^{3+}$ were located at the $Ca^{2+}$ site in the range of $0\le \textrm x\le0.8$. crystal structure in $;(0\le \textrm x\le0.6)$ maintained space group Pnma with CaTiO_3 structure. The tiled and distorted $TiO_6$ was gradually released with the increase of x in $0\le \textrm x\le0.6$ .The structure was changed to a new space group of $Pmn2_1$ at the x value of 0.8. The relative dielectric constant $(\epsilon_r)$ of $(1-x)CaTiO_3-x(La_{1/3} Nd_{1/3})TiO_3$ ($(0\le \textrm x\le0.8)$) system was exponentially decreased by with the increased of x. The temperature coefficient of resonant frequency $(\tau_f)$ decreased with the increase of x in $0\le \textrm x\le0.6$ and then increased again at x=0.8 due to the change of crystal structure. The value of Q$\cdot f_o$ was 13800 (GHz) at x=0.2 and was very low under 2000 (GHz) in 0.4$\leq$x$\leq$0.8.

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Study of Nonstoichiometry and Physical Properties of the Mixed Valency $Sr_xEu_{1-x}FeO_{3-y}$ ($0.00{\leq}x{\leq}$1.00) System (혼합원자가 $Sr_xEu_{1-x}FeO_{3-y}$ ($0.00{\leq}x{\leq}$1.00)계의 비화학량론과 물성 연구)

  • Ji Young Min;Kwon Sun Roh;Chul Hyun Yo
    • Journal of the Korean Chemical Society
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    • v.38 no.12
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    • pp.873-879
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    • 1994
  • A series of samples of solid solutions in the $Sr_xEu_{1-x}FeO_{3-y}(0.00{\leq}x{\leq}1.00)$ system has been prepared at $1200^{\circ}C$ under an atmospheric air pressure. The structures of solid solutions are studied by X-ray diffraction, thermal, Mohr salt, and Mossbauer spectroscopic analyses. Their physical properties are also discussed with the electrical conductivities. X-ray diffraction data for the compositions of x = 0.00, 0.25, and 1.00 are assigned to the orthorhombic and the compositions of x = 0.50 and 0.75 to the cubic systems. The lattice volume reduced to cubic cell increases with the x value. The mole ratio of $Fe^{4+}$ iometric chemical formulas of the system are formulated from the x, $\tau$, and y values. The mixed valency state of Fe ions, the oxygen coordination, and covalent bond character are discussed with the Mossbauer spectroscopic data. The activation enegy of the electrical conductivities depends on the $\tau$ value in the temperature range of -$100^{\circ}C$ to $600\circC$ under the air pressure. The Mossbauer spectrum and electrical conductivity of the solid solutions are discussed with nonstoichiometric chemical compositions.

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Analysis of the Crystal Structure and the Relation with the Temperature Coefficient au_\varepsilon$ in $BaORe_2O_3TiO_2$ (Re=La, Nd, Y) Microwave Dielectric Ceramics ($BaORe_2O_3TiO_2$ (Re=La, Nd, Y)계 고주파 유전체의 결정구조 분석 및 온도계수 au_\varepsilon$와의 관련성)

  • 김정석;강현주;심해섭;이창희;천채일
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.136-144
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    • 1999
  • Crystal structures of tungsten-bronze type microwave dielectric ceramics, $BaOLa_2O_34TiO_2$ (BLT) and $BaO(Nd_{0.77}Y_{0.23})_4TiO_2$ (B(NY)T), were analysed using the Rietveld method. The most relibale refinement was obtained by refining the cation and anion positions from the x-ray and neutron diffraction data, respectively. The ambiguites inherent in the refined crystal structure by Mateeva et al. were resolved. The $BaORe_2O_34TiO_2$ structure consiste of $3\times2$ perovskite blocks and 4 pentagon-channels. The Ti-O6 octahedrons are distroted and tilted, which, consequently, induces the displacements of Ba and Re ions producing the superlattics (c$\approx$ 7.6 $\AA$). The B(NY)T showed more severely tilted Ti-O6 octahedrons. The relative dielectric constant $\varepsilon_{\gamma}$ and temperature coefficient $\tau_\varepsilon$ are 109.5 and-$180 ppm/^{\circ}C$ in BLT, 76 and $+40 ppm/^{\circ}C$ in B(NY)T, respectively. The small Re ions produced a positive $\tau_\varepsilon$. The relation between $\tau_\varepsilon$ and the octahedron tilting in complex perovskite is discussed for the tungsten bronze type structure.

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