• Journal of the Korean Chemical Society
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• v.47 no.4
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• pp.334-338
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• 2003

The crystal structure of $[Co(phen)_2(Cl)(H_2O)] Clㆍ2H_2O$(phen=1,10-phenanthroline) has been determined by X-ray crystallography. It crystallizes in the triclinic system, space group P1, with lattice parameters a=9.662(2), b=11.445(1), c=13.037(2)${\AA}$ ${\alpha}$=64.02(1), ${\beta}$=86.364(9), ${\gamma}=78.58(2)^°$, and Z=2. The coordinated cations contain a six-coordinated cobalt atom chelated by two phen ligands and one chloride anion and one water ligand in cis arrangement. In addition to the chloride coordinated to the cobalt, there are one chloride ion and four water molecules which complete the crystal structure. In the solid state, the title compound forms three dimensional network structure through hydrogen bonds, within which exists the strongest hydrogen bond (O(3)-O(4)=2.33${\AA}$). The intermolecular hydrogen bonds connect the $[Co(phen)_2(Cl)(H_2O)]1+,\;H_2O$ moieties and chloride ion.

• Korean Journal of Materials Research
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• v.9 no.8
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• pp.854-857
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• 1999

The properties of Fe-Se-Te system(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8) have been studied by means of the X-ray diffraction method and Mossbauer spectroscopy. The results of X-ray diffraction patterns show that three samples have the ixed structure of tetragonal PbO and a small amount of hexagonal NiAs structure respectively. For x=0.5 the lattice parameters of tetragonal PbO structure are a=3.795$\AA$, c=5.896$\AA$ and c/a=1.55. The Mossbauer spectra were obtained with the various temperature variation and than they do not exhibit magnetic hyperfine structure but show a strong doublet. The values of observed isomer shift and quadrupole splitting suggest that the irons of all samples exist in the +2 oxidation state with a major covalent contribution. The temperature dependence of isomer shift values for x=0.8 seems to be originated from the second order Doppler effect.

• Korean Journal of Materials Research
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• v.8 no.12
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• pp.1165-1169
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• 1998

A single crystal cast blade was manufactured by CMSX 6, one of the first generarion nickel based single crystal superalloys by the selector method in a vacuum furnace. The single crystal has been grown with cooling rate of 2.5 mm/min, after pouring the molten alloy of 163$0^{\circ}C$ to the mold heated to 150$0^{\circ}C$. The cast structure could be classified into matrix (dendrite) and eutectic regions in ${\gamma}$'shape and size. The eutectic region showed higher Ti content. As the additional results of ${\gamma}$'precipitates by EPMA and CBED analysis the ${\gamma}$'size was less than 0.5~0.7$\mu\textrm{m}$, showing the chemical composition close to Ni$_3$Al of Ll$_2$ lattice structure. But ${\gamma}$'size has increased to bigger than 1.0$\mu\textrm{m}$, being near to eutectic region, changing its shape to bar or huge block types. These showed the chemical structure near to Ni$_3$Ti of D $O_{24}$ lattice structure. Therefore, ${\gamma}$'morphology of dendrite and eutectic regions depends absolutely on its chemical composition and lattice structure.

• Journal of the Society of Naval Architects of Korea
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• v.32 no.1
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• pp.70-82
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• 1995

A multi-layer simulation program is developed to estimate the ocean current considering sea bottom geometry. The so-called $\sigma$ coordinate system is introduced in vertical direction to describe sea bottom topography more accurately and effectively. Leapfrog scheme combined with Euler backward scheme is used to reduce computation error which may be possibly accumulated in time evolution by Leapfrog scheme alone. In this paper, very simple examples of rectangular basins with various bottom geometries were taken and the effect of sea bottom geometry on vertical structure of the ocean tidal current and its direction were investigated. Through comparisons between the present three dimensional calculation in which bottom topography is directly taken into consideration and the two dimensional calculation in which depth average concept is employed, it was found that magnitude of surface current and its direction could be largely affected by the sea bottom topography, particularly in shallow region with complex bottom shape.

• Korean Journal of Crystallography
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• v.4 no.1
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• pp.18-24
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• 1993

The phase diagram of the Pt-Sb system was reinvestigated, using the conventional sealedcapsule technique. The identification of phases present in the reaction products was made by reflected light microscopy, X-ray diffraction and electron microprobe analysis. The existence of compounds, Pt5Sb, Pt3Sb, Pt3Sb2, PtSb and PtSb5 was confirmed. A new phase, Pt5Sb with a composition of 83at% Pt and tetragonal structure of the lattice parameters a=3.948(3), c=16.85(1)A, was found. The X-ray powder data of Ptsb may be indexable on a tetragonal cell with a=3.9455(7), c=16.959(5)A. PtSb is stoichiometric up to 800t and becomes Pt-deficient as much as lat% at 1000t. Solid solubility limits of Sb in Pt were determined to be 7.5,10.0 and 6.1at% at 1000˚,800˚ and 600˚ , respectively. The earlier reported Pts Sbf was not found in this study. The liquidus curve between the Ptsb2 and Sb phases was revised.

• Korean Journal of Materials Research
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• v.5 no.8
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• pp.945-952
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• 1995

The effect of Zr content on the thermal stability of mechanically alloyed Al-8wt.% (Ti+Zr) alloys was investigated. As the Zr to Ti addition ratio increased the decrease of hardness due to the long time exposure at high temperature reduced so that the thermal stability of the alloy was improved. From the TEM work it was found that the coarsening of precipitates was responsible for the decrease of hardness and the coarsening of precipitates could be suppressed by the addition of Zr, XRD, SAD and EDS analyses confirmed that these precipitates were consisted of DO$\sub$22/, and DO$\sub$23/ type Al$_3$(Ti+Zr) ternary in termetallic compounds. Especially for the DO$\sub$23/ Al$_3$(Ti+Zr), the lattice parameter changed toward the smaller lattice mismatch between the precipitate and Al matrix as the Zr content increased. Therefore, it was considered that the improvement of thermal stability of Al-8wt.% (Ti+Zr) alloys was due to the formation of the ternary Al$_3$( Ti + Zr) intermetallic compounds.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.27-27
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• 2021

세굴은 유체와 유사의 상호작용으로 발생하는 중요한 자연 현상 중 하나로, 구조 및 지반 붕괴, 홍수, 생태계 파괴 등의 문제를 야기할 수 있다. 이러한 세굴 현상을 예측하기 위해 많은 수치적 연구가 진행되어왔지만, 대부분의 연구가 기존 격자기반방법인 유한체적법 (FVM)과 개별요소법 (DEM)이 연성된 모델을 이용하였고, 이는 격자 의존도로 인한 정확도와 효율성의 문제점을 보였다. 해결책으로 입자기반 유체해석 방법인 약압축성 SPH (WCSPH)와 개별요소법의 결합모델을 이용한 모의가 연구되어 왔지만, 단순 밀도차를 활용한 유체해석방법이 압력의 불안정성을 야기하여 유사의 운동에도 영향을 주는 결과를 보였다. 또한, 개별요소법의 특성상 모의 입자의 크기를 실제 실험 입자의 크기와 동일하게 설정하면서 입자수가 지나치게 증가해 계산의 효율성이 현저히 낮아지게 되었고, 이로 인해 실제 자연 지형에 적용하는데 어려움을 보여주었다. 본 연구에서는 향상된 세굴 수치모의해석을 위해 반복법을 통해 안정적인 유체 압력을 계산하는 비압축성 SPH (ISPH)와 개별요소법을 연성한 ISPH-DEM 모델을 사용하였다. 또한, 계산속도 향상을 위해 하나의 입자가 다수의 작은 입자의 움직임을 대표하는 Coarse-grained 방법을 적용하여 기존 모델을 개선하였다. 개선된 모델을 NFLOW ISPH PURPLE 소프트웨어를 이용하여 세굴 현상을 수치 모의하였고 실험 결과와 검증을 진행한 결과, 세굴의 깊이, 너비, 형상 등을 비교하였을 때 약 10% 이내의 오차를 보였고, Coarse-grained 방법을 통한 입자 수 감소로 최소 13배 증가된 해석 속도를 보였다. 이를 통해 본 연구에서 제시된 모델이 실제 자연 지형에서의 적용가능성을 확인할 수 있었다.

• Journal of the Korean Chemical Society
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• v.33 no.5
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• pp.445-451
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• 1989

A series of solid solutions with formula $Er_{1-x}Sr_xFeO_{3-y}, where x is from 0.0 to 1.0, has been synthesized by heating at $1200^{\circ}C$ for 24 hours. X-ray diffraction shows these samples to be orthorhombically distorted perovskites for compositions up to x = 0. 6 and apparantly simple cubic perovskite structures from $0.8{\leq}x{\leq}1.0$. Lattice volumes are increased with the introduction of Sr. The mixed valence state of two kinds of Fe ion in these ferrite systems is analyzed by the Mohr salt titration method. Mossbauer spectra measured at room temperature for x = 0.0 and 0.5 compositions shows hyperfine splitting for iron (III) due to magnetic ordering and indicates that these samples contain octahedrally and tetrahedrally coordinated iron sites. Electrical conductivity measurements indicate that conduction in these samples apparantly occurs over the octahedral sites by a hopping mechanism.

• Korean Journal of Crystallography
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• v.1 no.1
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• pp.49-56
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• 1990

The crystallizied Inactions of the two metastable phases in the glasses of plagioclase compositions were estimated by x-ray diffraction method. The orthorhombic metastable phase is easily drystaliized in the composition range of 70 to 80 mol% of albite, whereas the hexagonal metastable phase is mostly crystallized in the anonhite-rich side. For the purpose of refining the orthorhombic metastable structure some single crystal fragments of the composition Na,17ca‥‥All Isi2 nn were separated Som the crystallized glasses. The cell parameters of this crystal are a=8.237(1)A. b=8.644(1)A c=4.818(1)A. The space group of this crystal is Pn,2, Final atomic coordinates give R value of 0.040 and Rw of 0.028 with anisotropic thermal parameters. The position of Na and Ca atoms statistically distributed is splitted in two points with the occupancy of 0.5. The Si and Al atoms are statistically distributed in the six-membered ring of the Immm-type framework.

• 대한공업교육학회지
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• v.31 no.1
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• pp.185-199
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• 2006

In this paper, to detect lateral direction sound pressure fiber optic sensor using Fabry-Perot interferometeric sensor array was fabricated and experimented. This parallel sensor array composed of one light source and the light split into each sensor using directional coupler and to see the output signal the array system do not need any digital signal processor. As a lateral direction sound source arbitrary sound frequency of 100Hz, 200Hz, and 655Hz using by nondirectional speaker were applied to the array sensor which installed on $60cm{\times}60cm{\times}60cm$ latticed structure. The detected signals from the two sensors were analyzed in the time and frequency domains. It was confirmed that the suggested sensor array detected applied sound source well but there were a little amplitude differences in between the sensors. Because the sensor supported simply at both ends theoretical analysis was performed and its solution was suggested. To compare the theoretical and experimental results arbitrary sound frequency of 2kHz was applied to the sensor array. It shows that experimental results was good agreement with theoretical results.