• Title/Summary/Keyword: 교환계수

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Joint Characteristics in Sedimentary Rocks of Gyeongsang Supergroup (경상누층군 퇴적암의 절리 특성 연구)

  • Chang, Tae-Woo;Son, Byeong-Kook
    • The Journal of Engineering Geology
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    • v.19 no.3
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    • pp.351-363
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    • 2009
  • Two orthogonal joint sets develop well only in sandstone beds in the sandstone-mudstone sequences of Gumi and Dasa outcrops within Cretaceous Gyeongsang Basin. And various joint data are similar in the beds of the same thickness in both outcrops, meaning that the joint sets were homogeneously produced by extensional deformation in the same regional stress field. Most of joints in the sandstone beds are orthogonal to, and confined by bed boundaries, which are believed to be formed by hydrofracturing during consolidation after burial. Two orthogonal joint sets are considered to be almost coeval on the basis of mutual abutting relationship which makes up fracture grid-lock and a product of rapid switching of ${\sigma}_2$ and ${\sigma}_3$ axes with constant ${\sigma}_1$ direction oriented to vertical. The joint sets in the sandstone beds show planar surfaces, parallel orientations and regular spacing, with joint spacing linearly proportional to bed thickness. The spacing distributions of the joints seem to correspond to log-normal to almost normal distribution in most of the beds. But multilayer joints do not display regular spacing and dominant size. Either joint set in this study is characterized by a high level of joint density and a saturated spacing distribution as indicated by the mode/mean ratio values and the Cv(coefficient of variance) values. Joint aperture tends to increase with the vertical length of the joints controlled by bed thickness.

Environmentally friendly determination of urinary trans, trans-muconic acid for biological monitoring of benzene exposure by green high-performance liquid chromatography (소변 중 뮤콘산의 친환경 HPLC 분석방법을 이용한 벤젠 노출 생물학적 노출평가)

  • Yang, Dong-Hyug;Lee, Mi-Young;Won, Yong Lim
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.460-466
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    • 2012
  • An environmentally friendly, so-called green, high performance liquid chromatography method was developed and validated for the determination of trans, trans-muconic acid (t,t-MA) in human urine as a biomarker of benzene exposure. After urinary t,t-MA was extracted and enriched using solid-phase extraction, a MF-Ph1 SG80 ($150mm{\times}2.0mm$ I.D., 5 ${\mu}m$) column with a mobile phase of 10 mM $KH_2PO_4$ containing 0.1% $H_3PO_4$ was used for isocratic separation of t,t-MA with UV detection at 259 nm. The calibration curve was constructed in the range of 0.1-5.0 mg/L with good linearity ($r^2$=0.9992). The intra-day and inter-day precision (as RSD) were 0.9-8.5% and 3.1-4.5%, respectively. The average recovery ranged from 97.5% to 101.7%. The green sample preparation and separation with no organic solvents were successfully achieved. The validated method would be suitable for the routine biological monitoring of benzene exposure in the occupational settings.

Estimation of Surface Fluxes Using Noah LSM and Assessment of the Applicability in Korean Peninsula (Noah LSM을 이용한 지표 플럭스 산정 및 한반도에서의 적용성 검토)

  • Jang, Ehsun;Moon, Heewon;Hwang, Seok Hwan;Choi, Minha
    • Journal of Wetlands Research
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    • v.15 no.4
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    • pp.509-518
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    • 2013
  • Understanding of the exchange between the water and energy which is happening between the surface and atmosphere is the basic of studying water resources. To study these, lots of researches using Noah Land Surface Model(LSM) are in progress. Noah LSM is based on energy and water balance equation and simulates various hydrological factors. There are diverse researches with Noah LSM are ongoing in overseas, on the other hand not enough study has been done. Especially there is almost no study using uncoupled Noah LSM in Korea. In this study we used data from Korea Flux Tower in Haenam(HFK) and Gwangneung(GDK) as forcing data to simulate the model and compared its result of net radiation, sensible heat flux and latent heat flux with the observation data to assess the applicability of Noah LSM in Korea. Regression coefficients of the comparison results of Noah LSM and observation show good agreement with the value of 0.83~0.99 at Haenam and 0.64~0.99 at Gwangneung which means Noah LSM can be trusted.

The Properties of Vibration Absorption according to the Diameter of Fiberous $BaTiO_3$ Powder (섬유상 $BaTiO_3$의 분말 직경에 따른 흡진 특성)

  • Seo, Yong-Gyo
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.3-8
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    • 1994
  • Recently, sound and mechanical vibration are becoming important problems in our life. In the present study, the measurement of vibration absorption characteristics of barium titanate ceramics and the investigation of its relationship to microstructures were carried out. The barium titanate ceramics is expected to be better vibration absorption material owing to its chemical and physical stability than other conventional vibration absorbers like glasswool board. Barium titanate ceramics were prepared by sintering fiberous $BaTiO_{3}$ crystallites in order to enhance the vibration absorption characteristics. The fiberous $BaTiO_{3}$ ceramics were prepared through the ionic exchange after the preparation of fiberous $K_2Ti_4O_9$ with 0.2$\mu\textrm{m}$, 1.2$\mu\textrm{m}$, 2.0$\mu\textrm{m}$, diameter length by KDC method. The fiberous crystallites were oriented in a plane perpendicular to the press direction and sintered. The investigation of the grain diameters of the sintered ceramics, equivalent factor, electromechanical coupling factor($k_1$), and the generated voltage(V) shows that the grain's diameter decreases with the increase of the diameter of the used fiberous crystallites. The vibration absorption increases the crystallites' diameter. That means that the vibration absorption increases with the internal friction of grain boundary. Which was identified by the investigation of the equivallent circuit.

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Consumers' Subjective Risk Perceptions of Tab Water and Stated Preferences for Safe Drinking Water (소비자들의 수돗물에 대한 주관적 위험인지와 안전한 음용수에 대한 진술선호 분석)

  • Eom, Young Sook
    • Environmental and Resource Economics Review
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    • v.15 no.2
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    • pp.147-175
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    • 2006
  • This paper attempts to incorporate three important factors-perceptions, behavior and valuation-in analysing consumers' responses to health risks from environmental pollutants. Using a survey sample of 500 consumers in the Chonbuk province area, this paper empirically investigated determinants of risk perceptions from using tap water as drinking water. Most consumers were considerably concerned about health risks from drinking tap water. Moreover, those subjective concerns were not random, but were systematically related to individuals' demographic variables such as age, gender, and family size. Those subjective beliefs also influenced respondents' purchase intentions on safer water bottles, in response to a contingent behavior question of presenting two types of water bottles. The technical risk information provided in the survey had significant effects on purchase intentions only when it was interacted with respondents' actual averting practice. In addition, the sample selection effects were present by eliminating respondents who decided not to purchase either of two types of water bottles. The potential selection bias had impacts on the coefficients of the price difference variable, and subsequently the estimates of the price increments for health risk reductions.

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A Study on Thermal Performance Comparison between Large and Small Sized Plate Heat Exchanger (판형 열교환기 크기에 따른 전열성능 비교에 관한 연구)

  • Park, Jae-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.528-534
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    • 2020
  • The early development and use of plate heat exchangers (PHE) were in response to stringent statutory requirements from dairy products in the late 19th century, but PHEs were not exploited commercially until the 1920s. Since then, although the basic concept of PHEs has changed little, its design and construction have progressed significantly to accommodate higher temperatures and pressures, as well as large heat exchanging capacities. The development of current chevron-type corrugated heat plates has been ongoing since the oil shock in the 1970s to improve energy efficiency. The development trend of PHEs is consistent with the development of larger heat plates with better thermal efficiency, lower pressure drop, and good flow distribution. In this study, the thermal performance of small heat plates (PHE-S) and large heat plates (PHE-L) with the same plate depth and corrugation pitch were analyzed experimentally for each channel (H, M, and L type) to suggest development directions of heat plates. The test results showed that for the convectional heat transfer coefficient, the PHE-S was on average, 16.5% higher in the H type, 25% higher in the M type, and 40% higher in the L type than PHE-L. In the case of the pressure drop, the PHE-S was 19% higher in the H type, 46% higher in the M type, and 61% higher in the L type than PHE-L. These results were attributed to the differences in fluid distribution areas between the PHE-S and PHE-L, among other potential causes.

Evaluation of Thermal Response Test of Energy Pile (에너지 파일의 현장 열응답 시험에 관한 연구)

  • Yoon, Seok;Lee, Seung-Rae;Kim, Min-Jun;Go, Gyu-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.30 no.4
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    • pp.93-99
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    • 2014
  • Use of geothermal energy has been increased for its economical application and environmentally friendly utilization. Particularly, for energy piles, a spiral coil type ground heat exchanger (GHE) is more preferred than line type GHEs such as U and W shaped GHEs. A PHC energy pile with spiral coil type GHE was installed in an area of partially saturated dredged soil deposit, and a thermal response test (TRT) was conducted for 240 hours under a continuous operation condition. Besides, remolded soil samples from different layers were collected in the field, and soil specimens were reconstructed according to the field ground condition. Non-steady state probe methods were conducted in the lab, and ground thermal conductivity and thermal diffusivity were measured for the different soil layers. An equivalent ground thermal conductivity was calculated from the lab test results and it was compared with the field TRT result. The difference was less than 5%, which advocates the use of an equivalent ground thermal conductivity for the multi-layered ground. Furthermore, this paper also represents an equivalent ground thermal diffusivity evaluation method which is another very important design parameter.

Electrochemical Oxidation of Hydrogen at Palladium Electrode (팔라디움 전극에서의 전기화학적 수소산화반응)

  • Oh, M.H.;Paik, C.H.;Cho, B.W.;Yun, K.S.;Min, B.C.;Ju, J.B.;Sohn, T.W.
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.45-54
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    • 1996
  • Electrochemical oxidation of hydrogen on PdOx and Pd electrodes were investigated in aqueous 30% KOH solution at different temperatures and hydrogen concentrations(partial pressures). Anodic reaction by hydrogen on PdOx electrode was mainly due to the oxidation of adsorbed hydrogen at -0.8V~-0.5V(vs. Hg/HgO). For Pd electrode, the anodic reaction was participated by the adsorbed hydrogen on surface, as well as by the metal hydride formed from direct reaction between Pd and hydrogen at -0.5V~0.0V(vs. Hg/HgO). With the increase of hydrogen concentration the charge transfer resistance decreased and the exchange current increased. The transfer coefficient of PdOx and Pd electrodes were found to be 0.78 and 0.72 respectively, which shows the superior reactivity of Pd electrode. The activation energies of PdOx and Pd electrodes decreased with the increase of overpotential and were found to be 23.9~20.3 kJ/mole and 7.2~3.0kJ/mole, respectively.

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Performance analysis of a cooling system with refrigerant in a marine absorption refrigerator (선박용 흡수식 냉동기의 냉매적용 냉각 시스템 성능 분석)

  • Yun, Sang-Kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.4
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    • pp.282-287
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    • 2016
  • Recently in order to protect the ocean environment and to reduce energy consumption, shipbuilders have been developing highly economized ships. This research analyzed the possibility of adopting the onshore absorption refrigerator to offshore ships having a cooling system with refrigerant by using the waiste heat of the engine jacket cooling water instead of compression refrigerators. The results showed that R236fa could be a suitable medium for absorbing the heat of the absorber and condenser in an absorption refrigerator. The cooling system using R236fa achieved a high COP of 0.798, which is 15% and 5% higher than an air cooling system with a cooling tower and a water cooling system with a heat exchanger, respectively. The cooling system with R236fa achieved high efficiency with a 25% reduction in flow rate of LiBr solution and only 15.7% flow rate of cooling medium as compared to the water cooling system. The heating of sea water by the engine jacket water flowing out from the generator can prevent the crystallization of LiBr solution due to the low temperature of sea water.

Seasonal Monitoring of Residual Veterinary Antibiotics in Agricultural Soil, Surface Water and Sediment Adjacent to a Poultry Manure Composting Facility (계분 퇴비화 시설 인근 농경지 토양, 지표수 및 저질토의 계절별 잔류 항생물질 모니터링)

  • Lee, Sang-Soo;Kim, Sung-Chul;Kim, Kwon-Rae;Kwon, Oh-Kyung;Yang, Jae-E.;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.29 no.3
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    • pp.273-281
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    • 2010
  • Concentration of antibiotics including a tetracycline group (TCs) of tetracycline (TC), chlortetracycline (CTC), and oxytetracycline (OTC), a sulfonamide group (SAs) of sulfamethoxazole (SMX), sulfathiazole (STZ), and sulfamethazine (SMT), an ionophore group (IPs) of lasalocid (LSL), monensin (MNS), and salinomycin (SLM), and a macrolide group (MLs) of tylosin (TYL) was determined from samples collected from the agricultural soil, stream water, and sediment. For the agricultural soil samples, the concentration of TCs had the highest value among all tested antibiotic's groups due to its high accumulation rate on the surface soils. The lower concentrations of SAs in the agricultural soils may be resulted from its lower usage and lower distribution coefficient (Kd) compared to TCs. The concentration of TCs in stream water was significantly increased through June to September. It would be likely due to soil loss during an intensive rainfall event and a reduction of water level after the monsoon season. A significant amount of TCs in the sediment was also detected due to its accumulation from runoff, which occurred by complexation of divalent cations, ion exchange, and hydrogen bonding among humic acid molecules. To ensure environmental or human safety, continuous monitoring of antibiotics residues in surrounding ecosystems and systematic approach to the occurrence mechanism of antibiotic resistant bacteria are required.