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Changes of photoluminescence in silicon-oxide films (실리콘산화막의 광루미니센스 변화에 관한 연구)

  • 이재희
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.216-220
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    • 2000
  • Photoluminescence (PL) results of $Si^+$-implanted $SiO_2$films on crystalline silicon are reported. Visible and infrared PL are observed for all the samples. The PL spectrums have about 7000 $\AA$, 7400 $\AA$ and 8400 $\AA$ peak positions. As amount of $Si^+$ ion dose changed, the PL peak positions and intensity are changed. In particular, the PL spectrum has three peaks and more intensity than the other $Si^+$ ion implantation samples for $1{\times}10^{17}/cm^2$ $Si^+$ ion implantation. Not nanocrystal but defects that $Si^+$ ions treated are contributed to the PL spectrum. For the changes of $Si^+$ ion dose and annealing time, O rich radiative defects, Si rich radiative defects, and nonradiative defects control the PL spectrum. We confirmed that more radiative defects can be created by control of $Si^+$ ion dose.

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Cu-Pc 박막의 성장 조건에 따른 phase transition 현상 및 전기적.광학적 특성

  • Gang, Sang-Baek;Chae, Yeong-An;Yun, Chang-Seon;Kim, Mi-Jeong;Kim, Jin-Tae;Cha, Deok-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.230-230
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    • 2010
  • 유기물 반도체 화합물인 Cu-Pc(copper(II)-phthalocyanine)는 우수한 전기적 광학적 특성을 가지며, OLED, MISFET등 소자로서의 활용도가 높다. Cu-Pc 화합물은 $\alpha$-phase, $\beta$-phase, $\gamma$-phase를 포함하는 여러 가지 다결정 polymer로 존재할 수 있다. 가장 잘 알려진 구조로는 열적으로 준안정적인 $\alpha$-phase와 열적으로 안정적인 $\beta$-phase가 있다. Cu-Pc 박막의 구조 및 흡수 특성과 전기적 특성에 대한 기술이 확실히 규명되지 않아 본 연구에서는 두께와 열처리 조건에 따른 결정성 및 방향성을 조사하기 위하여 $\alpha$-phase와 $\beta$-phase의 phase transition 현상 및 전기적 광학적 특성을 규명 하고자 한다. 진공증착 방법 중 하나인 PVD 방법의 thermal evaporation deposition을 이용하여 glass, ITO 기판위에 두께와 열처리에 따른 전기적?광학적 특성을 연구하였다. Cu-Pc 박막의 성장두께는 5nm~50nm 이내로 fluxmeter 및 thickness monitor를 이용하여 제어하였다. 5nm~50nm의 두께에 따른 기판온도를 $200^{\circ}C$로 고정하여 전열 처리 및 후열 처리하여 온도에 따른 박막을 성장한 후, 결정 구조 및 특성 변화와 phase transition 분석하였다. 제작된 Cu-Pc의 박막은 $\alpha$-phase와 $\beta$-phase로 구분할 수 있으며, 열처리에 따른 phase transition 현상이 뚜렷함을 알 수 있다. XRD(X-ray diffraction)를 통하여 박막에 대한 결정 구조 분석 및 FE-SEM(field emission scanning electron microscopy)와 AFM(atomic force microscopy)을 이용하여 Cu-Pc 박막의 구조적 결정성과 방향성 등, 표면 상태와 형상구조에 대해 표면의 특성을 측정하며, 광 흡수도(UV-visible absorption spectra)을 이용하여 phase transition 현상에 따른 I-V 특성을 비교분석 하였다.

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Development of Texture Neutralization System for the Invisible e-Performance (투명 e-퍼포먼스를 위한 텍스쳐 중화 시스템 개발)

  • Lee, Dong-Hoon;Yun, Tae-Soo
    • Journal of Korea Multimedia Society
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    • v.14 no.4
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    • pp.585-594
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    • 2011
  • On live performance such as play and musical, various stage effects are utilized to attract a diverse audience. These stage effects include traditional direction techniques, striking display effects and all kinds of ways of being immersed in the scene. In this paper, we propose a novel digital visual effects(digilog) for controlling the surface texture of objects based on spatial augmented reality. For this purpose, we present a method of neutralizing the appearance of an arbitrary object using a projector-camera system. To make the object appear as if it is a transparent object by projecting a carefully determined compensation image onto the surface of objects, we use the homography method for a simple and effective off-line projector-camera calibration. The successful uses of the basic algorithm of Smart Projector for measuring radiometric parameters led us believe that this method may be used for temporal variation of plays and musicals.

온도 조건 변화에 따른 Cu-Pc 박막 $\beta$-phase type의 표면 결정 특성에 관한 연구

  • Kim, Hyeon-Suk;Gang, Sang-Baek;Chae, Yeong-An;Yun, Chang-Seon;Yun, Seong-Hyeon;Yu, Su-Chang;Kim, Jin-Tae;Cha, Deok-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.254-254
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    • 2010
  • Cu-Pc(copper(II)-phthalocyanine)는 박막의 형성과정에서 열처리 방식과 온도에 따라 박막의 구조가 변하며, 구조로는 열적으로 준 안정적인 $\alpha$-phase와 열적으로 안정적인 $\beta$-phase가 있다. 본 연구에서는 Cu-Pc 박막의 열적으로 안정적인 $\beta$-phase 구조에 대해 온도 조건 변화에 따른 표면 결정 성장의 특성을 연구하고자 한다. 진공증착 방법 중 하나인 thermal evaporation deposition을 이용하여 glass 기판위에 전열 처리 및 후열 처리에 대해 온도 조건 변화에 따른 $\beta$-phase type의 표면 결정 특성을 연구하였다. Cu-Pc 박막의 성장두께는 50nm 일정한 두께로 fluxmeter 및 thickness monitor를 이용하여 제어하였다. 50nm의 두께에 따른 기판온도를 $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$로 전열 처리한 후 각각 전열 처리한 기판온도에 대해 1hour, 2hour, 3hour 후열 처리하여 온도 조건에 따른 박막을 성장한 후, $\beta$-phase type에 대한 결정 구조 및 표면 특성 변화를 분석하였다. 제작된 Cu-Pc의 박막은 $\beta$-phase type으로, 열처리에 따른 $\beta$-phase transition 현상을 연구하였다. XRD(X-ray diffraction)를 통하여 박막에 대한 결정 구조 분석 및 FE-SEM(field emission scanning electron microscopy)을 이용하여 Cu-Pc 박막의 구조적 결정성과 방향성 등, 표면 상태와 형상구조에 대해 표면의 특성을 분석하며, 광 흡수도(UV-visible absorption spectra)을 이용하여 온도 조건에 따른 투과/흡수 현상을 비교분석하였다.

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Effects of Light-Quality Control on the Plant Growth in a Plant Factory System of Artificial Light Type (인공광 식물공장내 광질 제어가 작물생육에 미치는 영향)

  • Heo, Jeong-Wook;Baek, Jeong-Hyun
    • Korean Journal of Environmental Agriculture
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    • v.40 no.4
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    • pp.270-278
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    • 2021
  • BACKGROUND: Horticultural plant growth under field and/or greenhouse conditions is affected by the climate changes (e.g., temperature, humidity, and rainfall). Therefore investigation of hydroponics on field horticultural crops is necessary for year-round production of the plants regardless of external environment changes under plant factory system with artificial light sources. METHODS AND RESULTS: Common sage (Salvia plebeia), nasturtium (Tropaeolum majus), and hooker chive (Allium hookeri) plants were hydroponically culturing in the plant factory with blue-red-white LEDs (Light-Emitting Diodes) and fluorescent lights (FLs). Leaf numbers of common sage under mixture LED and FL treatments were 134% and 98% greater, respectively than those in the greenhouse condition. In hooker chives, unfolded leaf numbers were 35% greater under the artificial lights and leaf elongation was inhibited by the conventional sunlight compared to the artificial light treatments. Absorption pattern of NO3-N composition in hydroponic solution was not affected by the different light qualities. CONCLUSION(S): Plant factory system with different light qualities could be applied for fresh-leaf production of common sage, nasturtium, and hooker chive plants culturing under field and/or greenhouse. Controlled light qualities in the system resulted in significantly higher hydroponic growth of the plants comparing to conventional greenhouse condition in present.

Low-resistance Transparent Plane Heating System using CVD Graphene (CVD 그래핀을 이용한 저저항 투명면상발열 시스템)

  • Yoo, Byongwook;Han, Sangsoo
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.3
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    • pp.218-223
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    • 2019
  • To prevent the low heating effect of heating system caused by the high sheet resistance of CVD graphene, multi-layered graphene was laminated to implement a Transparent plane heating system with good optical properties of low-resistance. Low-resistance plane heating system implemented by $300{\times}400{\times}5mm$ heating plane laminated multi-layered CVD graphene film and PWM control system to drive efficient power. A plane resistance value of $85.5{\Omega}/sq$ was measured on average for 4-layer CVD graphene film used as a heating plane. Thus, the transfer by thermal film as the method of implementing low-resistance CVD graphene is reasonable. The experimental results of heat test show that an average heat-rise rate in low-resistance, transperent plane heating system using CVD graphene is $10^{\circ}C/min$ and has an optical transmittance rate of 86.44%. Therefore, the proposed heating system is applicable to large window glass and vehicle heating window-shild-glass.

Study of the Reflector Shape of a Test Lamp for a Flame Detector with Little Influence of Error in Optical-system Fabrication (광학계 제작 시 오차 영향이 적은 불꽃감지기용 테스트램프 반사경 형상에 관한 연구)

  • Park, Hye-Jin;Kang, Dong-Hwa;Kong, Mi-Seon;Kim, Eun-Ji;Lee, Ye-Eun;Jo, Ye-Ji;Jung, Mee-Suk
    • Korean Journal of Optics and Photonics
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    • v.29 no.6
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    • pp.233-240
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    • 2018
  • In this paper, a design method to reduce fabrication errors in reflector shape of a test lamp for a flame detector is carried out. Although the test lamp should be operated in parallel with a high-intensity light, it is difficult to fix the small reflector that controls the central light during fabrication. To solve these problems, a small spherical reflector is designed to minimize the performance degradation for a light loss factor of less than 5%, even during tilt and decenter, and a spherical shape is proposed for a small reflector with little effect on the error when designing the optical system.

Evaluation of Oxidation Efficiency of Aromatic Volatile Hydrocarbons using Visible-light-activated One-Dimensional Metal Oxide Doping Semiconductor Nanomaterials prepared by Ultrasonic-assisted Hydrothermal Synthesis (초음파-수열합성 적용 가시광 활성 일차원 금속산화물 도핑 반도체 나노소재를 이용한 방향족 휘발성 탄화수소 제어효율 평가)

  • Jo, Wan-Kuen;Shin, Seung-Ho;Choi, Jeong-Hak;Lee, Joon Yeob
    • Journal of Environmental Science International
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    • v.27 no.11
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    • pp.967-974
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    • 2018
  • In this study, we evaluated the photocatalytic oxidation efficiency of aromatic volatile hydrocarbons by using $WO_3$-doped $TiO_2$ nanotubes (WTNTs) under visible-light irradiation. One-dimensional WTNTs were synthesized by ultrasonic-assisted hydrothermal method and impregnation. XRD analysis revealed successful incorporation of $WO_3$ into $TiO_2$ nanotube (TNT) structures. UV-Vis spectra exhibited that the synthesized WTNT samples can be activated under visible light irradiation. FE-SEM and TEM images showed the one-dimensional structure of the prepared TNTs and WTNTs. The photocatalytic oxidation efficiencies of toluene, ethylbenzene, and o-xylene were higher using WTNT samples than undoped TNT. These results were explained based on the charge separation ability, adsorption capability, and light absorption of the sample photocatalysts. Among the different light sources, light-emitting-diodes (LEDs) are more highly energy-efficient than 8-W daylight used for the photocatalytic oxidation of toluene, ethylbenzene, and o-xylene, though the photocatalytic oxidation efficiency is higher for 8-W daylight.

Durability Improvement of Functional Polymer Film by Heat Treatment and Micro/nano Hierarchical Structure for Display Applications (열처리와 복합구조화를 통한 디스플레이용 기능성 고분자 필름의 내구성 향상 연구)

  • Yeo, N.E.;Cho, W.K.;Kim, D.I.;Jeong, M.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.47-52
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    • 2018
  • In this study, the effects of the heat treatment and multi-scale hierarchical structures on the durability of the nano-patterned functional PMMA(Poly(methyl-methacrylate)) film was evaluated. The heat treatments that consisted of high-pressure/high-temperature flat pressing and rapid cooling process were employed to improve mechanical property of the PMMA films. Multi-scale hierarchical structures were fabricated by thermal nanoimprint to protect nano-scale structures from the scratch. Examination on surface structures and functionalities such as wetting angle and transmittance revealed that the preopposed heat treatment and multi-scale hierarchical structures are effective to minimize surface damages.

A study on the heat treatment effect upon luminous properties of oxy-fluoride glass doped with TiO2 (TiO2가 첨가된 oxy-fluoride 계 유리의 발광특성에 미치는 열처리 효과 연구)

  • Woo, Heesu;Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.6
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    • pp.232-236
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    • 2020
  • In this study, the optical properties of CaF2-Al2O3-B2O3-TiO2 (CABT) system glass doped with rare earth ion, that is used in various light devices due to its excellent luminous properties, were analyzed as a function of kind of crystal phases formed and size of crystals generated in the glass matrix. TiO2 was added to control nucleation and crystallization, and Eu2O3 was added to enhance the luminescence characteristics. DTA analysis was performed to confirm the heat treatment condition of crystal generation, and XRD and SEM anal ysis were carried out for the crystal phase change of nanometer size. As a result of the analysis, the luminous properties of oxy-fluoride-based glass were improved duo to crystallization of nanometer size, but was rather degraded when excessively large crystals were generated.