• Title/Summary/Keyword: 광색소

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Study on the Stability of Anthocyanin Pigment Extracted from Purple Sweet Potato (자색고구마 색소의 안정성에 관한 연구)

  • Lee, Lan-Sook;Rhim, Jong-Whan;Kim, Seon-Jae;Chung, Byeong-Chun
    • Korean Journal of Food Science and Technology
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    • v.28 no.2
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    • pp.352-359
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    • 1996
  • Stabilities of purple sweet potato (PSP) anthocyanin pigment on pH, sugars, organic acids, metal ions, ascorbic acid and light were investigated to provide the basic information for utilization of PSP as a potential source of anthocyanin pigment. pH has a marked influences on the color of the PSP anthocyanin solution; i.e., at low pH the color of PSP was more intense and stable. It showed characteristic bathochromic shift as the pH of the solution increased. Among the sugars tested, glucose showed a protective effect on the color of PSP pigment to raise the color intensity and stability, while sucrose and fructose showed an adverse effect. Addition of organic acids greatly increased the stability of PSP anthocyanin pigment. Citric acid was found to be the most effective followed by malic. tartaric, and succinic acids. Most metal ions except $Al^{3+}$ and $Cd^{2+} were found to be detrimental effect on the stability of PSP pigment. Ascorbic acid degraded PSP pigment considerably, and had a synergistic effect with oxygen on the pigment degradation. The effect of light on PSP pigment was found to be very deleterious. The pigment degradation can be minimized by shielding the light from the pigment solution.

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Dye Circulator System for Long-Term Operation of Dye Laser (색소 레이저의 장시간 동작을 위한 색소 순환기 시스템)

  • Im, Gwon;Jeong, Do-Yeong;Go, Do-Gyeong;Park, Seong-Hui;Kim, Yong-Gi;Cha, Byeong-Heon;Kim, Cheol-Jung
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.64-65
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    • 2002
  • 파장가변 색소 레이저는 고분해능 분광학, 이온화 분광학, 원격감시용 Lidar 시스템 또는 의료용 레이저 분야 등에서 널리 사용되고 있다. 특히, 의료용 안정동위원소를 생산하는 기술의 한 방법으로 파장가변 색소 레이저를 사용하고 있다. [1] 이러한 시스템의 레이저는 안정적 동작은 물론이고, 동위원소 추출의 생산 단가를 낮추기 위하여 레이저 동작을 연속적으로 할 필요가 있다. 그러나, 레이저 색소를 이득매질로 사용하는 파장가변 레이저는 광펌핑하여 레이저를 동작시키는데, 이 때 광표백효과 및 색소수명감소에 따라서 색소 용액의 교체가 필수적이다. (중략)

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EFFECT OF LIGHT IRRADIATION MODES ON THE MARGINAL LEAKAGE OF COMPOSITE RESIN RESTORATION (광조사 방식이 복합레진 수복물의 변연누출에 미치는 영향)

  • 박은숙;김기옥;김성교
    • Restorative Dentistry and Endodontics
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    • v.26 no.4
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    • pp.263-272
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    • 2001
  • The aim of this study was to investigate the influence of four different light curing modes on the marginal leakage of Class V composite resin restoration. Eighty extracted human premolars were used. Wedge-shaped class Y cavities were prepared on the buccal surface of the tooth with high-speed diamond bur without bevel. The cavities were positioned half of the cavity above and half beyond the cemento-enamel junction. The depth, height, and width of the cavity were 2 mm, 3 mm and 2 mm respectively. The specimens were divided into 4 groups of 20 teeth each. All the specimen cavities were treated with Prime & Bond$^{R}$ NT dental adhesive system (Dentsply DeTrey GmbH, Germany) according to the manufacturer's instructions and cured for 10 seconds except group VI which were cured for 3 seconds. All the cavities were restored with resin composite Spectrum$^{TM}$ TPH A2 (Dentsply DeTrey GmbH, Germany) in a bulk. Resin composites were light-cured under 4 different modes. A regular intensity group (600 mW/${cm}^2$, group I) was irradiated for 30 s, a low intensity group (300 mW/${cm}^2$, group II) for 60 s and a ultra-high intensity group (1930 mW/${cm}^2$, group IV) for 3 s. A pulse-delay group (group III) was irradiated with 400 mW/${cm}^2$ for 2 s followed by 800 mW/${cm}^2$ for 10 s after 5 minutes delay. The Spectrum$^{TM}$ 800 (Dentsply DeTrey GmbH, Germany) light-curing units were used for groups I, II and III and Apollo 95E (DMD, U.S.A.) was used for group IV. The composite resin specimens were finished and polished immediately after light curing except group III which were finished and polished during delaying time. Specimens were stored in a physiologic saline solution at 37$^{\circ}C$ for 24 hours. After thermocycling (500$\times$, 5-55$^{\circ}C$), all teeth were covered with nail varnish up to 0.5 mm from the margins of the restorations, immersed in 37$^{\circ}C$, 2% methylene blue solution for 24 hours, and rinsed with tap water for 24 hours. After embedding in clear resin, the specimens were sectioned with a water-cooled diamond saw (Isomet$^{TM}$, Buehler Co., Lake Bluff, IL, U.S.A.) along the longitudinal axis of the tooth so as to pass the center of the restorations. The cut surfaces were examined under a stereomicroscope (SZ-PT Olympus, Japan) at ${\times}$25 magnification, and the images were captured with a CCD camera (GP-KR222, Panasonic, Japan) and stored in a computer with Studio Grabber program. Dye penetration depth at the restoration/dentin and the restoration/enamel interfaces was measured as a rate of the entire depth of the restoration using a software (Scion image, Scion Corp., U.S.A.) The data were analysed statistically using One-way ANOVA and Tukey's method. The results were as follows : 1. Pulse-Delay group did not show any significant difference in dye penetration rate from other groups at enamel and dentin margins (p>0.05) 2. At dentin margin, ultra-high intensity group showed significantly higher dye penetration rate than both regular intensity group and low intensity group (p<0.05). 3. At enamel margin, there were no statistically significant difference among four groups (p>0.05). 4. Dentin margin showed significantly higher dye penetration rate than enamel margin in all groups (p<0.05).

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Photostability of Anthocyanin Extracted from Purple-Fleshed Sweet Potato (자색고구마에서 추출한 anthocyanin의 광안정성)

  • Rhim, Jong-Whan;Lee, Jang-Wook
    • Korean Journal of Food Science and Technology
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    • v.34 no.2
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    • pp.346-349
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    • 2002
  • Effect of EDTA, gallic acid, phosphoric acid, propyl gallate and sodium ascorbate on the photostability of anthocyanin extracted from purple-fleshed sweet potato were investigated by measuring the absorbance at 530 nm with a spectrophotometer. White light of 20,000 lux was used to illuminate the pigment and the temperature was $20^{\circ}C$. EDTA and sodium ascorbate were more effective in improving the photostability of the pigment when added at least 100 or 1,000 ppm, respectively.

Characterization of CW Ring Dye Laser (연속발진 고리형 색소레이저의 동작특성 연구)

  • 김재완
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.06a
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    • pp.65-65
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    • 1991
  • 레이저 분광학의 연구에 있어서 고출력이며 좁은 선폭인 레이저광이 요구된다. 특히 고리형 공진기 레이저는 이득물질에서 공간 홀 버닝 효과 (Spatial Hole Burning effect)를 줄이거나 없앨수 있으므로 정상파로 발진하는 레이저에 비하여 높은 출력의 단일모드 발진을 얻을 수 있다. 8자형 고리 공진기 레이저에서 외부 되반사경과 코팅되지않은 에탈론의 조합을 사용하여 높은 출력의 단일모드를 얻었다. 색소분자의 에너지 준위를 2준위 구조로 가정하여 고리형 색소레이저에 있어서의 단일모드 발진의 안정성(Stability)을 살펴보았으며 양방향으로 단일모드 발진을 하는 경우에 있어서의 쌍안정(Bistability) 상태를 확인하였다.

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Characteristics of the Conversion Pigment from Gardenia jasminoides Yellow Pigment (치자황색소로부터 변환된 색소의 특성)

  • Jeong, Hyung-Seok;Park, Keun-Hyung
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.319-323
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    • 1998
  • Conversion of Gardenia jasminoides yellow pigment into blue-green pigment by 8 bacterial species was examed. Bioconversion pattern can be categorized into three types according to absorption spectra characteristics. The same pattern of the value of ${\Delta}E$ estimated by color differencemeter was also observed. Conversion rate by S. epidermidis was faster than other bacterial species. It took 16 hour for S. epidermidis to convert pigment at $37^{\circ}C$. Gardenia jasminoides yellow pigment and conversion pigment were completely separated by Amberlite XAD column chromatography with $H_2O-MeOH$ solvent system. Storage stability of the conversion pigment was better than Gardenia jasminoides yellow pigment.

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Stability of Monascus Pigment Produced by Monascus sp. MK2 (Monascus sp. MK2 균주가 생산하는 홍국색소의 안정성)

  • Jeon, Chun-Pyo;Lee, Jung-Bok;Kwon, Gi-Seok
    • Journal of Life Science
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    • v.23 no.5
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    • pp.669-675
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    • 2013
  • The stability of monascus pigment produced by Monascus sp. MK2 was investigated according to light, pH, temperature, organic acid, synthetic antioxidant, and natural substance. The light stability was increased (sun light < fluorescent lamp < ultraviolet rays < dark condition) when storing the monascus pigments. Although the monascus pigments were stable in the range of pH 3.0, the degradation rate of pigment was increased at pH 11.0. The stability of monascus pigment gradually decreased as temperature increased. In addition, pigment stability was increased by adding the synthetic antioxidant and natural substance.

고효율 색소결합 유-무기 하이브리드 레이저 재료의 제조와 특성평가

  • Gwak, Seung-Yeon;Yang, Seung-Cheol;Kim, Jae-Hong;Lee, Gang-In;Lee, Jong-Hun;Bae, Byeong-Su
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.57.1-57.1
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    • 2010
  • 레이저 색소 분자간의 회합을 막음으로써 높은 레이저 효율을 갖는 고체 색소 레이저를 제조하기 위해 레이저 색소인 DCM을 유-무기 하이브리드 재료에 화학적으로 결합시켰다. 수산화기를 기능기로 갖는 DCM을 합성하여 이를 솔-젤반응의 전구체로 활용하였다. 유기실란을 DCM과 함께 솔-젤반응을 시킴으로써 DCM이 결합된 유무기 하이브리드 재료를 제조하였다. DCM이 결합된 유-무기 하이브리드 재료는 유기물과 무기물의 특성을 각각 갖고 있기 때문에 용액공정을 통해 고체 색소 레이저를 단시간에 제작할 수가 있을 뿐만 아니라 열적 및 광학적으로 우수한 특성을 보여주었다. Nd:YAG 레이저를 여기광으로 이용하여 DCM이 결합된 유-무기 하이브리드 재료의 레이저 효율을 측정하여 DCM을 유기용매에 녹인 색소 레이저의 레이저 효율과 비교하였다. DCM이 결합된 유-무기 하이브리드 재료는 DCM의 농도가 높아질 수록 유기용매를 이용한 색소 레이저에 비해서 더 높은 레이저 효율을 가지는 것을 관찰하였다. 이는 DCM이 결합된 유-무기 하이브리드 재료에 각각의 DCM 분자가 실록산 망목구조와 화학적으로 결합이 되어있기 때문에 하이브리드 재료에 안정적으로 존재할 수 있게 되고 망목구조에 둘러쌓여 분자간의 회합이 방지되는 효과를 가지게 되기 때문이다.

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Characterictics and Stability of Anthocyanin Pigment Extracted from Purple-Fleshed Potato (자색감자 Anthocyanin 색소의 특성 및 안정성)

  • Rhim, Jong-Whan;Kim, Seon-Jae
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.348-355
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    • 1999
  • Effects of pH, sugars, organic acids, metal ions, ascorbic acid and light on the stability of anthocyanin pigment extracted from purple-fleshed potato (Solanum tuberosum L.) were studied. The pH had marked influences on the color of the potato anthocyanin pigment: i.e., the lower the pH of the anthocyanin solution was, the more stable and intenser of the pigment was. It showed characteristic bathochromic shift as the pH of the solution increased. Generally, the addition of sugars into the purple-fleshed potato anthocyanin solution caused decrease in color stability of the pigment. Among the sugars tested, maltose was the most deleterious followed by sucrose, galactose, fructose and glucose. The addition of organic acids greatly increased the stability of the pigment. Malic acid was found to be the most effective in stabilizing the pigment followed by tartaric, citric and succinic acids, while malonic acid was found to be deteriorative to the stability of the pigment. Most metal ions except $Cu^{2+}$ increased stability of the pigment-especially, $Cd^{2+}\;and\;Al^{3+}$ were more effective than the others. Ascorbic acid degraded the pigment considerably, but the adverse effect was diminished by adding thiourea. Light gave an adverse effect to the stability of the purple-fleshed potato anthocyanin pigment, which could be minimized by shielding the light from the pigment.

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