• Journal of the Mineralogical Society of Korea
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• v.16 no.4
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• pp.283-293
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• 2003

Domestic water treatment plants operate the rapid and slow filtering system using the filtering sands. Most of them are composed of beach sands, which have less sorption capacity of heavy metals as well as organic contaminants. Therefore, the development of fortified functional filtering materials with high removal capacity of organic and inorganic contaminants is needed to prevent the unexpected load of contaminated source water. This study aims to test the hydrochemical change and the removing capacity of heavy metals such as Cd, Cu, and Pb on the Jumunjin sand, feldspathic sand(weathering product of Jecheon granite), feldspathic mixing sand I(feldspathic sand mixed with 10 wt% zeolite), and feldspathic mixing sand II (feldspathic sand mixed with 20 wt% zeolite). Feldspathic mixing sand I and II showed the eruption of higher amounts of cations and anions compared with the Jumunjin sand and feldspathic sand. They also showed higher eruption of Si, Ca, $SO_4$ ions than that of Al, $NO_3$, Fe, K, Mg, and P. Feldspathic mixing sand II caused higher eruption of some cations of Na, Ca, Al than feldspathic mixing sud I, which is the result controlled by the dissolution of zeolite. Jumunjin sand and feldspathic sand showed very weak sorption of Cd, Cu and Pb. In contrast to this, feldspathic mixing sand I and II showed the high sorption and removal capacity of the increasing order of Cd, Cu and Pb. Feldspathic mixing sand II including 20% zeolite showed a fortified removal capacity of some heavy metals. Therefore, feldspathic mixing sand mixed with some contents of zeolite could be used as the fortified filtering materials for the water filtering and purification in the domestic water treatment plants.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.3
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• pp.97-105
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• 2006

The autogenous shrinkage of high-performance concrete is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of high-performance concrete with admixture and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the type and contents of admixture and water-cement ratio is fixed with 30%. The autogenous shrinkage of HPC with fly ash slightly decreased than that of OPC concrete, but the use of blast furnace slag increased the autogenous shrinkage. Also, the autogenous shrinkage of HPC is found to decrease with increasing shrinkage reduction agent and expansive additive. A prediction equation to estimate the autogenous shrinkage of HPC with admixture was derived and proposed in this study. The proposed equation show reasonably good correlation with test data on autogenous shrinkage of HPC with mineral and chemical admixture.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.102-110
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• 2004

Recently, production cost of ready mixed concrete(remicon) has been increased due to the rising cost of raw materials such as cement and aggregate etc. cause by the upturn of oil price and increase of shipping charge. The delivery cost of remicon companies, however, has been decreased owing to their excessive competition in sale. Consequently, remicon companies began to manufacture the concrete by mixing ground granulated blast furnace slag(GGBF) in order to lower the production cost. Therefore, the objective of this study was to predict 28-day strength of GGBF slag concrete by early strength(1 day-strength, 7 day-strength) for the sake of managing with ease the quality of remicon. In experimental results, the prediction equation for 28 day-strength of GGBF slag concrete could be produced through the linear regression analysis of early strength and 28 day-strength. In order to acquire the reliability, all mixture were repeated as 3 times and each mixture order was carried out by random sampling. The prediction equation for 28 day-strength of GGBF slag concrete by 1-day strength(hot-water method) won the good reliability.

• Journal of the Korea Concrete Institute
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• v.20 no.3
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• pp.307-315
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• 2008

In this study, it is investigated the properties of high strength concrete using mineral admixture, on the purpose of use of meta kaolin for the substitutive materials to silica fume which is so expensive. The plain mixtures are 3 degrees which are ordinary portland cement, blast furnace slag cement and OPC included fly ash 20%, and silica fume and meta kaolin are substituted for the each plain mixtures in the range of 20%. The results of experiment showed as follows. In case of silica fume was only used, the viscosity and slump flow of fresh concrete were much decreased, on the contrary air content increased. But as usage of meta kaolin increased, to being increase the viscosity of fresh concrete, slump flow increased and air content and usage of super-plasticizer were decreased. Accordingly the workabilities of concrete were against tendency between silica fume and meta kaolin. The compressive strength, velocity of ultrasonic pulse and unit weight were increased according to usage of meta kaolin, the properties of hardened concrete were judged that they are affected with air content of fresh concrete, so it is very important to control air content of high strength concrete. Therefore, the use of meta kaolin is prospected to the substitutive material of silica fume, in case of using silica fume and meta kaolin, it is judged that the optimum usage of silica fume and meta kaolin is about 10% respectively, considering workability and strength of concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.91-98
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• 2009

Recently, production cost of ready mixed concrete has been increased due to the rising cost of raw materials such as cement and aggregate etc. cause by the upturn of oil price and increase of shipping charge. The delivery cost of ready mixed concrete companies, however, has been decreased owing to their excessive competition in sale. Consequently, ready mixed concrete companies began to manufacture the concrete by mixing ground granulated blast furnace slag(GGBF) and fly-ash in order to lower the production cost. Therefore, the objective of this study was to predict 28 days strength of GGBF slag concrete by early strength(warm and hot water curing method) for the sake of managing with ease the quality of ready mixed concrete. In experimental results, the prediction equation for 28 days compressive strength of GGBF slag concrete could be produced through the linear regression analysis of early strength and 28 days strength. In order to acquire the reliability, all mixture were repeated as 3 times and each mixture order was carried out by random sampling. The prediction equation for 28 days strength of GGBF slag concrete by 1 day compressive strength(accelerated testing) according to warm and hot water curing method won the good reliability.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.94-101
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• 2016

This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.313-323
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• 1998

Fluidity retention of concrete used high range water reducing AE agent(HWAE) is varied according to main component, dosage amount and dosing method of HWAE. The type and substitution ratio of mineral admixture also have influence on the fluidity retention of concrete used HWAE. In this study, for the purpose of improving the fluidity retention in concrete used HWAE. 3 types of HWAE and ground granulated blast furnace slag(SG) are used in cement paste, mortar and concrete varing dosage amount and dosing time of HWAE and substitution ratio of SG respectively. According to using the HWAE of naphthalene sulfonates and SG, the fluidity retention of mortar and concrete is improved remarkably. And after 30 min, dosing method of HWAE is very effective in improving the fluidity retension and strength of concrete regardless of type of HWAE.

• Journal of the Society of Disaster Information
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• v.9 no.4
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• pp.469-475
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• 2013

The purpose of this experimental research is to estimate compressive strength and resistance to freezing and thawing of recycled aggregate concrete containing ground granulated blast furnace slag. For this purpose, concrete specimens according to substitution ratio of recycled aggregate were made for different replacement ratio of ground granulated blast furnace slag(GGBFS), and then compressive strength and resistance to freezing and thawing were evaluated for those. It was observed from the test results that compressive strength at 28 days of recycled aggregate concrete containing GGBFS of 20% was much more excellent than plain concrete and when air content of concrete was maintained 4 to 6%, influence of substitution ratio of recycled aggregate and replacement ratio of GGBFS on resistance to freezing and thawing was little up to 300 cycles of freezing and thawing.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.409-419
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• 2002

Nowadays, antiwashout underwater concrete is widely used for constructing underwater concrete structures but they, especially placed in marine environment, can be easily attacked by chemical ions such as SO$\^$2-/$\_$4/ Cl$\^$-/ and Mg$\^$2＋/, so the quality and capability of concrete structures go down. In this paper, to solve and improve those matters, flyash and GGBFS(ground granulated blast furnace slag) were used as partial replacements for ordinary portland cement. As results of experiments for fundamental properties of antiwashout underwater concrete containing 10, 20, 30％ of flyash and 40, 50, 60 ％ of GGBFS respectively, setting time, air contents, suspended solids and pH value were satisfied with the "Standard Specification of Antiwashout Admixtures for Concrete" prescribed by KSCE, and also slump flow, efflux time and elevation of head were more improved than that of control concrete. From the compressive strength test, it was revealed that the antiwashout underwater concrete containing mineral admixtures(flyash and GGBFS) is more effective for long term compressive strength than control concrete. An attempt to know how durable when they are under chemical attack has also been done by immersing in chemical solutions that were x2 artificial seawater, 5 ％ sulphuric acid solution, 10％, sodium sulfate solution and 10％ calcium chloride solution. After immersion test for 91days, XRD analysis was carried out to investigate the reactants between cement hydrates and chemical ions and some crystalline such as gypsum ettringite and Fridel′s salt were confirmed.

• Journal of The Korean Society of Agricultural Engineers
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• v.54 no.5
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• pp.25-34
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• 2012

It has been well known that concrete structures exposed to acid and sulfate environments such as sewer etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to cement mortar by forming expansive hydration products due to the reaction between cement hydration products and acid and sulfate ions. In this study, the effect of fly ash and blast furnace slag on the bond performances of structural synthetic fiber in latex modified cement mortar under sulfate environments. Fly ash and blast furnace slag contents ranging from 0 % to 20 % are used in the mix proportions. The latex modified cement mortar specimens were immersed in fresh water, 8 % sodium sulfate ($Na_2SO_4$) solutions for 28 and 50 days, respectively. Pullout tests are conducted to measure the bond performance of structural synthetic fiber from latex modified cement mortar after sulfate environments exposure. Test results are found that the incorporation of fly ash and blast furnace slag can effectively enhance the PVA fiber-latex modified cement mortar interfacial bond properties (bond behavior, bond strength and interface toughness) after sulfate environments exposure. The microstructural observation confirms the findings on the interface bond mechanism drawn from the fiber pullout test results under sulfate environments.