• The Journal of the Petrological Society of Korea
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• v.14 no.3 s.41
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• pp.141-148
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• 2005

Lead isotopic compositions are analyzed from the sulfide minerals of the Yeonhwa, Janggun and Uljin deposits and from host limestone, intrusives, and basement rocks to reveal the source of Pb in these deposits. In the $^{206}Pb/^{204}Pb$ vs $^{207}Pb/^{204}Pb$ plot, Galenas from the Yeonhwa mine display relatively well defined positive linear array, similar to the Precambrian basement rocks of the Korean peninsula. A galena sample from the Uljin mine, Janggun limestone and the basement rocks also follow the variation of Yeonhwa mine. However, ore minerals from the Janggun mine, having relatively low $^{206}Pb/^{204}Pb$ values, reveal offset from such trend toward lower $^{207}Pb/^{204}Pb$ values. Considering the fact that Mesozoic igneous rocks and ores within the Gyeongsang basin display considerably lower $^{207}Pb/^{204}Pb$ values than basement rocks of the Korean peninsula, the deviation of Janggun ore minerals can be interpreted as to reflect mixing between leads from old continental crustal materials and from Mesozoic igneous rocks with more mantle signature. The lead of the Yeonhwa and Uljin mine, following trend of Precambrian basement rather well, seems to have been originated mostly from such basement. However, regarding that they occupy low $^{207}Pb/^{204}Pb$ side of the variation trend of the basement, the possibility of having some leads derived from the Mesozoic igneous rocks cannot be excluded.

• Journal of the Mineralogical Society of Korea
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• v.29 no.3
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• pp.141-153
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• 2016

The Manjang deposit is emplaced in Hwajeonri formation comprising limestone that is interbeded with slate and phyllite in the central Okcheon Group. It consists of the Main and the Central orebody of Cu-bearing hydrothermal vein deposit and the Western orebody of iron skarn deposit. Based on coexisting mineral assemblage the skarnization can be divided into prograde skarnization (stage I : clinopyroxene ${\pm}$ magnetite ${\pm}$ quartz, stage II : garnet + clinopyroxene ${\pm}$ magnetite ${\pm}$ quartz) and retrograde hydrothermal alteration (stage III: magnetite + amphibole + quartz ${\pm}$ garnet ${\pm}$ clinopyroxene ${\pm}$ chlorite ${\pm}$ epidote ${\pm}$ fluorite ${\pm}$ calcite, stage IV: fluorite ${\pm}$ pyrrhotite ${\pm}$ chalcopyrite ${\pm}$ amphibole ${\pm}$ quartz ${\pm}$ calcite). Diopside is abundant in stage I, and hedenbergite was produced in stage II and III. Garnet compositions change from grandite to andradite, which suggests a redox transition from relatively reduced to oxidized condition during the skarn formation. Magnetite in stage I and II has relatively constant Fe contents, while in the stage III it has increased Si and Ca concentrations. This variation could indicate that magnetite was more strongly affected by host rocks during the retrograde stage. Sulfur isotope compositions of pyrrhotite and chalcopyrite produced in stage IV are within the range of + 5.9~6.9 ‰, corresponding to igneous origin, but slightly high sulfur isotope values could be attributed to an interaction with host rocks, limestone.

• Economic and Environmental Geology
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• v.26 no.1
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• pp.29-40
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• 1993

Several vermiculite deposits occur as the alteration product from phlogopite in ultramafic rock, in the Hongseong and Cheongyang area, South Korea. Some quarries show well-defined weathering profile. Samples collected from those quarries were examined by XRD and chemistry to define a vertical variations in mineralogy and chemistry of the weathering profile developed on ultramafic rocks. The analysis by X-ray diffractometry showed that mineral compositions changed continuously as depth of profile increasing, the vermiculite-the phlogopite/vermiculite interstratified-the phlogopite. Chemical analysis of bulk samples in altered zone revealed that regardless of composition and kinds of mineral in the rock, there are significant increase of MgO, CaO and $H_2O$, and decrease of K as depth of profile decrease reflecting the characteristics in vermiculitization. Also, there was a tendency that weathering indicies of each sample horizon change gradually with increasing depth. This tendency can be explained as variations of degree of vermiculitization. The regular changes of mineralogical and chemical composition in vertical profile suggest that weathering is the most important process in vermiculitization in this area.

• Journal of the Korean Geotechnical Society
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• v.27 no.10
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• pp.35-43
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• 2011

The area to be studied is the place where the main line rail way will be constructed in accordance with the scheduled construction project of Yeongju dam, and is a fold and mylonite zone over several km that is formed by ductile-shearing effect. The ductile shear zone, which has been transformed by faulting for long geological time, shows a complicated geological structure. Due to the recrystallization of mineral caused by transformation in deep underground (>8km), a mylonite zone with lamellar structure has properties distinguished from other fault zones formed by transformation near earth surface <2km). To see the properties of mylonite, this study analyzed the transformation rate of sample rocks and the shape of constriction structure accompanied with transformation. While the transformation of fault zone shows a round oblate, the mylonite zone shows a prolate form. Transformation rate in fault zone was measured to be less than 1.2 compared to the state before transformation while the measured rate in mylonite zone was 2.5 at most. Setting the surface of discontinuity as the base, the unconfined compressive strength of slickenside can be categorized in sedimentary rocks, and a change of strength was observed after water soaking over certain time. Taking into account that the weathering resistance of the rock based on mineral and chemical organization is relatively higher, its engineering properties seems to result from the shattered crack structure by crushing effect. When undertaking tunnel construction in mylonite zone, there should be a special care for the expansion of shattered cracks or the fall of strength by influx of ground water.

• The Korean Journal of Petroleum Geology
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• v.7 no.1_2 s.8
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• pp.28-34
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• 1999

The Cretaceous Poongam sedimentary Basin in Kangwon-do, Korea consists alluvial deposits of conglomerates, sandstones, mudstones or siltstones, and volcaniclastics. The Poongam Basin was formed as a fault margin sag or a transpressional basin developed along a strike-slip fault zone, and received huge amount of clastic sediments from the adjacent fault-scaip. It formed an aggrading alluvial fan system and a volcaniclast-supplied marginal lake environment, while tectonic activity and volcanism attenuated toward the end of basin formation. Following the Folk's classification, the sandstones of the Poongam Basin are identified as lithic wackes or feldspathic wackes. The areal and sequential variation of the mineral composition in the sandstones is not distinct. The results of K-Ar age dating from the intruding andesites, volcaniclastics and volcanic fragments in sedimentary rocks show a range of 70 Ma to 84 Ma. It suggests that volcarism occurred sequentially within a relatively short period as the pre-, syn-, and post-depositional events. It was the short period in the late Cretaceous that the basin had evolved i.e., the basin formation, the sediment input and fill, and the , intrusion and extrusion of volcanic rocks occurred. The Poongam sedimentary sequence is a typical tectonic-controlled coarse sedimentary facies which is texturally immature.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.493-507
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• 2018

The Wooseok deposit in Jecheon belongs to the Hwanggangri Mineralized Distict of the northeastern Ogcheon Metamorphic Belt. Its geology consists mostly of limestone of the Choseon Supergroup and the Cretaceous Muamsa granite intruded at the eastern area of the deposit. The deposit shows vertical occurrence of skarn and hydrothermal vein ores with W-Mo-Fe and Cu-Pb-Zn mineralization and skarn is developed only at lower levels of the deposit. Skarn minerals are replaced or cut by ore minerals in paragenetic sequence of magnetite-hematite, molybdenite-scheelite-wollframite, and higher abundances of pyrrhotite-chalcopyrite-pyrite-sphalerite-galena. Garnet has chemical compositions of $Ad_{65.9-97.8}Gr_{0.3-32.0}Pyr_{0.9-3.0}$, corresponding to andradite series, and pyroxene compositions are $Hd_{4.5-49.7}Di_{42.3-93.9}Jo_{0.5-7.9}$, prevailing in diopside compositions, both of which suggest oxidized conditions of skarnization. On the FeS-MnS-CdS ternary diagram, FeS contents of sphalerite in vein ores decrease with increasing MnS contents from bottom to top levels, possibly relating to W mineralization in deep and Pb-Zn mineralization in shallow level. Sulfur isotope values of sulfide minerals range from 5.1 to 6.8‰, reflecting magmatic sulfur affected by host rocks. W-Mo skarn and Pb-Zn vein mineralization in the Wooseok deposit were established by spatio-temporal variation of decreasing temperature and oxygen fugacity with increasing sulfur fugacity from bottom to top levels.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.5
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• pp.342-351
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• 2014

The present paper investigates the performance of direct wet mineral carbonation technology to fix carbon dioxide ($CO_2$) from relatively high $CO_2$ concentration feeding gas using wollastonite ($CaSiO_3$)-water (and 0.46 M acetic acid) suspension solution. To minimize the energy consumed on the process, the carbonation in this work is carried out at atmospheric pressure and slightly higher room temperature. As a result, carbon fixation is confirmed on the surface of $CaSiO_3$ after carbonation with wollastonite-water suspension solution and its amount is increased according to the $CO_2$ composition in the feeding gas. The leaching and carbonation ratio of wollastonite-water suspension system obtained from the carbonation with 50% of $CO_2$ composition feeding gas is 13.2% and 10.4%, respectively. On the other hand, the performance of wollastonite-acetic acid in the same condition is 63% for leaching and 1.39% for carbonation.

• Economic and Environmental Geology
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• v.25 no.4
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• pp.417-433
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• 1992

Lead-zinc-copper deposits of the Jeonheung and the Oksan mines around Euiseong area occur as hydrothermal quartz and calcite veins that crosscut Cretaceous sedimentary rocks of the Gyeongsang Basin. The mineralization occurred in three distinct stages (I, II, and III): (I) quartz-sulfides-sulfosalts-hematite mineralization stage; (II) barren quartz-fluorite stage; and (III) barren calcite stage. Stage I ore minerals comprise pyrite, chalcopyrite, sphalerite, galena and Pb-Ag-Bi-Sb sulfosalts. Mineralogies of the two mines are different, and arsenopyrite, pyrrhotite, tetrahedrite and iron-rich (up to 21 mole % FeS) sphalerite are restricted to the Oksan mine. A K-Ar radiometric dating for sericite indicates that the Pb-Zn-Cu deposits of the Euiseong area were formed during late Cretaceous age ($62.3{\pm}2.8Ma$), likely associated with a subvolcanic activity related to the volcanic complex in the nearby Geumseongsan Caldera and the ubiquitous felsite dykes. Stage I mineralization occurred at temperatures between > $380^{\circ}C$ and $240^{\circ}C$ from fluids with salinities between 6.3 and 0.7 equiv. wt. % NaCl. The chalcopyrite deposition occurred mostly at higher temperatures of > $300^{\circ}C$. Fluid inclusion data indicate that the Pb-Zn-Cu ore mineralization resulted from a complex history of boiling, cooling and dilution of ore fluids. The mineralization at Jeonheung resulted mainly from cooling and dilution by an influx of cooler meteoric waters, whereas the mineralization at Oksan was largely due to fluid boiling. Evidence of fluid boiling suggests that pressures decreased from about 210 bars to 80 bars. This corresponds to a depth of about 900 m in a hydrothermal system that changed from lithostatic (closed) toward hydrostatic (open) conditions. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S=2.9{\sim}9.6$ per mil) indicate that the ${\delta}^{34}S_{{\Sigma}S}$ value of ore fluids was ${\approx}8.6$ per mil. This ${\delta}^{34}S_{{\Sigma}S}$ value is likely consistent with an igneous sulfur mixed with sulfates (?) in surrounding sedimentary rocks. Measured and calculated hydrogen and oxygen isotope values of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values. Equilibrium thermodynamic interpretation indicates that the temperature versus $fs_2$ variation of stage I ore fluids differed between the two mines as follows: the $fs_2$ of ore fluids at Jeonheung changed with decreasing temperature constantly near the pyrite-hematite-magnetite sulfidation curve, whereas those at Oksan changed from the pyrite-pyrrhotite sulfidation state towards the pyrite-hematite-magnetite state. The shift in minerals precipitated during stage I also reflects a concomitant $fo_2$ increase, probably due to mixing of ore fluids with cooler, more oxidizing meteoric waters. Thermodynamic consideration of copper solubility suggests that the ore-forming fluids cooled through boiling at Oksan and mixing with less-evolved meteoric waters at Jeonheung, and that this cooling was the main cause of copper deposition through destabilization of copper chloride complexes.

• Journal of the Korea Institute of Building Construction
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• v.12 no.3
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• pp.284-290
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• 2012

Cement Fineness Modulus (CFM) is a method of expressing the distribution of particle sizes of cement in numeric form. If CFM is controlled through crush process of cement without modifying the chemical components or mineral composition of cement, it is judged to be able to produce a cement satisfying various requirements because it is estimated to enable various approaches to cement such as high early strength, moderate heat, low heat cement and so on. Therefore, in this study, as basic research for manufacturing special cement utilizing the controls of CFM, the intention was to review the impacts of CFM on the fundamental properties of concrete. To summarize the result, as mixture characteristics of fresh concrete, ratio of small aggregate and unit quantity were gradually increased, securing greater fluidity, with an increase in CFM, while the amount of AE and SP were reduced gradually. In addition, setting time was delayed as CFM increased. Furthermore, compression strength was relatively high during initial aging as CFM became smaller, but as time passed, compression strength became smaller, and it showed the same level of strength as aging time passed about three years.

• Economic and Environmental Geology
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• v.56 no.5
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• pp.581-588
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• 2023

This study reports depth-dependent elemental distribution and mineral abundance of the oceanic sediment sample (WP21GPC04) near the Mariana Trench collected during the WP21 expedition in 2021. The elemental distribution determined by μ-XRF shows no significant differences with varying depth, with an average SiO₂ 53.91 wt%, FeO 4.48 wt%, Al₂O₃ 16.56 wt%, MgO 2.56 wt%, CaO 4.79 wt%, Na₂O 3.52 wt%, K₂O 5.48 wt%, similar to the average chemical composition of global subducting sediments (GLOSS). The mineral abundances analyzed using synchrotron XRD, however, vary with depth. While quartz, mica, and plagioclase were identified at all depths, chlorite was found at shallow depths, and zeolite group minerals, phillipsite and heulandite, showed a gradual change in phase fraction with depth. This suggests a change in sedimentation and alteration environments in the region, or the potential for coexistence emerges due to similar sediment stability. Overall, this study will provide a basis for the future investigations on the evolution of sedimentary environment near the Mariana Trench in the western Pacific Ocean and the phase distribution and the behavior of subducting oceanic sediments, which will affect the lithological and geochemical characteristics of the Mariana susduction system.