• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.327-333
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• 2022

In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF₆ (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.

• Korean Journal of Optics and Photonics
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• v.35 no.4
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• pp.143-149
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• 2024

We analyze the effect of atmospheric fluctuation on laser beam propagation, using a single-phase screen model and a multi-phase screen model. When a laser beam (wavelength 1064 nm, radius 10 mm, collimated by 25.4 mm optics) propagates 3 km, atmospheric fluctuation with structure constant C_n² in the range of 10^-17 to 10^-14 is generated by the single- and multi-phase screen models. The results of short-term and long-term exposures are analyzed in terms of the beam profile, power in the bucket, and beam radius at the receiver plane. The power in the bucket and beam radius increase as the structure constant increases. When the structure constant is less than 2×10^-15, the results of the single- and multi-phase screen models are similar, within a difference of 1.5 %. However, when the structure constant is greater than 2×10^-15, the difference between the two models increases, and the multi-phase screen model is appropriate under this condition.

• Korean Journal of Optics and Photonics
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• v.35 no.4
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• pp.150-156
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• 2024

One of the key factors in research regarding long-distance laser beam propagation, as in free-space optical communication or laser power transmission, is the transmission efficiency of the laser beam. As a way to improve efficiency, we perform extensive numerical simulations of the effect of modifying the laser beam's profile, especially replacing the fundamental Gaussian beam with a super-Gaussian beam. Numerical simulations of the transmitted power in the ideal diffraction-limited beam diameter determined by the optical system of the transmitter, after about 1-km propagation, reveal that the second-order super-Gaussian beam can yield superior performance to that of the fundamental Gaussian beam, in both single-channel and coherently combined multi-channel laser transmitters. The improvement of the transmission efficiency for a 1-km propagation distance when using a second-order super-Gaussian beam, in comparison with a fundamental Gaussian beam, is estimated at over 1.2% in the singlechannel laser transmitter, and over 4.2% and over 4.6% in coherently combined 3- and 7-channel laser transmitters, respectively. For a range of the propagation distance varying from 750 to 1,250 m, the improvement in transmission efficiency by use of the second-order super-Gaussian beam is estimated at over 1.2% in the single-channel laser transmitter, and over 4.1% and over 4.0% in the coherently combined 3- and 7-channel laser transmitters, respectively. These simulation results will pave the way for future advances in the generation of higher-order super-Gaussian beams and the development of long-distance optical energy-transfer technology.