• Title/Summary/Keyword: 광경화성

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A study on color characteristics of Multi-color functional Rapid Prototypes Using laser stereolithography (광조형을 이용한 다색 기능성 시작품의 색상특성에 관한 연구)

  • 조진구;정해도;손재혁;임용관
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.824-828
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    • 2000
  • As production cycle has become more and more shorter, the demand of rapid prototyping technology has increased largely. There are many methods for rapid prototyping technology, such as SLA. SLS, FDM. INK JET, LOM and so on. Of all methods, SLA has been most widely used for fabricating precision parts. But products manufactured by this method have limitation of single color and single material. So the principal purpose of this study is to overcome the limit of single color product. If the internal structure of manufactured product is visible with multi-color characteristic, it is possible to check easily the designed model with reality. In order to give multi-color characteristic to the product, photocurable resin mixed with pigment is used in this study. First, transparency of photocurable resin without pigment is evaluated, and then color characteristic and curing characteristic of the mixture is evaluated changing mixing ratio. Through the basic experiments, it becomes possible to fabricate multi-color 3D prototype without assembly.

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Study on Process Parameters of a SU-8 Resin in Two-photon Streolithography for the Fabrication of Robust Three-dimensional Microstructures (SU-8 레진을 이용한 이광자 흡수 광조형 공정에서 고강성 3 차원 마이크로 형상 제작을 위한 공정 변수 분석)

  • Son, Yong;Lim, Tae-Woo;Yi, Shin-Wook;Kong, Hong-Jin;Park, Sang-Hu;Yang, Dong-Yol
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.1
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    • pp.130-137
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    • 2008
  • Two-photon stereolithography (TPS) is recognized as a useful process for the fabrication of three-dimensional microstructures. Recently, the need for a two-photon curable resin with high strength increases as 3-D moicrostructures of high aspect ratio or large scale of several hundreds micrometers are required for applications of nano/micro devices in IT/BT. In this work, process parameters of TPS employing the SU-8 which is a representative two-photon curable resin with high strength have been studied for the precise fabrication of 3-D microstructures with high strength. The pre-baking and post-baking processes are studied and the parameter study of the SU-8 in TPS is conducted. Through this work, very small roughness of 12 nm and the minimum aspect ratio of ${\sim}1$ which provides a precise accumulation of layers could be obtained. Using the conditions studied in this work, some 3-D examples are fabricated.

A Study on Resin flow Analysis and Free Surface forming at Micro-stereolithography using a Dynamic Pattern Generator (동적 패턴 생성기를 이용한 마이크로 광 조형 시스템에서 수지 유동 해석 및 자유표면 형성에 관한 연구)

  • Won M.H.;Choi J.W.;Ha Y.M.;Lee S.H.;Kim H.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.878-881
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    • 2005
  • A Stereolithography technology is based on stacking of sliced layer from STL file that is converted from 3-dimensional CAD data. A microstereolithography technology is evolved from conventional stereolithography to fabricate microstructures. In this technology, we have to consider influence of resin flow to make refresh surface. To generate new resin surface, stage has to be moved downward deeply and upward to desired position. At this time, resin flow affects to refresh surface of resin. And resin viscosity is the key factor in simulation of resin flow. By setting optimal refresh time for resin surface, total fabrication time is reduced and there is no damage to fabricated layers. In this research, we simulate resin flow using CFD software and derive optimal stage moving time and dwelling time.

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Evaluation of flexural properties and reliability with photo-curing 3D printing resin according to the printing orientations (광경화성 3D 프린팅 레진의 출력각도에 따른 굽힘 특성과 신뢰성 평가)

  • Im, Yong-Woon;Song, Doo-Bin;Hwang, Seong-Sig;Kim, Sa-Hak;Han, Man-So
    • Journal of Technologic Dentistry
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    • v.43 no.1
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    • pp.13-18
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    • 2021
  • Purpose: This study aimed to compare the flexural properties and perform the Weibull analysis of photo-curing three-dimensional (3D) printing resin. Methods: Photo-curing temporary resin (3D polymer) was used as a printing resin. Specimens (65 × 10 × 3.3 ㎣) were prepared following the ISO 20975-1 guidelines and according to the different printing orientations using a digital light processing 3D printer (D2 120; Dentium). The flexural strength (FS), flexural modulus, and work of fracture (WOF) were measured using a universal testing machine (Instron 3344; Instron) at a crosshead speed of 5 mm/min. Results: In this study, the 0° orientation exhibited higher FS and WOF than the 45° orientation. Significant differences were found among the printing orientations (p<0.05). Specimens printed at the 0° orientation were the most accurate. In the Weibull analysis, 0° showed the greatest Weibull modulus (m), which represents a higher reliability. Conclusion: 3D printing should be selected and used by considering flexural properties, size accuracy, and reliability.

Rheological behavior and IPL sintering properties of conductive nano copper ink using ink-jet printing (전도성 나노 구리잉크의 잉크젯 프린팅 유변학적 거동 및 광소결 특성 평가)

  • Lee, Jae-Young;Lee, Do Kyeong;Nahm, Sahn;Choi, Jung-Hoon;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.5
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    • pp.174-182
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    • 2020
  • The printed electronics field using ink-jet printing technology is in the spotlight as a next-generation technology, especially ink-jet 3D printing, which can simultaneously discharge and precisely control various ink materials, has been actively researched in recent years. In this study, complex structure of an insulating layer and a conductive layer was fabricated with photo-curable silica ink and PVP-added Cu nano ink using ink-jet 3D printing technology. A precise photocured silica insulating layer was designed by optimizing the printing conditions and the rheological properties of the ink, and the resistance of the insulating layer was 2.43 × 1013 Ω·cm. On the photo-cured silica insulating layer, a Cu conductive layer was printed by controlling droplet distance. The sintering of the PVP-added nano Cu ink was performed using an IPL flash sintering process, and electrical and mechanical properties were confirmed according to the annealing temperature and applied voltage. Finally, it was confirmed that the resistance of the PVP-added Cu conductive layer was very low as 29 μΩ·cm under 100℃ annealing temperature and 700 V of IPL applied voltage, and the adhesion to the photo-cured silica insulating layer was very good.

Restoration and Stability of the Glass Sarira Bottle (Treasure No. 1925) from the Sarira Reliquaries Commissioned by Yi Seonggye, Excavated from Geumgangsan Mountain (보물 제1925호 금강산 출토 이성계 발원 사리장 엄구 내 유리제 사리병의 복원 및 안정성 연구)

  • Na, Ahyoung;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.26
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    • pp.25-34
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    • 2021
  • 3D printing technology has been actively applied for the restoration of cultural properties. However, its application to the restoration of glass cultural properties has not yet been reported and thus requires further study. In this study, 3D printing technology was used to restore a defective part of a glass sarira bottle that forms an element of a series of sarira reliquaries commissioned by Yi Seonggye (known as King Taejo after founding the Joseon Dynasty) that was excavated from Geumgangsan Mountain (designated as Treasure No. 1925) and is currently housed at the National Museum of Korea. The defective area was reproduced using 3D printing and the printed reproduction was reproduced again using an epoxy resin. This latter piece was used as the restoration component rather than the 3D printed element. After the completion of the conservation treatment, the materials used for the 3D printing were compared with transparent materials used to restore ceramics to evaluate their usability and stability. A total of five specimens were produced, including from photocurable resin made by a stereo lithography apparatus (SLA), epoxy resin, acrylic resin, and more. They were exposed to UV for 96 hours to test for yellowing. Of the two specimens made of photocurable resins and exposed to UV, one was sprayed with a UV blocking agent but the other was exposed as-is. The UV exposure test showed that the specimen made by the SLA and sprayed with a UV blocking agent and the specimen made of epoxy resin were stable in terms of yellowing with a change in the b-value was less than 1. They are thus considered to be suitable materials for the restoration of glass cultural properties. Such glass cultural properties are often diverse in shape and their restoration can be difficult as they generally consist of a range of complex parts that hamper restoration. In this regard, diverse materials should be considered when selecting materials for the restoration of glass cultural properties.

Determination of Processing Parameters Affecting the Conversion and Thermal Stability of Photocurable Acrylate-based Binder (아크릴계 광바인더의 전환율과 열안정성 향상을 위한 공정변수 결정)

  • Kim, Byungchul;Seo, Dong Hak;Chae, Heon-Seung;Shin, Seunghan
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.18-22
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    • 2012
  • Photocurable binder for a transparent glass fiber composite was prepared with alicyclic methacrylate and fluorene-based diacrylate. ANOVA (analysis of variance) analysis was used to know main factors affecting the conversion of photocurable binder. It showed radiation intensity and photoinitiator (PI) concentration were main factors. The conversion of photocurable binder was simply increased with radiation intensity. Its increment however was abated with increasing PI concentration. We found that average conversion of the binder measured by FTIR-ATR was 87% when it was exposed to $5J/cm^2$ of UV dose with 5 wt% of PI. Oxime ester type PI was very effective to get a high degree of conversion, but it caused a yellowing problem. Owing to post-baking process, UV cured film showed an improved thermal stability by increase of conversion and removal of volatile organic compounds. TG% at $260^{\circ}C$ of film cured with 5 wt% of PI (TPO+MBF) and $5J/cm^2$ of UV radiation increased from 95.4 to 99.0% by post-baking at $230^{\circ}C$ for 5 min.

Joining Characteristics of Corrugated Polymer Surface by Laser (표면 요철 처리 된 광경화성수지의 레이저 접합 특성)

  • Yoon, Sung Chul;Choi, Hae-Woon
    • Laser Solutions
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    • v.18 no.4
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    • pp.6-11
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    • 2015
  • Specially designed and 3D printed samples were prepared and joined by a diode laser source. To increase the strength of joining and reliability of samples, the surface was patterned by using a 3D printer. The joining surface was prepared as hemispherical shape with no-patterns, 0.5mm pitch, 0.75mm pitch and 1mm pitch. The optical properties of samples were measured by using an integrated sphere where classical Kubelka-Munk theory and modified Richard-Mudgetts theory for the analysis applied. Scanning speed was set at 500mm/min and laser power was varied between 9 and 10watts for the preliminary joining characteristic analysis.

A Study on Algorithm Development of Offset Data Generation in Stereolithography (광조형법에 있어서 OFFSET정보생성 알고리즘 개발에 관한 연구)

  • Kim, Jun-An;Hong, Sam-Nyol;Paik, In-Hwan
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.9
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    • pp.70-76
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    • 1996
  • In the Stereolithography process, three-dimensional objects are built by sequentially curing, generated by horizontal slicing of a three-dimensional CAD model. The dimensional accuracy of a menufactured part depends on the accuracy of curing performed by laser beam radius and the half of curing width. When offsetting, some slices have collinear segments, coincident vertices, line jerks and open loops. After remove above issues we have correct offsets data. And in last step, these data are used to scan paths.

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Compositions for Photosensitive Polymer Resistor Paste Using Epoxy Acrylates (에폭시 아크릴레이트를 이용한 감광성 폴리머 저항 페이스트 조성)

  • Kim, Dong Kook;Park, Seong-Dae;Lee, Kyu-Bok;Kyoung, Jin-Bum
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.157-163
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    • 2012
  • Using six kinds of epoxy acrylates and a conductive carbon black, photosensitive resistor pastes were fabricated and then their developability in alkaline aqueous solution and the resistance values after thermal curing were evaluated. In order to impart the photocurability by UV exposure and the developability on alkaline solution, epoxy acrylate oligomers with carboxyl group, acrylate monomers, a photoinitiator and so forth were used. In addition, an organic peroxide was added into the paste to get a thermally curable composition. As a result, some of the pastes were not developed depending on the kinds of oligomers and, in the developed pastes, the measured resistance showed the different values depending on their compositions, even though they contain the same amount of carbon black. Finally, the optimum oligomer was selected and then, by adjusting the amount of carbon black, the kind of monomer and the curing temperature, the photosensitive resistor paste composition which showed the sheet resistance of about 0.5 $k{\Omega}/sq.$ could be obtained.