• Resources Recycling
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• v.28 no.4
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• pp.23-29
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• 2019

In order to recover pure alumina from balck dross, precipiatation experiments were done to the NaOH leaching solution of mechanically activated black dross. In this work, hydrogen peroxide was added to the synthic solution as a precipitating agent. Among some variables, the concentration of $H_2O_2$ and the volume ratio of $H_2O_2$ to solution showed a remarkable effect on the precipitation of aluminum hydroxide. At the optimum conditions, most of the aluminate was precipitated. Calcination of the aluminum hydroxide at $1200^{\circ}C$ led to the formation of ${\theta}$ and ${\alpha}$-alumina. The charactistics of the synthesized activated alumina was measured by XRD and EDS. The average particles size of the alumina was $3.73{\mu}m$.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05b
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• pp.283-288
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• 1997

고 준위 방사성 액체 패기물의 옥살산 침전 공정을 통하여 침전여액이 발생된다. 이 침전여액에는 옥살산과 같은 유기 물질이 함유되어 있으며 이 물질의 제거는 방사성 폐기물의 긍극적인 처리 처분에 대단히 중요하다 본 연구는 모의 침전여액을 제조하고 이로부터 옥살산 제거 연구가 두 가지 방법으로 수행되었다. 첫째 과산화수소를 이용한 제거 법으로서 침전여액 내 Ru$^{+4}$ 와 Fe$^{+3}$ 는 과산화수소를 자체 분해시키기 때문에 옥살산 제거를 방해함을 알 수 있었다 둘째는 NaOH를 용액 내 첨가하는 방법으로 pH증가에 따라 침전이 발생되면서 COD는 상당히 감소함을 보여주었다. 침전물은 $Na_2$C$_2$O$_4$로 확인되었고 pH9 이상에서 99%이상 감소함을 보여 주었다.다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.2
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• pp.77-85
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• 2012

This study was carried out to remove (/recover) the uranium from the Uranium-bearing Lime Precipitate (ULP). An oxidative dissolution of ULP with carbonate-acidified precipitation and a dissolution of ULP with nitric acid-hydrogen peroxide precipitation were discussed, respectively. In point of view the dissolution of uranium in ULP, nitric acid dissolution which could dissolved more than 98% of uranium was more effective than carbonate dissolution. However, in this case, uranium was dissolved together with a large amount of impurities such as Al, Ca, Fe, Mg, Si, etc. and some impurities were also co-precipitated with uranium during a hydrogen peroxide precipitation. On the other hand, in the case of carbonate dissolution-acidified precipitation, U was dissolved less than 90%. Therefore, it was less effective than nitric acid dissolution for the volume reduction of radioactive solid waste. However, it was very effective to recover the pure uranium, because impurities were hardly dissolved and hardly co-precipitated with uranium.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.10a
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• pp.47-50
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• 1997

희토류원소의 광 환원 침전 특성이 연구되었다. 환원제로 isopropyl alcohol, 침전제로 (NH$_4$)$_2$SO$_4$가 사용되었다. 그리고 250nm의 파장을 방출하는 수은 램프가 사용되었다. Eu원소만을 함유하는 용액으로부터 Eu+3의 Eu+2로의 광 환원 결과는 97%이상이었으며 과산화수소가 소량 첨가되었을 경우 침전 속도는 증가하였다. 이 결과를 토대로 하여 희토류원소들(Sm,Eu,Gd)을 함유하는 수용액과 유기용액(HDEPH-Dodecan)에 UV광을 조사하였을 시 선택적으로 Eu을 분리해 낼 수 있었다. Eu의 침전 회수율은 두 상의 경우 모두 97%이상이었다.

• Proceedings of the Korean Society of Fisheries Technology Conference
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• 2001.05a
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• pp.209-210
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• 2001

적조에 대한 대책으로서 가장 많이 이용되는 황토법은 적조생물을 침전시키므로써 제거하지만, 황토의 침전에 의한 2차적인 오염의 가능성이 있다 (Na et al., 1996). 황산구리, 과산화수소와 Triosyn에 의한 적조 살조효과가 있지만 이러한 화학물질은 모든 생물에 대한 살조효과가 있으므로 현상에 사용하기는 힘들다. 생물학적 방제에는 바이러스, 박테리아의 방법이 강구되고 있지만, 산소고갈 등의 2차적인 부작용이 야기된다. (중략)

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2011.05a
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• pp.219-220
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• 2011

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2011.10a
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• pp.293-294
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• 2011

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2008.11a
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• pp.277-278
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• 2008

• Resources Recycling
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• v.10 no.5
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• pp.22-28
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• 2001

Recovery of silver in the spent solution generated from MEO(Mediated Electrochemical Oxidation) process, which is a process to decompose radioactive organic mixed wastes at low temperature, was performed using chemical method. Silver nitrate in 5M nitric acid solution could be completely recovered as AgCl by using 1% excess of the stoichiometric HCl equivalents. Then, AgCl was transformed to Ag metal by reduction reaction with hydrogen peroxide under alkaline media. The optimum pH for the reduction to silver metal was found to be in the range of 12.8∼13.0.

• Journal of Animal Environmental Science
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• v.15 no.3
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• pp.209-216
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• 2009

The aim of this study was to investigate the removal effects of the color, nutritive salts and other pollutants on piggery slurry by advanced oxidation process (AOP) system. The experimental AOP system was designed to treat 300 L of piggery slurry per hour. To enhance oxidizing power of the experimental APO system, a ultraviolet irradiation system and the ultrasonic system were attached to the AOP system. With 5 min ultrasonic treatment, COD, SS and T-N concentrations were changed from 210, 820, and 309 to 200, 760, and 262 mg/L, respectively. With 10 min ultrasonic treatment, SS and T-N concentrations tended to decrease but T-P concentration was not changed. With the treatment of both ozone and ultrasonic waves for 30 min, COD, SS, T-N and T-P decreased from 238, 900, 400, and 5 to 165, 540, 263, and 4 mg/L, respectively. With the treatment of both ozone and ultraviolet irradiation for 30 min, COD, SS, T-N and T-P decreased from 321, 340, 204, and 15 to 151, 140, 111, and 7 mg/L, respectively, and color was changed from 4,344 to 624.