• Title/Summary/Keyword: 과불소 알킬 유도체

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Development of Perfluoroalkyl Derivative for $Cr^{3+}$ Adsorbent Promotion Process (3가 크롬 흡착 증진용 과불소 알킬유도체 제조 및 적용공정 개발)

  • Shin, Jong-Sub;Kum, Chang-Hun;Yun, Jong-Kuk;Park, Il-Kyu
    • Clean Technology
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    • v.14 no.3
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    • pp.193-203
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    • 2008
  • A surfactant is used to assist the effect of cleaning, dispersibility and adhesion during leather manufacturing process. Existing surfactant for that process includes many hydrophilic groups that may cause problem such as stain, bad water resistance and poor durability, etc. It is potential problem to make high-performance property for future leather market. In this study, we have synthesized the fluorinated surfactant of which property decreases surface tension, increases dispersion, cleaning effect and the better chrome absorption by the high bond energy of C-F to complement weakness that the present alkyl derivative surfactants have. Using fluorinated surfactant, we can confirm that dispersion is increased, chrome absorption ratio is augmented with high osmosis and coherence, chrome content in the tanning waste water is reduced, BOD and COD contents are diminished and physical characteristics are improved.

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A Synthesis of New Fluorine-containing Phenylformamidines Possessing N-Dialkylaminosulfenyl Group and Their Insecticidal Activities (N-Dialkylaminosulfenyl 치환체를 갖는 새로운 불소 함유 Phenylformamidine 유도체의 합성과 살충활성)

  • Lee, Dong-Guk;Chung, Kun-Hoe;Ko, Young-Kwan;Ryu, Jae-Wook;Woo, Jae-Chun;Koo, Dong-Wan;Choi, Yong-Ho;Park, No-Joong;Kim, Tae-Joon;Choi, In-Young
    • The Korean Journal of Pesticide Science
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    • v.14 no.3
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    • pp.199-208
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    • 2010
  • Phenylformamidine derivatives are well known as insecticides for their specific activity against the insects. It has now been established that they show insecticidal activity as agonists on the octopamine receptor. In order to get a highly active compound we have intensively exploited fluorine substituted-aromatic formamidines possessing N-dialkylaminosulfeny group. Up to now, there are several candidates we found: N-(dialkylamino)sulfenyl-N-methyl-N'-(4-fluoro-2-methylphenyl)formamidines. The miticidal activity of Compound 29 show five-fold higher than Amitraz.