• Title/Summary/Keyword: 공중선

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Directed Assembly of Block Copolymers for Defect-Free Nanofabrication (블록공중합체 자기조립제어를 통한 무결함 나노구조제작)

  • Shin, Dong-Ok;Jeong, Seong-Jun;Kim, Bong-Hoon;Lee, Hyung-Min;Park, Seung-Hak;Xia, Guodong;Nghiem, Quoc Dat;Kim, Sang-Ouk
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.1-6
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    • 2008
  • Block copolymers spontaneously assemble into various nanoscale structures such as spheres, cylinders, and lamellar structures according to the relative volumn ratio of each macromolecular block and their overall molecular weights. The self-assembled structures of block copolymer have been extensively investigated for the applications such as nanocomposites, photonic crystals, nanowires, magnetic-storage media, flash memory devices. However, the naturally formed nanostructures of block copolymers contain a high density of defects such that the practical applications for nanoscale devices have been limited. For the practical application of block copolymer nanostructures, a robust process to direct the assembly of block copolymers in thin film geometry is required to be established. To exploit self-assembly of block copolymer for the nanotechnology, it is indispensible to fabricate defect-free self-assembled nanostructure over an arbitrarily large area.

An Analysis of the Provision of Public Wireless Local Area Network Services (공중 무선랜서비스의 제공현황 분석)

  • Koh, S.J.
    • Electronics and Telecommunications Trends
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    • v.19 no.2 s.86
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    • pp.37-46
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    • 2004
  • 불안하고 예측불허인 시장 전망에도 불구하고, 공중 무선랜서비스는 유선통신사업자들에게는 유선 초고속인터넷서비스의 이동성, 향후의 유무선통합서비스 및 새로운 무선 사업 기반을 형성해 준다는 측면에서, 이동통신사업자들에게는 3G 서비스의 제공시기가 불투명한 상태에서 2G나 2.5G 이동통신에 비해 보다 빠르고 저렴한 무선데이터 통신 및 다양한 부가서비스를 제공할 수 있는 기반을 형성해 줄 수 있다는 측면에서, 독립계 사업자들에게는 틈새시장을 개척할 수 있는 기반을 형성해 준다는 측면에서 사업자들의 관심은 물론 매우 치열한 시장진입 경쟁이 전개되고 있다. 따라서 본 고에서는 핫스폿을 중심으로 한 공중 무선랜서비스의 제공현황을 미국, 유럽을 중심으로 살펴보고, 시장의 발전과 사업자들이 서로 상생할 수 있는 사업전개 방향을 모색하기 위한 시사점을 도출해 보고자 한다.

Design of Variable Life-Adjusted Display (VLAD) Charts (VLAD 관리도의 설계)

  • Lee, Jae-Heon;Jung, Sang-Hyun
    • The Korean Journal of Applied Statistics
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    • v.20 no.3
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    • pp.597-604
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    • 2007
  • There are many uses of control charts in health-care monitoring and in public-health surveillance. For example, control charts are used in monitoring and improvement of hospital performance, in monitoring chronic diseases and infectious diseases, and so on. We introduce the Variable Life-Adjusted Display (VLAD) chart and propose the method for choosing control limits of the VLAD chart to give specified in-control properties.

Synthesis of ion Exchange Fiber Containing Amidoxime and Phosphoric Acid Groups and Its Uranium Adsorption Properties (아미드옥심기와 인산기가 함유된 이온 교환 섬유의 합성 및 우라늄 흡착 특성)

  • 황택성;박진원
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.242-248
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    • 2003
  • PP-g-(AN/Sty) was synthesized by grafting with acrylonitrile (AN) and styrene (Sty) onto PP staple fiber using an electron beam accelerator and followed by amidoximination and phosphorylation. Mole fraction of AN in the graft chain increased with the increase of the AN content in the monomer mixture. The highest AN grafting yield of 45% was obtained at a monomer ratio of 40 vol% AN/60 vol% Sty. Mole fraction of AN in the graft chain decreased with the increase of methanol amount used its solvent. As reaction temperature increased, the grafting yield of copolymer increased and reached equilibrium at 50$^{\circ}C$. Amount of amidoxime group in fibrous ion exchanger was increased as increasing amount of hydroxylamine, and the maximum content of amidoxime group was observed at 5.8 mmol/g with the 9 wt% hydroxylamine concentration. Content of phosphorous group in fibrous ion exchanger increased up to 0.5 N phosphoric acid concentration, and then leveled off. The adsorption ability of the copolymer for uranyl ion by the chelating adsorbents was in the following order : bifunctional PP-g-(AN/sty) > amidoximated PP-g-(AN/Sty) > phosphorylated PP-g-(AN/Sty).

Synthesis and Characterization of Transparent Copolyimide Films (I) (투명한 폴리이미드 공중합체 필름의 합성과 특성 연구 (I))

  • Park, Jong-Su;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.580-586
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    • 2008
  • Copolyimides were synthesized from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 1,3-bis(3-aminophenoxy)benzene (BAPB) with different mole ratios of 2,2-bis[4-(4-aminophenoxy)pheny1]hexafluoropropane (BAPP). The solution cast film of poly(amic acid) (PAA) was heat treated at different temperatures to create copolyimide films. The PI copolymer films were found to exhibit good optical transparencies. The thermomechanical properties, morphology, and optical transparency of PI films were examined using fourier transform infrared spectroscopy (FT-IR), wide-angle X-ray diffraction (XRD), scanning electron microscopes (SEM), differential scanning calorimeter(DSC), thermo-gravimetric analyzer (TGA), universal tensile machine (UTM), and IN - Vis. spectrometer. The glass transition temperature ($T_g$), ultimate strength, and initial modulus linearly increased with increasing BAPP mole fraction. However, thermal stability($T_D{^i}$) of the copolyimide remains constant regardless of BAPP loadings. It was found, however, that the optical transparency decreases slightly upon increasing the BAPP content because of the formation of the charge transfer complexes.

Homopolymer Distribution in Polystyrene - Poly(methyl methacrylate) Diblock Copolymer (폴리스티렌-폴리(메틸 메타크릴레이트) 이종 블록 공중합체 내의 단일중합체 분포)

  • Hong, Sung-Ho;Lee, Eun-Ji;Song, Kwon-Bin;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.531-536
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    • 2011
  • Homopolymer distribution in block copolymer/homopolymer blends was investigated as a function of homopolymer concentration and homopolymer molecular weight. The deuterated poly(methyl methacrylate) or polystyrene was blended with a deuterated polystyrene-poly(methyl methacrylate) diblock copolymer up to a concentration of 20 wt%. Samples were characterized by small-angle X-ray scattering (SAXS), neutron reflectivity and transmission electron microscopy. The block copolymer with a thin-film geometry formed alternating lamellar microdomains oriented parallel to the substrate surface. By adding the homopolymer, the microdomain structure was significantly disturbed. As a consequence, a poorly ordered morphology appeared when the homopolymer concentration exceeded 15 wt%. Increasing the homopolymer concentration and/or the homopolymer molecular weight caused the microdomains to swell less uniformly, resulting in segregation of the homopolymer toward the middle of the microdomains.

Characteristics of PET-PEN Copolymer as a Material for Flexible Substrate (폴리(에틸렌 테레프탈레이트)/폴리(에틸렌 나프탈레이트) 공중합체의 유연기판 특성)

  • Youm, Joo-Sun;Kim, Jea-Hyun;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.599-604
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    • 2011
  • The PET-PEN copolymers have been synthesized and the effect of their morphology on the physical properties of polyester flexible substrate was investigated. It was found that the block sequence of synthesized copolymer was varied depending upon DMT/NDC ratio in polymerization. Higher PET-PEN and PEN block sequence in polyester copolymer resulted in the increase of glass transition temperature and it caused the enhancement of dimensional stability as a polyester flexible substrate. The highest coefficient of thermal expansion(CTE) was obtained when DMT/NDC ratio is 50/50. Synthesized PET-PEN copolymer seems to be acceptable as a flexible substrate since it shows that their optical transmittance at 550 nm is over 80% and thermal weight loss at $280^{\circ}C$ for 1 hr is less than 0.4 wt%.

MLP-A(Multi Link Protection for Airborne Network Verifying) algorithms and implementation in multiple air mobile/verification links (다중 공중 이동/검증 링크에서의 MLP-A 알고리즘 및 구현)

  • Youn, Jong-Taek;Jeong, Hyung-jin;Kim, Yongi;Jeon, Joon-Seok;Park, Juman;Joo, Taehwan;Go, Minsun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.3
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    • pp.422-429
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    • 2022
  • In this paper, the intermediate frequency transmission signal level between the network system-based baseband and RF unit consisting of multi-channel airborne relay devices and a lot of mission devices, which are currently undergoing technology development tasks, is kept constant at the reference signal level. Considering the other party's receiving input range, despite changes in the short-range long-range wireless communication environment, it presents a multi-link protection and MLP-A algorithm that allows signals to be transmitted stably and reliably through signal detection automatic gain control, and experiments and analysis considering short-distance and long-distance wireless environments were performed by designing, manufacturing, and implementing RF units to which MLP-A algorithms were applied, and applying distance calculation equations to the configuration of multiple air movements and verification networks. Through this, it was confirmed that a stable and reliable RF communication system can be operated.

Resistive Humidity Sensor from Copolymers Containing Quaternary Ammonium Salt (II): Four Component Copolymers (4차 암모늄염을 포함하는 공중합체를 이용한 저항형 습도센서 (II) : 4원 공중합체)

  • Lee, Dong-Geun;Lim, Tae-Ho;Jeon, Young-Min;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.302-307
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    • 2007
  • The resistive-type humidity sensors were prepared from the copolymers of [2-[(methacryloyloxy)ethyl]dimethyl]propylamonium bromide (MEPAB), [2-[(methacryloyloxy)ethyl]-2-hydroxyethyl]dimethylammonium bromide (MEHDAB), 2- [(methacryloyloxy)ethyl]trimethylammonium chloride (METAC), and n-butyl methylacrylate (MBA). Four component copolymers MEPAB/BMA/MEHDAB/METAC=4/4/1/1, 3/5/1/1, 2/6/1/1, 1/7/1/1 crosslinked with blocked-isocyanate on Ag/Pd electrode/alumina substrate showed a good durability at high humidities. The various electrical properties such as frequency dependency, temperature dependency, hysteresis, response time and water durability were examined. In the case of copolymer composed of MEPAB/BMA/MEHDAB/METAC=2/6/1/1, the resistance varied from $1.4\;M{\Omega}$ to $2.9\;k{\Omega}$ at $25^{\circ}C$ in the range of $30{\sim}90\;%RH$ and this copolymers showed a good linearity and low hysteresis.