• Title/Summary/Keyword: 공기 투과도

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농업용 폐비닐 열분해 파생물질의 조성분석과 유해성 평가

  • 신혜순;강주연;김미경;정기화;심성훈
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.151-151
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    • 2003
  • 토양에 방치된 농업용 폐비닐은 거의 분해가 되지 않으며, 수분과 공기의 유통을 차단하고 토양 내 미생물들의 흐름을 막아 토양을 더욱 황폐화시키게 된다. 불법적인 소각 때는 산불의 위험에다 다이옥신, 염소 및 염화수소가스 등을 배출해 대기오염을 유발시킨다. 폐비닐을 열분해과정으로 처리하여 아주 작은 입자로 미분쇄하고 겔상태로 용융된 원료물질속으로 완전히 균일하게 혼합하여 골재로 활용하는 과정에서 가스상과 액상의 여러 가지 중간생성물질이 발생하게 되며, 농약의 살포에 의한 잔류농약 둥 인체에 유해가능한 요소들이 있을 수 있다. 본 연구에서는 개발공정이나 제품에서 인체에 영향을 미칠 수 있는 물질에 대하여 유해성을 평가하고 용응 겔 및 가스와 오일에 함유된 화학성분을 분석하였기에 보고하고자 한다 시험동물의 혈액생화학적 검사에서는 농업용 폐비닐물질 및 열분해 파생물질의 혈청 Cholesterol, 혈청 Alanine aminotranseferse와 Aspartate aminotransferse, Albumin 수치, LDH, Glucose, Uric acid, A/C 비 등의 생화학적 활성도를 측정한 결과들에서는 농업용 폐비닐물질을 투여한 시험군에서 나타난 결과와 비교하여 열분해 파생물질을 투여한 시험군에서 나타난 결과가 감소된 통계결과를 보였다. 이 결과들은 농업용 폐비닐물질을 투여한 시험군보다 열분해 파생물질을 투여한 시험군의 외부독성물질 투여에 의한 생체독성의 영향과 생체에 가해진 스트레스강도가 작았음을 의미하는 것이다. 잔류농약분석에서는 시료로부터 농약을 추출하는 용매추출과정, 시료추출물 중 공존하는 방해성분을 제거하는 정제과정, 폐비닐물질 및 열분해 파생물질 성분을 100mg/kg 이상군의 투여 후 시험동물의 부검시 모든 투여군에서 독성소견이 인정되지 않았다. 이와 같은 결과로 열분해 및 연소과정에서 발생하는 파생물질의 분석결과를 응용하여 대기오염을 방지하고 인체 유해물질을 차단하는 공해 방지 설계의 기초자료를 제안하고자 한다.

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The Usefulness of Transesophageal Echocardiography During Heart Surgery (개심술을 시행하는 환자에서 경식도 심초음파의 이용)

  • 조규도;김치경
    • Journal of Chest Surgery
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    • v.30 no.12
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    • pp.1205-1213
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    • 1997
  • This study reviewed useful aspects of the intraoperative transesophageal echocardiography among the patients in whom heart surgery were undertaken between January 1996 and July 1996 at St.Pauls hospital, Medical College of Catholic University, Seoul, Korea. During that period, 61 patients were operated on because of valvular heart disease(25 patients), coronary artery disease(22 patients), congenital heart disease(13 patients), and combined coronary artery disease and valvular heart disease(1 patient). Two patients(1 redo-VSD and 1 valvular heart diease) needed repeated aortic cross clamping and complementary procedures because of incomplete initial procedures. There was no incidence of air embolism. We could observe significant relationship of cardiac output monitoring methods either by thermodilution technique and transesophageal echocardiography by linear regression analysis(p<0.001). We tested myocardial response(percentage of systolic wall thickness, PSWT) with low dose dobutamine challenge to predict post-CABG myocardial perfusion. And the test showed statistically significant resp.onse(sensitivity 76%, specificity 94.7%, positive predictive value 95%, negative predictive value 75%). These results suggest that cardiac surgeon could draw more benefits by intraoperative transesophageal echocardiography.

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ITO 전극에 성장된 ZnO 나노구조의 구조적 및 광학적 특성 연구

  • Lee, Hui-Gwan;Kim, Myeong-Seop;Yu, Jae-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.104-104
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    • 2011
  • ZnO는 3.37 eV의 넓은 에너지 밴드갭을 갖는 투명 전도성 반도체이며 우수한 전기적, 광학적 특성으로 인해 광원소자 개발을 위한 새로운 물질로 많은 주목을 받아왔다. 더욱이, ZnO는 쉽게 나노구조 형성이 가능하기 때문에 이를 응용한 가스센서, 염료감응태양전지, 광검출기 등의 소자 개발이 활발히 이루어지고 있다. 최근에는 GaN 기반 발광다이오드 (light emitting diode, LED)의 광추출 효율을 향상시키기 위한 ZnO 나노구조 응용에 관한 연구가 보고되고 있다. GaN 기반 LED의 경우 반도체 물질과 공기 사이의 높은 굴절률 차이로 인하여 낮은 광추출 효율을 나타낸다. 이를 해결하기 위한 방법으로 표면 roughening, texturing 등 에칭공정을 이용해 광추출 효율을 개선하려는 연구들이 보고되고 있으나, 복잡한 공정과정을 필요로 하고 에칭공정에 의한 소자 표면 손상으로 전기적 특성이 나빠질 수 있다. 반면 전기화학증착법으로 성장된 ZnO 나노구조를 이용할 때, 보다 간단한 방법으로 쉽고 빠르게 나노구조를 형성할 수 있고 낮은 공정온도를 가지기 때문에 소자의 전기적 특성에 큰 영향을 주지 않는다. 수직방향으로 잘 정렬된 ZnO 나노구조를 갖는 LED의 경우 내부 Fresnel 반사 손실을 효과적으로 줄여 발광 효율을 크게 향상시킬 수 있다. 따라서, ZnO 나노구조의 성장제어 및 성장특성을 분석하는 것은 매우 중요하다. 본 연구에서는 ITO glass 위에 ZnO 나노구조를 성장하고 그 특성을 분석하였다. ITO glass 기판 위에 RF magnetron 스퍼터를 사용하여 Al 도핑된 ZnO (AZO)를 얇게 증착한 후 전기화학증착법으로 ZnO 나노구조를 성장하였다. 농도, 인가전압, 공정시간 등 다양한 공정조건을 변화시키면서 성장 메커니즘을 분석하였고, scanning electron microscope (SEM) 및 X-ray diffraction (XRD)을 통하여 구조 및 결정성 등을 분석하였다. 또한, UV-Visible-NIR spectrophotometer를 사용하여 투과율을 실험적으로 측정하여 ZnO 나노구조의 광학적 특성을 분석하였고, rigorous coupled wave analysis (RCWA) 방법을 사용하여 계면에서 발생하는 내부 반사율을 계산함으로써 나노구조의 효과를 이론적으로 분석하였다.

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Measurement of Aerodynamic Properties of Screens for Windbreak Fence using the Apparatus for Testing Screens (공력 저항 측정기를 이용한 방풍펜스 방진막의 공기 투과 저항력 측정)

  • Kim, Rack-Woo;Lee, In-Bok;Hong, Se-Woon;Hwang, Hyun-Seob;Son, Young-Hwan;Kim, Tae-Wan;Kim, Min-Young;Song, Inhong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.6
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    • pp.145-154
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    • 2013
  • Recently, damage occurrence by wind erosion has been increasing in society. In times past, such problems only took place in desert area ; however, in recent years, the wind erosion problem is spreading out to agricultural land. Wind erosion in agricultural land can cause loss of loam soils, the disturbance of the photosynthesis of the crop fields and serious economic losses. To overcome the mentioned problems, installation of windbreak fence can be recommended which function as disturbing strong wind and wind erosion. However, there is still no proper guideline to install the windbreak fence and the installation used to rely on the intuition of the workers due to the lack of related studies. Therefore, this study measured the aerodynamic resistance of screens of the windbreak fence using the apparatus for testing screens. The apparatus for testing screens was designed to measure pressure loss around the screen. Measured pressure loss by wall friction compensated for pressure loss to calculate the aerodynamic resistance of screens. The result of pressure loss by regression analysis derived the aerodynamic coefficient of Darcy-Forchheimer equation and power law equation. The aerodynamic resistance was constant regardless of the overlapped shape when the screen was overlapped into several layers. Increasing the number of layers of the screen, internal resistance increased significantly more, and pressure loss caused by the screen also increased linearly when the wind speed was certain conditions, but permeability had no tendency. In the future, the results of this study will be applied to the computational fluid dynamics simulation. The simulation models will be also validated in advance by wind tunnel experiments. It will provide standard of a design for constructing windbreak fence.

A Study on the Computer Program for the Shipboard Noise Prediction - using Statistical Energy Analysis - (선박 소음 예측 전산 프로그램의 개발에 관한 연구 -통계적 에너지 해석법을 이용한-)

  • Sa-Soo Kim;Ku-Kyun Shin;Hong-Gi Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.293-306
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    • 1991
  • During the last few years recommendations or regulations concerning permissible noise levels on shirts have been issued by the authorities in most countries. For these reasons the need for useful and accurate noise prediction computer programs has been emphasized. A noise prediction program can make it possible to find the most economical solution to achieve a certain noise requirement. This paper attempts to develop a noise prediction computer program using statistical energy analysis(SEA). In this paper, the SEA is used to predict the sound transmission loss for airborne noise and the vibration amplitude of the panel consisting of ship spaces such as floor, wall, and ceiling for structureborne noise. And in order to verify the prediction, a small passenger vessel, G/T120 tons, is selected. It has been shown that the prediction is capable of giving results in good practical agreement with measurements and therefore it is useful for predicting the nolle levels in ships and establishing the countermeasures at early design stage.

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Preparation of Aminosiloxane-grafted Poly(imidesiloxane) Copolymer and its Morphology and Adhesive Properties in Film (아미노실록산이 그래프팅된 폴리(이미드실록산) 공중합체 제조와 필름 모폴로지 및 점착 특성 연구)

  • Lee, Ji Mok;Kwon, Eunjin;Lee, Sunyoung;Jung, Hyun Min
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.547-552
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    • 2013
  • Polyimide (PI) containing carboxyl functional group was prepared and reacted with diaminosiloxane during high temperature film casting. The morphology of resulting film was observed by using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX), which revealed that globular 100 nm-sized PI domains and continuous polysiloxane phase were formed. X-ray photoelectron spectroscopy (XPS) study indicated that air-film interface mainly consisted of polysiloxane blocks. Poly(imidesiloxane) thin layer was thermostable until $400^{\circ}C$ and its pressure- sensitive adhesive property was retained up to $300^{\circ}C$. The comparative experiments revealed that grafting between carboxyl groups of polyimide and aminosiloxane was crucial for formation of microdomain structure and pressure-sensitive adhesive property.

The Study of Antibiotic Resistance in Bacterial Biofilms (박테리아 생체막에 대한 항생제 내성 연구)

  • Kim Jin Wook;Joo Chi Un;Park Jin Yong;Lee Song Ae;Kim In Hae;Lee Jae Hwa
    • Environmental Mutagens and Carcinogens
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    • v.25 no.4
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    • pp.157-160
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    • 2005
  • Antibiotic resistance of bacteria in the biofilm mode of growth contributes to the chronicity of infection and disease. The penetration of antibiotic, through biofilm developed in an itt vitro model system was investigated. Antibiotic resistant bacteria (E. coli) were obtained from Culture Collection of Antibiotic Resistant Microbes. Ca-alginate bead used as simulated biofilm and a cell entrapment test using compressed air were experiment for the improvement cell viability. Antibiotic susceptibilities though biofilms was measured by assaying the concentration of antibiotic that diffused through the biofilm to minimal inhibition concentration (MIC). Survival of immobilized cells were reduced as compared to free cells. In case of antibiotic susceptible E. coli reduced continuously, but antibiotic resistant E. coli kept up survival rate constantly. Survival was showed after exposed to the antibiotics that the more treated antibiotic resistant E. coli and low concentration of antibiotics) the more survived.

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Heat treatment effects on the electrical properties of $In_2O_3$-ZnO films prepared by rf-magnetron sputtering method (마그네트론 스퍼터링 방법으로 제작된 $In_2O_3$-ZnO 박막의 전기적 특성에 대한 열처리 효과)

  • Kim, Hwa-Min;Kim, Jong-Jae
    • Journal of the Korean Vacuum Society
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    • v.14 no.4
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    • pp.238-244
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    • 2005
  • IZO thin films are prepared on a corning 7059 glass substrate in a mixed gases of Ar +$O_2$ by rf-magnetron sputtering, using a powder target with a composition ratio of $In_{2}O_{3}$ : ZnO=90 : 10 $wt.\%$. Their electrical sheet resistance are strongly dependent on the oxygen concentration introduced during the deposition, a minimum resistivity of $3.7\times10^{-4}\Omega\cdot$ cm and an average transmittance over $85\%$ in the visible range are obtained in a film deposited in pure Ar gas which is close to near the stoichiometry. During the heat treatment from room temperature up tp $600^{\circ}C$ in various environments, the electrical resistance changes are explained by cyrstallizations or oxidizations of In metal and InO contained in the IZO film. The electrical properties due to oxygen adsorption and phase transitions occurring at temperatures over $40000^{\circ}C$ during heat treatment in air are also investigated.

Properties of Transparent Conducting Zinc Oxide Films Prepared by RF Sputtering (RF Sputter 방법으로 제조한 투명전도막 ZnO 특성)

  • Choe, Byung-Ho
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.360-365
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    • 1992
  • Ga-doped polycrystalline ZnO films on glass substrates were prepared by sputtering the targets, which had been prepared by sintering discs consisting of ZnO powder and various amounts of G$a_2O_3$, to investigate the effects of gallium doping and sputtering conditions on electrical properties. Optimizing the RF power density, argon gas pressure and gallium content, transparent Ga-doped ZnO films with resistivity less than 1$0^{-3}$ohm-cm are obtained. Electron concentration of undoped and Ga-doped ZnO films are order of $10^{18}$, $10^{21}$/c$m^2$respectively. After heat treatment in air and $N_2atmosphere, $ the resistivity of Ga-doped ZnO films increases by about two orders of magnitude. The optical transmission is above 80% in the visible range and the optical band widens as the Ga content increases.

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Determination of optical properties of Pr3+-doped selenide glasses of Ge-Sb-Se system using spectroscopic ellipsometry (분광타원법을 이용한 Pr 첨가 Ge-Sb-Se 계열 셀레나이드 유리의 굴절률 결정)

  • 신상균;김상준;김상열;최용규;박봉제;서홍석
    • Korean Journal of Optics and Photonics
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    • v.14 no.6
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    • pp.594-599
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    • 2003
  • By using the spectroscopic ellipsometry, we have measured and analyzed the optical characteristics of P $r^3$$^{+}$-doped selenide glasses of Ge-Sb-Se system, a strong candidate material for U band fiber amplifiers. The ellipsometric spectra measured in the transparent wavelengths range of the material were all fitted to a model consisting of ambient/roughness/thin fil $m_strate structures to obtain simultaneously the optical properties such as refractive index, in terms of Sellmeier parameters and film structure of P $r^3$$^{+}$-doped selenide glasses. Repeated measurements on different positions in both polished faces rendered to verify positional dependence of measured spectre-ellipsometric data. Hence, the model made possible the analysis of the optical characteristics of the glasses. Even though surface roughness was mainly responsible for the position dependencies, the averaged refractive indexes were as precise as to reflect the minute compositional change tantamount to 1 mol%. The measured refractive indexes are useful for design of core and clad compositions of single-mode selenide optical fibers.