• Title/Summary/Keyword: 공극크기

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Fabrication and Characteristic Evaluation of Three-Dimensional Blended PCL (60 wt %)/β-TCP (40 wt %) Scaffold (3 차원 Blended PCL (60 wt %)/β-TCP (40 wt %) 인공지지체의 제작 및 특성 평가)

  • Sa, Min-Woo;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.4
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    • pp.371-377
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    • 2014
  • In tissue engineering, a scaffold is a three-dimensional(3D) structure that serves as a template for regeneration the functions of damaged tissues or organs. Among materials for scaffolds, polycaprolactone(PCL) and ${\beta}$-tricalcium phosphate(${\beta}$-TCP) are biodegradable and biocompatible. In this study, we fabricated 3D PCL, blended PCL (60 wt %)/${\beta}$-TCP (40 wt %), and pure ${\beta}$-TCP scaffolds by a multi-head scaffold fabrication system. Scaffolds with a pore size of $600{\pm}20{\mu}m$ was observed by scanning electron microscopy. The effects of 3D PCL, blended PCL (60 wt %)/${\beta}$-TCP (40 wt %) and pure ${\beta}$-TCP scaffolds were analyzed by evaluating their mechanical characteristics. In addition, in an in-vitro study using osteoblast-like saos-2 cells, we confirmed the effects of 3D scaffolds on cellular behaviors such as cell adhesion and proliferation. In summary, the 3D blended PCL (60 wt %)/${\beta}$-TCP (40 wt %) scaffold was found to be suitable for human cancellous bone in terms of its the compressive strength, biocompatibility, and osteoconductivity. Thus, blending PCL and ${\beta}$-TCP could be a promising approach for fabricating 3D scaffolds for effective bone regeneration.

Characteristics of A Diaphragm-Type Fiber Optic Fabry-Perot Interferometric Pressure Sensor Using A Dielectric Film (유전체 박막을 이용한 다이아프램형 광섬유 Fabry-Perot 간섭계 압력센서의 특성)

  • Kim, M.G.;Yoo, Y.W.;Kwon, D.H.;Lee, J.H.;Kim, J.S.;Park, J.H.;Chai, Y.Y.;Sohn, B.K.
    • Journal of Sensor Science and Technology
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    • v.7 no.3
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    • pp.147-153
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    • 1998
  • The strain characteristics of a fiber optic Fabry-Perot pressure sensor with high sensitivity using a $Si_{3}N_{4}/SiO_{2}/Si_{3}N_{4}$ (N/O/N) diaphragm is experimentally investigated. A 600 nm thick N/O/N diaphragm was fabricated by silicon anisotropic etching technology in 44 wt% KOH solution. An interferometric fiber optic pressure sensor has been manufactured by using a fiber optic Fabry-Perot intereferometer and a N/O/N diaphragm. The 2 cm length fiber optic Fabry-Perot interferometers in the continuous length of single mode fiber were produced with two pieces of single mode fiber coated with $TiO_{2}$ dielectric film utilizing the fusion splicing technique. The one end of the fiber optic Fabry-Perot interferometer was bonded to a N/O/N diaphragm. and the other end was connected to an optical setup through a 3 dB coupler. For the N/O/N diaphragm sized $2{\times}2\;mm^{2}$ and $8{\times}8\;mm^{2}$, the pressure sensitivity was measured 0.11 rad/kPa and 1.57 rad/kPa, respectively, and both of the nonlinearities were less than 0.2% FS.

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Effect of Cd Concentration on Characteristics of CdS Thin Films Prepared by Chemical Bath Deposition (화학용액증착법에 의하여 증착된 CdS 박막의 특성에 대한 Cd 농도의 영향)

  • Jung, SungHee;Chung, CheeWon
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.377-382
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    • 2012
  • CdS thin films have been widely used as a buffer layer of CIGS semiconductor solar cells to reduce the lattice mismatch between transparent electrode and absorber layer. In order to prepare the CdS films with high transparency and low resistivity, they were deposited by varying Cd concentration with the constant S concentration in the solution using chemical bath deposition method. They were analyzed in terms of structural, optical and electrical properties of CdS films according to the $[S^{2-}]/[Cd^{2+}]$ ratio. In the case of Cd concentration higher than S concectration, CdS thin films were formed mainly by cluster- by-cluster formation due to the homogeneous reaction between Cd and S in the solution. Therefore the grain size increased and the transmittance decreased. On the other hand, in the case of Cd concentration lower than S concentration, CdS films were formed by heterogeneous reaction on the substrate rather than in the solution. The CdS films have the grains with the uniform circular shape of a few hundreds ${\AA}$. As the Cd concentration increased in the solution, the $[S^{2-}]/[Cd^{2+}]$ ratio decreased and the resistivity decreased by the increase in the carrier concentration due to the formation S vacancy by the excess Cd.

A Study on the Surface Phenomena of Re-creational Gilt Layer by Conditions of Heat Treatment (열처리 조건에 따른 재현 도금층의 표면현상 연구)

  • Yang, Seok-Woo;Kim, Soo-Ki
    • Journal of Conservation Science
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    • v.28 no.1
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    • pp.29-37
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    • 2012
  • This study discusses a mercury amalgam gilding technique and examines how the color, surface and section of the gilt layer changes as the condition of heat treatment with mercury amalgam gilt object is changed. Some previous studies have mentioned reasons for various colors on gilt bronze artifacts depending on gilding manufacture and environment. However, reason for reddish color with gold on the artifacts' surface brought on high temperature corrosion has yet to be discussed and analyzed. A methodology was found in representing the mercury amalgam gilding technique and heat treatment test. According to the result of the heat treatment test, in the conditions of higher temperature and longer time, the oxidized layer on the gilt layer was distributed more widely and in the part when the oxide layer was eliminated, the gilt layer with a reddish color was observed. Moreover, in the surface observation of the specimen on which yellow and reddish colors were agitated, the changing aspects of its surface condition differed by colors. When investigated the section, it was observed that the void density and size became larger. After a test, the surface components changed; the temperature of heat treatment increased, component ratio of Hg and Au decreased gradually but component ratio of Cu increased. In regard to the gilt layer, as the time was longer and the temperature became higher for the heat treatment, the component ratio of Au and Cu by layers tended to change in inverse proportion. It is concluded that gilding techniques and the burial environment can make a difference in the surface color of the gilt layer on the gilt bronze artifacts, the high temperature corrosion that occurs by heat after they are manufactured is also one of the factors that affects their surface color.

The Method for Evaluating Unsaturated Hydraulic Conductivity of the Bentonite-buffer Using Relative Humidity (상대습도를 이용한 벤토나이트 완충재의 불포화 수리전도도 평가방안)

  • Lee, Hang-Bok;Kim, Jin-Seop;Choi, Young-Chul;Choi, Heui-Joo;Kim, Kyungsu
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.69-77
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    • 2014
  • Unsaturated hydraulic conductivity of the bentonite-buffer was evaluated using the relative humidity data. The method for calculating unsaturated hydraulic conductivity was deduced from the general analytical equation representing the movement of water in unsaturated media, which was applied to the experimental results of water infiltration tests for identifying the behavior of unsaturated hydraulic conductivity according to the water saturation. Unlike the saturated condition, the hydraulic gradient and water flux were irregularly changed, and the unsaturated hydraulic conductivity was increased with increasing the experimental time. Swelling of bentonite grains due to the water absorption increased the volume and size of pore within bentonite, resulting in the increase of water velocity and unsaturated hydraulic conductivity. This result suggested the necessity of further investigation on the correlation between the swelling degree of bentonite-buffer and unsaturated hydraulic conductivity. The method used in this study can be useful technique for evaluating long-term hydraulic performance of bentonite-buffer in the radioactive waste disposal system.

Immunosuppressive Activity of Cultured Broth of Entompathogenic Bacteria on the Beet Armyworm, Spodoptera exigua, and Their Mixture Effects with Bt Biopesticide on Insecticidal Pathogencity (파밤나방(Spodoptera exigua)에 대한 곤충병원세균류 배양액의 곤충면역억제활성 및 비티 생물농약과 혼합효과)

  • Kim, Jea-Min;Nalini, Madanagopal;Kim, Yong-Gyun
    • The Korean Journal of Pesticide Science
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    • v.12 no.2
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    • pp.184-191
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    • 2008
  • Entomopathogenic bacteria (Xenorhabdus nematophila, X. sp. and Photorhabdus temperata subsp. temperata) isolated from entomopathogenic nematodes express potent insecticidal activity in insect hemocoel. They are also known to suppress insect immune mediation by inhibiting phospholipase $A_2$, leading to host immunosuppression. This study analyzed effects of their cultured broths on inhibiting insect immunosuppression. For this, we removed all bacterial cells using $0.2\;{\mu}m$ pore sized membrane from the bacteria-cultured broth. All three sterilized cultured media, in dose-dependent manners, significantly inhibited hemocyte-spreading behavior of 5th instar larvae of Spodoptera exigua. However, they showed differential inhibitory activities among different bacterial species, in which X. nematophila showed the most potent inhibitory activity. This immunosuppressive effect was applied to increase the pathogenicity of Bacillus thuringiensis (Bt). All three bacterial cultured broths including bacterial cells significantly potentiated Bt pathogenicity against young S. exigua larvae when each of them was orally administered in a mixture of low dose of Bt. Finally, we tested the effect of oral administration of the cultured media containing the immunosuppressive compound(s) secreted by the bacteria. The membrane-sterilized cultured broths were mixed with the low dose of Bt and then orally administered to the young S. exigua. Only the cultured medium of X. nematophila showed increase of Bt pathogenicity. These results indicated that the; cultured media of the three bacteria possessed immunosuppressive factor(s), which may act to potentiate Bt toxicity to young S. exigua larvae.

Non Thermal Process and Quality Changes of Foxtail Millet Yakju by Micro Filtration (미세여과에 의한 비 가열살균 좁쌀약주의 제조 및 저장 중 품질변화)

  • Kang, Young-Joo;Oh, Young-Ju;Koh, Jeong-Sam
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.2
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    • pp.277-284
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    • 2005
  • Micro-filtration (MF) or ultra-filtration (UF) system with hollow-fiber cartridge was introduced in order to improve the Quality level of commercial foxtail millet Yakju, which has an off-flavour and/or undesired colour after the thermal treatment. The filtration effects of cartridges such as MF (0.65, 0.45, 0.2, 0.1 $\mu$m) and UF (500 K dalton) were investigated. The physicochemical and sensory characteristics of the Yakju were then evaluated during the 6 months storage at room temperature. The exclusion ability of microorganism in samples was confirmed in all cartridges, but 0.45 pm MF-cartridge was suitable in the Yakju manufacture due to its superior filtration rate and efficiency. Changes in reducing sugar and colour difference of foxtail millet Yakju untreated or treated by heat ($65^{\circ}C$${\times}$10 min) were observed during the storage; after 6 months the L-value of thermal-treatment sample was decreased and its b-value, however, significantly increased so that its color became dark, in comparison to non-thermal treatment sample. This decrease of reducing sugar is assumed that color change is associated with non-enzymatic browning reaction. Sensory Quality of foxtail millet Yakju produced by non-thermal treatment was better than that of thermal treatment.

IP Modeling and Inversion Using Complex Resistivity (복소 전기비저항을 이용한 IP 탐사 모델링 및 역산)

  • Son, Jeong-Sul;Kim, Junhg-Ho;Yi, Myeong-Jong
    • Geophysics and Geophysical Exploration
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    • v.10 no.2
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    • pp.138-146
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    • 2007
  • This paper describes 2.5D induced polarization (IP) modeling and inversion algorithms using complex resistivity. The complex resistivity method has merits for acquiring more valuable information about hydraulic parameters and pore fluid than the conventional IP methods. The IP modeling and inversion algorithms are developed by allowing complex arithmetic in existing DC modeling and inversion algorithms. The IP modeling and inversion algorithms use a 2.5D DC finite-element algorithm and a damped least-squares method with smoothness constraints, respectively. The accuracy of the IP modeling algorithm is verified by comparing its responses of two synthetic models with two different approaches: linear filtering for a three-layer model and an integral equation method for a 3D model. Results from these methods are well matched to each other. The inversion algorithm is validated by a synthetic example which has two anomalous bodies, one is more conductive but non-polarizable than the background, and the other is polarizable but has the same resistivity as the background. From the inverted section, we can cleary identify each anomalous body with different locations. Furthermore, in order to verify its efficiency to the real filed example, we apply the inversion algorithm to another three-layer model which includes phase anomaly in the second layer.

Effect of Cross-flow Velocity and TMP on Membrane Fouling in Thermophilic Anaerobic Membrane Bioreactor Treating Food Waste Leachate (음식물 침출수를 처리하는 막결합 고온혐기성 소화시스템에서 교차여과와 막간압력이 파울링에 미치는 영향)

  • Kim, Young-O;Jun, Duk-Woo;Yoon, Seong-Kyu;Chang, Chung-Hee;Bae, Jae-Ho;Yoo, Kwan-Sun;Kim, Jeong-Hwan
    • Membrane Journal
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    • v.21 no.4
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    • pp.360-366
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    • 2011
  • The effect of cross-flow velocity and transmembrane pressure (TMP) on membrane fouling was observed from pilot-scale operation of thermophilic anaerobic membrane bioreactor (AnMBR) treating food waste leachate. It was found that fouling rate was reduced significantly as cross-flow velocity increased at constant TMP mode of operation while this effectiveness was more pronounced at lower TMP. Higher TMP resulted in less permeable fouling layer possibly due to compressibility of foulant material on membrane surface. Particle sizes of membrane concentrate ranged from 10 to $100{\mu}m$, implying that shear-induced diffusion enhance back transport of these particle sizes away from the membrane effectively. From the continuous operation of AnMBR, it was confirmed that shear rate played an important role in the reduction of membrane fouling. Membrane autopsy works at the end of operation of AnMBR showed clearly that both organic and inorganic fouling were significant on membrane surface. Surface shear by cross-flow velocity was expected to be less effective to remove irreversible fouling which can be mainly caused by the adsorption of organic colloidal materials into membrane pores.

Effect of Polymer Structure on Membrane Morphology by Addition of 2-butoxyethanol (2-butoxyethanol 첨가에 따른 고분자 구조가 분리막 구조에 미치는 영향)

  • Son, Ye-Ji;Kim, No-Won
    • Membrane Journal
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    • v.21 no.4
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    • pp.377-388
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    • 2011
  • Flat sheet microfiltration membranes were prepared with polysulfone (PSF), polyethersulfone (PES), and polyphenylsulfone (PPS) by an immersion precipitation phase inversion method. In this method, dimethyl formamide (DMF) and polyvinylpyrrolidone (PVP) were used as a solvent and a wetting polymer additive, respectively. 2-butoxyethanol (BE) was used as a nonsolvent additive catalyst to form pore. The morphology of membranes was investigated by scanning electron microscopy and micropermporometer. The permeability of the membranes was evaluated with the flux of pure water. When the BE was added, the pore size of membranes became larger than blank membranes. The changes in the morphology of membrane due to the BE addition depend on polymer structure. All membranes have similar mean pore size and porosity. The mean pore sizes of PSF, PES, and PPS membranes were 0.282, 0.330 $0.308{\mu}m$, respectively. The porosities of PSF, PES and PPS membranes were 68.5, 66.1, 66.4%, respectively. However, the PPS membrane showed higher pore density on surface and narrower pore size distribution than PSF or PES membrane does. As a result, the pure water flux of PPS membrane ($357L/m^2\;hr$) was higher than that of PSF ($196L/m^2\;hr$) or PES membrane ($214L/m^2\;hr$).