• Journal of the Society of Disaster Information
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• v.19 no.2
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• pp.292-304
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• 2023

Purpose: This study was conducted to obtain experimental data for the establishment of preventive measures against fire, as large and small fire accidents occur at production and storage sites of superabsorbent polymers developed for the convenience of daily life. Method: The sample container was fixed at 0.2m in both length and width, and was shaped into a rectangular cuboid with heights of 3cm, 5cm, 7cm, and 14cm to access an infinite flat plane. The sample container was fixed in the center of a thermostatic bath that was heated to a predetermined temperature according to a preset temperature control program. If the central temperature of the sample rose more than 20℃ above the set temperature, it was determined to have 'ignited', and if it remained similar to the set temperature, it was determined to have 'unignited'. Result: The critical autoignition temperature was calculated to be 212.5℃ for a sample container with a height of 3cm, 202.5℃ for 5cm, 192.5℃ for 7cm, and 177.5℃ for 14cm. The ignition induction time to reach the highest temperature was approximately 42hours for 3cm, 91hours for 5cm, 151hours for 7cm, and 300hours for 14cm. Conclusion:① As the size of the sample container increased, the autoignition temperature decreased and the ignition induction time to reach the highest temperature increased. ② The apparent activation energy was calculated to be 39.30kcal/mol, with a correlation of 99.5%.

• Journal of Food Hygiene and Safety
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• v.8 no.2
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• pp.97-103
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• 1993

The acute toxicity of orally administered poly(sodium acrylic acid-acrylic acid), powerfully water-absorbent polymer, was el'aluated in Sprague-Dawley rats and feR mice. Rats and mice aging 6 weeks were gavaged with 0, 2.0, 3.0, 4.4, 6.7, or 10 g of poly(sodium acrylic acidacrylic acid)/kg in com oil. No animal died by treatment and any toxic symptom was not observed in the treated animals during 2 weeks. The body weight of the treated animals was not significantly different from the controls. The results of macroscopic examination on the organs of the treated animals revealed no abnormal findings. Therefore, it was concluded that poly(sodium acrylic acidacrylic acid) was practically non-toxic when it was orally administrated to rats and mice up to 10 g/kg, and its $LD_{50}$ was evaluated more than 10 g/kg in rats and mice.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.5
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• pp.350-357
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• 2001

This study was performed to evaluate an effect of soil water retention and chinese cabbage growth on application of super water absorbent(CPAM-AS-hyd). In seedling experiments, the CPAM-AS-hyd application rates were 0, 5 and 10kg/10a in bed soil of experimental field. The emergence percentage of chinese cabbage was increased by 9% with application of CPAM-AS-hyd otherwise emergence rates was delayed by 1 day. Water content in soil with CPAM-AS-hyd(10kg/10a) was 27.6%(v/v) at 10days after irrigation and that of control was 20.7%. The CPAM-AS-hyd application caused to alleviate wilting point by 5 days. The content of NO3-N in bed soil was increased with CPAM-AS-hyd application. In the field experiments, as the CPAM-AS-hyd application rates were 5kg/10a and 10kg $10a^{-1}$, the irrigation amounts applied during the growth periods were 1.87 ton, 1.65 ton and 1.53 ton at-0.2bar irrigation frequence and 1.38 ton, 1.25 ton and 1.15 ton at -0.5bar for growth period control, in the CPAM-AS-hyd of 5kg $10a^{-1}$ and CPAM-AS-hyd of 10kg $10a^{-1}$ plot, respectively. The CPAM-AS-hyd application caused to increase yield of chinese cabbage by 9~34% as compared to the control. The contents of $NH_4-N$ and $NO_3-N$ in soil were decreased with the CPAM-AS-hyd application in 10 days after transplanting of chinese cabbage, but the contents of those in soil were increased with the CPAM-AS-hyd application as compared to the control in 20 days after transplanting. The T-N, CaO, MgO and $K_2O$ contents in chinese cabbage increased due to the CPAM-AS-hyd application however $P_2O_5$ content was similar to the control.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.588-596
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• 1996

The optimum conditions of the 1st and 2nd distillation had been investigated to obtaine a high quality monomeric MDI and fire reactive polymeric MDI by purification of crude MDI. Effect of additives on the monomeric MDI's color change, dimerization and the reactivity of polymeric MDI with standard polyol system has been tested. When the monomeric MDI yield is approximately 32%, 4,4'-MDI content is above 98% in the monomeric MDI at the 1st distillation. When the separation ratio of initial portion and residue percentage, reflux ratio are set at respectively, approximately 20wt%, 9wt%, above 2 in order to minimize the content of 2,4'-MDI in monomeric MDI, the freezing point of final distilled monomeric MDI is above $38.4^{\circ}C$. Since the monomeric MDI is inherently unstable in the room condition, monomeric MDI easily changes it's color and conducts self-polymerization reaction. To increase the stability of monomeric MDI, the composition of antioxidant, which is composed of phenolic 1st antioxidant, phosphorus 2nd antioxidant, UV absorbent and Hindered amine light stabilizer are used, and benzoyl chloride as antipolymerization agent test are that APHA color is less than 20, dimer content is remained less than 0.36wt% after 45 days storage of monomeric MDI.