• 한국전기화학회:학술대회논문집
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• 2001.04a
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• pp.48-48
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• 2001

• 한국전기화학회:학술대회논문집
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• 2004.04a
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• pp.70-70
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• 2004

• 한국전기화학회:학술대회논문집
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• 2002.04a
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• pp.47-47
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• 2002

• 한국전기화학회:학술대회논문집
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• 2000.10a
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• pp.55-55
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• 2000

• 한국전기화학회:학술대회논문집
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• 2001.10a
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• pp.42-42
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• 2001

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.89.2-89.2
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• 2010

고체산화물 연료전지는 $800{\sim}1000^{\circ}C$인 고온에서 작동하므로 적용되는 밀봉재의 요구조건은 매우 중요하다. 본 연구에서는 SOFC 밀봉재로서 $SiO_2-B_2O_3-RO$계 결정화 유리를 선정하였으며 작동온도 부근에서 결정화를 유도하여 고온점성유동을 제어하고자 하였다. 따라서 $SiO_2-B_2O_3-RO$계에 RO인 CaO, SrO, BaO, MgO를 상호 치환하였을 때 결정상의 생성, 생성온도, 생성결정의 종류가 sealing 특성에 어떠한 영향을 주는가를 검토하였다. 결정화유리를 $800^{\circ}C$로 유지하였을 때 생성되는 주 결정상은 Calsium silicate, Strontium silicate, Barium silicate, Magnesium silicate이였으며 Strontium silicate 의 생성속도가 가장 빨랐으며 결정상은 불산으로 에칭하여 SEM으로 관찰하였다. Barium silicate를 유도한 결정화 유리가 $800^{\circ}C$에서 1000시간 유지하였을 경우 가장 내화학성이 우수하며 강도값도 154MPa로 가장 높았다. 또한 부분 결정화를 통해 $800^{\circ}C$ 점성유동이 제어됨을 고온현미경을 통해 관찰하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.3
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• pp.269-274
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• 2010

As a preliminary study on a SOFC-GT hybrid system integrated a with coal-gasification system, the influence of the concentrations of $H_2$ and CO in syngas on the performance characteristics of the hybrid system is investigated. It is expected that the differences in the heating values of fuels with different compositions trigger the off-design operation of the gas turbine and result in different performance characteristics of the overall hybrid system. Syngas compositions are found to affect the SOFC performance. Performance of hybrid system with carbon monoxide is poorer than the case with hydrogen. In the case of part-load performance with syngas, performance degradation at part-load operating conditions with hydrogen is more dominant than the case with carbon monoxide.

• Journal of the KSME
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• v.56 no.10
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• pp.38-43
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• 2016

고체연료인 석탄을 사용하기 편리한 기체나 액체연료로 변환하는 석탄가스화 기술은 1900년도 초 독일에서 필요한 연료의 많은 부분을 석탄을 이용해 사용했던 기술이며, 최근 석탄사용으로 인한 먼지, 황산화물 등 발생에 대해 상대적으로 친환경 설비인 IGCC 발전설비에 대해 소개하고자 한다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.9
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• pp.858-865
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• 2011

This paper describes the characteristics of hydrogen generation from solid-state $NaBH_4$ and fuel cell operation for fuel cell aircraft. The solid-state $NaBH_4$ was used for a high hydrogen storage density, and was reacted with hydrochloric acid to generate hydrogen. The hydrogen generation rate for the solid-state $NaBH_4$ reaction was measured at various conditions. As a result, the hydrogen generation rate was increased with the feed rate and concentration of hydrochloric acid, while not be affected by the reaction temperature. A fuel cell was connected with the solid-state $NaBH_4$ hydrogen generator. The stable power output was obtained at the gradual and sudden increases of electric loads.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.5
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• pp.12-18
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• 2014

A study of gas generator Fuel-Rich propellant for air-breathing propulsion system was performed in this paper. General solid propellant comprises a mean of 60% or more oxidizing agents. but, to develop the fuel-rich solid propellant increased the content of the metal fuel and reduced the content of the oxidizing agents by approximately 30%. Very high amount of heat per volume of fuel into the metal having the Boron was used. Amorphous Boron Powder was applied to propellant as beads type and it allowed to design more amount of metal fuel in the fuel-rich propellant. And the Combustion characteristics and properties of fuel-rich solid propellant according to the Boron-bead sizes were confirmed.