• Defense and Technology
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• no.8 s.174
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• pp.30-35
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• 1993

과학 1호로 로켓의 추진기관 개발을 통하여 항공우주연구소는 고체 추진제 로켓 모타 설계에 필요한 소프트웨어의 개발 및 그 활용, 그리고 경제적인 로켓 모타의 개발방법 등등 많은 것을 배웠습니다 또한 이는 앞으로 우주개발을 위한 새로운 로켓 추진기관 개발에 좋은 경험이 되었습니다 더욱 뜻깊은 것은 이번 과학 1호 로켓의 발사는 명실공히 산.학.연의 종합적인 연구체계로 이루어졌다는 것입니다

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.189-194
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• 2013

A sulfonated activated carbon (AC-$SO_3H$) was used as a solid acid catalyst for dehydration of sorbitol to isosorbide and its catalytic performance was compared with the commercial solid acid such as acidic ion exchange resin, Amberlyst-36, and sulfated copper oxide. The catalytic performance with 100% sorbitol conversion and 52% isosorbide selectivity was obtained over AC-$SO_3H$ at 423.15 K. Although AC-$SO_3H$ possessed only 0.5 mmol/g of sulfur content, it showed the similar dehydration activity of sorbitol to isosorbide with Amberlyst-36 (5.4 mmol/g) at 423.15 K. Based on the high thermal and chemical stability of AC-$SO_3H$, one-step reactive distillation, where isosorbide separation can be carried out simultaneously with sorbitol dehydration, was tried to increase the recovery yield of isosobide from sorbitol. The reactive distillation process using AC-$SO_3H$, the turnover number of AC-$SO_3H$ was 4 times higher than the conventional two-step process using sulfuric acid.

• Journal of Practical Agriculture & Fisheries Research
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• v.25 no.1
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• pp.20-35
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• 2023

Chemical preservatives have a good effect on antibacterial activity, but many side effects on the human body have been reported. Recently, the development of natural preservatives that are harmless to the human body and have preservative functions and self-efficacy is active. In addition, in order to increase the absorption rate of natural products by the human body, the method of fermentation using strains is also increasing. Therefore, this study selected varieties that are harmless to the human body and have good antibacterial activity. 1. The yield of origin, thickness and solvent was investigated. Scutellaria baicalensis Georgi was made in China and received a yield of 21.88% from 50% ethyl alcohol extract. Salvia miltiorrhiza Bunge was made in Korea and received a yield of 25.62% from 50% ethyl alcohol extract. Dryopteris crassirhizoma Nakai was made in China and received a yield of 6.50% from 70% ethyl alcohol extract. 2. The solid fermentation with the S. baicalensis and S. miltiorrhiza with B. Subtilis yield gained 24.40%, 39.30%, and D. crassirhizoma obtained 11.10% yield when fermented with L. casei. 3. After the liquid fermentation, a clear zone of 9mm was identified for the S. aureus strain in the S. baicalensis, and the antibacterial activity was not confirmed in S. miltiorrhiza and D. crassirhizoma. 4. When the S. baicalensis was fermented with L. Casei, it showed high antibacterial activity in C. albicans and S. aureus. S. miltiorrhiza showed antibacterial activity in S. aureus when it was solid with S. cerevisiae. When the spectators were solid with L. casei and S. cerevisiae, antibacterial activity was high in E. coli and S. aureus. Overall, the antibacterial activity after fermentation was much higher than when fermented. 5. The change in active ingredients was baicalin 101.57, baicalein 28.26, and wogonin 5.33mg/g in the S. baicalensis that did not ferment solid. When solid fermentation with S. cerevisiae, the content of baicalinin with baicalin 94.31, baicalein 30.41, and wogonin 3.57mg/g was found to have increased. S. miltiorrhiza that was not fermented, salvianolic acid A was 1.82mg/g, and when fermented with S. cerevisiae, it increased to 5.70mg/g. The active ingredients of the spectators were flavaspidic acid AP, flavaspidic acid PB, flavaspidic acid AB, and flavaspidic acid BB.

• Journal of the Korean Chemical Society
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• v.34 no.4
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• pp.352-359
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• 1990

An effecient gas chromatographic method is described to be used routinely for the rapid profiling and identification of biochemically important organic acids. It involves the solid-phase extraction of organic acids from aqueous samples using Chromosorb P as the solid sorbent and diethyl ether as the eluting solvent, with subsequent triethylamine treatment. The resulting triethylammonium salts of acids were directly converted to volatile tert-butyldimethylsiyl derivatives, which were simultaneously analyzed by two capillary columns of different polarity, DB-5 and DB-1701, under the identical temperature programming condition. The retention index (RI) and area ratio (AR) values of each peak measured on DB-5 and DB-1701 enabled rapid identification of acids by computer RI library search and AR comparison. The application of the present method to the organic acid profiling of various complex samples is demonstrated.

• Polymer(Korea)
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• v.36 no.2
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• pp.149-154
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• 2012

The amphiphilic copolymer by the conjugation of biocompatible chitosan and antioxidant lipoic acid was studied as a drug delivery carrier. The amphiphilic copolymer was self-assembled to form nanoparticles in the aqueous solution. 5-Fluorouracil widely used as an anticancer drug was encapsulated inside the nanoparticles by a solid dispersion method. The degree of branching of lipoic acid on chitosan was controlled to obtain the optimal condition for the drug delivery carrier. The sizes of nanoparticles were about 250 nm by the dynamic light scattering. The encapsulation efficiency of nanoparticles were about 10%. The copolymer with 42% degree of branching showed the best performance as a drug delivery carrier.

• Korean Journal of Agricultural Science
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• v.39 no.3
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• pp.395-405
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• 2012

Lipozyme TL IM-catalyzed esterification was carried out to produce functional hard fat (structured lipid, SL) using palm stearin (PS) and hydrolysate of pomegranate seed oil (HPSO) of 1:6 molar ratio. HPSO contained conjugated linolenic acid (CLnA, about 80%). The reaction was performed at non-solvent system and solvent (n-hexane) system using Lipozyme TL IM (10% of total substrates, w/w) for 12, 24, and 72 hr in a shaking water bath ($55^{\circ}C$ and 185 rpm), respectively. SL synthesized in non-solvent system (NH-SL) and SL synthesized in n-hexane system (H-SL) were refined after deacidification, respectively. Their physicochemical properties were compared to obtain desirable functional hard fat. The content of CLnA in NH-SL increased from 34.38% to 40.63% with increasing reaction time. Similar results also observed in H-SL resulting in 36.81~45.83% of CLnA. In triacylglycerol (TAG) composition, the main molecules of LnLnLn (Ln=linolenic acid, PN=36) and the LnLnP (P=palmitic acid, PN=40) were newly synthesized in NH-SL and H-SL with increasing reaction time. After 72 hr reaction, iodine values of NH-SL (136.49) and H-SL (140.37) showed high values because of the high content of CLnA. Solid fat index (SFI) in NH-SL was higher than that in H-SL at each measured temperature. The predominant polymorphic forms of NH-SL and H-SL obtained after esterification for 72 hr were the desirable crystalline structure of the ${\beta}$' form.

• JOURNAL OF ELECTRICAL WORLD
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• s.320
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• pp.66-71
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• 2003

연료전지는 환경에 친화적인 새로운 에너지기기로서, 업무$\cdot$가정용 전원, 자동차 등의 이동전원, 전자기기용 전원 등 많은 분야에 보급이 기대되고 있다. 그 중에서도 고체고분자 연료전지(이하 ''PEFC''라 함)는, 전해질이 고체로 취급하기 쉽고, 더욱이 동작온도가 실온(室溫)에 가까우며 값이 싸고 소용량화$\cdot$운전유연성이 기대되어, 산$\cdot$학$\cdot$연에서 개발이 활발히 추진되고 있다. PEFC 전원의 실용화는, 가정용으로 대표되는 소용랑 코제너레이션 전원으로 먼저 시작될 것으로 생각된다. 구체적으로는, 1kW 출력수준의 코제너레이션 전원 겸 급탕기(給湯器)를 가정에 설치하여 배열(背熱)을 유효 이용함으로써 연료비와 $CO_2$ 배출량을 경감하는 것이다. 여기서는, 이러한 가정용 전원에 대하여 우선 첫째로 전원 운용에 관련된 계산$\cdot$검토를 실시하고 연료비/$CO_2$ 배출량의 삭감효과를 조사했다. 그 결과에 의하면, 예상했던 대로 도입효과가 크게 기대되는 한편, 그 효과는 연료단가와 운전 상황에 따라서도 크게 좌우된다. 어떠한 환경에서도 확실하게 메리트가 있도록 전원의 가일층의 성능향상이 요망된다. 그 외에, 전원의 용량과 부분부하에 대한 검토가 중요하다. 또한, 시스템 시험에서는, 1kW 전원을 시험$\cdot$제작하여 성능시험, 코스트분석을 실시했다. 그 결과 배열회수와 전지/직류교환부의 성능으로 시장도입시의 목표에 가까운 것을 알 수 있었다. 한편 저(低)코스트화에 관해서는, 시스템을 간소하게 하는 기술을 개발중에 있다. 연료전지기술은 앞으로의 사회에 매우 중요하며, 보다 좋은 사회의 실현을 위해 개발에 계속 진력해 나갈 것이다.

• Analytical Science and Technology
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• v.7 no.4
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• pp.441-453
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• 1994

Two extraction methods, liquid-liquid extraction(LLE) and solid-phase extraction(SPE), coupled with GC/MS were compared as preconcentration procedures for priority pollutants in water. Among the semi-volatile priority pollutants, 11 acid and 44 base/neutral compounds were spiked in reagent water. With LLE, which is a modification of EPA Method 625, the overall mean recovery of the 54 compounds was 91% with a mean relative standard deviation(RSD) of 4.6%. With SPE, the overall mean recovery of the 52 compounds was 53% with a mean RSD of 8.9%. The detection limits of both methods were in the range of $1{\sim}5{\mu}g/l$.

• Journal of the Korean Chemical Society
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• v.41 no.8
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• pp.399-405
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• 1997

We examined the determination of trace amount of germanium in rocks and sediments by hydride vapor generation-ICP-AES. Germanium is formed volatile compounds with various types of acid reagents, but volatilizing of germanium was decreased in the presence of $H_3PO_4$. Sediments and rocks can be dissolved by mixed acids of $HF-HNO_3-H_3PO_4$ without volatilizing loss of germanium in open digestion system and it was possible to determine germanium by hydride generation-ICP-AES without further sample treatment. Detection limit of Ge is reached to 0.08 ppb under the condition of 5M $H_3PO_4$ and 1% $NaBH_4$ as a supporting acid and a reducing reagent, respectively. The measured values by hydride generation-ICP-AES agreed well with the reference values of SRMs as well as the values determined by solution nebulization-ICP-MS.

• Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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• 2003.10a
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• pp.218.1-218
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• 2003

쌀을 기질로 하는 유산균 음료 발효에서 Bacillus와 효모의 혼합배용을 이용한 고체상태 예비발효와 extruder를 이용한 압출조리 전처리가 유산균의 생육을 증진하는 효과에 대하여 검토하였다. Bacillus laevolacticus 와 Saccharomyces cerevisiae의 혼합배양을 쌀과 탈지 대두분의 혼합물에 접종하여 고체 상태로 45$^{\circ}C$에서 배양한 후 자가발열형 단일촉압출성형기를 통하여 처리함으로서 살균과 조직의 변화를 도모하였다. 이렇게 처리된 물질을 분산액으로 만들어 Lactobacillus plantaum 과 Leuconostoc mesenteroides 혼합배양을 접종하여 유산발효시켰다. 예비발효와 압출조리에 의하여 유산균의 증식속도와 산생성이 증가하였으며 가용성 고형분의 함량이 크게 증가하였고 분산 안정성이 향상되었고 관능적 기호도 증가하였다.