• Title/Summary/Keyword: 고온 플라즈마

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Optimization of DME Reforming using Steam Plasma (수증기 플라즈마를 이용한 DME 개질의 최적화 방안 연구)

  • Jung, Kyeongsoo;Chae, U-Ri;Chae, Ho Keun;Chung, Myeong-Sug;Lee, Joo-Yeoun
    • Journal of Korea Society of Industrial Information Systems
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    • v.24 no.5
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    • pp.9-16
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    • 2019
  • In today's global energy market, the importance of green energy is emerging. Hydrogen energy is the future clean energy source and one of the pollution-free energy sources. In particular, the fuel cell method using hydrogen enhances the flexibility of renewable energy and enables energy storage and conversion for a long time. Therefore, it is considered to be a solution that can solve environmental problems caused by the use of fossil resources and energy problems caused by exhaustion of resources simultaneously. The purpose of this study is to efficiently produce hydrogen using plasma, and to study the optimization of DME reforming by checking the reforming reaction and yield according to temperature. The research method uses a 2.45 GHz electromagnetic plasma torch to produce hydrogen by reforming DME(Di Methyl Ether), a clean fuel. Gasification analysis was performed under low temperature conditions ($T3=1100^{\circ}C$), low temperature peroxygen conditions ($T3=1100^{\circ}C$), and high temperature conditions ($T3=1376^{\circ}C$). The low temperature gasification analysis showed that methane is generated due to unstable reforming reaction near $1100^{\circ}C$. The low temperature peroxygen gasification analysis showed less hydrogen but more carbon dioxide than the low temperature gasification analysis. Gasification analysis at high temperature indicated that methane was generated from about $1150^{\circ}C$, but it was not generated above $1200^{\circ}C$. In conclusion, the higher the temperature during the reforming reaction, the higher the proportion of hydrogen, but the higher the proportion of CO. However, it was confirmed that the problem of heat loss and reforming occurred due to the structural problem of the gasifier. In future developments, there is a need to reduce incomplete combustion by improving gasifiers to obtain high yields of hydrogen and to reduce the generation of gases such as carbon monoxide and methane. The optimization plan to produce hydrogen by steam plasma reforming of DME proposed in this study is expected to make a meaningful contribution to producing eco-friendly and renewable energy in the future.

A Study on the Plasma Hot Machining to Improve the Machinability of Inconel 718 (Inconel 718 의 절삭성 개선을 위한 플라즈마 고온 절삭 가공법에 관한 연구)

  • 김진남
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.4 no.3
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    • pp.67-76
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    • 1995
  • An experimental study of hot machining has performed to improve the machinability of Inconel718. This experiment used plasma are for heating materials and Whisker0reinforce aluminum oxide ceramic tool insert. An assembled plasma heating system are described and experimental results from both conventional and plasma hot machining of Inconel 718 are compared. The experiments with plasma heating demonstrated the following effectiveness. 1)The cutting force was reduced with increasing surface temperature of workpiece from 450$^{\circ}C$ up to 720$^{\circ}C$ as much as approximately from 20 to 40%. 2) Surface roughness(Ra) was improved by as much as a factor 2 in case of one pass cutting with new ceramic tool inserts.3) The depth of cut notch were at promary cutting tool was significantly reduced.

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High Temperature Friction Characteristic of $Al-SiC_{p}$ Composite Coating Prepared by Plasma Thermal Spray (플라즈마 용사에 의해 제조한 $Al-SiC_{p}$ 복합재료 코팅층의 고온마찰특성)

  • 민준원;유승을;서동수
    • Tribology and Lubricants
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    • v.19 no.5
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    • pp.274-279
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    • 2003
  • $Al-SiC_{p}$ composite layer was prepared by plasma thermal spray on aluminum substrate. The homogeneously dispersed composite powder for thermal spray was fabricated by mechanical alloying with ball mill. The friction tests of the composite layers and commercial aluminum alloys for comparison were performed in the temperature range of 20∼$260^{\circ}C$ with the interval of $40^{\circ}C$ with steel counter-face. Friction coefficient was recorded during test sequence, and the microstructure of surface and debris was investigated by optical and scanning electron microscope. Friction coefficients of composite and aluminum alloys at room temperature were similar except pure aluminum. As the temperature increase, friction coefficient was increased rapidly in AC4C, AC2A. But friction coefficient of $Al-SiC_{p}$ composite was not increased so much up to $220^{\circ}C$. Consequently, the reinforcement of $SiC_{p}$ into aluminum matrix increased the stability of friction coefficient as well as wear resistance.

High Temperature Wear Behavior of Plasma-Sprayed Zirconia-Alumina Composite Coatings (플라즈마 용사된 알루미나-지르코니아 복합체의 고온 마모.마찰 거동)

  • 김장엽;임대순;안효석
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.33-38
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    • 1996
  • High temperature wear behaviors of plasma-sprayed ZrO$_{2}$-$Y_{2}O_{3}$ composite coatings were investigated for high temperature wear resistance applications. The composite powders containing 20, 50, 80 vol% of alumina for plasma spray were made by spray drying method. Wear tests with composite coated specimens were performed at temperature ranges from room temperature to 800$^{\circ}$C. Wear tests were also carried out with heat treated specimens at room temperature. The microstructural change of coatings and the worn surface were examined by SEM and XRD. Sharp increase of wear loss at high temperature wear test was observed in specimens containing 50 and 80 vol% alumina. Similar trend was observed in the heat treated coatings. The measured residual stress was increased with increased alumina contents and heat treating temperatures. Residual stress induced during heat treatment appeared to be responsible to the observed harmful effect of alumina additions on the high temperature wear.

Steady State Analysis of Nozzle Ablation Under High Temperature and High Pressure Arc Plasma (고온ㆍ고압 아크 플라즈마 하에서의 정상상태 노즐용삭 해석 기술)

  • 이병윤;송기동;정진교;박경엽
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.9
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    • pp.395-399
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    • 2003
  • In this paper, physical phenomena which are related to the high temperature and high pressure arc plasma generated during the fault current interruption by SF6 gas circuit breakers are reviewed. In particular, in order to analyze nozzle ablation induced by the heats transferred to the surface of the poly-tetrafluoroethylene(PTFE) nozzle through arc radiation, a governing equation for the calculation of PTFE concentration is added to the governing equations for SF6 arc Plasma analysis. The proposed method is applied to the steady state analysis of $SF_6$ arc plasma generated by direct current taking account of the nozzle ablation and the results are presented.

NUMERICAL ANALYSIS OF A 150KW HUELS TYPE ARC HEATER (150kW급 Huels형 아크 히터 내부의 유동 해석)

  • Han, S.H.;Byeon, J.Y.;Kim, K.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.562-566
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    • 2010
  • Numerical analysis of 150kW Huels-type arc jet was performed using compressible Navier-Stokes CFD code. To consider chemical reaction by high temperature, the flow was assumed to be chemical equilibrium states. As a turbulence and a radiation model, the two-equation k-epsilon model and the 3-band radiation model were adopted, respectively. Mass flow rate and current density were given as conditions for calculations. In this study, two kinds of mechanisms for injection of air flow wire considered. One is that air is provided by left wall surface and the other is that air is injected from upper wall surface. The pressure, density and temperature contours of two cases were compared and heat transfer rates were estimated. The numerical results of two cases were not much different to each other. However, in real 150KW device, air is injected from upper wall surface with swirl. To calculate more accurately, swirl effect is must be considered.

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Characteristics for Adsorption and Thermal Decomposition of Ammonia and Trimethylamine on Honeycomb Photocatalyst (허니컴형 광촉매에 대한 암모니아와 트리메틸아민의 흡착 및 열 분해 특성)

  • 김대중;손건석;고성혁;윤승원;송재원;강진아;이귀영;이재의
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.295-296
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    • 2001
  • 동물 축사, 폐수 및 하수처리장, 피혁공장, 생선처리시설 등에서 주로 발생하는 암모니아(NH$_3$) 및 트리메틸아민(($CH_3$)$_3$N)과 같은 악취 물질 제거에 대한 많은 연구가 진행되고 있다. 악취 물질에 대한 처리 기술에는 직접 산화법, 고온 연소법, 효소분해법, 흡착법, 촉매 산화법, 플라즈마 제거법 등과 같은 악취 물질을 분해 제거하는 방법과 단순히 악취를 은폐시키는 마스킹법이 있다. (중략)

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Raman 분광법에 의한 질화된 GaAs의 결함 연구

  • 고의관;김은규;민석기;조성호
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.121-122
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    • 1998
  • Raman 분광학을 이용하여 질화된 GaAs 박막의 특성을 조사 하였다. GaAs 질화 과 정은 상온에서부터 $600^{\circ}C$까지의 여러 가지 온도에서 ECR질소 플라즈마를 조사함으로써 시 료를 준비하였다. Raman 측정의 결과 온도가 증가함에 따라 세로 광학(LO) 포논 및 가로 광학 (TO) 포논모드의 진동수는 낮은 진동수로 이동하였고 또한 LO-TO 분리 크기 역시 감소하였다. 진동수의 이동의 근원을 격자상수의 변화에 따른 변형 및 유효전하의 감소등으 로 설명하였다. LO 포논 모드의 밴드 폭의 넓어어지는 $600^{\circ}C$에서 가장 컸으며 이는 고온에 서 표면의 무질서 구조가 가장 많이 일어났음을 뜻한다. 이와 같은 원인으로 질화된 GaAs 박막의 몇 가지 물리적 변수인 결함의 비율, 변형의 크기 및 상관 길이 등을 계산하였다.

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High Temperature Wear of Plasma-Sprayed $ZrO_2-Y_2O_3$ Coatings (플라즈마사용법에 의한 $ZrO_2-Y_2O_3$ 코팅의 고온에서의 마모)

  • 김장엽;임대순;안효석
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.1059-1065
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    • 1993
  • The sliding wear behavior of the plasma sprayed zirconia containing 8wt% yttria was investigated over a range of room temperature to 800℃. Both of the friction coefficient and the wear loss increased reaching its maximum at about to 499℃. and then decreased again with increasing temperature up to 800℃. The worn surface at elevated temperature were observed and analyzed by scanning electron microscopy and X-ray diffractometer to study the mechanisms of high temperature wear behavior. Surface morphology of the worn samples changes with temperature. Monoclinic (m)/tetragonal (t) x-ray peak intensity ratio of wear debris and worn surface decreased with increasing temperature. Non-transformable tetragonal (t') to metastable tetragonal (t) phase transformation of worn surface increased with increasing temperature. The results indicate that dehumidification and above phase changes are contributing to the high temperature wear behavior of the plasma sprayed ZrO2-Y2O3 coatings.

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Charge Density Modeling of Silion Nitride Thin Films Using Neural Network (신경망을 이용한 실리콘 나이트라이드 박막의 전하밀도 모델링)

  • Gwon, Sang-Hui;Kim, Byeong-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.114-115
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    • 2007
  • 플라즈마 응용화학기상법을 이용하여 Silicon Nitride (SiN) 박막을 증착하였다. PECVD 공정은 Box Wilson 실험계획표를 이용하여 수행하였다. SiN박막의 전하밀도를 신경망과 유전자 알고리즘을 이용하여 모델링하였다. 개발된 모델을 이용하여 전하밀도에의 $N_2$$NH_3$의 영향을 다양한 온도에서 고찰하였다. $N_2$ (or $NH_3$)의 증가에 따라 전하밀도는 증가하였으며, 이는 전하밀도의 [N-H]에의 강하게 의존하고 있음을 보인다. 전하밀도는 고온에서의 $NH_3$의 증가, 또는 높은 $NH_3$ 유량에서의 온도의 증가에 따라 급격히 증가하였다. 굴절률 모델과 비교할 때, 이 같은 현상이 [N-H]의 증가에 기인하는 것으로 해석되었다.

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