• Journal of the Korean Ceramic Society
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• v.42 no.3 s.274
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• pp.188-192
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• 2005

The conversions to SiC-based ceramics of a polycarbosilane (PCS) with and without oxidation curing were carried out. A yield and an oxygen content of conversed SiC-based ceramics were evaluated. The weight losses of conversed SiC-based ceramics by both processes analyzed to estimate the high temperature stability after heat treatment at high temperature in vacuum. The yield of SiC­based ceramics after oxidation curing was higher than that without curing process. However, the weight loss of SiC-based ceramics with oxidation curing was larger than that without curing process after heat treatment.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.98-103
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• 2018

Many coating technologies have been developed so far to improve the corrosion resistance, strength, abrasion resistance and other surface properties of materials and equipment. Among them, the formation of CCO (CaCoO, then CCO) thin films has been studied and used in the electronic material field. One of the characteristics of CCO thin films is that it is resistant to high temperature heat. Particularly, the method of forming the CCO thin film is relatively simple, and it was judged that it could be introduced into the existing equipment. Therefore, in this study, an experiment and analysis were carried out to determine whether the coating of CCO thin films can be applied to hot dip galvanizing facilities. A CCO thin film was formed on the surface of STS304 base material and oxidized in a Zn fume atmosphere in a $650^{\circ}C$ furnace with an air atmosphere. Oxidation was carried out for 30 days, after which the shape of the CCO thin film was confirmed by SEM and its corrosivity was analyzed through a potentiodynamic polarization experiment.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.4
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• pp.183-189
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• 2012

Surface treatments and their effects on high temperature properties for the Hastelloy X, which is a promising candidate alloy for high temperature heat-transport system, have been evaluated. For TiAlN and $Al_2O_3$ overlay coatings, the two different PVD (physical vapor deposition) methods using an arc discharge and a sputtering, were applied, respectively. In addition, a different surface treatment method of the diffusion coating by a pack cementation of Al (aluminiding) was also adopted in this study. To achieve enhanced thermal oxidation resistance at $1000^{\circ}C$ by suppressing the inhomogeneous formation of thick $Cr_2O_3$ crust at the surface region, a study for the surface modification methods on the morphological and structural properties of Hastelloy X substrates has been conducted. The structural and compositional properties of each sample were characterized before and after heat-treatment at $1000^{\circ}C$ under air and He environment. The results showed that the Al diffusion coating showed the more enhanced high temperature properties than the overlay coatings such as the suppressed thick $Cr_2O_3$ crust formation and lower wear loss.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.134-134
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• 2016

CMC(Ceramic Matrix Composites)는 $1500^{\circ}C$ 이상의 고온에서 내열성, 내산화성, 내식성이 우수하여, 초음속 비행체, 가스터빈 엔진 및 원자로용 초고온 부품 등에 수요가 증가하고 있다. 하지만 이러한 특성은 비산소 환경에 국한되는 것으로 약 $400^{\circ}C$ 이상의 산화 분위기에는 탄소섬유가 산화되는 문제로 인하여 적용의 한계를 가지고 있다. 따라서 CMC의 적용범위 확대를 위하여 내산화 코팅으로 CMC의 초고온 산화특성을 개선하는 것이 필수적이며, 장시간 초고온 산화환경 분위기에서 사용되기 위하여 안정적인 코팅기술이 최근 기술개발의 핵심현안으로 부각되고 있다. 본 연구에서는 pack cementation 공정을 이용하여 내산화성이 우수한 SiC 코팅층을 제조하였다. Pack cementation 공정에 사용된 코팅 분말은 57wt.% SiC, 30wt.% Si, 3wt.% B, 10wt.% Al2O3의 비율로 혼합된 것이다. 실험은 3D 직조된 CMC 모재를 혼합분말 내에 침적한 후, Ar 분위기에서 $1600^{\circ}C$, 4~12시간 반응시켜 수 마이크론 두께의 SiC 코팅층을 형성하였다. 더 우수한 산화 특성을 부여하기 위하여 pack 처리된 CMC 표면에 초고온 세라믹인 TaC 소재를 진공플라즈마 코팅 공정으로 적층시켰다. 제조된 코팅층을 SEM, XRD를 이용하여 미세구조 및 결정구조를 분석하였으며, pack cementation에 따른 내산화 특성을 비교 분석하고자 $2000^{\circ}C$에서 산화 실험을 진행하였다. 산화 실험 이후 미세구조 및 결정구조 분석으로 산화거동을 규명하고자 하였다.

• Korean Journal of Materials Research
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• v.10 no.11
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• pp.743-748
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• 2000

Amorphous carbons(neddle cokes), which are used as anode materials for lithium ion secondary batteries, were graphitized or heat-treated at high temperature in $N_2$ atmosphere and in Ar atmosphere, after adding $B_2O_3$. After then, using transmission eletron microscopy, their surface micro-structures and the formations and distributions of the second phases were analyzed. It was studied that such analyzed results were related to the cell capacities and efficiencies.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.36-43
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• 2002

The characteristics of spray has much effect on performance and emissions for automobile, diesel engine, gas turbine and combustion engines. So spray behavior after impinging the wall is very important for prediction the engine performance. This studies examined about impingement spray considering ambient density(18,24,30kg/ms), temperature(293,473K), impingement angle(0,30,45°). The images of impingement spray were obtained by the high speed video camera. After that we analyzed impingement spray characteristics to use this images. In this experiment, we found that 1) The spray width is reduced by increasing the ambient gas density and temperature,2) The growth of downstream is increased by increasing the impingement angle.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.133-133
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• 2003

가스센서는 인간의 오감 중에 후각 기능을 대신하는 것으로 사회 여러 분야에 응용범위가 확대되고 있다. 유기화합물(VOC; volatile organic compounds) 가스는 대기환경을 오염시켜 스모그를 발생하며 인체에 발암을 유발하는 물질이기 때문에 많은 문제와 규제가 예상되고 있다. 따라서 VOC를 감지하고 정확히 분석할 수 있는 환경 측정용 센서에 대한 요구가 절실해지고 있다. 최근에는 고온에서 동작하는 산화물 반도체 센서와는 달리 상온에서 유해성 가스를 감지할 수 있는 전도성 고분자의 특성이 알려지면서 센서 물질로 각광을 받고 있으며, 특히 유해성 가스인 VOC 가스를 검지 할 수 있는 센서로서 주목을 받고 있다. 전도성 고분자인 Polypyrrole를 pyrrole monomer, APS, DBSA를 사용하여 $0^{\circ}C$, 1기압에서 화학중합을 하였다. 만들어진 powder를 chloroform과 DBSA를 사용하여 용액을 만들어 전극에 dipping하고 7$0^{\circ}C$, 질소 분위기에서 1시간동안 건조를 하고 methanol에서 1시간동안 soaking 처리를 한 뒤 7$0^{\circ}C$, 질소 분위기에서 4시간동안 열처리 과정을 통해 센서를 제조하였다.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.410-415
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• 2000

A diesel engine is one of the major prime movers to its high thermal efficiency. But due to the recent attention far the environmental pollution, the emissions of diesel engine became to a important problem. So it is needed to understand the characteristics of diesel spray injected into a combustion chamber. The factor which controls the diesel spray are the injection pressure, the nozzle diameter, the impinging angle and the variation of pressure and temperature. In this paper, experiments were conducted far the variation of the environmental temperature(273k, 373k, 573k), free spray and impinging spray. And the notions of penetration, spray angle, axial distance for free spray, and axial distance, spray thickness from impinging wall fur impinging spray.

• Journal of environmental and Sanitary engineering
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• v.13 no.1
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• pp.1-8
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• 1998

Musty-odorous compound (Geosmin, 2-Methylisobrneol) 수용액 중에 초음파 (200kHz, $6.0W/cm^{2}$)를 조사시켜 조사시간에 따른 농도 및 취기의 변화를 고찰했다. 초음파 조사에 의해 이 물질들은 빠르게 분해되었고 분해 형태는 농도에 대한 유사1차 반응을 나타내었다. 공기 포화 분위기에서 이들의 초기 분해속도는 각각 2.5 $10^{-3}{\;}Msec^{-1}$(2-MIB), 3.2 $10^{-3}{\;}Msec^{-1}$ (Geosmin)로 나타났다. 초음파 조사 시 포화가스 (Envelope gas)의 영향은 아르곤(Ar) 산소($O_{2}$) 공기(Air) 질소($N_{2}$) 순서로 순수한 아르곤(Ar) 분위기에서 musty-odorous compound 류의 분해가 가장 빠르게 진행되었고 그 분해생성물로 CO, $CO_{2}$ 그리고 HCOOH, $CH_{3}COOH$ 등의 저급 유기산류가 검출되었다. 또한 이들의 분해반응은 물의 초음파분해에 따라 생성된 hydroxylradical에 의한 radical반응, cavitation bubble내에서의 고온고압에 의한 열분해 및 직접연소반응으로 진행됨을 알 수 있었다.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.4
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• pp.454-459
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• 2000

Diesel engine which has high thermal efficiency is one of the major movers. Recently, as people pay attention to the environmental pollution, the emission of Diesel engine becomes an important problem. So it is needed to understand the characteristics of diesel fuel spray injected into a combustion chamber to reduce the emission. The factors which control the diesel fuel spray are the injection pressure, the nozzle diameter, the impinging angle and the variation of an ambient pressure and temperature. In this paper, the experiments were conducted in the free spray and the impinging spray with various ambient temperatures(273K, 373K, 573K). And the behaviors of the diesel fuel spray, such as penetration, spray angle and axial distance in the free spray and axial distance and spray thickness in the impinging spray were studied.