• Title/Summary/Keyword: 고압화학

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Changes in The Chemical Composition of Apple Slices Pretreated with Supercritical Carbon Dioxide (건조 전처리 방법으로써 초임계 이산화탄소가 사과절편의 화학적 성분에 미치는 영향)

  • Lee, Bo-Su;Lee, Won-Young
    • Food Science and Preservation
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    • v.17 no.2
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    • pp.256-260
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    • 2010
  • We investigated changes in the chemical composition of apple slices after pretreatment with supercritical $CO_2$. Total phenolic levels increased with increasing temperature, although the concentrations were lower in pretreated material than in fresh or untreated slices. The levels of vitamin C and malic acid in pretreated slices were also lower than in untreated or fresh apple slices. Little difference was evident among various pretreatmentconditions. It was found that supercritical $CO_2$ served not as a solvent but rather as a means of tissue compression. Supercritical $CO_2$ compressed the apple slices, causing juice to be extruded. The juice disappeared when the supercritical $CO_2$ pressure was released.

Development of Integrated Design System for High Temperature, High Pressure Parts for Chemical Plants (화학플랜트 고온고압부 설계 효율화를 위한 일관시스템 구축)

  • Jeong Dong Gwan
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.1-6
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    • 1998
  • In order to increase design efficiency, it is required to design steam boiler pressure parts systematically considering daily start-stop operation and load variation. The objective of this research is to develope an integrated system for increasing design efficiency of boiler pressure parts. The developed system consists of three program modules: (1) flexibility design module for the header stub considering fatigue life, (2) fatigue limit calculation and life evaluation module for the thick-walled boiler pressure part under cyclic operation using TRD301 code, (3) drawing automation module for the header and drum producing design drawings, welding data and bill of materials.

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Numerical Study on Heat Transfer Characteristic in Combustor Nozzle (추진기관 노즐의 열전달 특성에 관한 수치적 연구)

  • Namkoung, Hyuck-Joon;Han, Poong-Gyoo;Lee, Kyoung-Hoon;Kim, Young-Soo;Jeong, Hae-Seung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.275-281
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    • 2007
  • For a cooling performance research of the combustor operated in a extreme environment of a high temperature and high pressure, we accomplished a cooling performance analysis. Generally a heat transfer characteristic in cooling passage is known well experimentally and theoretically, however heat flux in the combustion chamber isn't. In this study, fluid flow combined with heat transfer analysis is accomplished about a combustor nozzle. We tried to analyze the cooling performance with a heat transfer characteristic of a gas and coolant side in the view point of quantity on the mass flow rate to be supplied to the cooling channel. And finally, evaluation on the thermal safety of nozzle wall material was accomplished.

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Simulation and Optimization Study on the Pressure-Swing Distillation of Ethanol-Benzene Azeotrope (Ethanol-Benzene 공비혼합물의 분리를 위한 압력변환 증류공정의 전산모사)

  • Park, Hoey Kyung;Kim, Dong Sun;Cho, JungHo
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.450-456
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    • 2015
  • In the present study, modelling and optimization of ethanol-benzene separation process were performed using pressure-swing distillation. Order to obtain a reliable results, vapour-liquid equilibrium (VLE) experiments of ethanol-benzene binary system were performed. The parameters of thermodynamic equation were determined using experimental data and the regression. The pressure-swing distillation process optimization was performed to obtain high purity ethanol and high purity benzene into a low-high pressure columns configuration and a high-low pressure columns configuration. The heat duty values of the reboiler from simulation were compared, and the process was optimized to minimize the heat duty.

Spectroscopic Characterization of Phosphorus Doped HPHT Diamond (인이 첨가된 고온 . 고압 다이아몬드의 분광학적 특성)

  • Chung Jung In;Kim Hee-Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.291-297
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    • 2004
  • Phosphorus is one of the interesting impurities in diamond, because it produces n-type semiconducting character. The character has been studied with spectroscopic methods as well as electric method, but most of the diamond used for these studies are conducted by the CVD (Chemical Vapor Deposition) diamond. In this study, we synthesized the phosphorus doped HPHT (High Pressure and High Temperature) diamond and investigated the characterization using CL spectroscopy to determine how phosphorus incorporated. As a result, the undocumented peaks of 248 and 603 nm as well as the reported peaks (239 nm, 240 ~ 270 nm) at the previous studies were observed. These luminescence peaks may be due to the complex defect of phosphorus with other impurities such as boron and nitrogen.

Development of Real-Fluid Package Compatible with Chemkin for High-Pressure Kerosene/LOx Combustion (케로신/액체산소의 고압 연소해석을 위한 열역학/전달 물성치 해석 패키지 개발)

  • Kim, Seong-Ku;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.89-92
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    • 2011
  • The modeling of thermodynamic non-idealities and transport anomalies is a crucial prerequisite to realistically simulate the mixing and combustion processes of liquid propellants injected above critical pressures. This study has developed a specific set of subroutines to calculate the thermodynamic and transport properties based on the generalized cubic equation of state (EoS) in a coupled manner with the standard chemical kinetics packages (Chemkin). The existing flamelet analysis code is extended with the real-fluid package and applied to numerical investigation of local flame structures of kerosene and liquid oxygen at high pressure conditions relevant to the actual rocket engines.

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Preparation of B4C-Al2O3 Composite Powder by Self-propagation High-temperature Synthesis(SHS) Process under High Pressure (고압 자전 고온반응 합성법에 의한 B4C-Al2O3복합분말 제조)

  • 임경란;강덕일;김창삼
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.18-23
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    • 2003
  • Composite powder of$B_4C-A1_2O_3$was prepared from a mixed powder of$B_2O_3/A1/C$by SHS under argon pressure instead of using a chemical furnace. A mixture of$B_2O_3,$Al and C powder (equivalent amounts to the reaction,$2B_2O_3+4A1+C=B_4C+2A1_2O_3)$was ball milled for 2 h. The mixed powder was placed in a SHS reactor and filled with 10 atm of argon gas and ignited. The inner and outer products were the same by XRD analysis. It was consisted of a composite powder of$B_4C-A1_2O_3$without $AlB_{12}/C_2$which was always produced using a chemical furnace. The composite powder was about$60~100{mu}m$size which was composed of crystalline particles of about 0.3~l${mu}m$size. But when 15 atm of argon was employed, partial sintering took place to give rise hard composite powder of$15~25{mu}m$$B_4C$with $0.1~0.2{mu}m$$A1_2O_3.$

Reactivity of SO2 Catalytic Reduction over Sn-Zr Based Catalyst under High Pressure Condition (고압조건에서 Sn-Zr계 촉매상에서 SO2 촉매환원 반응특성)

  • Park, Jung Yun;Park, No-Kuk;Lee, Tae Jin;Baek, Jeom-In;Ryu, Chong Kul
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.316-321
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    • 2010
  • The $SO_2$ catalytic reduction was carried out under the condition of high pressure in this study. Sn-Zr based oxide and CO were used as the catalyst and reducing agent for the reduction of $SO_2$ to element sulfur, respectively. In order to compare the reactivity with the pressure on the catalytic process, the reactivity tests were performed under the conditions of atmospheric pressure and 20 atm. $SO_2$ conversion, the element sulfur yield and COS selectivity were also compared with changing the reaction temperature, $CO/SO_2$ mole ratio and the space velocity(GHSV). $SO_2$ conversion increased with increasing temperature and $CO/SO_2$ mole ratio under the condition of atmospheric pressure and element sulfur yield decreased due to the production of COS by the series reaction of CO and the produced sulfur. However, high $SO_2$ conversion and high element sulfur were obtained under the condition of 20 atm. It was concluded that COS decreased due to the condensation of the produced element sulfur under the condition of high pressure. Therefore, the high sulfur yield for $SO_2$ catalytic reduction could be profitably obtained under the condition of high pressure.

Changes in Lactic Acid Bacteria and Physicochemical Properties of Yogurt Made with High Pressure Processing Treated Milk (고압처리 원유로 제조한 발효유의 저장 중 유산균 수 변화와 이화학적 특성)

  • Ahn, Sung-Il;Chung, In-Ae;Chung, Woon-Si;Jhoo, Jin-Woo;Kim, Gur-Yoo;Jeon, Jung-Tae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.6
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    • pp.889-893
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    • 2016
  • This study was carried out to investigate the physicochemical and fermentation properties of yogurt made from high pressure processing (HPP) treated milk. Raw milk and commercial yogurt starter were used to make yogurt. Raw milk was HPP treated at 350 or 450 MPa (HPP 350 or 450) for 15 min or heat treated at $80^{\circ}C$ for 10 min. The numbers of lactic acid bacteria of the HPP treated group (HPP yogurt) rapidly increased during 2~4 h, whereas there was not significant difference from control (P<0.05). Titratable acidity of all samples increased, and pH decreased during storage from 0.99 to 1.24%, as well as from 4.59 to 4.20, respectively. It is confirmed that these values are in general ranges for yogurt. Control showed higher viscosity than HPP 350. Syneresis was significantly lower than that of the control (P<0.05). Based on the data obtained from the present study, HPP treatment was effective to enhance the quality of yogurt.

Observation of Dendritic Spines of Purkinje Cell Using High-Voltage Electron Microscopy (고압전자현미경을 이용한 소뇌 조롱박세포 가지돌기가시 관찰)

  • Rhyu, Im-Joo;Lee, Kea-Joo;Suh, Young-Suk
    • Applied Microscopy
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    • v.31 no.1
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    • pp.1-8
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    • 2001
  • The morphological features of neuronal dendritic spines are changed their shapes, sizes and density in response to physiological or pathological conditions . Therefore, exact analysis of spines warrants understanding of neuronal function. The size of the spine is at the borderline of resolution with light microscopy. High voltage electron microscopy Provide excellent resolution of the spines with proper stain techniques thanks to its higher resolution and penetration power. We evaluated more effective staining method for observing dendritic spines after labeling Purkinje cells with anti-calbindin 28 kD immunohistochemistry or Golgi staining methods. 4 fm thickness sections were observed with high voltage electron microscopy and some morphometric analyses were performed. Both Golgi staining and immunohistochemistry revealed the detail structures of the Purkinje cell such as soma, dendrites, and dendritic spines. High voltage electron micrographs with Golgi staining provide more precise morphology and are easy to measure. Average density of spine is $24.5{\pm}3.6/10{\mu}m$ and its length is $1.12{\pm}0.22{\mu}m$. For quantitative analysis of the spines, high voltage electron, micrographs with Golgi staining are more effective. This preliminary result is expected to be useful for further study of spine plasticity in various conditions.

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