• Applied Chemistry for Engineering
• /
• v.8 no.1
• /
• pp.16-22
• /
• 1997

When platinum wan impregnated on carbon by methanol, surfactant have an important effect on the stability of platinum colloid. As the increase of amounts of surfactant enhanced the stability of platinum colloid, the particle size of platinum on carbon was diminished. But, after heat treatment, residue of surfactant remained in electrode to decrease current density of oxygen reduction. To remove surfactant, as temperature of heat treatment enhanced, platinum particle was aggromerated and current density was decreased.

• Korean Journal of Materials Research
• /
• v.4 no.3
• /
• pp.329-333
• /
• 1994

A large number of grain boundaries were seen to crack in near-eutectic solder joints of leadless ceramic chip carriers (LLCC's) during thermal cycling at temperature ranges from -$35^{\circ}C$ to +$125^{\circ}C$ with lhr time period. One potential explanation for this type of cracking might be the presence of embrittling species on the boundary. Although there do not appear to be any instances reported in the literature of solders being embrittled by small amounts of contaminating species, the possibility of such an occurrence exists. The potential presence of impurities located at crack surfaces was inspected using Scanning Auger Microprobe(SAM) and it was found that intergranular cracking could be accomplished by the oxidation of the grain boundary. A physical model for fatigue crack growth was introduced, in which grain boundary separation took place under oxidation facilitated by sliding.

• Proceedings of the KWS Conference
• /
• 2006.10a
• /
• pp.196-198
• /
• 2006

이 연구는 CBN을 건전한 브레이징을 하기 위해서, CBN과 금속필러메탈 접합계면에서의 금속성분과 산화물, 탄화물의 거동을 분석하는데 있다. 진공 인덕션 브레이징으로 온도는 $950{\sim}1100^{\circ}C$에서 브레이징 유지시간은 $5{\sim}30$분로 실시하였다. 금속필러로는 Ni-7Cr-3Fe-3B-4Si(wt.%)와 Ag-25Cu-5Ti(wt.%)을 사용하여 브레이징된 CBN은 $950{\sim}1000$도, 유지시간 10분 사이에서 각각 건전한 계면과 표면을 얻을 수 있었으며, 계면에서 Ti-rich상과 화합물이 확인되었다. 이상의 결과로 부터 화합물의 생성과 건전한 접합공정은 브레이징 온도와 시간이 좌우하며, N과 B, Ti의 함유량이 CBN의 브레이징 접합 특성의 중요변수로 생각되어진다. CBN과 Ni계/Ag계 브레이징 필러의 계면에서의 미세조직 및 화학반응의 메커니즘은 SEM, EPMA, XRD를 이용하여 분석하였다.

• Journal of the Microelectronics and Packaging Society
• /
• v.30 no.2
• /
• pp.52-59
• /
• 2023

The effects of dielectric curing temperature and temperature/humidity treatment conditions on the interfacial adhesion energies between Ti diffusion barrier/polybenzoxazole (PBO) dielectric layers were systematically investigated for Cu redistribution layer applications of fan-out wafer level package. The initial interfacial adhesion energies were 16.63, 25.95, 16.58 J/m² for PBO curing temperatures at 175, 200, and 225 ℃, respectively. X-ray photoelectron spectroscopy analysis showed that there exists a good correlation between the interfacial adhesion energy and the C-O peak area fractions at PBO delaminated surfaces. And the interfacial adhesion energies of samples cured at 200 ℃ decreased to 3.99 J/m² after 500 h at 85 ℃/85 % relative humidity, possibly due to the weak boundary layer formation inside PBO near Ti/PBO interface.

• Journal of the Korean Applied Science and Technology
• /
• v.31 no.4
• /
• pp.602-611
• /
• 2014

The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.

• Korean Journal of Materials Research
• /
• v.9 no.11
• /
• pp.1108-1111
• /
• 1999

The Peltier heat absorbed or evolved at the solidiliquid interface in the unidirectional solidification process could contribute to the increase of temperature gradient in liquid and growth velocity, and the enhancement of crystal orientation. In this study, in order to measure the Peltier heat generated at the solidiliquid interface as a way of application to crystal growth, the thermoelectric effects were investigated on the temperature changes at the solid- and liquid-phase of the same material and its interface. Through the theoretical consideration, it was possible to separate sole Peltier. Thomson or Joule heat from the temperature changes due to current density, polarity, and temperature gradient. Thomson coefficient of solid- and liquid-phase as well as Peltier coefficient at the solid/liquid interface could be obtained.

• Korean Journal of Materials Research
• /
• v.5 no.1
• /
• pp.123-131
• /
• 1995

Natural convection in bridgman growth and it's effect on macrosegregation in unidirectionally solidified off-eutectic alloys were examined in this study. AlCu off-eutectic alloys(27.5wt% ~35. 6wt% ) were solidified upward or downward for producing a different natural convection and then Cu concentrations of off-eutectic composites were measured as a function of solidified fraction. Solutal and temperature distributions ahead of the solid/liquid interface were measured on quenched specimen. When hypo-utectic AlCu alloys are directionally solidified with downward growth, considerable macrosegregation occurs due to flow induced by thermal and solutal convection in melt. Soultal convection affects the macrosegregation of hyper-eutectic AlCu alloys more severely than thermal convection. Solute composition at solid/liquid interface of offkutectic composites was eutectic and also temperature was near eutectic point without large undercooling.

• Journal of the Korean Chemical Society
• /
• v.50 no.3
• /
• pp.190-195
• /
• 2006

The critical micelle concentrations (CMC) and the counter ion binding constants (B) in a micellar state of the mixed surfactant systems of sodium dodecylbenzenesulfonate (DBS) with polyoxyethylene(4) lauryl ether (Brij 30) in water were determined as a function of 1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method from 288 K to 308 K. Various thermodynamic parameters (Smo, Hmo, and Gmo) for the micellization of DBS/Brij 30 mixtures were calculated and analyzed from the temperature dependence of CMC values. The measured values of Gomare all negative but the values of Smo are positive in the whole measured temperature region. On the other hand, the values of Hmo are positive or negative, depending on the measured temperature and 1.

• Journal of the Korean Electrochemical Society
• /
• v.3 no.4
• /
• pp.191-195
• /
• 2000

Electrochemical properties of the oxygen electrode in phosphoric acid fuel cell have been studied using AC impedance method as a function of applied potential, operating temperature and teflon content in the electrode. The oxygen electrode reaction in the $105wt.\%$ phosphoric acid is characterized by a parallel resistive component, $R_p$ and a capacitive component, $C_p$ with serial electrolyte resistance, $R_s$. The conductivity of the phosphoric acid is found to be 0.31-0.47 S/cm in the range of $130\;to\;190^{\circ}C$ from the measured impedance. The increase of applied potential and temperature produced the decreased RP and the increased $C_p$, which means the increase of the oxygen electrode reaction rate. The single cells with the cathode of various teflon contents were tested, and the cathode with $40wt.\%$ teflon showed good performance, which is considered to be related to an optimized impedance behavior.

• Applied Biological Chemistry
• /
• v.37 no.6
• /
• pp.463-471
• /
• 1994

Physicochemical properties, gelatinization and retrogradation characteristics of surfactant added sweet potato starches were investigated. Three different surfactants, SSL (sodium stearoyl-2-lactylate), Dimodan (mono/diglyceride) and SE1670 (sucrose fatty acid ester 1670) were used. Shapes and crystallinities of starch granules were not changed by the addition of surfactants. Total lipid contents increased and the amylose content decreased by the addition of surfactants and the order was as follows: SE1670>SSL>Dimodan. The swelling power and solubility at $80^{\circ}C$ decreased in the surfactant added starches. By amylograph, initial gelatinization temperature of untreated sweet potato starch was $72.5^{\circ}C$, and did not change by the addition of surfactants, but SE1670 or Dimodan added starch showed the peak viscosity. The peak temperature of gelatinization and enthalpy of untreated starch by DSC were $53.9^{\circ}C$ and 1.3cal/g, respectively. The peak temperature increased by the addition of surfactants, while the enthalpy decreased. In gelatinization by alkali, the viscosity was lower in surfactant added starches than in untreated starch at concentration. The degree of retrogradation by ${\alpha}-amylase-iodine$ method was a lower in SSL and SE1670 added starches than untreated starch and the enthalpy by DSC also decreased in surfactant added and retrograded starches.