• Title/Summary/Keyword: 경화온도

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작물별 주요 병해 - 수박

  • Lee, Se-Won
    • Life and Agrochemicals
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    • s.250
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    • pp.36-37
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    • 2009
  • 보통 $7\sim8$월에 수확하는 수박은 수분이 96%로 대부분이 당질이며 비타민은 극히 적으나 많은 양의 과당은 신장병에 좋다고 한다. 주과육 중에 있는 citrulline과 arginine은 이뇨효과는 껍질 쪽이 뛰어나다. 또한 씨에는 linoleic acid가 풍부하여 동맥경화 예방 효과가 있다. 저장은 보통 최적 온도 $2.2\sim4.4^{\circ}C$, 최적 습도 $80\sim85%$의 저온이며 $1\sim2$주간 저장 할 수 있다.

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Setting Shrinkage, Thermal Expansion Coefficient and Compressive Strength of Recycled PET Polymer Concrete with Montmorillonite (몬모릴로라이트를 이용한 재활용 PET폴리머 콘크리트의 경화수축, 온도팽창계수, 압축강도)

  • Jo Byong-Wan;Tae Ghi-Ho;Lee Du-Wha
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.205-212
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    • 2004
  • Recently, as concerns over environmental issues are raised more and more trend to use recycled waste for producing construction materials is also raised. Especially, a case of waste resin is considerably destroying the environment due to disposal way that most waste resin produced is disposed of landfill. This study is performed by polymer concrete with recycled PET resin in terms of obtaining safely clean construction resources and protection of environment. High setting shrinkage and sensitivity to heat are main disadvantages of Polymer Concrete (PC) despites of a lot merits. The aim of this study is to investigate basic properties such as setting shrinkage, length change and sensitivity to heat about PET recycled polymer concrete. The other is to check the possibility of use of Montmorillonite as one of a lot of additive without special coupling agent. As results of experiments, various properties of polymer concrete with recycled PET resin are similar with conventional PC except that polymerization time is longer. Montmorillonite was efficiently used to reduce setting shrinkage, length change and coenicient of thermal expansion related to heat with enhanced strength

Effects of Temperature on Diacylglycerol Production by Enzymatic Soli-Phase Glycerolysis of Hydrogenated Beef Tallow (온도조절이 고상계에 경화우지로부터 디글리세리드의 효소적생산에 미치는 영향)

  • Kang, Sung-Tae;Yamane, Tsuneo
    • Korean Journal of Food Science and Technology
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    • v.26 no.5
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    • pp.567-572
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    • 1994
  • Diglyceride was prepared by reaction of hydrogenated beef tallow and glycerol (GL) in the presence of a Pseudomonas lipase. Both substrates were mixed at the ratio of GL/Triglyceride of 0.5 which is the stoichiometric molar ratio for the complete conversion of triglyceride (TG) to diglyceride (DG). DG can be obtained by solid phase-glycerolysis of hydrogenated beef tallow without use of organic solvents or emulsifiers by careful control of reaction temperature. Optimized reaction temperature condition was as follows: An initial incubation at$60^{\circ}C$ for 2h followed by the first temperature shift down to $55^{\circ}C$ for 4h, and then the second shift down to $50^{\circ}C$ for up to 3 days. There was a large decrease in the content of TG during the first $60^{\circ}C$ incubation for 2h. Even a prolonged incubation at $60^{\circ}C$ could not make a change of the composition of the reaction mixture at liquid state. By controlling the temperature lower than $60^{\circ}C$, reaction mixtures were solidified. The reaction temperature at $50^{\circ}C$ below the melting temperature of hydrogenaed beef tallow gave an 71% optimum yield of DG after 72h enzymatic glycerolysis and about 73% of total DG was 1,3-DG.

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Improvement in Adhesion Properties of Epoxy/Polyamide/MPD Reactive Blends by means of AP Plasma Treatment and Morphological Tuning (상압 플라즈마 표면처리와 형태학적 조절에 의한 에폭시/폴리아미드/MPD 반응성 블렌드의 접착력 향상)

  • Song, Hyun-Woo;Kang, Hak-Su;Kim, Won-Ho;Marzi, Stephan;Kim, Byung-Min;Choe, Young-Son
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.284-289
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    • 2009
  • The morphology and mechanical properties of epoxy/polyamide/MPD reactive blends with various amount of polyamide were investigated. The cure behaviors, mechanical strengths, and morphological changes of the epoxy blend systems were analyzed by using DSC, UTM, and SEM, respectively. The amount of high soluble polyamide in epoxy ranged from 0 to 30 phr, and the cure reaction occurred at $170^{\circ}$ for 30 min. The start and maximum exothermic temperature in heat flows during cure reactions appeared at almost same temperature, indicating that soluble polyamide could rarely hinder the cure reactions. From the SEM images, it was found that the size of separated-phase was very fine about 100-300 nm, and at 20 phr of polyamide the boundary of separated-phase was unclear and the phase revealed co-continuous. By AP plasma treatment of specimen surface, the adhesion strength was increased by 20% due to enhanced surface free energy. By blending 20 phr of polyamide with epoxy, the adhesion strength was increased by 50% due to co-continuous phase in morphology. By considering the surface treatment of specimen and morphological tuning of the blends, it can be expected that the improvement in toughness and excellent adhesion strength can be achieved in structural adhesive systems.

Mathematical Modeling of Degree of Hydration and Adiabatic Temperature Rise (콘크리트의 수화도 및 단열온도상승량 예측모델 개발)

  • 차수원
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.118-125
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    • 2002
  • Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

The effects of heat-treatment on the mechanical properties of the Cu-bearing HSLA steels (Cu를 함유한 저합금 고장력강의 기계적 성질에 미치는 열처리의 영향)

  • Park, Tae-Won;Sim, In-Ok;Kim, Yeong-U;Gang, Jeong-Yun
    • Korean Journal of Materials Research
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    • v.5 no.3
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    • pp.333-344
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    • 1995
  • Cu를 함유한 2종의 저합금 고장력강(HSLA-A, HSLA-B)\ulcorner 기계적 성질에 미치는 시효처리의 영향을 조사하였다. 탄소량이 적음에도 불구하고 Cu첨가로 석출물을 생성시킴으로서 2합금 모두 $650^{\circ}C$에서 시효한 경우 양호한 강도(HSLA-A:Y.S 703Mpa, E.L 22.6% HSLA-B:Y.S 810 Mpa, E.L 23.8%)와 인성(HSLA-A:271.4J, HSLA-B:197.5J at -5$0^{\circ}C$)의 조합을 나타내었다. 50$0^{\circ}C$에서 시효할 때 가장 높은 항복 강도를 나타내나 인성은 아주 낮은 값을 나타내었다. 50$0^{\circ}C$이상 시효 온도가 증가하면 강도는 감소하고 인성은 증가하였다. HSLA-B강의 강도가 HSLA-A 강보다 높은데, \ulcorner칭 상태에서의 강도 차이는 경화능을 증가시키는 원소인 Ni, Mn, Mo, Cu의 첨가량 차이에 의한 기지 조직의 차이에 의한 것이며, 시효한 상태에서의 강도 차이는 기지 조직과 석출 강화에 기여하는 Cu량의 차이에 의한 것으로 판단된다. 시효 경화 곡선에서 $700^{\circ}C$에서의 경도 증가는 오스테나이트-페라이트 2상 영역으로부터 냉각시 생성된 “M-A constituents”에 의한 것이다. HSLA-A강과 HSLA-B강의 충격 천이 온도는 각각 -1$25^{\circ}C$와 -145$^{\circ}C$이었다.

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Study on matching property of mixed powder electrode and dielectric for application of PDP panel (PDP 패널 적용을 위한 복합분말 전극과 유전체의 상호 매칭성 연구)

  • Park, Jung-Ho;Ji, Mi-Jung;Choi, Byung-Heon;Lee, Jung-Min;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.92-92
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    • 2008
  • PDP의 저가화, 친환경화, 고화질화는 타 디스플레이와 경쟁을 위해 필수적이고 그로 인한 소재의 개발이 필요하다. 저가화는 부품, 공정에서도 가능하지만 소재에서의 원가가 상당부분을 차지하고 있기 때문에 소재 개발이 중요하며, 친환경화는 현재 유전체에서 많이 사용되고 있는 유해소재를 친환경 소재로 대체함으로써 개발이 이루어지고 있다. 그래서 우리는 현재 PDP에서 전극물질로 사용되어지는 고가의 Ag를 Gu입자에 Ag 박막으로 코팅한 Ag/Cu 전극 powder를 사용하여 저가의 전극 paste를 만들고 스크린 프린터와 노광장비를 사용하여 전극을 형성하였다. 그 후 친환경적인 Pb free 투명유전체를 입히고 전극과의 상호 매칭성을 연구 하였다. 결과적으로 기존 PDP 공정에서 볼 수 없었던 황변현상, 전극착색현상, 전극입자의 터짐성 등 많은 현상이 일어났지만, 기존 공정 온도보다 낮은 온도로 공정한 결과, 이러한 문제들이 줄어드는 것을 확인하였다. 이로써 공정단가의 저가화와 제품의 친환경을 가면서도 기존과 차이가 제품을 실현할 수 있을 것이다.

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High Power Diode Laser를 이용한 금형재료의 표면처리에 따른 재료의 물성 평가

  • Hwang, Hyeon-Tae;Kim, Jong-Do;Song, Hyeon-Su;Kim, Yeong-Guk;Kim, Jong-Ha
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.41.1-41.1
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    • 2009
  • 최근 금형은 자동차뿐만 아니라 여러 산업에서 필수적이며 제품의 품질은 물론 제조원가에 막대한 영향을 미친다. 이러한 금형은 침탄, 질화, 고주파담금질등에 의해 표면처리 되어져 왔으나, 이와 같이 기존의 처리 방법은 모두 처리물 전체를 가열하거나 균일한 가열을 하지 못하기 때문에 변형의 문제와 처리후의 후가공의 경비 문제, 그리고 극히 일부분만 경화가 필요한 부품에는 적용하기 어려운 문제점이 있다. 이러한 문제를 해결할 수 있는 표면처리로서 레이저 표면처리 방법이 대두되고 있으며, 레이저 표면처리는 레이저 빔을 피처리물의 표면에 조사하고 적당한 속도로 이동을 하게 되면 레이저조사부위가 급속하게 가열되고 레이저빔이 통과한 후에는 표면의 열이 내부로 열전도 되어 급속히 자기냉각(Self-quenching)됨으로서 표면에 새로운 기계적 성질을 갖게 하는 표면처리법이다. 이와 같이 레이저를 이용한 표면처리로 기존의 CW Nd:YAG 레이저 열원보다 효율이 좋은 HPDL(High Power Diode Laser)를 이용한 고효율, 고기능 금형 표면처리 후 재료적 물성을 평가하고자 한다. 평가방법은 레이저빔의 조사속도 및 온도변화에 따른 표면처리부, 열영향부 그리고 모재 부분에 대한 경도특성 및 미세조직 변화를 관찰하였다. 또한 조사속도 및 온도변화에 대해 경화깊이를 관찰하였다.

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The Thermal Properties Analysis of the Mixtures Composed with Epoxy Resin and Amine Curing Agent (에폭시 수지/방향족 아민 경화물의 배합비 변화에 따른 열적 특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young-Il;Kim, Young Chul;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.15 no.3
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    • pp.100-108
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    • 2014
  • In this work, a series of molar ratios composed with YD-128 and DDM were chosen based on the viscosity analysis. The mixtures of YD-128 and DDM with the different molar ratios were cured at $170^{\circ}C$ for 15 min followed by post cure at $190^{\circ}C$ for two hours. The thermal properties of the cured samples were investigated with DSC, TGA, DMA, and TMA. The conversion ratio of the mixtures of YD-128 and DDM (1 : 1.1) was calculated by dividing ${\Delta}H$ obtained from DSC experiments for each cured sample by ${\Delta}H$. The TGA data of the cured samples showed that the thermal stability and thermal degradation activation energy were proportional to the amount of DDM in the mixtures. However, the highest tan ${\delta}$, and the lowest thermal expansion data with DMA and TMA respectively were obtained from the stoichiometric mixture of YD-128 and DDM. Furthermore, the different ratio of mixtures were applied to test specimens to be cured at $170^{\circ}C$ to measure single lap shear strength with universal testing machine.

Mechanical Property and Thermal Stability of Epoxy Composites Containing Poly(ether sulfone) (폴리에테르설폰이 도입된 에폭시 복합재의 열 안정성 및 기계적 특성)

  • Lee, Si-Eun;Park, Mi-Seon;Jeong, Euigyung;Lee, Man Young;Lee, Min-Kyung;Lee, Young-Seak
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.426-432
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    • 2015
  • Poly(ether sulfone) (PES) embedded diglycidylether of bisphenol-A (DGEBA) epoxy composites were fabricated for improving its mechanical properties and thermal stability. The mechanical properties such as tensile, flexural and impact strength of the composites changed significantly with the introduction of PES. The value of the fracture toughness of this composite also was increased remarkably about 24%. Thermal stability of PES/epoxy composites also improved 12%, which was calculated with integral procedural decomposition temperature (IPDT). From the differential scanning calorimeter (DSC) result, the curing temperature and curing heat decreased according to the increase of PES contents. These were attributed to the good distribution and the formation of the semi-interpenetrating polymer networks (semi-IPNs) composed of the epoxy network and linear PES.