• Title/Summary/Keyword: 경질우레탄

Search Result 26, Processing Time 0.033 seconds

Open-Cell Rigid Polyurethane Foam Using Reactive Cell Opening Agents (반응성 기포개방제를 이용한 개방기포형 경질우레탄폼)

  • Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.14 no.5
    • /
    • pp.2524-2528
    • /
    • 2013
  • Cell opening characteristics dependent on the cell openers for the conventional formulation of a closed-cell polyurethane foam (PUF) was studied using 1-butanol and lithium salt of 12-hydroxystearic acid (Li-12HSA) as the reactive cell opening agents. While cell openining content of only 10.5 % was obtained for the sample with 4 phr of 1-butanol as the single reactive cell opener, that of 98.0% could be obtained for the sample with 2 phr of Li-12HSA as the reactive co-cell opener. As the results, it showed that a fully open-cell rigid PUF could be obtained by introducing a novel reactive cell opener, having a functional group able to form a bulky side-chain on the urethane networks, without severe loss of mechanical properties of the closed-cell PUF like cell size, bulk density, and thermal conductivity.

An Experimental Study on Reusing of Waste Materials in Ligh-Weigh Composite Bridge Deck for Civil Structures (폐기물의 재이용과 경량 합성 상판 개발을 위한 실험적 연구)

  • 김경진;박제선;민창동;오오다도시아끼
    • Magazine of the Korea Concrete Institute
    • /
    • v.6 no.5
    • /
    • pp.123-130
    • /
    • 1994
  • In this paper, a development of composite bridge decks was proposed for design of civil and architectural structures to reuse the empty cans and plastics etc. The experimental specimens were made of rigid foamed urethane taking advantage of corrosionlessness in steel bridge decks, and simplicity in the field construction. 'Therefore, introducing the empty cans into the rigid foamed urethane, this experimentation have been carried out to demonstrate and evaluate the structural behavior by means of loading and vibration tests in composite bridge decks. Consequently, it was possible that had a good effect on the structural behavior by absorbing the strain due to the low elasticity of rigid foamed urethane, and not influence to cans in composite bridges.

A study on the improvement for performance of floor finishing materials using poly urethane with water reacting urethane (수반응 우레탄과 바닥용 경질 폴리우레탄을 이용한 바닥마감재의 성능향상에 관한 실험적 연구)

  • Park Jin-Sang;Kang Hyo-Jin;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2006.05a
    • /
    • pp.43-46
    • /
    • 2006
  • In this study on the appliable Asphalt sheet of monolithic and inorganic matter waterproofing material using of field because of problem of complex waterproofing sheet. Before this cement polymer modified waterproof coating and appliable asphalt sheet of monolithic whether have stability by method of construction about all style waterproofing that evaluate to new method of construction development naturally big emphasis put and try to approach. Did performance test item first at, as a result, drew by suitable thing in all KS items. This is considered to have more effective spot construction work because if means that have stability by material as well as method of construction.

  • PDF

The Study on the Synthesis of Urethane Polymer and Their Application for the Exclusive Use of Soil Layer Transcription and the 1st Transcript of Historical Site (유구 전사 및 토층 전사 전용 우레탄 수지의 합성과 그 적용에 관한 연구)

  • Han, Won-Sik;Wi, Koang-Chul
    • Journal of Conservation Science
    • /
    • v.26 no.3
    • /
    • pp.335-340
    • /
    • 2010
  • Urethane resin applicable for the first transcription of historical site and transcription of soil layer were synthesized in order to replace the imported urethane resin, NS-10. Comparing to the NS-10, the urethane polymers showed similar penetration to wet soil and formed a stable layer of polyurethane during progress working the peeling off the polyurethane pre-product from epoxy surface of final product. The urethane resins used for the first transcription of historical site improved tensile strength, which is consistent with that of NS-10. In addition the urethane resin for transcription of soil layer was supplied with hardness that have a also same strong point as like NS-10. This property is advantage due to simplifying the transcription work of soil layer in backward. When we tested to the real ground soil as well as experimentation compressed soil with use these synthesis urethane resin, we ca get the satisfying result in penetration property and stability and these properties evaluated the resins as an advanced product serving better convenience for worker.

Effects of Polyol Types and Hard Segment Contents on the Crystallization of Thermoplastic Polyurethanes (열가소성 폴리우레탄의 결정화에 미치는 폴리올 종류 및 경질부 함량의 영향)

  • Kim Sung Geun;Li Ming Ji;Ramesan M. T.;Lee Dae Soo
    • Polymer(Korea)
    • /
    • v.29 no.2
    • /
    • pp.140-145
    • /
    • 2005
  • Effects of the polyol type and the hard segment content of thermoplastic polyurethane (TPU) on the crystallization of hard segments in TPUs were studied employing differential scanning calorimetry. Diols used for the preparation of TPUs were poly(tetramethylene ether glycol) (PTMEG), poly(propylene glycol) (PPG), polycaprolactone (PCL), poly(butylene adipate) (PBA) the molecular weights of which were 2000 and the hard segments contents of TPUs were $35\~44\;wt\%$. We found that crystallization of hard segments in TPUs were observed at higher temperatures and became faster with increasing hard segment contents of TPUs. The crystallization rate of TPU was also affected by the types of polyols used for the preparation of TPUs. It is postulated that lower miscibility of soft segments and hard segments results in higher crystallization rate and increase of cooling crystallization temperatures due to better hydrogen bending between hard segments in melts.

A Study on New Technology Development of Air Filter Sealing for Vehicles and Upper-under Cap (차량용 에어필터 Sealing 및 상.하 Cap의 신기술 개발에 관한 연구)

  • Yoon, Sung-Un;Kim, Jae-Yeol
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.18 no.4
    • /
    • pp.436-441
    • /
    • 2009
  • An air filter is a device to remove dust from the air supplied to the automotive engine. A requirement for the optimum air filter is to improve the capability to remove particles from the air it takes in, that is the efficiency and amount of dust collection. By removing dust from the air, the air filter prevents the engine cylinder from wear, reduces ventilation resistance, and thus improves engine output and guarantees intake performance. In order to guarantee such air filter performance, it is very important to properly seal the air filter. For passenger cars made in Korea, the air filters are fabricated with steel caps as their frames are large and their engine capacity is big. Recently however, European countries and Japan started using urethane for manufacturing the air filter, so that all foreign-made cars now have urethane filters. The urethanes used for air filters are applied in two ways: One is to use soft urethane for both top and bottom of the air filter and the other is to use soft urethane for the top and hard urethane for the bottom. Each of these method has unique problems. In this study, hard urethane is used for both top and bottom of the filter in order to improve those problems and increase the sealing efficiency. Especially for the top, NBR (rubber mold) is pre-settled in tough urethane and then the urethane is solidified through foaming, which makes it possible to develop a solid and double-sealed filter.

  • PDF

Preparation and Properties of Waterborne Polyurethanes Based on Mixtures of Hydroxy-Terminated Polybutadiene and Poly(propylene glycol) (수산기말단 폴리부타디엔/폴리 (프로필렌 글리콜) 혼합물을 이용한 수분산 폴리우레탄의 제조와 물성)

  • Lee Seon-Suk;Lee Si-Ho;Lee Dai-Soo
    • Polymer(Korea)
    • /
    • v.30 no.2
    • /
    • pp.152-157
    • /
    • 2006
  • Anionic or Zwitter-ionic waterbone polyurethanes (WPU) based on mixtures of hydroxy terminated poly-butadiene and poly(propylene glycol) were prepared and their physical properties were characterized. Particle size of WPU increased with increasing the content of HTPB. It was observed that the microphase separation of soft segments and hart segments increased with increasing the content of HTPB in the WPUs. Zwitter-ionic WPU showed stronger hydrogen bonds between molecules than anionic WPU after drying. Polyurethane films obtained after drying of WPUs exhibit besmechanical properties when the HTPB content among polyols for WPUs were 25wt%. It is postulated that such mechanical properties resulted from different microphase separation of soft segments and hard segments of polyurethane films obtainec after drying of WPUs.