• Title/Summary/Keyword: 결합 가능성

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Sequential Fractionation of Heavy metals from Mine Tailings and Two Series of Agricultural Soils (광미장과 두개의 농업토양통 토양으로 부터의 중금속의 연속 분획)

  • Chung, Doug-Young;Lee, Do-Kyoung
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.4
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    • pp.375-382
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    • 1999
  • In order to investigate the contamination characteristics of the heavy metals in the mine tailings of abandoned gold mine and its surrounding agricultural soils, a sequential extraction procedure of increasing reactivity in the dissolution processes of the heavy metals(Cd, Cu, and Pb) which were associated with solid and/or solution phase in soils was attempted to partition into six particulate fractions : exchangeable, bound to carbonate, bound to Fe-Mn oxides, bound to organic matter, residual, and soluble. Among indigenous heavy metals in the mine tailings, Pb was the most abundant and Cu and Cd were followed by. Fractionation result of Pb obtained from the triplicate samples of the mine tailings were in the order of Fe-Mn oxide> Carbonate> Residual> Organic> Exchangeable> Soluble, while Wolgok series were Exchangeable > Fe-Mn oxide > Carbonate> Organic> Residual> Soluable. However the other heavy metals studied were not followed this trend. The fractionation results of mine tailing and agricultural soils demonstrated that different geochemical fractions were operationally defined by an extraction sequence that generally followed the order of decreasing solubility. Therefore potential mobility and bioavailability of heavy metals as toxic pollution sources can be evaluated when studying the pollution levels of heavy metals in soils.

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Service Life Variation Considering Increasing Initial Chloride Content and Characteristics of Mix Proportions and Design Parameters (초기 염화물량의 증가와 배합 및 설계 변수 특성을 고려한 콘크리트 내구수명의 변동성)

  • Park, Sun-Kyung;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.236-245
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    • 2021
  • It is very important for structure designer to understand the service life variation since a wide range of service life is evaluated with changing exposure conditions and design parameters. Recently, for zero-carbon, waste plastic has been used for fuel for clinker production and this yields increase in chloride content in cement. This study is for evaluation of changing service life in the concrete with increasing initial chloride content due to usage of plastic-SRF(Solid Refuse Fuel) considering various exposure conditions and design parameters. For this, 4 levels of initial chloride content were assumed, and the service life was assessed using LIFE 365 program considering various environmental conditions including 3 levels of surface chloride content. As for analysis parameters, critical/initial chloride content, blast furnace slag powder replacement ratio, W/B(Water to Binder) ratio, cover depth, and unit mass for binder are adopted. Service life decreases with increasing initial chloride content and a significant reduction of service life is not evaluated permitting up to 1,000ppm of initial chloride content. With increasing slag replacement ratio, a longer service life can be secured since blast furnace slag powder has the effect of reducing the diffusion of external chloride ions and fixing the free chloride. It is thought that increasing initial chloride content up to European standard is helpful for enhancing sustainability and reducing carbon emission. Though the reduction in service life due to an increase in the initial chloride content is not significant in slag-concrete with low surface chloride content, careful consideration for mixing design should be paid for the exposure environment with high surface chloride content.

Research on the ancient iron technology of Jungwon, the center of iron industry (제철산업의 중심 중원에서 고대 제철기술을 탐구하다)

  • Do, Eui Chul;Lee, Eun Woo;Seok, Je Seop;Jang, Min Seong
    • Korean Journal of Heritage: History & Science
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    • v.48 no.1
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    • pp.148-165
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    • 2015
  • Iron was one of the most influential factors for formation and development of ancient countries. The diffusion of ironware had increased agricultural productivity and brought about military technical revolution. Needless to say, the rise and fall of the countries depended on the possession of stable iron production. Raw materials and fuels are the key factors for mass production of iron and a transportation route is essential to supply the goods. Jungwon area satisfies the three factors. There are many iron manufacture sites such as Jincheon Seokjang-ri Gusan-ri, and Chunju Chilgeum-dong Tangeumdae earthen ramparts in the Jungwon area. In order to study the ancient iron manufacture technique, reconstitution experiment was carried out using restored furnace which was made based on the Jincheon Seokjang-ri B-23 furnace. Some notable results were identified with the experiment as in the followings. Firstly, a roasting process has a connection with the decrease of hardness of the iron ore. Secondly, melting of the blast pipe as well as the formation of product within the furnace had a crucial effect on the cessation of the experiment. Thirdly, reduced iron in various locations within the furnace prove that there was enough reducing environment during the working. Not only melting point but also properties of iron can vary depending on the carbon contents. For the reason, formation of approximate environment in which iron can react to the chalcoal is the most important factor in terms of iron manufacture.

Negative Regulation of Tumor Suppressor p53 at the Promoter Regions of Oncogenic SETDB1 and FosB Genes (암종양유전자 SETDB1과 FosB 발현에 대한 p53의 음성 조절기작)

  • Yun, Hyeon Ji;Na, Han-Heom;Kim, Keun-Cheol
    • Journal of Life Science
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    • v.30 no.12
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    • pp.1070-1077
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    • 2020
  • Treatment with anticancer drugs changes the expression of multiple genes related to cell proliferation, migration, and drug resistance. These changes in gene expression may be connected to regulatory networks for each other. This study showed that doxorubicin treatment induces the expression of oncogenic FosB and decreases the expression of oncogenic SETDB1 in A549 and H1299 human lung cancer cells, which are different in tumor suppressor p53 status. However, a small difference was detected in the quantitative expression of those proteins in the two kinds of cells. To examine the potential regulation of SETDB1 and FosB by p53, we predicted putative p53 binding sites on the genomic DNA of SETDB1 and FosB using a TF motif binding search program. These putative p53 binding sites were identified as 18 sites in the promoter regions of SETDB1 and 21 sites in the genomic DNA of FosB. A luciferase assay confirmed that p53 negatively regulated the promoter activities of SETDB1 and FosB. Furthermore, the results of RT-PCR, western blot, qPCR, and immunostaining experiments indicated that the transfection of exogenous p53 decreases the expression of SETDB1 and FosB in H1299 cells. This indicates that p53 negatively regulates the expression of SETDB1 and FosB at the transcriptional level. Collectively, the downregulation of SETDB1 and FosB by p53 may provide functional networks for apoptosis and for the survival of cancer cells during anticancer drug treatment.

A Study on Grotesque Images in Dimitris Papaioannou's Work (디미트리스 파파이오아누 작품에 나타난 그로테스크 이미지 연구)

  • CHOI, Young-hyun
    • Trans-
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    • v.11
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    • pp.65-95
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    • 2021
  • Grotesque, which has often emerged as a breakthrough in Western art to protest rational and classical pure beauty, is often seen in modern art. Grotesque, along with the concept of pendulum, appears in infinitely expanded forms across cultures, arts, and society. In particular, transformed body images through deformatization and deformatization of the body are interpreted as strong rejections that seek to break away from formalized beauty. The main purpose of this study is how the body reproduced through body deformation, distortion, and bonding in Dimitris Papaioannou's work can be interpreted within the grotesque category. To this end, he examines the Grotesque discourse and modern meaning underlying the interpretation of the work and identifies how the fragmented and expanding body, which is currently actively discussed in the dance world, has an interaction with Grotesque. It selects , , , and , which are the main attributes of the grotesque, focus on conflicting familiarity, life, hatred, and beauty. Based on this, we would like to confirm that in contemporary dance, the reconstructed body reveals concealed things rather than expressing an unrealistic fictional world, and seeks new possibilities beyond boundaries as well as reconsider existing aesthetic views.

A study on the digitalization of 3D Pen (3D펜의 디지털화에 대한 연구)

  • Kim, Jong-Young;Jeon, Byung-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.6
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    • pp.583-590
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    • 2021
  • This paper is a study on the digitization of an analog 3D pen. The term digital implies features such as homeostasis, transformability, combinability, reproducibility, and convenience of storage. One device that produces a combination of these digital characteristics is a 3D printer, but its industrial use is limited due to low productivity and limitations with materials and physical characteristics. In particular, improvements are required to use 3D printers, such as better user accessibility owing to expertise and skills in modeling software and printers. Complementing this fact is the 3D pen, which is excellent in portability and ease of use, but has a limitation in that it cannot be digitized. Therefore, in order to secure a digitalization capability and ease of use, and to secure the safety of printing materials that pose controversial hazards during the printing process, research problems and alternatives have been derived by combining food, and digitization was demonstrated with a newly developed 3D pen. In order to digitize the 3D pen, a sensor in a structured device detects the motion of an analog 3D pen, and this motion is converted into 3D data (X-Y-Z coordinate values) through a spatial analysis algorithm. To prove this method, the similarity was confirmed by visualization using MeshLab version 1.3.4. It is expected that this food pen can be used in youth education and senior healthcare programs in the future.

Development of Voltammetric Nanobio-incorporated Analytical Method for Protein Biomarker Specific to Early Diagnosis of Lung Cancer (폐암 조기 진단을 위한 단백질 바이오마커 측정용 전압-전류법 기반의 나노바이오 분석법 개발)

  • Li, Jingjing;Si, Yunpei;Nde, Dieudonne Tanue;Lee, Hye Jin
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.461-466
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    • 2021
  • In this article, a portable and cost-effective voltammetric biosensor with nanoparticles was developed for the measurements of heterogeneous nuclear ribonucleoprotein A1 protein (hnRNP A1) biomarker which can potentially be used for lung cancer diagnosis. Gold nanoparticles were first electrodeposited onto screen printed carbon electrode (SPCE) followed by immobilizing a single stranded DNA aptamer specific to hnRNP A1 onto the electrode surface. Ethanolamine was also used when immobilizing DNA aptamer on the surface to prevent signals from non-specific adsorption events. Sequential injection of hnRNP A1 biomarker and anti-hnRNP A1 conjugated with alkaline phosphatase (ALP) onto the aptamer chip surface allows to form the sandwich complex of DNA aptamer/hnRNP A1/ALP-anti-hnRNP A1 on the electrode surface which further reacted with 4-aminophenyl phosphate (APP). The electrocatalytic reaction of the enzyme, ALP, and the substrate, APP, resulting in the oxidative current response changes at -0.05 and -0.17 V (vs. Ag/AgCl) against the hnRNP A1 concentration was measured using cyclic and differential pulse voltammetry, respectively. The Au nanoparticles-integrated voltammetric biosensor was applied to analyze human normal serum solutions possibly suggesting potential applicability for lung cancer diagnosis.

Recycle of Unburned Carbon and Microceramics as Alternatives to Rubber Weight-Adding Materials and Polypropylene Filling Agents (고무증량재 및 플라스틱 충진재의 대체재로 UC와 CM의 재활용)

  • Han, Gwang Su;Kim, Dul-Sun;Lee, Dong-Keun
    • Clean Technology
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    • v.27 no.1
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    • pp.24-32
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    • 2021
  • Unburned carbon (UC) was successfully separated from fly ash by up to 85.8% in weight via froth flotation using soybean oil as a collector. An 18 wt% yield of microceramics (CM) could be achieved by employing a hydro cyclone separator located immediately after the flotation equipment. UC and CM were tested as alternatives to weight-adding material and polymer (especially polypropylene in this study) filler, respectively. Large particles of UC were broken down into smaller ones via ball milling to have an average particle diameter of 10.2 ㎛. When crushed UC was used as an alternative to clay as a rubber weight-adding material, a somewhat lower tensile strength and elongation rate than the allowed values were unfortunately obtained. In order to satisfy the standard limits, further treatment of UC is required to enhance surface energy for more intimate bonding with rubber. CM was observed in spherical forms with an average diameter of 5 ㎛. The surface of the CM particles was modified with phenol, polyol, stearic acid, and oleic acid so that the surface modified CM could be used as a polypropylene-filling agent. The flowability was good, but due to the lack of coupling forces with polypropylene, successful impact strength and flexural strength could not be obtained. However, when mixing the surface-modified CM with 1% silane by weight, a drastic increase in both the impact strength and flexural strength were obtained.

Combining Conditional Generative Adversarial Network and Regression-based Calibration for Cloud Removal of Optical Imagery (광학 영상의 구름 제거를 위한 조건부 생성적 적대 신경망과 회귀 기반 보정의 결합)

  • Kwak, Geun-Ho;Park, Soyeon;Park, No-Wook
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1357-1369
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    • 2022
  • Cloud removal is an essential image processing step for any task requiring time-series optical images, such as vegetation monitoring and change detection. This paper presents a two-stage cloud removal method that combines conditional generative adversarial networks (cGANs) with regression-based calibration to construct a cloud-free time-series optical image set. In the first stage, the cGANs generate initial prediction results using quantitative relationships between optical and synthetic aperture radar images. In the second stage, the relationships between the predicted results and the actual values in non-cloud areas are first quantified via random forest-based regression modeling and then used to calibrate the cGAN-based prediction results. The potential of the proposed method was evaluated from a cloud removal experiment using Sentinel-2 and COSMO-SkyMed images in the rice field cultivation area of Gimje. The cGAN model could effectively predict the reflectance values in the cloud-contaminated rice fields where severe changes in physical surface conditions happened. Moreover, the regression-based calibration in the second stage could improve the prediction accuracy, compared with a regression-based cloud removal method using a supplementary image that is temporally distant from the target image. These experimental results indicate that the proposed method can be effectively applied to restore cloud-contaminated areas when cloud-free optical images are unavailable for environmental monitoring.

Covalent Organic Framework Based Composite Separation Membrane: A Review (공유 유기 골격체 기반 복합 분리막 : 고찰)

  • Jeong Hwan Shim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.149-157
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    • 2023
  • Covalent organic frameworks (COFs) have shown promise in various applications, including molecular separation, dye separation, gas separation, filtration, and desalination. Integrating COFs into membranes enhances permeability, selectivity, and stability, improving separation processes. Combining COFs with single-walled carbon nanotubes (SWCNT) creates nanocomposite membranes with high permeability and stability, ideal for dye separation. Incorporating COFs into polyamide (PA) membranes improves permeability and selectivity through a synthetic interfacial strategy. Three-dimensional COF fillers in mixed-matrix membranes (MMMs) enhance CO2/CH4 separation, making them suitable for biogas upgrading. All-nanoporous composite (ANC) membranes, which combine COFs and metal-organic framework (MOF) membranes, overcome permeance-selectivity trade-offs, significantly improving gas permeance. Computational simulations using hypothetical COFs (hypoCOFs) demonstrate superior CO2 selectivity and working capacity relevant for CO2 separation and H2 purification. COFs integrated into thin-film composite (TFC) and polysulfonamide (PSA) membranes enhance rejection performance for organic contaminants, salt contaminants, and heavy metal ions, improving separation capabilities. TpPa-SO3H/PAN covalent organic framework membranes (COFMs) exhibited superior desalination performance compared to traditional polyamide membranes by utilizing charged groups to enable efficient desalination through electrostatic repulsion, suggesting their potential for ionic and molecular separations. These findings highlight COFs' potential in membrane technology for enhanced separation processes by improving permeability, selectivity, and stability. In this review, COF applied for the separation process is discussed.