• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.823-831
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• 1996

At the ratio [$H_2O$]/[TEOS]=1.7, the silica sol was synthesized by partial hydrolysis in the presence of acid catalyst. After stabilizing the silica sol by trimethylsilylation, the molecular weight and viscosity of the sol obtained at various reaction times were examined to determine a best spinnability of the sol. Gel fibers were prepared from the sol solution after removing solvent in the solution, and the gel fibers were heated at $1,000^{\circ}C$. The prepared silica fibers were in the shape of circular cross-section and their tensile strength and $SiO_2$ purity were $83{\pm}20kg/mm^2$ and about 99.997%, respectively.

• Journal of Welding and Joining
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• v.21 no.1
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• pp.107-113
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• 2003

Joining of $Si_3N_4$ to $Si_3N_4$ with crystallized glass solder was studied. $SiO_2-Al_2O_3-MgO$ glass with $P_2O_5$ as a crystallizing reagent was used as a solder. To improve the hish temperature toughness of joined specimen, two stage heat treatment was applied to Joined sample for the crystallization of joined layer, Two factors, i.e. thickness of soldered layer and crystallization were taken and thier effects on joining strength were investigated by a SEM-EDX observation of joined interface and bending strength both at room and elevated temperatures. Obtained results are summarized as follows: (1) Nitrogen diffused from $Si_3N_4$ to solder during the Joining process. Average amount of nitrogen in soldered layer depended on the thickness of the soldered layer and increased with decrease of the thickness. (2) Joining strength of the specimen having a thinner soldered layer was stronger than that of thicker layer. This can be mainly attributed to the difference of the nitrogen content in the soldered layer. (3) Higher content of nitrogen in solder brought forth higher viscosity of the solder. Hence the crystallization of the solder become more difficult in thinner layer of the solder than thicker one. (4) Thus, the effect of crystallization was evaluated mostly by the thicker layer specimen. Crystallization of soldered layer improved markedly the fracure strength of joining at higher temperatures than the softening temperature of glass solder.

• Journal of Bio-Environment Control
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• v.6 no.4
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• pp.242-249
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• 1997

Environmental control operations have been considerably contributed to the reduction of labor cost in both plastic film and glass greenhouses since government supported projects were begun. However, some problems are still remaining on the optimal environmental control and excessive operation due to an inflexible software regulating ventilation gear - reducers. The unadjustable software caused the damage of ventilation system, resulting in heat stresses of crops. This study was performed to develop a ventilation software controlling the vent opening level, opening sequence, based on the wind direction, and control interval according to the difference between ambient and set- up temperatures. The software included a beeper system alarming urgent cases, while a manager was remote from the greenhouse. A compatible hardware with the software was also developed by using a low-cost diffused DSP controller.

• Journal of Conservation Science
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• v.30 no.4
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• pp.365-372
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• 2014

The purpose of the present study is to determine the species of red and green pigments used on paintings of Korean temples and also to compare the two pigments according to the particle characteristics. The component analysis shows that the red pigment consists of cinnabar, hematite, and minium and the green pigment are composed of atacamite, celadonite, and malachite. The result suggests that mixture of various pigments were applied to the painting. When it comes to the particle characteristics, there are various hedral or anhedral shapes such as sharp, long, angular, and platy shapes even in the same cinnabar. In addition, the green pigment also shows a similar pattern with those of the red pigment. Up to now, an identification of minerals has been relied on examination of component and crystal shape. However, it is notable that using form related characteristics can be a better and useful method not only for categorization of pigments which are similar in terms of color and species but also specific index.

• Proceedings of the Korea Technology Innovation Society Conference
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• 2017.05a
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• pp.559-570
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• 2017

우리나라는 과거부터 현재까지 미래 성장동력 육성을 목표로 정부주도하에 국가 R&D 투자를 점진적으로 늘려왔다. 그 결과, 최근에는 GDP 대비 연구개발비 비중이 세계 최고 수준에 이르렀다. 이렇게 연구개발 예산의 양적인 확대와 함께 연구개발 예산의 효율적 활용은 더욱 중요한 과학기술 분야의 정책적 이슈로 부각되고 있다. 연구개발 예산의 효율적인 집행을 위해서는 R&D 사업의 유사 중복성의 검토가 필수적이지만, 대부분의 유사 중복성 검토는 전문가의 직관적인 판단에 근거하여 이루어져왔다. 하지만, 전문가의 직관에만 의지한 판단은 때로는 불명확하거나 잘못된 결과를 가져올 수도 있다. 따라서, 본 연구에서는 네트워크 분석을 통해 정부 R&D 사업의 유사 중복성을 체계적으로 검토하기 위한 데이터기반의 방법론을 제안하여 전문가의 직관에 의한 유사 중복성 검토를 보완할 수 있는 가능성을 모색하고자 한다. 먼저, 본 연구에서는 정부 R&D사업 유사영역의 전체적인 구조 및 형태와 국가과학기술연구회 소속 25개 정부출연연구기관 R&D사업의 유사영역의 전반적인 형태를 시각화하여 유사영역을 파악하고 직관적인 판단과 선택을 할 수 있는 의사결정 정보를 제공하는데 초점을 두었다. 이를 위해, NTIS의 2015년 데이터를 사용하여 과제 키워드 기반으로 동시단어출현 분석을 수행하였다. 본 분석을 통해 25개 기관의 세부적인 유사연구영역 형태를 제시하였으며, 국내의 과학기술정책적 또는 과학기술학적인 현상들을 시각화하였다. 그 결과, 국내 출연연 R&D사업이 기관별 고유영역이 확고히 보이는 Mode 1적인 형태와 사회경제적인 맥락과 필요 및 유망성을 따르고, 다학제적, 적용중심적이며 과제별로 다양한 과제수행기관들이 과제들을 동시에 수행하는 Mode 2적인 형태가 출연연의 R&D사업 내에 공존하고 있음을 확인하였다.

• KOMUNHWA
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• no.60
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• pp.101-120
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• 2002

The floor tile on a coated green-glass was excavated from the Beobgwangsa Temple Site in the Pohang City. We analyzed using the MXRD, ICP-AES, EDXRF, TG/DTA and TIMS. As a result of microscope analysis, it was composed of quartz, feldspar and clay particl

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.535-542
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• 1993

It was investigated in this study that a preparation method, activation energy, surface area, pore volume, pore size distribution and DTA analysis of the dry gel in process of producing monolithic porous gel in Li2O-Al2O3-TiO2-SiO2 system by the sol-gel technique using metal alkoxides. Activation energy for gellation according to the variation of water concentration and the kind of catalysts ranged from 10 to 20kcal/mole. Monolithic dry gels were prepared after drying at 9$0^{\circ}C$ when the amount of water for gellation was 4~8 times more than the stoichiometric amount, that was necessary for the full hydrolysis of the mixed metal alkoxide. The specific surface area, the pore volume, the average pore radius of the dried gel at 18$0^{\circ}C$ according to the various kinds of catalyst were about 348~734$m^2$/g, 0.35~0.70ml/g and 10~35$\AA$, respectively. It showed that the dry gels were porous body. As a result ofthe analysis of DTA, it was confirmed that the exothermaic peaks at 715$^{\circ}C$ and 77$0^{\circ}C$ was clue to the crystallization of dried gel.

• Journal of the Korean Ceramic Society
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• v.44 no.8
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• pp.451-456
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• 2007

This paper presents results and observations obtained from a study of sintering behavior and crystallization in $Li_2O-Al_2O_3-SiO_2$ (LAS) Glass by screen printing method. The variable experimental conditions were determined carefully by Thermal-Mechanical Analyzer (TMA), Differential Thermal Analyzer (DTA) for setting the optimum transparent sintering conditions in LAS glass system, $10.5Li_2O-14.7Al_2O_3-58.1SiO_2-16.7B_2O_3(wt%)$, such as glass-ceramics which usually have low crystallization temperatures. Crystallization glasses generated during sintering was observed from diffraction patterns by X-Ray Diffraction (XRD), transmittance by UV-Vis spectrometer. Finally, the optimum sintering condition of LAS glass and the relation between factors and results in several sintering conditions were given by using Response Surface Methodology (RSM). From this study, we confirmed that crystallization interrupted densification during glass powder sintering. Furthermore, we observed that main effect of factors in glass powder sintering with concurrent crystallization depended on experimental conditions from main effects plot by MINTAB-14.

• Nuclear Engineering and Technology
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• v.9 no.4
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• pp.211-222
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• 1977

The decomposition of all the individual chemicals used in the Harwell inactive vitrification pilot plant has been studied by means of a thermal balance. Weight loss curves to 110$0^{\circ}C$ have been obtained. The four materials (sodium nitrate, cesium nitrate, lithium nitrate and ruthenium nitroso-nitrate solution) showed a greater weight loss than that based on an oxide yield, and hence these compounds of their products of decomposition are volatile below 110$0^{\circ}C$. The remaining materials suffered a weight loss no more than that corresponding to a full yield of the oxide, and hence they were not volatile below 110$0^{\circ}C$. Most of chemicals begin to decompose at less than 75$^{\circ}C$ but the nitrates of cesium, strontium, barium and sodium not until 295$^{\circ}C$ to 59$0^{\circ}C$. The results obtained can be used in the analysis of process conditions in the vitrification and calcination of highly radioactive wastes and also of the thermal decomposition behaviour of mixtures containing those materials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1992.11a
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• pp.77-81
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• 1992

The purpose of this research was th evaluate conductivity of electricity of Ge-Se-Bi system Chalcogenide glass as a amorphous semiconductor by observing its dissolution and crystallization. In this experiment. Ge-Se-Bi metal powder in the rage of $Ge_{12-25}$, $Se_{65-85}$, $Bi_{2.5-15}$ was used as the sample ore. The ore was. put into a vaccous quartz tube and then melted. The condition of heat treatment was to dispose it to $1000^{\circ}C$ heat for 10 hours and then rapidly quenched it at $3834^{\circ}C$/see. The crystallization of the fused sample ripened as the change of temperature and time, after the crystal core was formell. At that time it was possible to observe the state that $Bi_2Se_3$ and $GeSe_2$ were crystallized. In the experiment of making memberance, the memberance was produced by using the previously experimented bulk sample. And decrystalization was well progressed when Ge was over 15 at %, Se was over 70 at %, and Bi was under 10 at%. As for bulk. when Ge was fixed to 20 at %, the conducting of electricity was increased as Bi gained at %. In the case of memberance, the conductivity was much more increased than that of bulk sample as the increase of at the increase of at % of Bi. In the experiment on $Ge_{20}$, $Se_{77.5}$ and $Bi_{2.5}$, the crystallization sswas most vigorous when they were kept at $330^{\circ}C$ for 4 hours.