• Title/Summary/Keyword: 결정소성

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The Recycling of Inorganic Industrial Waste in Cement Industry (시멘트산업에서 무기질 산업 폐·부산물의 재활용)

  • Kang, S.K.;Nam, K.U.;Seo, H.N.;Kim, N.J.;Min, K.S.;Chung, H.S.;Oh, H.K.
    • Clean Technology
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    • v.6 no.1
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    • pp.61-69
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    • 2000
  • In this study, generation process and properties of inorganic industrial waste which can be used in cement industry were investigated. The scheme of recycling to use the selected waste as raw materials, mineralizer and flux, admixture and raw materials for special cement was decided and then various experiments were carried out. The experimental results were as follows ; In the use of industrial waste as raw materials, ferrous materials could be substituted by Cu-slag, Zn-slag, electric arc furnace or convertor furnace slag etc., and a siliceous material could be substituted by sand from cast-iron industry. By-products from sugar or fertilizer industry, which has $CaF_2$ as the main component, and jarosite from Zn refinery enabled clinker phases to be formed at lower temperature by $100{\sim}150^{\circ}C$. Adding Cu slag and STS sludge in proper proportion to cement improved properties of cement. Fly ash and limestone powder as admixture had the same effect on cement. As a raw material for special cement, aluminium waste sludge could be used in making ultra early strength cement, which had the compressive strength of $300kg/cm^2$ within 2hours. And two different ashes from municipal incinerator could be raw materials of the cement which was mainly composed of $C_3S$ and $C_{11}A_7{\cdot}CaCl_2$ as clinker phases.

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Implications of the effects of gravity load for earthquake resistant design of multistory building structurtes (고층건물의 내진설계에 미치는 중력하중의 영향)

  • 이동근;이석용
    • Computational Structural Engineering
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    • v.6 no.3
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    • pp.67-80
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    • 1993
  • This paper presents the results of an analytical study to evaluate the inelastic seismic response characteristics of multistory building structures, the effects of gravity load on the seismic responses and its implications on the earthquake resistant design. Static analyses for incremental lateral force and nonlinear dynamic analyses for earthquake motions were performed to evaluate the seismic response of example multistory building structures. Most of considerations are placed on the distribution of inelastic responses over the height of the structure. When an earthquake occurs, bending moment demand is increased considerably from the top to the bottom of multistory structures, so that differences between bending moment demands and supplies are greater in lower floos of multistory structures. As a result, for building structures designed by the current earthquake resistant design procedure, inelastic deformations for earthquake ground motions do not distribute uniformly over the height of structures and those are induced mainly in bottom floors. In addition, gravity load considerded in design procedure tends to cause much larger damages in lower floors. From the point of view of seismic responses, gravity load affects the initial yield time of griders in earlier stage of strong earthquakes and results in different inelastic responses among the plastic hinges that form in the girders of a same floor. However, gravity load moments at beam ends are gradually reduced and finally fully relaxed after a structure experiences some inelastic excursions as a ground motion is getting stronger. Reduction of gravity load moment results in much increased structural damages in lower floors building structures. The implications of the effects of gravity load for seismic design of multistory building structures are to reduce the contributions of gravity load and to increased those of seismic load in determination of flexual strength for girders and columns.

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Evaluation of Applicability of Apparent Track Stiffness Measured by Light-Weight Deflectometer as a Ballasted Track Condition Index (소형동평판재하시험기로 측정한 궤도 겉보기 강성의 자갈궤도 상태평가 지표로서의 적용성 고찰)

  • Choi, Yeong-Tae;Hwang, Sung Ho;Jang, Seung Yup;Park, Bongsik;Shim, Gwang Seop
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.2
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    • pp.37-44
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    • 2018
  • Ballasted track has been widely used due to its flexibility. However, the plastic deformation of ballasted track causes the evolution of track geometrical errors, and hence it requires continuous maintenance; increase in number of trains, weight, and speed expedites maintenance frequency and cost as well. Ballast stiffness is well-known as an indicator of design and maintenance. In this regard, this paper aims to suggest the method to measure ballast track stiffness using light-weight deflectometer (LWD) and thus verify its applicability as a maintenance measure. Preliminary field tests determined simple field testing protocol to measure track stiffness. The apparent ballast stiffness by LWD shows good corelation with TQI (Track Quality Index) and maintenance length. That is, as average of apparent stiffness increase, TQI and tamping length decrease exponentially. Therefore, apparent stiffness can be used as an index for ballast condition assessment.

Characterization of Transparent TiO2 Power and Thin Films through Sol-Gel Process (졸-겔법을 이용한 투과성 TiO2 분말 및 박막의 특성 연구)

  • Jung, Mie-Won;Lee, Zee-Young;Son, Hyun-Jin
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.252-258
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    • 2002
  • Transparent $TiO_2$ thin films prepared by sol-gel process using the modification of titanium(IV) alkoxide showed improved thermal stability and high refraction index. Compared to the pure $TiO_2$ film, the modified $TiO_2$ films show the increased index of refraction under proper condition at pH 2.5. Transparency of these $TiO_2$ thin films were more than 80% in the visible region. It has been demonstrated that the reaction occurs in the amorphous phase: an exchange of phase results in anatase before and after 400$^{\circ}C$, in rutile over 700$^{\circ}$C form the XRD results. The particle sizes, shapes and structures of these nanoclusters in the $TiO_2$ films have been identified through a SEM and XRD. The physical properties and structures of their powders have also been studied through a SEM, XRD, TGA and DSC. The thickness and index of refraction have been determined by the analysis of ellipsometric spectra.

A Study on the Characteristics of Bearing Capacity for SIP Piles in Domestic Areas (국내 SIP 말뚝의 지지력 특성에 관한 연구)

  • Lee, Song;Park, Jun-Hong;Park, Joong-Bai;Kim, Tae-Hwoon
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.319-327
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    • 2002
  • In this research, problems of recent design methods and their improvement for SIP(Soil-Cement Injected precast Pile) in domestic areas were studied by using the properties of load-settlement curves and bearing capacity from field loading tests. Elastic and plastic settlement for total settlement in each loading step of loading tests conducted in domestic areas has been shown to have a tendency. From this tendency and bearing capacity determined by loading tests, it could be ascertained that empirical chart could be an assistant tool in SIP design. It was shown that SIP design using N-value in domestic area with soil condition of granitic type resulted in very conservative hearing capacity. On the other hands, in soil with unfitted geological conditions, the design could be insecure. Also, we could ascertain that Meyerhof's bearing capacity using modified N-value on the tip part of pile was more applicable than recent design method where tip bearing capacity was 20NA$_p$ N-value limited to 50. These results showed that modified design method could be more economic than those in the past because it used pile's bearing capacity unto tolerable load of pile material.

Feasibility Analysis of Wasted Limestone Powder as a Viscosity Reducing Material for Cement Based Materials (시멘트 계열 재료의 점도 저하용 혼화재료로서 폐석회석 미분말의 사용 가능성 분석)

  • Lee, Hyang-Seon;Jeon, Jong-Un;Son, Bae-Geun;Han, Dongyeop
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.123-129
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    • 2018
  • The aim of the research is providing a fundamental idea of reducing viscosity of cement based materials by replacing powder based material. With developing concrete technology, high performance concrete with high solid volume fraction has been used widely. Under the conditions of the high solid volume fraction due to the low w/c and replacement of SCMs, decreased fluidity is one of the critical problem, and thus plasticizer has been used to improve fluidity of the mixture. However, in rheological aspect, the fluidity of cement based materials can be defined with yield stress and viscosity, and using plasticizer only decreases yield stress without least controlling on viscosity. Therefore, based on the idea of Krieger-Dougherty model, a feasibility of wasted limestone powder from cement manufacturing process was used to decrease the viscosity of the mixture by replacing cement powder. According to a series of experiment, by replacing wasted limestone powder solely, there was a possibility of reducing viscosity was observed. Thus, in this research scope, it is considered to contribute on providing a fundamental idea of reducing viscosity with powder replacement and it is expected to contribute on further research using various conditions of replacing powders for reducing viscosity of cementitious materials.

A Study on Improvement of Field Implementation of Asphalt Surface Reinforcement Method (아스팔트 표면 강화공법의 현장 적용성 개선 방안 연구)

  • Jo, Shin Haeng;Kim, Kyungnam;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.2
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    • pp.389-395
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    • 2017
  • A study was carried out to improve the field implementation of asphalt surface reinforcement method which is a preventive maintenance. Mean Texture Depth (MTD) was measured to quantify the surface condition and used to determine the optimum application rate. Determining the application rate using MTD can reduce the material loss from 30% to 15%. In order to reduce the curing time to 30 minutes, the heat capacity of $317kcal/m^2$ is required. Therefore, the design capacity of the heating curing device requires more than 380,000 kcal/hr. The asphalt surface reinforcement method is preferably applied at a time when slight cracking occurs before the permanent deformation becomes serious. Through the analysis of the pavement survey data, it was decided to apply the surface reinforcement method at the crack rate of 3~4%. Heating the surface reinforcement agent to $50^{\circ}C$ improves workability and ensures sufficient penetration depth even at a crack width of 1 mm. The results will be utilized as basic data for the development of automated construction equipment for efficiency improvement.

Characteristics of Sintered Composites for $ZnO-{B_2}{O_3}-{SiO_2}-PbO$ Glass and $ZrB_2$Powders ($ZnO-{B_2}{O_3}-{SiO_2}-PbO$계 유리와 $ZrB_2$분말의 소결체의 특성)

  • Song, Hyun-Jin;Lee, Byung-Chul;Ryu, Bong-Ki
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.562-568
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    • 2001
  • Devitrifiable solder glass/$ZrB_2$ sintered composites were prepared by using glass with the composition of $60ZnO-20B_2O_3-10SiO_2-10PbO$(in wt%) and $ZrB_2$, powder as starting materials under the $N_2$atmosphere. $ZrB_2$which the good conduction materials showed sensitive oxidation characteristics, because some parts of the $ZrB_2$in specimens changed into the insulated phase of $ZrO_2$. These Phenomena would be estimated that it caused a few amount of residual oxygen in the furnace and/or specimens and the coordination number change of $B_2O_3$ in the glass. The sintering temperature and the mixed ratios of each phase were control of large ranged the resistivity ranged from 10 to 10$^{3}{\Omega}/cm^2$ orders, and to make a conductible microstructure. From these results, it would be explained that the conduction path of $ZrB_2$particles built up within sintered glass matrix.

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Explicit Nonlinear Finite Element Analysis for Flexural/Shear Behavior of Perfobond FRP-Concrete Composite Beam (퍼포본드 FRP-콘크리트 합성보의 휨/전단거동에 관한 외연적 비선형 유한요소해석 연구)

  • Yoo, Seung-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.771-776
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    • 2020
  • In this study, the flexural/shear behavior characteristics of perfobond FRP-concrete composite beams using an FRP plate with perforated webs as formwork and reinforcement are analyzed through an analytical method. Compared with the existing experimental results, we have proved its usefulness and use it in future practice. When the nonlinearity is very large in this case, the nonlinear finite element analysis by an explicit method will be effective. The concrete damage plasticity (CDP) model adopted in this study is considered to be able to adequately simulate the nonlinear behavior of concrete, and the determination of several variable factors required in the model is compared with the experimental results and values used in the study. This recommendation will require review and adjustment for more diverse cases. The effect of the perfobond of the composite beam with perforated web is considered to be somewhat effective in terms of securing the initial stiffness, but in the case of the apex, it is considered that the cross-sectional loss and the effect of improving the bonding force should be properly arranged. The contact problem, such as slipping of the FRP plate and concrete, is considered to be one of the reasons that the initial stiffness is slightly larger than the test result, and the slightly difference from the experimental results is attributed to the separation problem between concrete and FRP after the peak.

Occurrence and Mineral Chemistry of Pb-Ag-Bi-S System Minerals in the Nakdong As-Bi Deposits, South Korea (낙동 비소-비스무스 광상의 Pb-Ag-Bi-S계 광물의 산출양상과 화학조성)

  • Shin, Dong-Bok
    • Economic and Environmental Geology
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    • v.39 no.6 s.181
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    • pp.643-651
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    • 2006
  • The Pb-Ag-Bi-S system minerals such as galena-matildite solid solutions, cosalite and heyrovskyite occur in the Nakdong As-Bi deposits. Galena-matildite solid solutions commonly coexisting with native bismuth fill in microfractures of pyrite grains and form irregular shapes. Cosalite forms composite grains including native bismuth, heyrovskyite and Bi-Te-S system minerals in the matrix of quartz vein. Matildite from the Nakdong deposits has an end member composition, $Ag_{1.07-1.11}Bi_{1.12-1.20}S_2$, and an excess concentration of $0.3{\sim}2.4$ mole % $Bi_2S_3$ compared to the stoichiomeoic value. PbS concentrations in $PbS-AgBiS_2$ solid solutions do not exceed 54 mole %. The average chemical composition of cosalite in the study area is $Pb_{1.79}Bi_{2.29}Ag_{0.12}S_5$. Pb is slightly depleted compared to the ideal composition, but the concentrations of Ag and Cu reach as much as 1.47 wt.% and 0.27 wt.%, respectively. Heyrovskyite has the chemical formula of $Pb_{5.01}Ag_{0.26}Bi_{2.70}S_9$ suggesting that there occurs the coupled substitution of $2Bi^{3+}$ for $3Pb^{2+}$ as well as that of $Ag^++Bi^{3+}$ for $2Pb^{2+}$. The genetic condition of Pb-Ag-Bi-S system minerals can be confined to the temperature of $220{\sim}270^{\circ}C$ and the pressure below 200 bars.