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Slope Failure Along the Weathered And Mobilized Foliation Plane : Studies for Causes of the Failure and the Supporting Methodologies (풍화된 엽리면을 따라 붕괴된 대절토 사면의 붕괴요인 분석과 보강방안에 대한 연구)

  • Hwang, Sang-Gi;Kim, Young-Muk;Ji, In-Taeg;Jeon, Byoung-Choo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.775-784
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    • 2009
  • Weathered foliation could act as a critical failure plane because this type of plane tend to have low roughness and long extensions. A big constructed slope at $\bigcirc\bigcirc$ road construction site was failed due to the block movement along a fault zone which is parallel to foliation. Tectonic activity reactivated a fault zone parallel to foliation, and the fault clay within the shear zone metamorphosed retrogressively to chrolite. The failed block moved when the block weigh lost the balancing with the resisting force of the retrogressively metamorphosed chrolite. Evaluating the three dimensional distribution of the foliation was critical for establishing a plan for the stabilization of the slope. For this purpose, 10 boreholes were drilled as a lattice distribution, and the BIPS analyses are performed at each boreholes. The fractures measured in the boreholes are projected into 15 cross sections and their distributions are analysed, using Fracjection software. The projection analyse show that the strike of the foliation gets dipper towards left side of the slope. This geometry indicates that there are more failure block geometry at left side of the slope. Potential failure planes are searched using the projection method, and these information are provided for further support design.

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Pd/Pd3Fe Alloy Catalyst for Enhancing Hydrogen Production Rate from Formic Acid Decomposition: Density Functional Theory Study (개미산 분해 반응에서 수소 생산성 증대를 위한 Pd/Pd3Fe 합금 촉매: 범밀도 함수 이론 연구)

  • Cho, Jinwon;Han, Jonghee;Yoon, Sung Pil;Nam, Suk Woo;Ham, Hyung Chul
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.270-274
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    • 2017
  • Formic acid has been known as one of key sources of hydrogen. Among various monometallic catalysts, hydrogen can be efficiently produced on Pd catalyst. However, the catalytic activity of Pd is gradually reduced by the blocking of active sites by CO, which is formed from the unwanted indirect oxidation of formic acid. One of promising solutions to overcome such issue is the design of alloy catalyst by adding other metal into Pd since alloying effect (such as ligand and strain effect) can increase the chance to mitigate CO poisoning issue. In this study, we have investigated formic acid deposition on the bimetallic $Pd/Pd_3Fe$ core-shell nanocatalyst using DFT (density functional theory) calculation. In comparison to Pd catalyst, the activation energy of formic acid dehydrogenation is greatly reduced on $Pd/Pd_3Fe$ catalyst. In order to understand the importance of alloying effects in catalysis, we decoupled the strain effect from ligand effect. We found that both strain effect and ligand effect reduced the binding energy of HCOO by 0.03 eV and 0.29 eV, respectively, compared to the pure Pd case. Our DFT analysis of electronic structure suggested that such decrease of HCOO binding energy is related to the dramatic reduction of density of state near the fermi level.

A Study on the Systematic Integration of WASP5 Water Quality Model with a GIS (GIS와 WASP5 수질모델의 유기적 통합에 관한 연구)

  • 최성규;김계현
    • Spatial Information Research
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    • v.9 no.2
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    • pp.291-307
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    • 2001
  • In today's environmental engineering practice, many technologies such as GIS have been adopted to analyze chemical and biological process in water bodies and pollutants movements on the land surface. However, the linkage between spatially represented land surface pollutants and the in-stream processes has been relatively weak. This lack of continuity needs to develop a method in order to link the spatially-based pollutant source characterization with the water quality modeling. The objective of this thesis was to develop a two-way(forward and backward) link between ArcView GIS software and the USEPA water quality model, WASP5. This thesis includes a literature review, the determination of the point source and non-point source loadings from WASP5 modeling, and the linkage of a GIS with WASP5 model. The GIS and model linkage includes pre-processing of the input data within a GIS to provide necessary information for running a model in the forms of external input files. The model results has been post-processed and stored in the GIS database to be reviewed in a user defined form such as a chart, or a table. The interface developed from this study would provide efficient environment to support the easier decision making form water quality management.

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Coastal Wave Hind-Casting Modelling Using ECMWF Wind Dataset (ECMWF 바람자료를 이용한 연안 파랑후측모델링)

  • Kang, Tae-Soon;Park, Jong-Jip;Eum, Ho-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.5
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    • pp.599-607
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    • 2015
  • The purpose of this study is to reproduce long-term wave fields in coastal waters of Korea based on wave hind-casting modelling and discuss its applications. To validate wind data(NCEP, ECMWF, JMA-MSM), comparison of wind data was done with wave buoy data. JMA-MSM predicted wind data with high accuracy. But due to relatively longer period of ECMWF wind data as compared to that of JMA-MSM, wind data set of ECMWF(2001~2014) was used to perform wave hind-casting modelling. Results from numerical modelling were verified with the observed data of wave buoys installed by Korea Meteorological Administration(KMA) and Korea Hydrographic and Oceanographic Agency(KHOA) on offshore waters. The results agree well with observations at buoy stations, especially during the event periods such as a typhoon. Consequently, the wave data reproduced by wave hind-casting modelling was used to obtain missing data in wave observation buoys. The obtained missing data indicated underestimation of maximum wave height during the event period at some points of buoys. Reasons for such underestimation may be due to larger time interval and resolution of the input wind data, water depth and grid size etc. The methodology used in present study can be used to analyze coastal erosion data in conjunction with a wave characteristic of the event period in coastal areas. Additionally, the method can be used in the coastal disaster vulnerability assessment to generate wave points of interest.

강지진동 분석의 최적화를 위한 고려요소

  • 이석태;조봉곤;이정모;조영삼
    • Proceedings of the International Union of Geodesy And Geophysics Korea Journal of Geophysical Research Conference
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    • 2003.05a
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    • pp.17-17
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    • 2003
  • 한반도에 있어서의 지진의 영향을 분석하기 위해서는 강지진동 연구가 필수적이다. 강지진동 자료가 부족한 한반도의 특성상 모사를 통해 연구하고 있다. 강지진동 분석을 하기 위해서는 되도록 노이즈가 포함되어 있지 않은 지진파자료를 선택하여 그 지진자료의 스펙트럼 분석을 통해 감쇠상수 k, Q 등을 구한다. 이러한 감쇠상수 값을 통해 한반도의 진동 특성을 이해할 수 있다. 그러나 감쇠상수를 구하는 과정에서 감쇠상수 분석에 사용된 지진자료에 노이즈가 더해졌을 경우, 어떤 형태로 스펙트럼 영역에 영향을 미치고, 감쇠상수에는 어떤 영향을 미치는 지를 연구하여 노이즈효과를 제거할 수 있는 최적화된 분석에 관한 연구가 선행되어야 한다고 본다. 따라서 이번 연구에서는 강지진동 모사프로그램을 가지고 노이즈효과를 적용하면서 감쇠상수에 노이즈가 어떤 영향을 미치는 지에 대한 수치 해석적 연구를 실시하였다. 합성지진파에 이 합성지진파와 전혀 다른 주파수 형태를 보이는 노이즈를 강도를 달리하면서 합성해 본 결과, 노이즈효과를 고려할 수 있는 몇 가지 요소가 있음을 알 수 있었다. 감쇠상수 k값을 강지진동 모사프로그램으로부터 값을 달리하며 합성해 본 결과 노이즈효과를 보이는 것을 알 수 있었으며, 감쇠상수 k를 선형회귀를 통해 $k_{s}$$k_{q}$를 구할 때의 적용 주파수 범위를 변화시켰을 때도 일정한 양상의 노이즈 효과를 보였다. 또 지진자료와 노이즈를 중첩시킨 지진파 시계열 자료의 정부분만을 감쇠상수 k를 구하는 선형회귀에 이용했을 경우에도 노이즈 효과를 보였다. 또한 계산되어 나온 감쇠상수 값으로부터 특정지역의 지반운동의 특성을 이해할 수 있는 스펙트럼 가속도, 최대 가속도, 및 최대속도 값에 따른 감쇠식을 구하였다. 이것을 한반도와 같은 판 내부 환경인 ENA 값과 비교하였으며 기존의 연구와도 비교하였다.심으로부터 지오이드까지의 거리, 지오이드로부터 지표까지의 거리를 정의해주었으며, 각 격자점의 수직구조를 정의하기 위해 깊이에 따른 각 매질의 밀도, P파의 속도, S파의 속도, P파에 대한 Q값, S파에 대한 Q값을 정의 해주었다. S파의 속도를 구하기 위해서 지구 내부 물질을 포아송 매질이라는 가정 하에, 관계식을 $Vp{\;}={\;}SQRT(3){\;}{\times}{\;}Vs$ 이용하였다. 획득한 모델치들을 이용해 동해와 동해 인근 지역에 대한 초기모델을 구축하였다. 약 1 × 10/sup 6/ e/sup -//sec·n㎡ 의 전자선량에 해당되며 이를 기준으로 각각의 illumination angle에 대한 임계전자선량을 평가할 수 있었다. 실질적으로 Cibbsite와 같은 무기수화물의 직접가열실험 시 전자빔 조사에 의해 야기되는 상전이 영향을 배제하고 실험을 수행하려면 illumination angle 0.2mrad (Dose rate : 8000 e/sup -//sec·n㎡)이하로 관찰하고 기록되어야 함을 본 자료로부터 알 수 있었다.운동횟수에 의한 영향으로써 운동시간을 1일 6시간으로 설정하여, 운동횟수를 결정하기 위하여 오전, 오후에 각 3시간씩 운동시키는 방법과 오전부터 6시간동안 운동시키는 두 방법을 이용하여 품질을 비교하였다. 각 조건에 따라 운동시킨 참돔의 수분함량을 나타낸 것으로, 2회(오전 3시간, 오후 3시간)에 나누어서 운동시키기 위한 육의 수분함량은 73.37±2.02%를 나타냈으며, 1회(6시간 운동)운동시키기 위한 육은 71.74±1.66%을 나타내었다. 각각의 운동조건에서 양식된 참돔은 사육초기에는 큰 변화가 없었으나, 사육 5일 이후에는 수분함량이 증가하여 15일에는 76.40±0.14, 75.62±0.98%의 수분함량을 2회와 1회 운동시킨 참돔의 육에서 각각 나타났다. 운동횟수에 따른 지

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Synthesis and Characterization of a Series of PtRu/C Catalysts for the Electrooxidation of CO (일산화탄소 산화를 위한 PtRu/C 시리즈 촉매의 합성 및 특성 연구)

  • Lee, Seonhwa;Choi, Sung Mook;Kim, Won Bae
    • Clean Technology
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    • v.18 no.4
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    • pp.432-439
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    • 2012
  • The electrocatalytic oxidation of CO was studied using carbon-supported 20 wt% PtRu (PtRu/C) catalysts, which were prepared with different Pt : Ru atomic ratios from 7 : 3 to 3 : 7 using a colloidal method combined with a freeze-drying procedure. The bimetallic PtRu/C catalysts were characterized by various physicochemical analyses, including X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). CO stripping voltammetry measurements indicated that the addition of Ru with a Pt catalyst significantly improved the electrocatalytic activity for CO electrooxidation. Among the tested catalysts, the $Pt_5Ru_5/C$ catalyst had the lowest onset potential (vs.Ag/AgCl) and the largest CO EAS. Structural modification via lattice parameter change and electronic modification in the unfilled d band states for Pt atoms may facilitate the electrooxidation of CO.

Fabrication and performance analysis of cost-effective fiber grating lasers for WDM-PON systems (WDM-PON 시스템용 저가형 Fiber Grating Laser의 제작 및 성능 분석)

  • Cho, Seung-Hyun;Lee, Woo-Ram;Lee, Jie-Hyun;Park, Jae-Dong;Kim, Byoung-Whi;Kang, Min-Ho;Shin, Dong-Wook
    • Korean Journal of Optics and Photonics
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    • v.16 no.1
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    • pp.13-20
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    • 2005
  • Fiber-Bragg-grating external cavity laser(FGL) modules were fabricated and experimentally analyzed. Proposed as a cost-effective solution for optical sources in the WDM-PON access network, FGL modules were packaged to TO-CAN type. We obtained a low threshold current of 13 mA, and an optical output power of 3.6 mW with a bias current of 60 mA at $25^{\circ}C$. The lasing wavelength dependencies on current and temperature were as small as 5.2 pm/mA and 30 pm/$^{\circ}C$, respectively. These change rates of the wavelength with the temperature and current are smaller than those of the DFB laser. Single-mode oscillations with the side-mode suppression ratio(SMSR) over 30 dB are maintained above the threshold current level. The FGL modules can be directly modulated at 155 Mbps, PRBS(2$^{23}$ -1) NRZ signal. Through the BER plots, we did not see the significant degradations before and after the transmission over 20km of the SMF at 155 Mb/s.

Analysis of Hydrological Impact for Long-Term Land Cover Change Using the WMS HEC-1 Model in the Upstream Watershed of Pyeongtaek Gauging Station of Anseong-cheon (WMS HEC-1을 이용한 안성천 평택수위관측소 상류유역의 수문 경년변화 분석)

  • Kim, Seong-Joon;Park, Geun-Ae;Jung, In-Kyun;Kwon, Hyung-Joong
    • Journal of Korea Water Resources Association
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    • v.36 no.4
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    • pp.609-621
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    • 2003
  • The purpose of this study is to evaluate the hydrological impact due to temporal land cover change by gradual urbanization of upstream watershed of Pyeongtaek gauging station of Anseong -cheon. WMS HEC-1 was adopted, and DEM with 200$\times$200m resolution and hydrologic soil group from 1:50,000 soil map were prepared. Land covers of 1986, 1990, 1994 and 1999 Landsat TM images were classified by maximum likelihood method. The watershed showed a trend that forest & paddy areas decreased and urban/residential area gradually increased for the period of 14 years. The model was calibrated at 2 locations (Pyeongtaek and Gongdo) by comparing observed with simulated discharge results for 5 summer storm events from 1998 to 2001. The watershed average CN values varied from 61.7 to 62.3 for the 4 selected years. To identify the impact of streamflow by temporal area change of a target land use, a simple evaluation method that the CN values of areas except the target land use are unified as one representative CN value was suggested. By applying the method, watershed average CN value was affected in the order of paddy, forest and urban/residential, respectively.

Assessing the Performance of CMIP5 GCMs for Various Climatic Elements and Indicators over the Southeast US (다양한 기후요소와 지표에 대한 CMIP5 GCMs 모델 성능 평가 -미국 남동부 지역을 대상으로-)

  • Hwang, Syewoon
    • Journal of Korea Water Resources Association
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    • v.47 no.11
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    • pp.1039-1050
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    • 2014
  • The goal of this study is to demonstrate the diversity of model performance for various climatic elements and indicators. We evaluated the skills of the most advanced 17 General Circulation Models (GCMs) i.e., CMIP5 (Climate Model Inter-comparison project, phase 5) climate models in reproducing retrospective climatology from 1950 to 2000 over the Southeast US for the key climatic elements important in the hydrological and agricultural perspectives (i.e., precipitation, maximum and minimum temperature, and wind speed). The biases of raw CMIP5 GCMs were estimated for 16 different climatic indicators that imply mean climatology, temporal variability, extreme frequency, etc. using a grid-based observational dataset as reference. Based on the error (RMSE) and correlation (R) of GCM outputs, the error-based GCM ranks were assigned on average over the indicators. Overall, the GCMs showed much better accuracy in representing mean climatology of temperature comparing to other elements whereas few GCM showed acceptable skills for precipitation. It was also found that the model skills and ranks would be substantially different by the climatic elements, error statistics applied for evaluation, and indicators as well. This study presents significance of GCM uncertainty and the needs of considering rational strategies for climate model evaluation and selection.

FFT/IFFT IP Generator for OFDM Modems (OFDM 모뎀용 FFT/IFFT IP 자동 생성기)

  • Lee Jin-Woo;Shin Kyung-Wook;Kim Jong-Whan;Baek Young-Seok;Eo Ik-Soo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.3A
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    • pp.368-376
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    • 2006
  • This paper describes a Fcore_GenSim(Parameterized FFT Core Generation & Simulation Program), which can be used as an essential If(Intellectual Property) in various OFDM modem designs. The Fcore_Gensim is composed of two parts, a parameterized core generator(PFFT_CoreGen) that generates Verilog-HDL models of FFT cores, and a fixed-point FFT simulator(FXP_FFTSim) which can be used to estimate the SQNR performance of the generated cores. The parameters that can be specified for core generation are FFT length in the range of 64 ~2048-point and word-lengths of input/output/internal/twiddle data in the range of 8-b "24-b with 2-b step. Total 43,659 FFT cores can be generated by Fcore_Gensim. In addition, CBFP(Convergent Block Floating Point) scaling can be optionally specified. To achieve an optimized hardware and SQNR performance of the generated core, a hybrid structure of R2SDF and R2SDC stages and a hybrid algorithm of radix-2, radix-2/4, radix-2/4/8 are adopted according to FFT length and CBFP scaling.