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Treatment of AP Solutions Extracted from Solid Propellant by NF/RO Membrane Process (NF/RO 멤브레인 공정을 적용한 고체추진제에서 추출된 암모늄 퍼클로레이트 (AP) 처리 연구)

  • Kong, Choongsik;Heo, Jiyong;Yoon, Yeomin;Han, Jonghun;Her, Namguk
    • Membrane Journal
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    • v.22 no.4
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    • pp.235-242
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    • 2012
  • Ammonium perchlorate (AP) is primarily derived from the process of liquid incineration treatment when dismantling a solid rocket propellant. A series of batch dead-end nanofiltration (NF) and reverse osmosis (RO) membrane experiments were conducted to explore the retention mechanisms of AP under various hydrodynamic and solution conditions. Low levels of silicate type of siloxane had been detected through the GC/MS and FTIR analysis of liquid solutions extracted from solid ammonium perchlorate composite propellant (APCP). It is indicated that NF/RO membranes fouling in the presence of APCP was mainly attributed to the AP interactions because the concentration of silicate type of siloxane was negligible compared to that of AP. The osmotic pressure of AP was presumably resulted in the flux declines ranging from 13 to 17% in the case of the application of low-pressure (551 and 896 kPa for NF and RO) compared to those in application of high-pressure. The retention of AP by NF/RO membranes significantly varied from approximately 10 to 70% for NF and 26 to 87% for RO, depending on the operating and solution water chemistry conditions. The results suggested that retention efficiency of AP was fairly increased by reducing concentration polarization (i.e. application of low-pressure and stirring speed of 600 rpm) and increasing the pH of a solution. The result of this study was also consistent with the previous modeling of 'solute mass transfer of NF/RO membranes' and demonstrated that hydrodynamic and solution water chemistry conditions are to be a key factor in the retention of AP by NF/RO membranes.

A UTMI-Compatible USB2.0 Transceiver Chip Design (UTMI 표준에 부합하는 USB2.0 송수신기 칩 설계)

  • Nam Jang-Jin;Kim Bong-Jin;Park Hong-June
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.42 no.5 s.335
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    • pp.31-38
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    • 2005
  • The architecture and the implementation details of a UTMI(USB2.0 Transceiver Macrocell Interface) compatible USB2.0 transceiver chip were presented. To confirm the validation of the incoming data in noisy channel environment, a squelch state detector and a current mode Schmitt-trigger circuit were proposed. A current mode output driver to transmit 480Mbps data on the USB cable was designed and an on-die termination(ODT) which is controlled by a replica bias circuit was presented. In the USB system using plesiochronous clocking, to compensate for the frequency difference between a transmitter and a receiver, a synchronizer using clock data recovery circuit and FIFO was designed. The USB cable was modeled as the lossy transmission line model(W model) for circuit simulation by using a network analyzer measurements. The USB2.0 PHY chip was implemented by using 0.25um CMOS process and test results were presented. The core area excluding the IO pads was $0.91{\times}1.82mm^2$. The power consumptions at the supply voltage of 2.5V were 245mW and 150mW for high-speed and full-speed operations, respectively.

A Correlation Analysis between Land Surface Temperature and NDVI in Kunsan City using Landsat 7 TM/ETM+ Satellite Images (Landsat 7 TM/ETM+ 위성영상을 이용한 군산지역 지표 온도와 NDVI에 대한 상관분석)

  • Lee, Hong-Ro;Kim, Hyung-Moo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.8 no.2
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    • pp.31-43
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    • 2005
  • Four time points of the fractional area data during the 15 years of the highest group of land surface temperature and the lowest group of NDVl of the Kunsan city Chollabuk_do, Korea located beneath the Yellow sea coast, are observed and analyzed their correlations for the intention to detect the changes of urban land cover. As long as the effective contributions of satellite images in the continuous monitoring of the wide area for wide range of time period, Landsat-5 TM and Landsat-7 ETM+ artificial satellite images, acquisited over the Kunsan city area, are surveyed by the compared calibration after quantization and classification of the deviations between TM and ETM+ images substituted approved error correction thresholds such as gains and biases or offsets. This experiment and research applied Landsat-5 TM and Landsat-7 ETM+ artificial satellite images in change detection of urban land cover in urbanized Kunsan city, then detected strong and proportional correlation relationship between the highest group of land surface temperature and the lowest group of NDVI which exceeded R=(+)0.9478, so the proposed Correlation Analysis Model between the highest group of land surface temperature and the lowest group of NDVI will be able to give proof an effective suitability to the land city change detection monitoring.

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A Study on Spectra of Laser Induced Flourescence in Phantom of N-propyl-N,N-dimethylethanolamine (N-propyl-N,N-dimethylethanolamine의 Phantom에서 Laser Induced Fluorescence의 스펙트라에 관한 연구)

  • Kim, Ki-Jun;Lee, Joo-Ho;Lee, Joo-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.330-338
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    • 2015
  • The influences of fluorescence, scattering, and flocculation in turbid material by light scattering of N-propyl-N,N-dimethylethanolamine, fluorescence agent and absorption agent were interpreted for the scattered fluorescence intensity and wavelength. They have been studied the molecular properties by the spectroscopy of laser induced fluorescence (LIF) and flocculation. The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used. When two particles approach each other, interactions of several colloid particles can come into play which may have major effect on the flocculation and LIF process. The values of scattering coefficient ${\mu}_s$ are large by means of the increasing scattering of scatterer, The values have been found that the slope decays exponentially as a function of concentration from laser source to detector by our experimental result. It may also aid in designing the best model for oil chemistry, bio-pharmaceutical, laser medicine and application of medical engineering on LIF and coagulation in particle transport mode.

Simulation Study on Atmospheric Emission Scenarios of Radioxenon Produced by the North Korea's 6th Nuclear Test (북한 6차 핵실험으로 생성된 방사성제논의 대기 중 방출 시나리오에 대한 모의실험 연구)

  • Park, Kihyun;Min, Byung-Il;Kim, Sora;Kim, Jiyoon;Suh, Kyung-Suk
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2_spc
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    • pp.261-273
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    • 2020
  • North Korea conducted the sixth underground nuclear test on September 3, 2017 at the Punggye-ri Nuclear Test Site (NTS). In contrast to the previous five nuclear tests, several induced earthquakes occurred around the NTS after the sixth nuclear test and this may have caused radioxenon leakages at the site. Considering these reported earthquakes, we performed atmospheric dispersion simulations on some radioxenon emission scenarios for this event using our Lagrangian Atmospheric Dose Assessment System (LADAS) model by employing the Unified Model (UM) based numerical weather prediction data produced by the Korea Meteorological Administration (KMA). To find out possible detection locations and times, we combined not only daily and weekly based delayed releases but also leakages after the reported earthquakes around the NTS to create emission scenarios. Our simulation results were generally in good agreement with the measured data of the Nuclear Safety and Security Commission and International Monitoring System (IMS) stations operated by the Comprehensive nuclear Test-Ban-Treaty Organization (CTBTO).

Synergistic Inhibition of Escherichia coli by a Combination of Bacteriophage and Organic Acid (박테리오파지와 유기산의 병용처리에 의한 효율적인 대장균 생육 억제)

  • Kim, Seon-Gyu;Moon, Gi-Seong
    • Journal of Food Hygiene and Safety
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    • v.34 no.6
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    • pp.591-594
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    • 2019
  • Some strains of Escherichia coli are categorized as pathogenic bacteria and alternative antimicrobials including bacteriophages for controlling these bacteria have been studied. In this study we screened antimicrobial candidates that present synergistic inhibition of the growth of E. coli DH5α as a model when co-treated with the bacteriophage ECP27 to target the bacteria. As candidates, CaCl2, lactic acid, and citric acid were tested. CaCl2 showed a synergistic inhibition against the strain by dose-dependent manner at 6 h of incubation but the viable cell count was recovered at 12 h. However, lactic acid and citric acid at 30 mM concentration showed synergistic inhibitions at 6 h of incubation and cleared the viable cells of E. coli DH5α at 12 h when co-treated with the bacteriophage even though lactic acid or citric acid alone was effective. Therefore, co-treatment using the bacteriophage and organic acids such as lactic acid and citric acid can be a solution for synergistic inhibition of the growth of E. coli.

Regulatory mechanism of Angelica Gigas extract powder on matrix metalloproteinases in vitro and in vivo model (참당귀 추출분말이 in vitro and in vivo model에서 MMPs 조절 기전)

  • Kwon, Jin-Hwan;Han, Min-Seok;Lee, Yong-Moon
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.361-369
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    • 2015
  • The precise mechanism underlying the therapeutic efficacy of an extraction powder of Angelica gigas (AGE) for the treatment of degenerative osteoarthritis was investigated in primary cultured rabbit chondrocytes and in a monosodium-iodoacetate (MIA)-induced osteoarthritis rat model. The treatment with AGE (50 μg/mL) effectively inhibited NF-B activation. The anti-inflammatory mechanism was clarified by gelatin zymography and western blotting measurements of matrix metalloproteinase-2 (MMP-2) and matrix metalloproteinase-9 (MMP-9) activities. The AGE (50 μg/mL) treatment significantly reduced MMP-9 activity. The constituents of AGE— decursinol, decursin, and decursinol angelate—were determined by LC-MS/MS after a 24 hr treatment of rabbit chondrocytes. The contents of the major products, decursin and decursinol angelate, were 3.62±0.47 and 2.14 ±0.36 μg/mg protein, respectively in AGE-treated (50 μg/mL) rabbit chondrocytes. An in vivo animal study on rats fed a diet containing 25, 50, and 100 mg/kg AGE for 3 weeks revealed a significant inhibition of the MMPs in the MIA-induced rat articular cartilage. The genetic expression of arthritic factors in the articular cartilage was examined by RT-PCR of collagen Type I, collagen Type II, aggrecan, and MMP (MMP3, MMP-9, MMP13). Specifically, AGE up-regulated the expression of collagen Type I, collagen Type II, and aggrecan and inhibited MMP levels at all tested concentrations. Collectively, AGE showed a strong specific site of action on MMP regulation and protected against the degeneration of articular cartilage via cellular regulation of MMP expression both in vitro and in vivo.

A Study on the Soil Contamination(Maps) Using the Handheld XRF and GIS in Abandoned Mining Areas (휴대용 XRF와 GIS를 이용한 폐광산 지역의 토양오염에 관한 연구)

  • Lee, Hyeon-Gyu;Choi, Yo-Soon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.3
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    • pp.195-206
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    • 2014
  • In this study, soil contamination maps related to Cu and Pb were created at the Busan abandoned mine in Korea using a handheld X-Ray Fluorescence(XRF) and Geographic Information Systems(GIS). Hydrological analysis was performed using the Digital Elevation Model(DEM) of the study area to identify the flow directions of surface runoff where pollutants can be dispersed from the soil contamination sources. 24 locations for measuring the soil contamination related to Cu and Pb were selected by considering the result of hydrological analysis. The results measured at the 24 locations using the handheld XRF showed that the highest value of Cu contamination is 8,255ppm and that of Pb is 2,146ppm. The field investigation data were entered into ArcGIS software, and then soil contamination maps regarding Cu and Pb with a 5m grid-spacing were created after performing spatial interpolations using the ordinary kriging method. As a result, we could know that high concentrations of Cu and Pb are presented at the waste and tailings dumps around the abandoned mine openings. This study also showed that the handheld XRF and GIS can be utilized to create soil contamination maps related to Cu and Pb in the field.

A Study on the Prediction of Nugget Diameter of Resistance Spot Welded Part of 1.2GPa Ultra High Strength TRIP Steel for Vehicle (차체용 1.2GPa급 초고장력 TRIP강판의 저항 점 용접부 너겟 지름 예측에 관한 연구)

  • Shin, Seok-Woo;Lee, Jong-Hun;Park, Sang-Heup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.52-60
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    • 2018
  • In the automobile industry, in order to increase the fuel efficiency and conform to the safety regulations, it is necessary to make the vehicles as light as possible. Therefore, it is crucial to manufacture dual phase steels, complex phases steels, MS steels, TRIP steels, and TWIP from high strength steels with a tensile strength of 700Mpa or more. In order to apply ultra-high tensile strength steel to the body, the welding process is essential. Resistance spot welding, which is advantageous in terms of its cost, is used in more than 80% of cases in body welding. It is generally accepted that ultra-high tensile strength steel has poor weldability, because its alloy element content is increased to improve its strength. In the case of the resistance spot welding of ultra-high tensile steel, it has been reported that the proper welding condition area is reduced and interfacial fracture and partial interfacial fracture occur in the weld zone. Therefore, research into the welding quality judgment that can predict the defect and quality in real time is being actively conducted. In this study, the dynamic resistance of the weld was monitored using the secondary circuit process variables detected during resistance spot welding, and the factors necessary for the determination of the welding quality were extracted from the dynamic resistance pattern. The correlations between the extracted factors and the weld quality were analyzed and a regression analysis was carried out using highly correlated pendulums. Based on this research, a regression model that can be applied to the field was proposed.

Influence of Dispersed and Anaerobic Bacteria in Aerobic Paper-making Wastewater Treatment (호기적 제지폐수 처리공정중에의 분산 혐기성 미생물의 영향)

  • 박종현;김선영;한완택
    • Microbiology and Biotechnology Letters
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    • v.28 no.3
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    • pp.180-184
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    • 2000
  • Tn order to be helpful to control dispersed microorganisms for stabLlization of wastewater treatment in a paper-makillg process, dominant strains were isolated aerobically and anaerobically. and identified and physiological characteristics were also analyzed. Pseudomonas carboxydohydrogena, Cardiobacten'm hominis, lvIicrococcus lylae, XanfomonCls campestris p" juglandis, Micrococcus diversus, and Comamonas terrigencl as aerobic dominants, and Streptococcus bovis and Prevotella buccae as anaerobIc dominants were identified fi'om the supernatent of the primary settling tank. It seemed that microflora in the treatment process would consist of many kinds of microorganisms, whose dominant would change easily according to environmental conditions, They all grew well at $37^{\circ}C$ and at different initial medium pH's. Especially, some of them required sulfate ion for their growth, which came from a chemical coagulant of aluminium sulfate in the primary settling tank. Interestingly. many anaerobes grew well even in the aerobic wastewater treatment process and seemed to have some functions. Population of anaerobes increased three times in the supematant of primary settling tank and ten times in Lhe bottom sludge of primary settling tank than in the prime wastewater. Therefore, these anaerobes contributed to the producH tion of offensive gases, which would make some microorganisms not precLpitate and be buoyant.

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