• Title/Summary/Keyword: 강도 열화

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Chemical Degradation of e-PTFE Support Used in PEMFC after Fenton Reaction (고분자연료전지에 사용되는 e-PTFE 지지체의 펜톤반응 후 화학적 열화)

  • Oh, Sohyeong;Lim, Daehyun;Lee, Mooseok;Lee, Donghoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.536-540
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    • 2020
  • The support of the PEMFC membrane plays a key role in improving mechanical durability. The e-PTFE used as a support is chemically stable, so electro-chemical degradation in the PEMFC driving process has been rarely studied. In this study, we investigated whether e-PTFE is chemically stable to radicals and hydrogen peroxide during Fenton reaction. After the Fenton reaction, the main chain of e-PTFE broke, resulting in a change in the chemical structure and morphology of the support, resulting in a decrease in tensile strength. The results of this study showed that electrochemical degradation of the membrane ionomer in the PEMFC process occurs inside the membrane by radicals and hydrogen peroxide, so that electrochemical degradation may also occur at the e-PTFE support in the cell.

The Effect of Heat Exposure on Fatigue Properties of INVAR Steel Core for STACIR/AW Conductor (증용량저이도송전선(STACIR/AW)용 인바강선의 피로특성에 미치는 경년열화의 효과)

  • Kim, Shang-Shu;Kim, Byung-Geol;Park, Su-Dong;Lee, Hee-Woong;Sin, Goo-Yong;Lee, Dong-Il;Min, Byung-Uk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1274-1277
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    • 2004
  • 최근 에너지 소비구조의 선진화에 따라 전력수요는 매년 10%이상 증가하고 있지만 철탑부지확보 및 환경 문제 둥에 의해 신규 송전선의 건설은 점차 어려워지고 있다. 이에 대한 대책으로 철탑의 교체 없이 송전선의 전류용량간 증가시키는 방안이 우선적으로 고려되어 적용되고 있다. 이미 국내에서도 기존 송전선인 ACSR 전선을 중용량 저이도의 특성을 가진 STACIR/AW(Super Thermal-resistant Aluminum alloy Conductors, aluminum-clad Invar-Reinforced)송전선으로 교체하여 전력 수송량을 증가시키고 있다. STACIR/AW전선은 도체의 내열성을 향상시켜 연속허용온도$(210^{\circ}C)$를 높임으로 전류용량을 증가시키고, ACSR에 사용되는 강심재료인 고탄소강선을 선팽창계수가 낮은 인바강선(INVAR)으로 대체함으로 고온환경에 따른 이도증가를 방지하고 있다. 그러나 STACIR/AW 송전선은 ACSR 송전선에 비하여 연속허용온도가 높고 경간의 거리가 멀기 때문에 열화에 의한 피로특성의 변화 가능성이 높다. 따라서 본 연구에서는 증용량저이도전선의 강심소재인 INVAR/AW강선을 소정의 온도에서 경년 열화하고, 열화시간에 따른 강도와 피로특성의 변화를 조사하여, STACIR/AW전선의 안정적 운전을 위한 재료물성적 관리인자를 도출하고자 하였다.

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The Study on Interpretation of the Scatter Degradation Factor using an additional Filter in a Medical Imaging System (의료 영상 시스템에서 부가 필터를 이용한 산란 열화 인자의 해석에 관한 연구)

  • Kang, Sang Sik;Kim, Kyo Tae;Park, Ji Koon
    • Journal of the Korean Society of Radiology
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    • v.13 no.4
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    • pp.589-596
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    • 2019
  • X-rays used for diagnosis have a continuous energy distribution. However, photons with low energy not only reduce image contrast, but also contribute to the patient's radiation exposure. Therefore, clinics currently use filters made of aluminum. Such filters are advantageous because they can reduce the exposure of the patient to radiation. However, they may have negative effects on imaging quality, as they lead to increases in the scattered dose. In this study, we investigated the effects of the scattered dose generated by an aluminum filter on medical image quality. We used the relative standard deviation and the scatter degradation factor as evaluation indices, as they can be used to quantitatively express the decrease in the degree of contrast in imaging. We verified that the scattered dose generated by the increase in the thickness of the aluminum filter causes degradation of the quality of medical images.

Differences of Physical, Mechanical and Chemical Properties of Korean Red Pine(Pinus densiflora) Between Old and New Wood (소나무 고목재와 건전재의 물리, 기계, 화학적 특성 차이)

  • Shim, Kug-Bo;Lee, Do-Sik;Park, Byung-Soo;Cho, Sung-Taig;Kim, Kwang-Mo;Yeo, Hwan-Myeong
    • Journal of Korea Foresty Energy
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    • v.25 no.2
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    • pp.1-8
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    • 2006
  • The physical, mechanical and chemical properties of old and new Korean red pine (Pinus densiflora) were analyzed. The old woods were from dismantled timbers of Bonjungsa temple. The crystallized resin in the latewood was observed by microscopic analysis. Also, reduction of specific gravity, occurrence of microscopic cleavage of tracheid was observed in the old wood. The angle of microscopic cleavage of tracheid is estimated with the same angle of micro-fibril angle of 52 layer. The bending, compression and shear strength of old world were decreased about 35-27% than those of new wood. Dynamic modulus of elasticity measured by ultrasonic nondestructive test has the tendency of reducing by the time elapse of the wood usage. Therefore, deterioration of wood could be measured by reduction of specific gravity and dynamic MOE. The static MOE and mechanical properties of old wood could be predictable by measuring dynamic MOE in the longitudinal direction. Extractives of the old wood in 1-% NaOH solution are larger quantity than new wood. Therefore the decay of the wood could be evaluated by analyzing the chemical compound, especially 1-% NaOH solution. The results of this research could be used for understanding and prediction of the changing properties with elapsing time of wood.

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The Evaluation of Flexural Performance in UHPC(Ultra High Performance Concrete) according to Placement Methods (타설방법에 따른 초고성능 콘크리트의 휨성능 평가)

  • Ryu, Gum-Sung;Kang, Su-Tae;Park, Jung-Jun;Ahn, Ki-Hong;Koh, Kyung-Taek;Kim, Sung-Wook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.357-360
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    • 2008
  • UHPC which was a structural material exhibiting very remarkable mechanical performances with compressive strength, tensile strength and flexural strength rising up to 200MPa, 15MPa and 35MPa, respectively. In addition, this material presents exceptional durability regard to the very low diffusion and penetration speeds of noxious substances like chloride ions This study was carry out to evaluate the effect of flexural behavior according to placement method in UHPC. The results is showing that the placement methods have remarkable influence flexural strength Addition to it is showing that the placement methods made little difference in the first cracking strength but considerable gap up to 2 or 3 times in the ultimate flexural strength.

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A Study on the Change of Strength of FRP Member Immersed in Chemical Solution (화학약품용액에 침지한 FRP 부재의 강도 변화에 대한 연구)

  • Kim, Ho-Sun;Kim, Woo-Jong;Jang, Hwa-Sup;Kwak, Kae-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.117-123
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    • 2010
  • If FRP materials that have been known as high durability materials are exposed to harmful environmental factors, deterioration and characteristics of materials can be reduced due to chemical reaction such as hydrolysis. Therefore, to use FRP materials as building major materials, it is important to exactly grasp dynamic properties by use condition. Accordingly, this study stored FRP materials in a strong acid and alkali compound solution for a certain period to conduct simulation for acute or chronic, extreme changes by chemicals, and conducted a test for compressive, tensile, shear and bending strength to analyze changes in strength by kinds and storage days of chemicals. In conclusion, the study findings indicate excellent chemical resistance of FRP materials.

A Study on Degradation Characteristic of High Strength Fire Resistance Steel for Frame Structure by Acoustic Emission (음향방출법에 의한 고강도 구조요 내화강의 열화특성에 관한 연구)

  • 김현수;남기우;강창룡
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.04a
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    • pp.51-56
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    • 2000
  • Demand for new nondestructive evaluations is growing to detect tensile crack growth behavior to predict long term performance of materials and structure in aggressive environments, especially when they are in non-visible area. Acoustic emission technique is well suited to these problems and has drawn a keen interests because of its dynamic detection ability, extreme sensitivity and location of growing defects. In this study, we analysed acoustic emission signals obtained in tensile test of high strength fire resistance steel for frame structure with time frequency analysis methods. The results obtained are summaries as follows ; In the T and TN specimen consisting of ferrite and pearlite grains, most of acoustic emission events were produced near yield point, mainly due to the dislocation activities during the deformation. However, B specimen under $600^{\circ}C$ - 10min had a two peak which was attribute to the presence of martensite phase. The first peak is before yield point the second is after yield point. The sources of second acoustic emission peak were the debonding of martensite-martensite interface and the micro-cracking of brittle martensite phase. In $600^{\circ}C$-30min to $700^{\circ}C$-60min specimens, many signals were observed from area before yield point and counts were decreased after yield point.

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입계부식법에 의한 고온플랜트 요소의 크리프 잔여수명 평가

  • 윤기봉;한상인;강태연;박종진
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1998.05a
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    • pp.71-76
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    • 1998
  • 고온플랜트 설비 고온요소의 재질열화 정도를 평가하기 위해서 사용되는 방법 중 입계부식법은 시험절차가 간단하고 실제 플랜트에서의 적용이 용이하여 안전 및 수명진단시에 많이 이용되어 왔다. 본 논문에서는 오랜 기간 고온에서 사용된 고온$\cdot$고압플랜트의 실기 요소에 입계부식법을 적용하여 재질의 고온에서의 장시간 노출에 의한 인성저하로 발생되는 잔여 수명을 평가한 결과를 제시하였다. (중략)

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Echo Canceller using Cross-Correlation of Input and Output Singnals (입/출력 신호의 상관계수를 이용한 반향제거기)

  • 강명구
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1998.06c
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    • pp.189-192
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    • 1998
  • 전화망을 이용한 음성인식 시스팀에서 출력신호의 반향에 의한 입력신호의 음질 열화현상을 막기위해서 적응디지털 필터를 이용한 반향제거기가 필수적이다. 대표적인 적응 필터 알고리즘인 LMS와 NLMS 들을 각각 이용한 적응 반향제거기들과 입/출력신호의 상관계수를 이용한 개선된 적응 필터 알고리즘의 성능을 비교하였다. 개선된 알고리즘의 경우 NLMS 알고리즘의 빠른 수렴특성을 가지면서도 더블톡(double talk)구간에서의 음질왜곡 현상을 LMS보다 개선시켰다.

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PVAc Latex 접착제의 열적특성

  • 권재범;이내우;강돈오;설수덕
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.11a
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    • pp.297-300
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    • 2002
  • 고분자물질의 용도는 다양하다. 그러나, 열에 약한 것이 고분자물질의 가장 큰 단점으로서 이러한 열화현상은 피하거나 예방되어야 할 과제이다. 이런 과정을 제거하거나 지연시키는 작업 즉, 안정화가 필요하다. 따라서 공중합물질을 제조하는 과정은 안정화에 큰 영향을 미치고, 특히 유리전이온도나 기계적 강도를 높이기 위하여는 공중합에 의한 조성변화가 필요하다. 그 외에 형태학적 입자나 오염물질들도 안정화에 영향을 미치고, 고분자의 입체규칙도 역시 안정화에 영향을 미친다.(중략)

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