• Analytical Science and Technology
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• v.22 no.4
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• pp.302-306
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• 2009

A trace amount of boron in steel significantly influences its mechanical and physical properties. A prompt gamma ray activation analysis (PGAA) method is used to measure boron in low alloy steel samples of KRISS 101-01-C21~C26. NIST SRMs of 362, 364, 1761 and 1767 serve as the control standards to validate the measurement method. The measured values of the NIST SRMs are consistent with their certified values within the expected uncertainties, except for that of NIST SRM 362. Experimental uncertainties are evaluated according to the guidelines given by the International Organization for Standardization (ISO). The expanded uncertainties are calculated with a coverage factor of 2, at approximately 95% confidence level. The calculated relative expanded uncertainties of boron mass fractions are between 3% and 7% at the mg/kg level. The results are compared with the results measured by the solvent extraction-inductively coupled optical emission spectrometry (ICP/OES) method.

• Journal of the Korean Society of Radiology
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• v.12 no.5
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• pp.557-563
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• 2018

Coincidence summing correction effects are known to be greater as the efficiency of the detector increases and as the distance between the source and the detector increases. A point source($^{60}Co$) was used to vary the distance in the direction of the detector's center axis and in the radial direction to obtain the P/T ratio for Coincidence summing correction calibration. In this study, values for coincidence summing corrected calibration of the values in the central and radial directions were applied to the mixed volume source(450 ml CRM source) to compare the overall peak efficiency change according to P/T with Geant4. In addition, the efficiency obtained from the mapping method is applied to the seaweed, a marine sample, and the compatibility of the P/T ratio with the detector and sample very dose together. The efficiency corrected to 1,836 keV was applied to the energy zone affected by the efficiency of 500 keV and the relative error of the measured and corrected values was well matcched by the 3.2 % peak efficiency correction. As with 450 mL CRM source, the larger the volume, the lower the P/T ratio was by ${\pm}5%$. This is due to the increased scattering of gamma-rays emitted as the source becomes farther away from the detector, and this change in P/T has been confirmed to affect the Coincidence summing corrected peak efficiency.

• Journal of the Korean Vacuum Society
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• v.22 no.6
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• pp.341-347
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• 2013

The n-type and p-type silicon samples were exposed by 40.0, 3.98 MeV proton beams ranging between 0 to $20.0{\times}10^{13}protons/cm^2$. Coincidence Doppler Broadening Positron Annihilation Spectroscopy (CDBPAS) were applied to study of defect characteristics of p type and n type silicon samples. In this investigation the numerical analysis of the spectra was employed to the determination of the shape parameter, S, defined as the ratio between the amount of counts in a central portion of the gamma spectrum and the total counts of whole gamma spectrum. The S-parameter values strongly depend on the irradiated proton beam that indicated the defects generate more, rather than the energy intensity. 40 MeV irradiated proton beam in the n-type silicon at $20.0{\times}10^{13}protons/cm^2$ was larger defects than 3.98 MeV irradiated proton beam. It was analysis between the proton irradiation beams and the proton intensities of the irradiation. Because of the Bragg peak, SRIM results shows mainly in a certain depth of the sample to form the defect by the proton irradiation, rather than the defects to appear for the entire sample.

• Journal of the Korean Chemical Society
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• v.21 no.6
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• pp.427-433
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• 1977

A neutron activation method has been developed for the simultaneous determination of chromium, iron, lanthanum, scandium and zinc in river-water samples. The sample is sealed in the silica ampoule without pretreatment and irradiated for a week at a thermal neutron flux of $1{\times}10^{13}n{\cdot}cm^{-2}{\cdot}sec^{-1}$. After cooling for about two days, the elements in the sample are sequentially extracted at different pH by 0.1M oxine-chloroform solution. The organic layers are checked by Gamma-ray spectrometry with $″3\;{\times}\;3″$ NaI (T1) detector connected to a 800-channel pulse hight analyzer. The ppb concentration of the elements in most of river-water samples could be determined by this method. The tracer study for the quantitative separation of the elements was also carried out.

• Journal of Radiation Protection and Research
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• v.24 no.3
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• pp.155-160
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• 1999

In the natural, there exist several kinds of radioactive isotopes. From atmospheric weapon tests and then some isotopes are naturally radioactivity above all things, nuclear power plant operation and man-made radioactive isotopes concern steadily growing in the environment. During the fission process of nuclear weapon tests and nuclear power plant operation, more than 200 radioactive isotopes are generated. Among them, $^{90}Sr$ and $^{137}Cs$ has been regarded as very important isotopes due to characteristics. In this paper, a quantitative analysis method of environment low level $^{90}Sr$ is studied. Radioactivity level of the environmental $^{90}Sr$ is very low, and it emits continuous beta spectrum, and $^{90}Sr$ exists together with $^{89}Sr$, $^{90}Y$ and other radioactive isotopes. It very difficult to make the quantitative analysis of $^{90}Sr$. For the analysis of low level radioactive strontium, enrich and chemical separation of strontium from the other radioactive isotopes are needed. For the estimation of strontium recovery ratio, so called SGAT(Strontium Gravimetric Analysis Technique) was generally used among the domestic research groups, and chemical procedures were developed appropriation for the SGAT, Recently, by using ICP(Inductively Coupled atomic Plasma emission spectrophotometer), amounts of stable atoms can be measured easily and accurately to the extend of ppm or ppb. In this paper, new chemical procedures are developed to exploits the ICP technique. New developed method has simpler chemical treatment procedures and then it gives more accurate results compared with the traditional SGAT.

• Journal of the Korean Magnetics Society
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• v.11 no.1
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• pp.21-25
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• 2001

$\alpha$-Fe$_2$O$_3$ thin films were prepared on Si substrate by a pulsed laser deposition system and characterized by X-ray and Mossbauer spectroscopy. The appropriate conditions of pulsation was the power of 5.128 W/cm2 at on oxygen pressure of 0.1 Torr at a substrate temperature of 30$0^{\circ}C$. After that the film was heated at 80$0^{\circ}C$ for 1 day. The particles shape deposited on the film was ellipsoidal and the average length and width were 200~300 nm, 70~150 am respectively. The crystal structure was conformed to be of corundums symmetry with the hexagonal unit cell having a lattice constant of u = 5.03$\pm$0.05 $\AA$, c = 13.735$\pm$0.05 $\AA$. The average angles between the atomic spin and the magnetic hyperfine field of Fe ion were 38$^{\circ}$and 48$^{\circ}$ at above and blow the Morin transition temperature respectively. The Morin transition was found to occur at the temperature ranges from 200 K to room temperature and atomic spin direction was assumed to change from 48$^{\circ}$ to 80$^{\circ}$in respect to the c-axis.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.3
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• pp.133-142
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• 2009

In order to understand the present environmental condition and future impingement of Changjiang(Yangtze River) outflow upon the adjacent seas after the scheduled completion of the Sanxia (Three Gorges) Dam in 2009, we tried to estimate the mixing ratios among surface waters of three end-members: Changjiang Water (CW), Kuroshio Water (KW), and East China Sea Water (ECSW) using $^{228}Ra/^{226}Ra$ activity ratio and salinity as tracers. Water samples were collected from 32 stations in November 2005 (R/V Tamgu 3), from 20 stations in July 2006 (R/V Ocean 2000) and from 17 stations in August 2006 (R/V Ieodo) in the northern part of the East China Sea. Radium isotopes in ~300 liters of surface seawater were extracted onboard by filtering through manganese impregnated acrylic fibers and following coprecipitation as $Ba(Ra)SO_4$. Activities of radium isotopes were determined by a high purity germanium detector. Results show that the fraction of CW was in the range of 1-23% in the study area, while KW was in the range of 0-30 % and ECSW 58-100 %. The eastward plume of Changjiang outflow, commonly observed in satellite images during summer and also displayed by the eastward-decreasing CW fraction in this study, could be attributed to Ekman transport caused by the SE monsoon prevailing in this region during summer. Results of this study showed that in the drought season, there was a little or no fraction of CW in the study area. Concentration of dissolved inorganic nitrogen (DIN) showed strong positive relationship with the fraction of CW, suggesting Changjiang as the major source of nitrogen. The mixing curve of DIN indicates the removal of nitrate by biological uptake during the mixing of CW with ambient seawater in the study area.

• Analytical Science and Technology
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• v.21 no.6
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• pp.474-479
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• 2008

Radioactivity of naturally occurring radioactive nuclides (NORN) such as $^{226}Ra$, $^{228}Ac$ and $^{40}K$ were investigated for surface sediments collected from Ordos, Alashan, Taklimakan deserts and Loess plateau regions in China. By a Gamma-ray spectrometry, specific activity (SA) and SA ratio (SAR) of the NORN were determined for each source region of Asian dust. Characterization of the source regions of Asian dust was performed with the SA and SAR values. SA of $^{226}Ra$ in the three desert regions have almost same values in the range of mean value 17.9~21.9 Bq/kg, however, the SA in Loess Plateau has much higher values in the mean value of 35 Bq/Kg. SA of $^{228}Ac$ in the Ordos and Alashan desert regions have almost same values in the range of mean value 27.1~27.2 Bq/kg, and those in Taklimakan desert and Loess Plateau were 31.7 and 49.0 Bq/kg, respectively. In case of 40K, the SA in all regions have similar values in the range of 636~943 Bq/kg. The mean SAR value of $^{226}Ra/^{228}Ac$ in four source regions was almost same in the range of 0.708-0.721. It is shown that relationship between $^{226}Ra$ and $^{228}Ac$ is clearly presented in the source regions. The mean SAR values of $^{226}Ra/^{40}K$, $^{228}Ac/^{40}K$ are 0.0209-0.056, 0.0287-0.0773, respectively.