• Clean Technology
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• v.28 no.1
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• pp.1-8
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• 2022

To confirm the applicability of the water gas shift reaction for the production of high purity hydrogen for petroleum cokes, an unutilized low grade resource, Cu/ZnO/MgO/Al₂O₃ (CZMA), catalyst was prepared using the co-precipitation method. The prepared catalyst was analyzed using BET and H₂-TPR. Catalyst reactivity tests were compared and analyzed in two cases: a single LTS reaction from syngas containing a high concentration of CO, and an LTS reaction immediately after the syngas passed through a HTS reaction without condensation of steam. Reaction characteristics in accordance with steam/CO ratio, flow rate, and temperature were confirmed under both conditions. When the converted low concentration of CO and steam were immediately injected into the LTS, the CO conversion was rather low in most conditions despite the presence of large amounts of steam. In addition, because the influence of the steam/CO ratio, temperature, and flow rate was significant, additional analysis was required to determine the optimal operating conditions. Meanwhile, carbon deposition or activity degradation of the catalyst did not appear under high CO concentration, and high CO conversion was exhibited in most cases. In conclusion, it was confirmed that when the Cu/ZnO/MgO/Al₂O₃ catalyst and the appropriate operating conditions were applied to the syngas composition containing a high concentration of CO, the high concentration of CO could be converted in sufficient amounts into CO₂ by applying a single LTS reaction.

• Journal of the Korean Institute of Gas
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• v.18 no.4
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• pp.13-20
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• 2014

In natural gas distribution system, gas pressure is regulated correspond to requirement using throttle valve which is releasing huge pressure energy as useless form. The waste pressure can be recovered by using turbo machinery devices such as a turbo expander. In this process, excessive temperature drop occurs due to Joule-Thompson effect during the expansion process. Installing natural gas boiler before or after the turbo expander prevents temperature drop. Fuel cell or gas engine hybrid system further improve the efficiency, but 1~2% of total transporting natural gas is used for operating the hybrid system. In this study, a heat pump system is proposed as a preheating device which can be operated without using transporting natural gas. Thermodynamic analysis on evaporating and condensing temperatures and refrigerants is conducted. Results show that R717 is proper refrigerant for the hybrid system with high COP and low turbine work within the defined operating conditions. In domestic usage in Korea, the heat pump system has more economic feasibility owing to natural gas being imported with a high price of LNG form.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.8
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• pp.552-561
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• 2018

Biomass, a carbon-neutral resource, is an alternative energy source for exhaustion of fossil fuel and environmental problems. Most of energy production systems using biomass operate with a thermal chemical conversion method. Amongst them, gasification generates syngas and applies to boilers or engines for the production of heat and electricity. However, Tar could be formed during the production of syngas and it is condensed at low temperature which may cause to clog the pipelines and combustion chamber, ultimately resulting in decrease of process efficiency. Thus this work utilized water and oily materials such as soybean oil, waste cooking oil and mineral oil for scrubbing liquid. The removal efficiency of Tar appeared 97%, 70%, 63% and 30% for soybean oil, waste cooking oil, mineral oil and water respectively.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.483-486
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• 2008

본 연구에서는 디스크 이동식 열분해 실증 설비를 이용하여 폐타이어 열분해 반응을 수행하였고, 생성된 열분해 생성물들의 특성을 분석하였다. 폐타이어 열분해 반응은 약 $550^{\circ}C$에서 90분간 진행되었고, 반응 결과 Recovered Oil, Carbon Black, Non Condensing Gas(NC Gas)가 생성되었다. 폐타이어 열분해 생성물의 수율은 Recovered Oil $40{\sim}50%$, Carbon Black 30$\sim$35%, NC Gas 10$\sim$15%, Steel 10$\sim$15%로 나타났다. 폐타이어 열분해 반응 후 생성된 Recovered Oil은 비점 및 특성 분석 결과 상업용 중유와 비슷한 성질을 나타냈고, 폐타이어 열분해 반응의 또 다른 생성물인 Carbon Black은 특성 분석 결과 고정 탄소 비율이 낮은 반면 회분과 휘발분의 비율이 높아 상업용으로 사용하기 위해서는 적절한 정제 과정이 필요함을 알 수 있었다.열분해 과정 중에 생성된NC Gas는 GC/MS를 이용하여 성분 분석을 수행한 결과, $CO_2$, $CH_4$를 비롯하여 주로 탄화수소류로 이루어졌으며, 대부분이 연료 가스로 구성되어 있어 열분해 반응의 열원으로서 사용이 가능하였다.

• Journal of the Korean Institute of Gas
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• v.12 no.4
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• pp.52-57
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• 2008

This paper studies on the wear corrosion behavior of induction hardening high strength cast iron in the acidic environments. In a variety of pH solutions, wear corrosion behavior of GC 300 with a variety of contact pressures was investigated, and corrosion wear behavior after immersion test was considered. Also, electrochemical polarization test for GC 300 was carried out in various pH solutions. The main results are as following: In the strong acidic environment, wear corrosion rate of GC 300 appears highly and in the neutral environment is stable. Also, graphitic corrosion in the strong acidic environment occurs. The corrosion current density of GC 300 becomes high in a order of pH 1 > pH 2 > pH 4 > pH 6.5.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.6
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• pp.702-708
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• 2006

This study shows the experimental characteristics of the double pipe inserted liquid pipe with small diameter in the gas pipe with large diameter for circulating of a liquid of high temperature, pressure and a gas of low temperature, pressure at the same time. So the functions of pipe and pipe's expansion and heat transfer are presented simultaneously. In the result, the temperature of gas refrigerant at the inlet of compressor increased about $5^{\circ}C$ by the heat transfer with liquid refrigerant in case of the double pipe. And liquid gas refrigerant which the temperature at the inlet of evaporator decreased about $3^{\circ}C$ comparing with the existing type flows into an evaporator COP of the double pipe increased about $7{\sim}10%$ comparing with that of the conventional pipe. And the noise of the double pipe at capillary tube is less than that of the conventional type about 3dB. Consequently. it is convinced the superiority of the double pipe in the heat loss and soundproofing aspect.

• Journal of the Korean Institute of Gas
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• v.18 no.2
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• pp.41-47
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• 2014

In this work a thermodynamic performance analysis is carried out for a combined cycle consisted of an organic Rankine cycle (ORC) and a LNG cycle. The combined system uses a low grade waste heat in the form of sensible energy and the LNG cold energy is used for power generation as well as for heat sink. The effects of the key parameters of th system such as turbine inlet pressure, condensation temperature and source temperature on the characteristics of system are throughly investigated. The simulation results show that the thermodynamic performance of the combined system can be significantly improved compared to the normal ORC which is not using the LNG cold energy.

• Journal of Powder Materials
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• v.17 no.5
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• pp.379-384
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• 2010

In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 $m^2g^{-1}$ of specific surface area and 45.6 nm of average particles diameter.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.374-384
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• 2016

Concern about air pollution is gradually rising up in domestic and foreign, automotive and fuel researchers are trying to reduce vehicle exhaust emissions, through a lot of approaches, which consist of new engine design and innovative after-treatment systems, using clean (eco-friendly alternative) fuels and fuel quality improvement. This research is proceeding by two main issues : exhaust emissions and PM particle emissions of gasoline vehicle. Exhaust emissions, non-regulated emissions and PM (particulate matter) particles of automotive are causing many problems which ambient pollution and harmful effects on the human body. The main particulate fraction of automotive exhaust emissions consists of small particles. Because of their small size, inhaled particles can easily penetrate deep into the lungs. The rough surfaces of these particles make it easier for them to combine with other toxins in the environment. Thus, the hazards of particle inhalation are increased. Based on the oxygenated fuel additive types (MTBE, Bio-ETBE, Bio-ethanol, Bio-butanol), this paper discussed the influence of oxygen contents on gasoline vehicle exhaust emissions, non-regulated emissions and nano-particle emissions. Also, this paper assessed exhaust emission characteristics at 2 type test modes. The test modes were FTP-75 and HWFET. All measurement items be verified less than the value of regulated emissions. It could be known difference increase and decrease by each measurement item depending on increase the oxygen contents.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.1
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• pp.61-67
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• 2015

The cooling of hot exhaust gas is an important issue for the construction of combustor test facility. Water spray is an effective method for exhaust gas cooling due to its large latent heat in process of evaporation. In this study, 1-D analysis has been performed based on continuity, energy conservation, and saturated vapor property to understand water spray cooling of combustion gas. In the exhaust duct of combustor test facility, the injected water decreases combustion gas temperature, and evaporates in the combustion gas. However, some of the injected water is collected in the sump due to condensation. The evaporation of water helps combustion gas cooling, but causes pressure increase inside the exhaust duct due to increase of vapor pressure. These phenomena has been analyzed by 1-D modeling in this study. From 1-D analysis, the adequate mass flow rate of water spray to cool combustion gas and to avoid excessive pressure rise inside the exhaust duct has been decided.