• Title/Summary/Keyword: 가속열화

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Evaluation of the Activation Energy of Chlorinated Poly Vinyl Chloride (CPVC) Using Thermogravimetric Analysis (TGA를 이용한 Chlorinated Poly Vinyl Chloride(CPVC)의 활성화 에너지 평가)

  • Park, Hyung-Ju
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.1-6
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    • 2019
  • The activation energy of CPVC (Chlorinated Poly Vinyl Chloride) used for non-metallic synthetic resin piping in fire-fighting was measured by thermogravimetric analysis (TGA). The activation energy was determined using by TGA kinetic methods, such as Kissinger and Flynn-Wall-Ozawa method. The calculated activation energy was 128.07 kJ/mol (Kissinger method) and 145.60 kJ/mol (Flynn-Wall-Ozawa method). The difference in activation energies calculated by the Kissinger method and Flynn-Wall-Ozawa method was not considered to be significant considering that the different analysis methods. The combustion characteristics will be tested in a future study through an evaluation of thermal deterioration using an accelerated deterioration and air oven aging test and the lifetime of CPVC will be predicted.

A Comparison Study on Mechanical Properties of XLPE Insulation Thermally Degraded at Equivalent and Variable Temperature Conditions (XLPE 절연체의 등가 및 가변온도 가속열화실험을 통한 기계적 특성 비교 분석)

  • Taejoon, Kim;Jae-Sang, Hwang;Sung Hoon, Jung;Tae Young, Kim
    • KEPCO Journal on Electric Power and Energy
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    • v.8 no.2
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    • pp.73-77
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    • 2022
  • Recently, as the number of years of operation has increased for more than 30 years, interest in evaluating the remaining life of major power facilities such as transformers and ultra-high voltage cables is increasing. In particular, the risk of failure is increasing because the underground transmission XLPE cable has been built since 1980 and has been operating in excess of 30 years of design life or close proximity. Therefore, it is necessary to develop an algorithm to evaluate the residual life of the XLPE cable considering the load to determine the risk of failure. Since load data is large amount of data, it is necessary to make the variable load information equivalent to the time unit first in order to calculate the remaining life of the system quickly. In overseas literature, transformers are reported to be standardized for variable load equivalent conversion formulas, but they have not been reported for ultra-high voltage cables. Therefore, in this paper, whether the equivalent conversion formula of a transformer can be applied to XLPE cables was reviewed through accelerated degradation tests under equivalent and variable temperature conditions, and considerations were studied when evaluating the remaining operating life of XLPE cables based on the experimental results.

A Study on the Physical Characteristics of the Low-voltage Circuit Breaker Based on the Accelerated Degradation Test (가속 열화 시험에 따른 저압용 차단기의 물리적 특성에 관한 연구)

  • Sin dong, Kang;Jae-Ho, Kim
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.1-8
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    • 2022
  • This study analyzed the characteristics of insulation resistance and operating time based on an accelerated degradation test of a low-voltage circuit breaker. The experimental sample used a molded case circuit breaker (MCCB) and an earth leakage circuit breaker (ELCB). After measuring the insulation resistance of the circuit breakers, the leakage current was affected by an external rather than an internal structure. Furthermore, the insulation resistance of the circuit breakers with accelerated degradation was measured using a Megger insulation tester. In the accelerated degradation test, aging times of five, ten, 15, and 20 years were applied according to a temperature derived using the Arrhenius equation. Circuit breakers with an equivalent life of ten, 15, and 20 years had increased insulation resistance compared to those with less degradation time. In particular, the circuit breaker with an equivalent life of ten years had the highest insulation resistance. Component analysis of the circuit breaker manufactured through an accelerated degradation test confirmed that the timing of the increase in insulation resistance and the time of additive loss were the same. Finally, after analyzing the operating time of the circuit breakers with degradation, it was confirmed that the MCCB did not change, but the ELCB breaker failed.

Study on the Estimation of Long Life Cycle and Reliability Tests for Epoxy Insulation Busway System (에폭시 박막 절연형 버스웨이 시스템의 장기 수명 및 신뢰성 평가에 관한 연구)

  • Jang, Dong-Uk;Park, Seong-Hee;Lee, Kang-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.261-268
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    • 2018
  • The use of electric cable was limited due to the installation time and large space as the increase of power demand and load quantity in side line. In order to solve these problems, the application of busway system which can supply the large current was increasing. But it was lack of methods of performance tests to evaluate the reliability and results of test for busway system. In this paper, we presented items to evaluate the reliability test for epoxy coated busway system with reference to IEC 61349-6. In addition, we proposed items to evaluate the reliability and long term life cycle test for the epoxy coated busway system. The combined acceleration deterioration test that reflects actual conditions of the survey as much as possible was conducted considering both thermal and electrical stresses. The deterioration condition was selected to satisfy fifty years life expectation and the insulation performance verification test of the busway system confirmed the long term life prediction. Furthermore, as test items for reliability assessment of compliance with the environment for the use of temperature, humidity and load current where busway system was installed, thermal overload test, water immersion test, cold shock temperature test and thermal cycle test were performed. And we examined changes in characteristics and abnormality after tests. From results, the test items presented to evaluate performance and reliability of the epoxy insulated busway system were confirmed to be appropriate in this paper, and the performance of the product was also confirmed to be excellent for reliability tests.

Effects of Freshwater Flooding on the Properties of the Accelerated Thermally Aged CSPE (가속열화 된 CSPE의 특성에 미치는 담수침지의 영향)

  • Kang, Myeong-Gyun;Lee, Jung-Hoon;Lee, Seung-Hoon;Jeon, Jun-Soo;Kim, In-Yong;Shin, Yong-Deok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.3
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    • pp.367-370
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    • 2014
  • The accelerated thermal aging of a CSPE were carried out for 0, 80.82, 161.63 days at $100^{\circ}C$, which are equal to 0, 40 and 80 years, respectively. The volume electrical resistivities of the non-accelerated thermally aged CSPE and the accelerated thermally aged CSPE for 40y and 80y were $9.620{\times}10^{12}{\sim}1.246{\times}10^{13}{\Omega}{\cdot}cm$, $5.066{\times}10^{12}{\sim}7.576{\times}10^{12}{\Omega}{\cdot}cm$ and $7.195{\times}10^{12}{\sim}9.208{\times}10^{12}{\Omega}{\cdot}cm$ at room temperature, respectively. The dielectric constant of the non-accelerated thermally aged CSPE and the accelerated thermally aged CSPE for 40y and 80y were 3.355~4.030, 2.996~3.963 and 3.020~4.776 at room temperature, respectively. After seawater and freshwater flooding, the volume electrical resistivity of the CSPE trend slightly upward according to drying day at room temperature. After seawater flooding, the dielectric constant of the accelerated thermally aged CSPE were not measured. After seawater flooding, bright open pores of the accelerated thermally aged CSPE were partly transferred to dark close pores due to salinity. After freshwater flooding, dark close pores of the accelerated thermally aged CSPE were partly transferred to bright open pores because salinity of them is decreased. An insulation property of a cable in NPPs was decreased because of the seawater flooding, and an insulation property of them was recovered through the freshwater flooding. As a result, it is considered that an insulation property of a contaminated cable through Tsunami can be recovered if it is cleaned quickly.

Verification of the Viability of Equipotential Switching Direct Current Potential Drop Method for Piping Wall Loss Monitoring with Signal Sensitivity Analysis (등전위 교번식 직류전위차법의 신호 정밀도 검증을 통한 배관 감육 진단 기술에의 적용성 검증)

  • Ryu, Kyung-Ha;Hwang, Il-Soon;Kim, Ji-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.2
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    • pp.191-198
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    • 2008
  • Flow accelerated corrosion (FAC) phenomenon of low alloy carbon steels in nuclear power plant has been known as one of major degradation mechanisms. It has a potential to cause nuclear pipe rupture accident which may directly impact on the plant reliability and safety. Recently, the equipotential switching direct current potential drop (ES-DCPD) method has been developed, by the present authors, as a method to monitor wall loss in a piping. This method can rapidly monitor the thinning of piping, utilizing either the wide range monitoring (WiRM) or the narrow range monitoring (NaRM) technique. WiRM is a method to monitor wide range of straight piping, whereas NaRM focuses significantly on a narrow range such as an elbow. WiRM and NaRM can improve the reliability of the current FAC screening method that is based on computer modeling on fluid flow conditions. In this paper, the measurements by ES-DCPD are performed with signal sensitivity analyses in the laboratory environment for extended period and showed the viability of ES-DCPD for real plant applications.

Effects of Seawater & Freshwater Soaking on the Cure Properties of Accelerated Thermally Aged CSPE (가속열화 된 CSPE의 경화특성에 미치는 해수 담수 침지의 영향)

  • Shin, Yong-Deok;Lee, Jeong-U
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.5
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    • pp.819-824
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    • 2016
  • The accelerated thermal aging of CSPE (chlorosulfonated polyethylene) was carried out for 33.64 and 67.27 days at 110[$^{\circ}C$], equivalent to 40 and 80 years of aging at 50[$^{\circ}C$], respectively. These samples were referred to as CSPE-0y, CSPE-40y and CSPE-80y, respectively. As the accelerated thermally aged years of the CSPE increase, the insulation resistance[$\Omega$] at 20[Hz], 500[Hz], and 2[KHz], and the percent elongation [%EL] of the CSPE decrease. However, the dissipation factor($tan{\delta}$) at 20[Hz], 500[Hz], and 2[KHz], the apparent density[$g/cm^3$], the glass transition temperature and the melting temperature of the CSPE were increased. The period of time that the voltage has to be applied until electric breakdown of the CSPE-0y is longer than that of the CSPE-40y, and the CSPE-80y, but the dielectric strength of the CSPE-80y is lower than that of the CSPE-0y and the CSPE-40y. The differential temperatures after the AC and DC voltages are applied to CSPE-0y, CSPE-40y and CSPE-80y are 0.026~0.028[$^{\circ}C$], 0.030~0.042[$^{\circ}C$], 0.018~0.045[$^{\circ}C$], respectively. The variations of temperature for the AC voltage are higher than those for the DC voltage when an AC voltage is applied to CSPE-0y, CSPE-40y and CSPE-80y. It is found that the dielectric loss owing to the dissipation factor[$tan{\delta}$] is related to the electric dipole conduction current. It is ascertained that the ionic (electron or hole) leakage current is increased by the separation of the branch chain of CSPE polymer from the main chain of the polyethylene as a result of thermal stress due to accelerated thermal aging as well as by conducting ions such as $Na^+$, $Cl^-$, $Mg^{2+}$, $SO_4^{2-}$, $Ca^{2+}$ and $K^+$ after seawater soaking.

Electrical Stability of Zn-Pr-Co-Cr-Dy Oxides-based Varistor Ceramics (Zn-Pr-Co-Cr-Dy 산화물계 바리스터 세라믹스의 전기적 안정성)

  • 남춘우;박종아;김명준;류정선
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1067-1072
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    • 2003
  • The electrical stability of the varistor ceramics composed of Zn-Pr-Co-Cr-Dy oxides-based varistors was investigated at 0.0∼2.0 mol% Dy$_2$O$_3$ content under DC accelerated aging stress. The ceramic density was increased up to 0.5 mol% Dy$_2$O$_3$ whereas further addition of Dy$_2$O$_3$ decreased sintered ceramic density. The density sailently affected the stability due to the variation of conduction path. The nonlinearity of varistor ceramics was greatly improved above 45 in the nonlinear exponent and below nearly 1.0 ${\mu}$A by incorporating Dy$_2$O$_3$. Under 0.95 V$\_$1mA/150$^{\circ}C$/24 h stress state, the varistor ceramics doped with 0.5 mol% Dy$_2$O$_3$ exhibited the highest electrical stability, in which the variation rates of varistor voltage, nonlinear exponent, and leakage current were -0.9%, -14.4%, and +483.3%, respectively. The variation rates of relative permittivity and dissipation factor were +7.1% and +315.4%, respectively. The varistors with further addition of Dy$_2$O$_3$ exhibited very unstable state resulting in the thermal runaway due to low density.

Analysis on the Voltage, Current and Temperature Signals for Free and Locked Operation of Three Speed Electric Fan (3단 스피드 선풍기 모터의 정상 및 고정 운전에 대한 전압, 전류 및 온도 신호 분석)

  • Kim, Yoon Bok;Kim, Doo Hyun
    • Fire Science and Engineering
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    • v.28 no.3
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    • pp.87-91
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    • 2014
  • This paper is aimed to find electrical fire danger for analyzing the characteristics of temperature, current and voltage signals for motor on electric fan. In order to attain this purpose, detected were the temperature, current and voltage signals on electric wire with free (normal state) and locked (abnormal state) motor. For voltage and current signals, voltage signal is no big difference with normal and abnormal states and current signal is higher in abnormal state (highest 309 mA) than the normal state (highest 203 mA). In the case of Temperature signal, the temperature distribution of the motor as a whole is different. It is difference in the case of the normal state $4^{\circ}C$ and the abnormal state $18^{\circ}C$. In particular, most of the electric wiring to the motor of the fan is attached to the fixture of motor back. Considering at allowable temperature ($60^{\circ}C$) of the electric wire could be accelerated to insulation deterioration. The results of this study will be effectively used in analyzing for electric fire and developing the preventive devices of electric fan.

Study on Possibility of Diesel Reforming with Hydrogen Peroxide in Low-Oxygen Environments (산소희박환경에서 과산화수소를 이용한 디젤개질 가능성 탐구)

  • Han, Gwangwoo;Bae, Minseok;Bae, Joongmyeon
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.584-589
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    • 2015
  • For effective power generation with fuel cells in low-oxygen environments such as submarines and unmanned underwater vehicles, a hydrogen source which has a high hydrogen storage density is required. Diesel fuel is easy to storage and supply due to its liquid phase and it has a high density per unit volume and unit mass of hydrogen that required for driving the fuel cells. In this paper, diesel fuel was selected as a hydrogen source for driving the fuel cell in oxygen lean environments. In addition, the aqueous hydrogen peroxide solution was suggested as an alternative oxidant for hydrogen production through the diesel reforming reaction because of its high oxygen density and liquid phase which makes it easy to storage. In order to determine the characteristics of hydrogen peroxide as an oxidant of diesel reforming, comparative experiments were conducted and it was found that hydrogen peroxide solution has the same characteristics when reformed with oxidants of both steam and oxygen. Moreover, the commercial diesel reforming performances were analyzed according to the reaction temperature and concentration of aqueous hydrogen peroxide solution. Then, through the 49 hours accelerated degradation tests, the possibility of hydrogen production via diesel and aqueous hydrogen peroxide solution was confirmed.