• 제목/요약/키워드: 가속열화

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Application of Accelerated Degradation Testing for VFD (Vacuum Fluorescent Display) (VFD(Vacuum Fluorescent Display) 가속열화시험 응용사례)

  • Bae, Suk-Joo
    • Journal of Applied Reliability
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    • v.5 no.4
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    • pp.413-425
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    • 2005
  • As an alternative to traditional life testing, degradation tests can be effective in assessing product reliability when measurements of degradation leading to failure can be observed. This article presents an accelerated degradation testing for vacuum fluorescent displays (VFDs). The accelerated degradation model is based on Arrhenius-lifetime relationship for cathode temperatures. We compare the results between accelerated degradation test and test at normal use condition. Accelerated degradation test for display devices is observed as an efficient method to warrantee product reliability to customers, as well as a tool to save time and costs.

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Electrical properties and degradation behavior of Tm2O3 doped barium titanate ceramics for MLCCs (Tm2O3가 첨가된 MLCC용 BaTiO3 유전체의 전기적 특성 및 열화거동)

  • Kim, Do-Wan;Kim, Jin-Seong;Hui, K.N.;Lee, Hee-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.6
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    • pp.278-282
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    • 2010
  • The doping effect of thulium on electrical properties and degradation behavior in barium titanate ceramics ($BaTiO_3$) was investigated in terms of generations of core-shell structure and micro-chemical changes through highly accelerated degradation test. The dielectric specimens of pellet type and multi-layered sheets were prepared by using $BaTiO_3$ with undoped and doped with 1 mol% $Tm_2O_3$. The $BaTiO_3$ ceramics doped with 1 mol% $Tm_2O_3$ had 40% higher dielectric constant (${\varepsilon}$ = 2700) than that of the undoped $BaTiO_3$ specimen at curie temperature and met X7R specification. According to the result of highly accelerated degradation test conducted at $150^{\circ}C$, 70 V, and 24 hr, the oxygen diffusion was declined in dielectrics doped with 1 mol% $Tm_2O_3$. The $Tm^{3+}$ ion substituted selectively Ba site and Ti site and contributed to the generation of the core-shell structure. Oxygen vacancies occurred by substitution for Ti site could reduce excess oxygen that reacted to the Ni electrode.

Effects of Changes in Accelerated Degradation Conditions for Catalyst Supports in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지(PEMFC)에서 촉매 지지체 가속 열화 조건 변화의 영향)

  • Sohyeong Oh;Yuhan Han;Donggeun Yoo;Myoung Hwan Kim;Ji Young Park;Youngjin Choi;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.7-12
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    • 2024
  • The durability of the catalyst support has a significant effect on the durability of proton exchange membrane fuel cells (PEMFC). The accelerated durability evaluation of the catalyst support is performed at a high voltage (1.0 to 1.5 V), and the catalyst and ionomer binder in the catalyst layer are also deteriorated, hindering the evaluation of the durability of the support. The existing protocol (DOE protocol) was improved to find conditions in which the support, which is a durability evaluation target, deteriorates further. A protocol (MDOE) was developed in which the relative humidity was lowered by 35% and the number of voltage changes was reduced. After repeating the 1.0 ↔ 1.5 V voltage change cycle, the catalyst mass activitiy (MA), electrochemical active area (ECSA), electrical double layer capacity (DLC), Pt dissolution and particle growth were analyzed. Reaching 40% reduction in mass activity, the MDOE protocol took only 500 cycles, reducing the number of voltage changes compared to the DOE method and increasing the degradation of the carbon support by 50% compared to the DOE protocol.

Effect of Sintering Time on Degradation Characteristics of ZPCCY-Based Varistors (ZPCCY계 바리스터의 열화특성에 미치는 소결시간의 영향)

  • 남춘우;박종아
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.464-470
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    • 2004
  • The electrical stability of ZPCCY-based varistors composing of ZnO-Pr$_{6}$O$_{11}$-CoO-C $r_2$ $O_3$- $Y_2$ $O_3$ ceramics were investigated in various DC accelerated aging stress with sintering times. Sintering time greatly affected electrical properties and stability. Sintering time decreased nonlinear exponent in the range of 51.2∼23.8 and increased leakage current in the range of 1.3∼5.6 ${\mu}$A. The varistor sintered for 1 h exhibited high nonlinearity, whereas relatively low stability. On the contrary, the varistor sintered for 3 h exhibited low nonlinearity, whereas relatively high stability. But the varistor sintered for 2 h exhibited not only good nonlinearity, with nonlinear exponent of 38.6 and leakage current of 3.6 ${\mu}$A but also high stability, in which the variation rates of varistor voltage, nonlinear exponent, leakage current, and dissipation factor are -0.80%, -1.81 %, +74.4%, and +0.88%, respectively.

Discoloration Effects of LEDs on Painting Binder Materials (LED광원에 의한 회화 전색제의 변색 영향 연구)

  • Kim, Ji Won;Lee, Yu Jung;Kim, Kyu Lin;Lee, Hwa Soo;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.34 no.2
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    • pp.77-85
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    • 2018
  • In order to understand the influence of light artifact discoloration, priority must be given to the reaction characteristics of the light the materials constituting the product. In this study, we focus on two representative medium, animal glue and linseed oil which constitute the colored layer of the painting relics. This study is based on an accelerated degradation test using two types of light emitting diods (LEDs) with different wavelength characteristics. In the experiments, discoloration appeared markedly in the animal glue and linseed oil under accelerated aging test conditions using Blue LED. Among the two types of LEDs, the degree of discoloration of the material was much higher with the Blue LED having the total radiation flux (mW). This indicates that the discoloration of painting artifacts such as animal glue and linseed oil is more significantly influenced by the total radiation flux (mW) of the light source than the total luminous flux (lm).

Reducing the Test Time for Chemical Durability of PEMFC Polymer Membrane (PEMFC 고분자막의 화학적 내구성 평가시간 단축)

  • Oh, Sohyeong;Cho, Wonjin;Lim, Daehyeon;Yoo, Donggeun;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.333-338
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    • 2021
  • The durability of the PEMFC stack for large commercial vehicles should be more than 5 times that for passenger vehicles. If the Chemical Accelerated Stress Test (AST) of PEMFC(Proton Exchange Membrane Fuel Cells) membrane for passenger cars is applied as it is for large commercial vehicles, there is a problem that the AST time becomes more than 2,500 hours. In order to shorten the AST time of DOE (Department of Energy), the chemical durability of the polymer membrane was evaluated using oxygen instead of air as a cathode gas. In this study, Nafion XL was used as a polymer membrane to evaluate accelerated durability under OCV, 90?, RH 30%, H2/(air or oxygen) conditions. Among the DOE membrane durability target criteria, the decrease rate of short resistance was the fastest. By using oxygen instead of air, the degradation rate of the polymer membrane was accelerated while being less affected by electrode deterioration, reducing the polymer membrane durability evaluation time to less than half.

Effect of Combined Environmental Factors on Degradation Behavior of Carbon Fiber/Epoxy Composites (복합적인 환경인자의 영향에 따른 탄소섬유/에폭시 복합재의 열화 특성)

  • Hwang, Young-Eun;Lee, Gil-Hyung;Yoon, Sung-Ho
    • Composites Research
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    • v.22 no.5
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    • pp.37-42
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    • 2009
  • Thermal analysis properties and chemical structure of carbon fiber/epoxy composites under environmental exposure were examined using an accelerated aging tester which can simulate real weather conditions such as temperature, moisture and ultraviolet. The composite specimens were exposed to combined environmental factors up to 3000 hours. Thermal analysis properties and chemical structure of the composites were evaluated with various exposure times through Modulated DSC and FTIR. According to the results of Modulated DSC, the glass transition temperature increased as exposure time increased due to the formation of network structures in the composites. Also endotherm peaks of enthalpy relaxation related to physical aging that can affect the properties of the composites were observed as exposure time increased. From the results of FTIR, it was found that the location of the peaks was little affected by exposure time, but the intensity of the peaks slightly decreased as exposure time increased due to the curing reaction in the epoxy group.

A Study on Irreversible Degradation through OCV Reduction and Recovery Behavior in the Electrochemical Degradation Process of PEMFC Polymer Membrane (PEMFC 고분자 막의 전기화학적 열화과정에서 OCV 감소 및 회복 거동을 통한 비가역적 열화 연구)

  • Yoo, Donggeun;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.217-222
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    • 2022
  • It is very important to analyze the OCV change behavior during the open circuit potential holding (OCV holding) process, which accelerates the evaluation of the electrochemical durability of the PEMFC membrane. In this study, an empirical formula using the experimental data of three MEAs with different durability was created and compared. The durability evaluation time of the reinforced membrane MEA without radical scavenger inside the membrane was 383 h, and the durability evaluation time of the reinforced membrane MEA with radical scavenger inside the membrane was 1,000 and 1,650 h, respectively. The degradation of the membrane was divided into the reversible degradation that can be recovered by activation and the irreversible degradation that is not recovered. The irreversible degradation of the membrane was indicated by an increase in hydrogen permeability, and the change in hydrogen permeability was similar to the irreversible degradation constant c of all three MEAs. The initiation of irreversible deterioration without recovery is indicated by an increase in hydrogen permeability, and the OCV is not recovered due to an increase in hydrogen permeability, so the slope of the OCV recovery line (ORL) decreases, which can be confirmed by an increase in the constant c value of the empirical formula.

Leakage cerrent characteristics of 154kV porcelain insulators with various ambient humidity (습도 변화에 따른 154kV급 송전용 자기애자의 누설전류 특성연구)

  • Oh, Chung-Seok;Lee, Young-Jo;Ryu, Cheol-Hwi;Lee, Bang-Wook;Choi, Gwang-Beom;Koo, Ja-Yoon
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1461_1462
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    • 2009
  • 송전선로에 설취된 애자들은 지속적인 전기적 기계적 스트레스에 노출되어 있기 때문에 여러 환경적 요인으로 인해 애자 표면의 열화가 가속된다. 이와 같은 애자의 표면 열화는 dryband를 형성하게 되고 지속적인 애자 표면상의 dryband와 누설 전류 증가의 상호작용은 애자의 섬락를 일으키는 원인이 된다. 이러한 연구의 결과 고전압용 애자로 유입되는 누설 전류는 애자 열화의 정도를 평가할 수 있는 매우 중요한 parameter임을 알 수 있다. 따라서 고전압용 애자의 누설전류를 분석하고 취득하여 애자의 열화 평가 및 이로 인해 발생할 수 있는 결함 애자의 검출에 대한 연구가 절실히 요구되고 있다. 본 논문에서는 고전압용 애자 중 자기애자의 습도변화에 따른 누설전류 특성을 조사하기 위해 자체 제작한 실험 챔버, power transformer, 전류센서, 오실로스코프, PC등으로 구성된 실험 시스템을 구축하였고, 데이터 분석을 위한 S/W로서 LabView를 사용하였다. 그에 따른 실험결과로서 다양한 습도변화(30%~90%)의 경우 정상 애자련과 결함 애자를 포함한 애자련의 누설전류 데이터를 취득하여 본 연구에서 제시한 알고리즘을 통해 분석함으로써 정상 애자 내의 결함 애자 포함 여부를 판별하고 다양한 습도 변화시에 정상 애자련과 불량 애자련의 특징을 볼 수 있었다.

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A Study on the Aging Diagnosis of Transformer oil by Spectrometric and Electroanalytical Methods (분광광도법 및 전기분석법을 이용한 절연유의 경년열화 진단에 관한 연구)

  • 김경렬;곽희로;윤영자;남궁미옥;이동준
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.12 no.2
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    • pp.15-20
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    • 1998
  • The furfural, generated by decomposition of insulating paper, the amount of metal in insulating oil, and tano(electrical properties of insulating oil)have been studied for the insulating oil in pole transformer with accelarated thermal aging test. It has been found that tan $\delta$ is affected by adding components of the transformer. The examination of amount of metal, which exhibits catalytic behavior to oxidation of insulating oil, suggested that the amounts of copper increase with degradation time. A comparison between tano and copper amount suggested that the amounts of copper for attention are above 0.2[pp]). Finally, the examination of amount of furfural revealed that the amounts of furfural increase with degradation time. As a consequence, these results could be used for diagnosis of pole transformer.former.

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