• Polymer(Korea)
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• v.29 no.5
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• pp.518-521
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• 2005

Biodegradable polymers and hydrogels have been increasingly applied in a variety of biomedical applications including current drug delivery system and tissue engineering field. ${\alpha},\;{\beta}-Poly$(N-2-hydroxyethyl-DL-aspart-amide), PHEA. is one of poly(amino acids) with hydroxyethyl pendants, which is hewn to be biodegradable and potentially biocompatible. So that, the utilization and various chemical modifications of PHEA have been attempted for useful biomedical applications. In this wort chemical gels based on PHEA were prepared by crosslinking with diisocyanate compound in DMF in the presence of catalyst. Here, the PHEA was prepared from polysuccinimde, the thermal polycondensation product of aspartic acid, via ring-opening reaction with ethanolamine. The preparation of gels and their swelling behavior, depending on the different medium and pH, were investigated. Also the morphology by SEM and simple hydrolytic degradation were observed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.4039-4045
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• 2014

The crystallization behavior of irradiated polypropylene (PP) and the blend is an important parameter for polymer processing. Blends of PP/low density polyethylene (LDPE) with different LDPE contents were prepared by melt mixing in a twin screw extruder. The effect of the LDPE content on the irradiation effectiveness of the PP/LDPE blend with trimethylolpropane-trimetacrylate (TMPTMA) as a crosslinking co-agent was investigated in conjunction with the LDPE loading in the blend. The non-isothermal crystallization and crystal structure were measured by DSC, X-ray diffraction (XRD), and polarized optical microscopy (POM). A decrease in the melting temperature of PP was observed due to irradiation, which may be due to the PP chain scissioning effect of irradiation. The Ozawa component n represents a rod shaped, disc shaped and sphere-shaped geometry of the crystal if the value corresponds to 2, 3 and 4, respectively. Based on Ozawa analysis, the values of n were 3.8 and 2.3 for the pure PP and PP blends with 30 wt% LDPE, respectively. The fact that the crystal geometry of PP changed from spherical to disc and rod shaped was confirmed by Ozawa analysis and POM. The ${\beta}$ form XRD peak of the PP/LDPE blend at $16.1^{\circ}$ disappeared after irradiation due to the crosslinking reaction.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.305-312
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• 2005

Poly(urethane-imide)s were prepared by reaction between crosslinkable endgroup containing soluble polyimide (PI) by chemical imidization and acrylate end-capped polyurethane (PU). Poly (amic acid) was prepared from 2,2'-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) and 4,4'-oxydianiline (ODA) and then end-capped with maleic anhydride (MA). The PU prepolymers were prepared by the reaction of polycaprolactone diol, tolylene 2,4-diisocyanate and end-capped with hydroxyl ethyl acrylate. The effect of PU content on the residual stress behavior, morphology and thermal property was studied. The poly(urethane-imide)s were characterized by thin film stress analyzer (TFSA), XRD, TGA and DMTA. Low residual stress and slope in cooling curve were achieved by higher PU content. Compared to typical polyurethane, these polymers exhibited better thermal stability due to the presence of the imide groups. Finally the residual stress of poly(urethane-imide)s was strongly affected by the morphological structure.

• Journal of Korean Society of Steel Construction
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• v.17 no.5 s.78
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• pp.637-648
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• 2005

Innovative prestressed steel plate girders were presented in this study. Hot-rolled H beams were loaded first, then relatively high-strengthsteel plates were welded on the top and bottom flanges of preloaded H beams. Finally, high prestressed plate (HiPP) girder was manufactured by simply releasing prestresses of rolled beams. To verify prestress distributions induced in this girder, the experimental study was conducted and some guidelines to manufacture these girders effectively were addressed. In addition, methods to determine the allowable bending stress of HiPP girders and to check welding stresses were addressed for design of temporary bridges. The efficiency and effectiveness of the present girder were demonstrated through design examples of temporary bridges adapting the prestress-induced girder or the plate girder of the same section without prestresses. As a result, it has been found to be possible that the span length of HiPP girders for temporary bridges is longer than that of girders without prestresses.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.44 no.1
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• pp.23-29
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• 2018

In this study, sequential cross-linked collagen gels were successfully prepared with collagen, which is biomaterial, and acrylamide (AAm), which is a synthetic monomer. The elastic moduli (E) of cross-linked collagen gels were increased from 1.5 to 3.0 kPa by varying of AAm concentrations. In addition, human dermal fibroblasts were encapsulated into the porous pores introduced into the gels, and cell growth and behavior were investigated. Increasing E of the gels led to decreases in cell growth rate, while the cellular glycosaminoglycan (GAG) production level was elevated. Overall, the growth and cellular activity of skin cells were influenced by the extracellular matrix properties of the collagen gels. In conclusion, these results will be highly useful for designing reconstructive skins and various tissue engineering researches.

• Journal of Adhesion and Interface
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• v.9 no.3
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• pp.14-19
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• 2008

In this study, silicone rubber (SR40) and fluororubber (FKM) mixture blends were prepared by various weight percentages, and their properties were characterized. The crosslinking rate increased as the contents of SR40 due to the crosslinking agent in SR40. As contents of FKM increase in SR40/FKM blends, thermal decomposition temperature of blends increased. When SR40/FKM blend ratio was at 50/50, the thermal decomposition stabilization was higher than that of pure SR40. The contact angle of SR40/FKM blend increased as the increase of SR40 contents in blend. All composition of SR40/FKM blends showed typical phase separation morphology. As the contents of SR40 increase in SR40/FKM blend, the degree of separation in SR40/FKM blends also increased.

• Elastomers and Composites
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• v.22 no.3
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• pp.213-218
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• 1987

In this study, the rheological properties of a partially valcanized black filled EPDM were investigated as a function of degree of crosslinks using capillary rheometer. In order to obtain the samples having various degree of crosslinks between 0 and 6 percent, the vulcanization kinetics was also studied by Monsanto rheometer. The results showed that the die swell ana the pressure drop at the capillary entrance and exit increase nearly linearly with the increase in degree of crosslinks. However, melt fracture occurred at a lower shear rate for the samples of higher degree of crosslinks. These results were discussed in terms of the melt elasticity produced at the entrance region of capillary by the partial vulcanization. It is also interesting to note that the fluctuation of die swell during the practical extrusion or calendering process in the factories can be caused by the partial vulcanization occurred during the process.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.933-936
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• 2008

An engineered cementitious composite (Engineered Cementitious Composite) had been developed in previous study. Theoretical prediction of the tensile stress-strain relation of ECC is important in providing the material constitutive relation necessary for designing structural members. But, few studies have been reported with regard to predicting the tensile stress-strain relation of ECC. Prediction of the tensile stress-strain relation of ECC accounting for actual bridging curve, such as fiber dispersion is needed. The present study extends the work as developed by Kanda et al., by modeling the bridging curve, accounting for fiber dispersion, the degree of matrix spalling, and fiber rupture to predict the tensile stress-strain relation of ECC. The role of material variation in the bridging curve, such as number of effective fiber actually involved in the bridging capacity and how it affects the multiple cracking process is discussed. The approach for formulating the tensile stress-strain relation is discussed next, where the procedure for obtaining the necessary parameters, such as the crack spacing, is presented. Finally, the predicted stress-strain relation will be validated with experimental tests results.

• Composites Research
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• v.30 no.3
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• pp.193-201
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• 2017

Molecular dynamics simulation and the Mori-Tanaka micromechanics study are performed to investigate the effect of the covalent grafting between CNT and polyester on the mechanical behavior and load transfer of nanocomposites. The transversely isotropic stress-strain curves are determined through the tension and shear simulations according to the covalent grafting. Also, isotropic properties of randomly dispersed nanocomposites are obtained by orientation averaging the transversely isotropic stiffness matrix. By addressing the grafting, the transverse Young's modulus and shear moduli of the nanocomposites are improved, while the longitudinal Young's modulus decreases due to the degradation of the grafted CNT.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.33-36
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• 2006

The kinetics of photopolymerization of urethane-acrylate oligomer which has many applications in photopolymerizable adhesives was analysed to investigate the influence of polymerization temperature and functionality of oligomer using the autocatalytic model. It was revealed that the maximum polymerization rate decreased as the polymerization temperature increased. The reaction rate constant, k, showed little change with the increase in polymerization temperature, while exponents m and n exhibited an increase. These results could be related to the diffusion and mobility restriction of reactive species during the cross-linking reaction. The decrease in photopolymerization rate with increase of temperature was mainly controlled by the reaction order n.