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Thermal analysis of LNG storage tank for LNG bunkering system (LNG 벙커링용 고효율 LNG 저장탱크 열해석)

  • Yun, Sang-kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.9
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    • pp.876-880
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    • 2015
  • In 2016, the IMO's new rules for an 80% reduction in NOx emissions in newly built ships will necessitate the use of LNG as a clean fuel. So far, the developed European countries have led the development of LNG bunkering ships and related facilities. An LNG bunkering system stores LNG in a horizontal or vertical IMO "C"-Type tank insulated with perlite powder, and a vacuum in the annular space between the double walls, like the cryogenic liquid nitrogen tank. Current storage tanks have high heat leakage, evaporating over 2.0% daily, and are difficult to build with the required vacuum. A more efficiently insulated storage tank could reduce the evaporation rate. This research carried out thermal analysis on a new effective insulation method that separates high vacuum in the annular space between two tanks with a solid insulation material, such as urethane foam, lining the outer vessel. This highly efficient insulation system obtained an evaporation rate of 0.03% per day under a $10^{-3}torr$ vacuum, and an evaporation rate of 0.11% at $10^{-45}torr$. Even if the space loses its vacuum, the new insulation system showed a lower evaporation rate of 4.12% than the present perlite system of 4.9%. This newly developed tank can increase the efficiency of LNG storage tank and may help keep LNG bunkering systems safe.

An Experimental Study for Reinforcement Effect of Adhesive Stiffeners Depending on the Aspect Ratio of Masonry Wall (조적벽체의 형상비에 따른 접착형 보강재의 보강효과에 관한 실험적 연구)

  • Park, Byung-Tae;Kwon, Ki-Hyuk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.13-20
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    • 2017
  • Unreinforced masonry buildings are vulnerable to lateral forces, such as earthquakes, owing to the nature of the building materials, yet numerous masonry buildings remain in South Korea. Since the majority of the existing masonry buildings were constructed more than 20 years ago, it is necessary to develop economical reinforcement methods for disaster reduction. In this study, external reinforcement of masonry walls using adhesive stiffeners was proposed as a reinforcement method for such age-old masonry buildings. Six specimens were fabricated with different aspect ratios (L/H = 1.0, 1.3, and 2.0) and used in static load tests to verify the reinforcement effect. The experimental results showed that the masonry walls before and after reinforcement were ruptured by rigid body rotation and slip. In addition, the maximum strength, maximum displacement, and dissipated energy of the walls were shown to increase after applying the adhesive stiffeners, thereby verifying the excellent reinforcement effect. Furthermore, an adhesive stiffener design for unreinforced masonry walls was proposed based on the increased shear strength achieved by using conventional glass fibers. The proposed design can be used as a basis for the application of adhesive stiffeners for unreinforced masonry walls.

Conservation Treatment of Sand Stone by Pressurized Impregnation with Acrylic Materials (아크릴계 보존처리제를 이용한 사암의 가압함침 보존처리)

  • Kim, Youn-Cheol;Kim, Sa-Duk;Kim, Hyung-Joong
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.395-401
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    • 2011
  • After pressurized impregnation treatment, which has been proposed as an effective conservation method for stone cultural property, was executed with methyl metacrylate (MMA), MMA-butyl acrylate (PMB73) mixture and MMA-vinyl trimethoxy silane (PMV5) co-monomer mixture, the physical-chemical properties on the sand stone and the granite impregnated were evaluated. Compared to the case of granite, the impregnation ratios of sand stone showed larger values in the range of 3.2 to 3.7 wt% and these were increased up to 32% when the decompression process was applied to autoclave. The physical properties of sand stone such as anti-moisture property, flexural strength, impact property and ultrasonic velocity were also higher values than those of granite, which can be interpreted by high impregnation ratio resulted in many void within sand stone. The impact failure energy was 1.22 J for PMMA, 1.84 J for PMB73, and 2.8 J for PMV5, respectively. Since the inorganic affinity of treatment agent is more effective than the molecular structure of acrylic agent, PMV5 improved inorganic property indicates the optimum impact property.

Evaluating Seismic Performance of Steel Welded Moment Connections Fabricated with SN Steel (SN 강재가 사용된 강구조 용접모멘트접합부의 내진성능 평가)

  • Oh, Sang-Hoon;Choi, Young-Jae;Yoon, Sung-Kee;Lee, Dong-Gue
    • Journal of Korean Society of Steel Construction
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    • v.22 no.3
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    • pp.271-280
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    • 2010
  • This study was programmed to fabricate a beam-to-column connection that is limited to a steel-welded moment connection with full-scale members, using SN steel. A cyclic seismic test was conducted of the nine specimens that were fabricated by choosing the test variable for the weld access hole geometry, connection design method, and RBS. From the test results, failure modes, the moment-drift behavior, and the strain distribution were provided. From the specimen material properties, the beam's nominal plastic flexural capacity and classified qualified connection as a special moment flame were calculated. By analyzing the skeleton part and the baushinger part, a range of strength-raising effects, and deformation ratios were provided, with which the seismic performance of the specimens were evaluated. The test results showed that the specimens eliminated their weld access holes that demonstrated higher seismic performance than the specimens' existing weld access holes, and that the WUF-W connection that was reinforced by the supplemental fillet weld around the shear tap that was fastened by five bolts demonstrated superior seismic performance.

Conjugate Simulation of Heat Transfer and Ablation in a Small Rocket Nozzle (소형 시험모터의 노즐 열전달 및 삭마 통합해석)

  • Bae, Ji-Yeul;Kim, Taehwan;Kim, Ji Hyuk;Ham, Heecheol;Cho, Hyung Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.2
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    • pp.119-125
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    • 2017
  • Ablative material in a rocket nozzle is exposed to high temperature combustion gas, thus undergoes complicated thermal/chemical change in terms of chemical destruction of surface and thermal decomposition of inner material. Therefore, method for conjugate analysis of thermal response inside carbon/phenolic material including rocket nozzle flow, surface chemical reaction and thermal decomposition is developed in this research. CFD is used to simulate flow field inside nozzle and conduction in the ablative material. A change in material density and a heat absorption caused by the thermal decomposition is considered in solid energy equation. And algebraic equation under boundary layer assumption is used to deduce reaction rate on the surface and resulting destruction of the surface. In order to test the developed method, small rocket nozzle is solved numerically. Although the ablation of nozzle throat is deduced to be higher than the experiment, shape change and temperature distribution inside material is well predicted. Error in temperature with experimental results in rapid heating region is found to be within 100 K.

Friction Welding of Ni-Base ODS Alloy Prepared by Mechanical Alloying (기계적 합금법으로 제조된 Ni기 산화물 분산강화 합금의 마찰압접에 관한 연구)

  • 강지훈;박성계;김지순;권영순
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1994.10b
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    • pp.15-15
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    • 1994
  • M MA ODS 합금의 보다 폭넓용 실용확훌 위해 크게 요구되고 있는 적정 접합기술 개발의 한 방안£로, 마찰압접(Friction Welding) 방법의 가능성옳 조사하기 위하여 마찰압력과 시간, 마 찰 후 접촉압력(Upset Pressure) 풍을 다양하게 변화시켜 접합체톨 제조한 후, 접합체 강도에 대한 인장시험과 접합계연의 결합 및 미세구조에 대한 현미경 관찰, EDS에 의한 원소분석, 접 합이옴부의 경도분포와 파단면 분석 풍율 행하였다. 실험에 사용된 모재는 기계적 합금법으로 제조된 Inca사의 Ni기 MA 754 합금이었으며, 직경 l 10 mm, 길이 50 mm로 가공한 후, 아세통£로 초음파 세척하여 접합에 사용하였다. 접합온 브 레이크식 마찰압접기틀 사용하여 행하였으며, 회전시험편의 회전수는 2400 rpm이었A며, 다른 한쪽의 고정시험편과의 마찰압력 및 마찰시간온 각각 50 - 500 MPa과 1-5초로, 또한 업셋압 력도 50 - 600 MPa로 변화시켰다. 이때 업셋압력은 모든 시편에 대해 일정하게 6초동안 가하 였다. 얻어진 접합체는 각 압접조건 당 2개 이상의 접합시험편에 대해 상온 인장강도톨 측정하 였으며, 파단이 일어난 위치를 확인한 후 파면에 대한 분석율 주사전자현미경(SEM)과 에너지 분산형 분광분석기mDS)릎 사용하여 행하였다. 컵합이옴부의 첩합성올 확인하기 위하여, 접합 체를 접합변에 수직으로 절단, 연마한 후 광학현미경과 SEM, EDS 퉁으로 관찰, 분석하여 접 합부의 형상과 결합형성 여부, 접합계면의 미세조직 퉁옳 조사하였다. 또한 마찰압접에 따론 모재와 접합계연부의 경도분포훌 접합이옴부로부터 모재쪽으로 일정 간격율 두어 마이크로 비 커스 경도기로 측정, 조사하였다. 이상의 설험 결과, 다옴과 같온 결론옳 얻었다. ( (1) 접합체 강도가 모채 강도의 95% 이상이 되는 양호한 렵합체흩 얻기 위한 마찰압력 조건 온, 2400 rpm의 회전속도와 6초의 업셋압력 유지시간에서 마찰압력과 업셋압력, 그리고 마찰시 간이 각각 400 MPa 이상과 500 MPa 이상,2초입율 확인하였다. ( (2) 컵합이옴부의 관찰 결과, 모든 마찰압접 조건에서 컵합이옴부는, 기폰 모재의 texture 조직 을 유지하고 있는 모재부 영역(영역 ill)과 첩합계면부에 인접하여 업셋압력이 주어질 때 단조 효과에 의해 계연 외부로 metal flow가 일어나면서 형성된 영역 II, 매우 미세한 결정립으로 구성된 중앙부의 영역 1 로 이투어져 있옴융 확인하였다. ( (3) 최적접합조건이 충족되지 않온 경우, 접합부의 영역 I 에서 관찰된 void와 균열, 불균일한 접합계면 통의 접합결함에 Al과 Y. Ti 퉁£로 구성된 산화물률이 용집되어 있옴을 확인하였 다-( (4) 접합체의 파단 양상온 크게 접합부 파단과 모재부 파단, 이률의 혼합형 파단i로 나눌수 있었다. 모재부 파단의 경우, 파단면이 매끄럽고 파변상의 결정립도 매우 미세하였으며, 산확물 의 용집도 찾아보기 어려웠 나, 접합부 파단의 경우에는 파변의 굴곡이 비교척 심하고 연성 입계파괴의 형태를 보였£며, 결정립도 모채부 파단의 경우에 비해 조대하였다. 조대하였다.

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Studies on Oleoresin Product from Spices 2. Quality Stability of Red Pepper Oleoresin (향신재료를 이용한 Oleoresin제조에 관한 연구 2. 고추 Oleoresin의 품질안정성)

  • 배태진;최옥수;박재림;김무남;한봉호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.6
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    • pp.609-614
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    • 1991
  • Thermal stability and quality change during storage of red pepper oleoresin were studied. Upon heat treatment, carotenoids in oleoresin from red pepper were more stable under nitrogen than air. In the thermal stabilities, the presence of air at $100^{\circ}C$ for 3 hours and 10 hours were 69.1% and 42.3%, respectively ; whereas, in the presence of nitrogen, 95.4% and 92.3%, respectively. In contrast, capsaicin was comparatively stable upon heat treatment in the presence of air. The retentions of capsaicin at $100^{\circ}C$ for 3 hours and 10 hours were 84.7% and 81.3% with air, those were 90.7% and 87.5% with nitrogen, respectively. Color appearance showed close relation to the stability of total carotenoids during 60 days storage at varying temperatures ; $5^{\circ}C,\;25^{\circ}C\;and\;40^{\circ}C$ were 69.4%, 48.0% and 35.1%, respectively. The degradation of total carotenoids during storage could be interpreted as a first order reaction. The activation energy obtained from the Arrhenius plot was 5.03 kcal/mole. Conversely, capsaicin was very stable under storage temperatures. More than 90% of capsaicin was remained upon completion of storage. In the mean time, pH of oleoresin was increased slightly as increasing storage temperatures.

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디엔제3성분단위체(第三成分單位體)가 EPDM가황체(加黃體)에 미치는 영향(影響)

  • Baek, Nam-Cheol
    • Elastomers and Composites
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    • v.14 no.3
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    • pp.161-168
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    • 1979
  • 이 논문(論文)의 목적(目的)은 열적안정성(熱的安定性) 및 내노화성면(耐老化性面)에 있어서 디엔제3성분단위체(第三成分單位體)(diene termonomer)의 각각(各各)의 종류(種類)가 EPDM의 중합체(重合體)의 성질(性質)에 미치는 효과(效果)를 구명(究明)하는데 있다. 제3성분단위체(第三成分單位體) 5종(種)으로 각각(各各) 다음과 같다. 즉, ethylidene norbonene(ENB), butadiene(BD), dicyclopentadiene(DCPD), methyltetrahydroindene (MTHI) 및 1,4-hexadiene(HD)이다. 이들을 써서 만든 각각(各各)의 EPDM은 동(同)몰의 불포화도(不飽和度)로 만들어졌다. 또한 가황계(加黃系)는 동일(同一)한 황/촉진제계(黃/促進劑系)를 사용(使用)하였다. ENB-EPDM이 순(純)고무배합체(配合體) 및 충전제함유배합체(充塡劑含有配合體)의 가황(加黃)에 있어서 모두 함께 가장 빠른 가황속도(加黃速度)를 보였다. HD-EPDM은 순(純)고무배합체(配合體)에서 가황속도(加黃速度)가 가장느렸으나 충전제함유배합물(充塡劑含有配合物)에서는 DCPD-EPDM보다는 발랐다. BD-EPDM을 제외(除外)한 이들 중합체(重合禮)는 거의 같은 초기가교밀도(初期架橋密度)를 갖는다. 가교밀도(架橋密度) 및 가교형(架橋型)을 분석(分析)하여 보면 BD-EPDM 쇄(鎖)에서 부타디엔 단위(單位)는 블럭을 이루고 있다. 또한 HD-EPDM은 순(純)고무가황체(加黃體) 및 충전제배합가황체(充塡劑配合加黃體)에 있어서 원가교결합(原架橋結合)의 50%가 monosulfide의 구조(構造)를 가지고있다. 이외(外)의 4종(四種)의 EPDM 폴리머는 보다 낮은 monosulfide구조를 가진다. $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 ENB 및 HD폴리머는 약(約) 65% monosulfide 가교(架橋) 및 거의 동일(同一)한 파괴에너지값$(E_b)$을 가진다. 그러나 1,4HD의 원가교(原架橋)의 monosulfide 구조함량(含量)이 보다 높다고 해서 그의 내노화성(耐老化性)이 다른 폴리머보다 더 좋다고는 생각되지 않는다. DCPD는 $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 똑같은 monosulfide가교(架橋)를 가지나 노화온도(老化溫度)가 $259^{\circ}C(500^{\circ}F)$로 높아짐에 따라 monosulfide 함량(含量)도 증가(增加)한다. $550^{\circ}F(287.7^{\circ}C)$의 노화온도(老化溫度)에서는 EPDM폴리머의 모든 가교(架橋)가 monosulfide구조가 되나 전가교밀도(全架橋密度) 및 $E_b$ (신장률(伸長率), 절단시(切斷時)의)는 대단(大端)히 낮은 것으로 나타나는데 이것은 산화(酸化)에 의한 노화(劣化)에 기인(基因)되는 것으로 보인다. 질소기류(窒素氣流)속에서의 TGA의 분석결과(分析結果)를 보면 EPDM 가황체(加黃體)는 $800\sim935^{\circ}F(427\sim502^{\circ}C)$의 온도범위(溫度範圍)에서 분해(分解)되며 공기중(空氣中)에서는 $750\sim935^{\circ}F$ 범위(範圍)에서 분해(分解)한다.

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Comparison of Anti-Inflammatory Activity of Spirulina maxima Extract by Ultrasonication and Water Extraction Process (Spirulina maxima의 초음파 및 열수 추출 공정에 따른 항염증 효과 비교 탐색)

  • Sin, Jae Bin;Choi, Woon Yong;Kang, Do Hyung;Lee, Hyeon Yong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.12
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    • pp.1852-1857
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    • 2014
  • The aim of this study was to compare the anti-inflammatory activities of Spirulina maxima treated with ultrasonication and water extraction process. S. maxima extracted via ultrasonication showed low cytotoxicity (16.90%) in a normal human cell line, CCD-986sk. Especially, S. maxima ultrasonication extract showed the highest DPPH radical scavenging activities (46.82%) compared to water extract (31.30%) at $100^{\circ}C$. In addition, ultrasonication extract showed a high amount of flavonoids (21.60 mg/g) and total phenols ($8.36{\mu}g/mL$). Nitric oxide production by 1.0 mg/mL of S. maxima ultrasonication extract strongly inhibited ($1.3770{\mu}M$), whereas water extract showed lower inhibition ($1.5784{\mu}M$). TNF-${\alpha}$ and IL-6 cytokines were effectively inhibited by 1.0 mg/mL of S. maxima ultrasonication extract, which shows strong antioxidant activities. Based on these results, it can be concluded that the ultrasonication process increase anti-inflammatory activity of S. maxima extract.

A Study on Improvement of Seismic Performance of High Strength Reinforced Concrete Interior Beam-Column Joints Using High Ductile Fiber-Reinforced Mortar and Advanced Reinforcing Detailings (고인성섬유 복합 모르타르 및 고성능 배근상세를 활용한 고강도 철근콘크리트 내부 보-기둥 접합부의 내진성능 개선 연구)

  • Ha, Gee-Joo;Yi, Dong-Ryul;Hong, Kun-Ho
    • Journal of the Korea Concrete Institute
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    • v.25 no.2
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    • pp.233-240
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    • 2013
  • In this study, experimental research was carried out to evaluate and improve the seismic performance of high strength R/C interior beam-column joints regions using advanced reinforcing detailings and high ductile fiber-reinforced mortar. Five specimens of retrofitted the beam-column joint regions using advanced reinforcing detailings and high ductile fiber-reinforced mortar were constructed and tested for their retrofitring performances. Specimens designed by retrofitting the interior beam-column joint regions (IJIR series) of existing reinforced concrete building showed a stable mode of failure and an increase in load-carrying capacity. Specimens of IJIR series, designed by the retrofitting of advanced reinforcing detailings and high ductile fiber-reinforced mortar in reinforecd beam-column joint regions increased its maximum load carrying capacity by 114.2~123.5% and its energy dissipation capacity by 1.55~1.85 times in comparison with the standard specimen of SIJC with a displacement ductility of 5.