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유류오염 토양에서 유류성분의 생분해와 무기오염 물질 함량의 관계성에 대한 예비 연구

  • 강진규;송윤구;문지원;이민희;이규호
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.241-244
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    • 2003
  • 유류오염 토양내 유류의 분해와 무기오염물질의 함량과의 관계성을 알아보기위해 부산 문헌지구의 유류 오염 토양 profile중 유류가 비교적 많은 두 층과 유기물이 다량 함유된 제주도 토양을 경유로 오염시킨 토양을 선택하여 유류가 분해 정도와 Pb, Zn, Cd, Ni의 함량을 측정 비교하였다. 토양 채취후 즉시 유류를 추출한 것, 15일간 별도의 미생물 영양원을 가하지 않고 습도와 통풍만을 행하여 토양내 존재하는 미생물들에 의하여만 유류가 분해되도록 한 것, $105^{\circ}C$에서 24시간 열처리를 행하여 미생물에 의한 분해보다는 물리적인 방법으로 비교적 강하게 처리한 것 세가지 경우에서 토양에서 추출한 유류를 분석한 결과 normal alkane이 서서히 상당량 분해되는 양상을 보여주었다. 토양내 Pb, Zn, Cd, Ni를 분석한 결과 부산 시료의 경우 두 층(B2, B3)모두 Cd은 검출한계 이하로, Ni의 경우 극소량의 함량을 보여주었다. Zn의 경우 B2는 28~29ug/g, B3는 12~14ug/g으로 세가지 경우 별 차이 없는 양상을 보여 주었다. 하지만, Pb의 경우 B2에서는 그 함량이 유류의 normal alkane의 분해와 함께 서서히 증가하는 경향을 확연히 보여주었으며, B3의 경우도 B2와 유사한 변화 양상을 보여주었다. 제주도 토양의 경우 Pb는 검출되지 않았고, Zn은 소량 검출되었다. Ba, Ni 함량은 normal alkane 분해에 따라 다소 증가하였다. 따라서, 본 예비실험을 통하여 유류오염 토양에서 유류의 분해와 일부 무기이온사이에는 관련성을 갖고 있으며, 이는 유류 분해정도를 파악하는 지시자로써 특정 무기 오염물질을 이용할 수 있을 가능성이 있으므로 좀더 이들 관계성에 대한 연구가 진행될 필요성이 있다고 판단된다.고 과학적으로 분석할 수 있는 방법이 될 수 있을 것으로 기대된다. 의미를 되새기는 것으로 짧은 연구를 시작하겠다. 등은 활성 값이 70% 이상으로 퇴적물 독성이 상대적으로 낮았다. 이중나선 DNA 함량은 28.4 % - 49%로 대조군에 비해서 감소가 크다. 대부분의 정점이 대조군의 30% 내외로 정점 간의 차이는 크지는 않다. 그러나 다른 측정자료와 같이 정점 22에서 18%로 최소치를 나타내고, 정점 2, 12에서 20% 내외의 값을 보인다. 종합적으로 볼 때 오염물질의 유입이 크고, 광양제철 인근 정점 들이 모두 다른 정점에 비해서 낮아서, 퇴적물 독성이 높은 정점으로 조사되었다.hiwo의 광합성 능력은 낮은 농도들에서는 대조구와 유사하였으나, 5 $\mu\textrm{g}$/l의 높은 농도에서는 초기에 매우 낮은 광합성 능력을 보이다가 시간이 경과하면서 대조군보다 더 높은 경향을 나타냈다. 이러한 결과는 식물플랑크톤이 benso[a]pyrene의 낮은 농도에서 노출될 때는 이 물질을 탄소원으로 사용할 가능성이 있음을 시사한다. 본 연구의 결과들은 연안해역에 benso[a]pyrene과 같은 지속성 유기오염물질이 유입되었을 때 내정여부에 따라 식물플랑크톤 군집내 종 천이와 일차생산력에 크게 영향을 미칠 수 있음을 시사한다.TEX>5.2개)였으며, 등급별 회수율은 각각 GI(8.5%), GII(13.4%), GIII(43.9%), GIV(34.2%)로 나타났다.ments of that period left both in Japan and Korea. "Hyojedo" in Korea is supposed to have been influenced by the letter design. Asite- is also considered to have been "Japan

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Water Environments and Species Compositions of Phytoplankton at the Depths during Summer in the Coast of Dokdo, Korea (하계 독도연안의 수심별 수환경과 식물플랑크톤의 종조성 변화)

  • Kim, Mi-Kyung;Park, Jung-Won
    • Korean Journal of Environmental Biology
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    • v.27 no.1
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    • pp.48-57
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    • 2009
  • The characteristics of physico-chemical factors and the species compositions of phytoplankton were investigated to analyze the marine ecosystem at the depths during summer in the coast of Dokdo (stations DOK1$\sim$3). The mean values of conductivity (32 mS cm$^{-1}$), total dissolved solids (45 mg L$^{-1}$), salinity (35.5 psu), total suspended solids (39 mg L$^{-1}$) were the highest in DOK1. The biomass (chl-${\alpha}$) of phytoplankton was the highest in the surface of station DOK1 (3.1 ${\mu}g$ L$^{-1}$). By means of physico-chemical factors (salinity, turbidity, chl-${\alpha}$, T-N, T-P and Si), the coast of Dokdo was estimated to be more polluted than the previous results in 2000. A total of 72 species in Dokdo were composed of 54 species (76.1%) for Bacillariophyceae and 13 species (18.3%) for Dinophyceae, 3 species (4.2%) for Chrysophyceae and 1 species (1.4%) for Cyanophyceae. The standing crops of phytoplankton were the highest (8.5 $\times$ 10$^4$ cells L$^{-1}$) at 20 m of station DOK1, while they were the lowest (1.65 $\times$ 10$^4$ cells L$^{-1}$) at 30 m of station 1. The dominance index was maximum (0.73) at 10 m of station DOK1 and was minimum (0.4) at 30 m of station 1. The diversity index was the highest (2.92) in the surface of station 2, while it was the lowest at 20 m (1.58). The dominant species of phytoplankton were Chaetoceros affinis (3.3 $\times$ 10$^4$ cells L$^{-1}$) at 20 m, Climacosphenia moniligera (2.8 $\times$ 10$^4$ cells L$^{-1}$) at 40 m and Melosira juergensii (1.7 $\times$ 10$^4$ cells L$^{-1}$) at 10 m of station DOK1. At the surface of station DOK2, the dominant species were Bacillaria paxillifer and Richelia intracellularis (1.4 $\times$ 10$^4$ cells L$^{-1}$, respectively), while it was Paralia sulcata (1.6 $\times$ 10$^4$ cells L$^{-1}$) at the surface of station DOK3. The station DOKl, where affected by upwelling, turbulence and convection due to the East Korean Warm Current, was the most eutrophicated water body in three stations. The monitoring of marine ecosystem in the coast of Dokdo should be continued to show the alternatives for water and species conservation and to purify the eutrophicated water body due to artificial pollutants as well as physico-chemical factors by the global warming, the climatic change, CO$_2$ etc.

Study on the Young Yellowtail, Seriola quinqueradiata (Carangidae, Perciformes) from Drifting Seaweeds in the Coast of Tongyeong, Korea (경남 통영해역의 뜬말에 서식하는 방어 유어에 관한 연구)

  • CHO Sun Hyung;Myoung Jung Goo;Kim Jong Man;Lee Jin Hwan;Park Yong Joo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.6
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    • pp.583-588
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    • 2002
  • Young Seriola quinqueradiata associated with drifting seaweeds weye investigated monthly between April 1998 and March 1999 in the coastal area of Tongyeong, Korea, The most abundant types of seaweed were in the genus Sargassum, including S. horneri, S. miyabei and S. thunbergii. The size of seaweed patches varied by season: patches larger than 4 m in diameter were found in May, whereas patches smaller than 0.5 m in diameter were abundant in August and September. Young Serioia quinqueradiata ranged from 11.9 to 135.4 mm in total length were collected from May to July at the study area. The striped bands on the bodies of young Seriola quinqueradiata were developed at 10.0$\~$15.0 mm in total length and increased up to 12 bands with growth, These bands were gradually disappeared at 130.0$\~$150.0 mm in total length. There was no significant relationship between the number of Seriola quinqueradiata collected and the weights of the seaweed patches ($r^2=0.04,\;p<0.05$).

The Changes of Coastal Water Level due to the Development of Mokpo Harbor and Construction of Daebul Industrial Complex (목포항 개발 및 대불 산업단지 조성에 따른 연안해역 해면변화)

  • 정명선;이중우
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 1991.06a
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    • pp.37-44
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    • 1991
  • 영산강 하구언 방조제의 건설로 인한 항만 및 이의 인접해역 해면의 변화는 예상한 바 있으며 실제 여러개소에서 월 2회정도의 주기로 목포 구항부근 상업지역에서 해면상승에 따라 주기적으로 침수되는 현상이 나타나고 있다 목포항의 영산강 하구언 방조제 조성으로 인한 조류성분중 최고기록을 가진 수로에서는 6kts 정도로 감소된 것으로 보고되고 있으나 주위자연환경 변화에 따른 수면 상승 및 해수면의 주기적인 변화 등에 대한 상세한 언급 및 깊이 있는 분석은 회피되어왔다. 수자원의 효율적관리를 위해 하구언 방조제는 이미 건설되었고 앞으로 대규모의 항만개발과 대불산업단지조성을 위해 추가 3개의 만입해안해역에 댐으로 해역을 막아 매립공사를 추진하고 있다 그러나 이 지역에 대한 분석은 타당성의 여부만을 강조한 상업적 용역이 이루어지고 있고 장래 개발에 대해 학술적이고 실질적인 문제점 추출과 해결방아네 대해서는 무시하거나 경시한 바가 많다 더구나 태풍 저기압 등과 같은 자연재해를 고려한 분석은 시도되지 못하고 있다 따라서 개발전후의 현상에 대한 상세한 자료 및 현장 조사와 극한 상태를 고려하여 개발에 따른 수위상승 부진동, 조류 수질등 이해역의 변화요소를 수집하고 분석하며 과학적 접근방법에 기초를 둔 수치모델의 실험을 포함하여 현장관측 및 측정자료를 검증하는 것이 필수적이라고 사료되어 종합분석의 한단계로 여기서는 하구언 및 하구간척(Land Reclamatic of Estuary barren)으로 해역축소에 따른 해면변화의 실제현상을 조사하여 정리하고 이를 수치모델을 통해 시뮬레이션하여 보았다 이는 종합개발의 좋은 기초자료로 이용됨은 물론이로 이지역의 개발에 기여할 것으로본다.적절하게 가정된 지반의 응력-변형률 관계와 간극수압특성에 의하여 고려되었다. 그 결과 응력 및 변위가 심하게 발생하는 지역은 황색 점토층이었으며 이로부터 황색 점토층에서 부터 파괴면이 생성되어 다른 지역으로 전파되었음을 유추할 수 있었다.form trap with 2.88[eV] deep of injected space charge from the chathode in the crystaline regions. The origin of ${\alpha}$$_2$ peak was regarded as the detrapping process of ions trapped with 0.9[eV] deep originated from impurity-ion remained in the specimen during production process of the material, in the crystalline regions. The origin of ${\beta}$ peak was concluded to be due to the depolarization process of "C=0"dipole with the activation energy of 0.75[eV] in the amorphous regions. The origin of ${\gamma}$ peak was responsible to the process combined with the depolarization of "CH$_3$", chain segment, with the activation energy of ca

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A Study of DEM Generation in the Ganghwado Southern Intertidal Flat Using Waterline Method and InSAR (수륙경계선 방법과 위상간섭기법을 이용한 강화도 남단 갯벌의 DEM 생성 연구)

  • Lee, Yoon-Kyung;Ryu, Joo-Hyung;Hong, Sang-Hoon;Won, Joong-Sun;Yoo, Hong-Rhyong
    • Journal of Wetlands Research
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    • v.8 no.3
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    • pp.29-38
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    • 2006
  • Digital Elevation Model (DEM) of intertidal flat can be widely used not only for scientific fields, coastal management, fisheries, ocean safety, military, but also for understanding natural and artificial topographic changes of the tidal flat. In this study, we generated DEM of the Ganghwado southern intertidal flat, the largest tidal flat in the west coast of the Korean Peninsula, using waterline method and interferometric synthetic aperture radar (InSAR). Constructed DEM which applied waterline method to the Landsat-5 TM and Landsat-7 ETM+ images closely expresses overall topographic relief of tidal flat. We found that the accuracy was determined by the number of waterlines which reflect various tidal conditions. The application of InSAR to the ERS-1/2 and ENVISAT images showed that only ERS-1/2 tandem pairs successfully generated DEM in the part of northern Yeongjongdo, but construction of DEM in the other areas was difficult due to the low coherence caused by a lot of surface remnant waters. In the near future, Kompsat-2 will provide satellite images having multi-spectral and high spatial resolution within a relatively short period at different sea levels. Application of waterline method to these images will help us construct a high precision tidal flat DEM. Also, we should develop DEM generation method using single-pass microwave satellite images.

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A Practical Algorithm to Simulate Erosion of On-Shore Zone (실용적 해안선 후퇴 반영 알고리즘)

  • Kim, Hyoseob;Lee, Jungsu;Jin, Jae-Youll;Jang, Changhwan
    • Journal of Wetlands Research
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    • v.15 no.3
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    • pp.423-430
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    • 2013
  • An algorithm to allow shoreline movement during numerical experiment on sediment transport, deposition or resuspension for general coastal morphology is proposed here. The bed slope near shoreline, i.e. mean sea level, is influenced by bed material, tidal current, waves, and wave-induced current, but has been reported to remain within a stable range. Its annual variation is not large, either. The algorithm is adjusting the bathymetry, if the largest bed slope within shoreline band exceeds a given bed slope due to continuous erosion at zones below the shoreline. This algorithm automatically describes retreat of shoreline caused by erosion, when used within a numerical system. The algorithm was tested to a situation which includes a continuous dredging at a point, and showed satisfactory development of concentric circle contours. Next, the algorithm was tested to another situation which includes sinking of eroded part of bed plate, and produced satisfactory results, too. Finally, the algorithm was tested to a movable-bed laboratory experimental conditions. The shoreline movement behind detached breakwater was reasonably reproduced with this algorithm.

A Research Review for Establishing Effective Management Practices of the Highly Invasive Cordgrass (Spartina spp.) (생태계 교란식물 cordgrass (Spartina spp.)의 효과적인 관리방안 수립을 위한 고찰)

  • Kim, Jin-Seog
    • Weed & Turfgrass Science
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    • v.5 no.3
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    • pp.111-125
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    • 2016
  • Cordgrass (Spartina spp.) is recognized as a highly invasive plant in estuaries throughout the world because of remarkable versatility and resiliency, significant reproduction, strong adaptability, rapid spreading, and vigorous growth. In this review, therefore, to provide insights on the effective management practices, the previous research works were summarized and discussed. Spartina spp. is a perennial halophyte, warm-season (C4) grass that reproduces both sexually through seeds and asexually by rhizomes. Management strategies for cordgrass have included various physical, biological, and chemical controls. Herbicides are usually the most cost-effective means of control. Currently, glyphosate, imazapyr, fluazifop and haloxyfop have been practically used. To improve the control efficacy, a combination of two more than methods (example, mowing-spraying) is needed to be applied consistently every year for at least 3 to 4 years and to be sprayed with enough dry time (>4-6 hr) at an early growth stage (before flowering). Consistently repeated application of same herbicide have to be avoided to prevent an unexpected emergence of herbicide-resistant lines. On the other hand, Spartina spp. have many positive functions for agricultural and eco-engineering purposes. Thus, we have to give more intensive research for effectively managing advantages and disadvantages of Spartina plantations.

Characteristics of Manganese Nodule from the East Siberian Sea (동시베리아해 망간단괴의 특성)

  • Koo, Hyo Jin;Cho, Hyen Goo;Yoo, Chan Min;Jin, Young Keun
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.219-227
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    • 2017
  • Manganese (Mn) nodules in the Arctic Sea have been founded in the Kara Sea and Barents Sea, but mineral and chemical compositions have been rarely investigated. In this study, mineralogical and geochemical characteristics of Mn nodules obtained during the Arctic Expedition ARA07C in northern East Siberian Sea were identified, and then genesis of Mn nodules were estimated by using these characteristics. Main manganese oxide minerals constituting the manganese nodule were buserite, birnessite, and vernadite. The Mn nodules generally represent radiated and massive texture, and the layered texture was developed restrictively. The radiated texture, main feature of the manganese nodule in the East Siberian Sea, is mainly composed of cuspate-globular microstructure. Compared with the Mn nodules in Pacific and Indian Oceans, Mn nodules of the East Siberian Sea are abundant in Mn, but Fe is too scarce. There was no difference in the chemical composition and microstructures between outer and inner part of nodule. Therefore, nodules are most likely to have only one genesis during their growth, and all of nodules indicate the diagenetic in $Mn-Fe-(Cu+Ni+Co){\times}10$ ternary diagram. It is considered that the manganese nodules in the East Siberian Sea are characterized by high Mn contents because manganese contents in the Arctic Ocean were mainly resulted from river or coastal erosion and most of them are trapped in the Arctic Ocean.

A Study on Optimization for Location and type of Dam Considering the Characteristic of Large Fault (대규모 단층특성을 고려한 최적 댐위치 및 형식 선정)

  • Kim, Han-Jung;Lyu, Young-Gwon;Kim, Young-Geun;Lim, Hee-Dae
    • Tunnel and Underground Space
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    • v.22 no.4
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    • pp.227-242
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    • 2012
  • Youngju multipurpose dam is planned to minimizing the damage by flood and obtaining the water for industrial use in Nakdong river region. Faults in rock mass have strong influences on the behaviors of dam structure. Thus, it is very important to analyse for the characteristics of fault rocks in dam design. However, due to the limitation of geotechnical investigation in design stages, engineers have to carry out the additional geological survey including directional boring to find the distribution of faults and the engineering properties of faults for stability of dam. Especially, the selection of location of dam and type of dam considering fault zone must be analyzed through various experimental and numerical analysis. In this study, various geological survey and field tests were carried out to analyse the characteristics of the large fault zone through the complex dam is designed in foundation region. Also, the distribution of structural geology, the shape of faults and the mechanical properties of fault rock were studied for the reasonable design of the location and type of dam for long-term stability of the complex dam.

Purification and characterization of the extracellular alginate lyase from Streptomyces sp. MET 0515 (Streptomces sp. MET 0515의 균체외 Alginate lyase의 정제 및 특성)

  • Kim, Hyun-Kyoung;Lee, Jae-Chang;Kang, Nam-Hyun;Kim, Song-Hee;Kim, Jong-Guk;Chung, Ki-Chul
    • Journal of Life Science
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    • v.17 no.5 s.85
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    • pp.625-633
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    • 2007
  • We isolated a new extracellular alginate lyase-producing microorganism, which displayed alginate-depolymerizing activity in plate assays, from coastal soils in Wando, Jeollanam-do, Korea. This alginate-depolymerizing bacterium belonged to the genus Streptomyces and it was named Streptomyces sp. MET 0515. An extracellular alginate lyase(ALY1) secreted by Streptomyces sp. MET 0515, was purified to homogeneity by a combination of acetone precipitation, anion-exchange chromatography (Q-Sepharose and DEAE-Sepharose) and Sephacryl S-200 HR gel filtration chromatography. Its molecular mass was 26 kDa as determined by SDS-PACE analysis. The enzyme had an optimal temperature of $70^{\circ}C$ for its activity, and was most active at pH 7.5. The thermal and pH stability were $0-50^{\circ}C$, and pH 6.0-9.0, respectively. The enzyme activity was stimulated by 1mM $Mn^{2+}$, and inhibited by 1mM $Fe^{3+}$, 1mM EDTA and 1mM $Zn^{2+}$. Preliminary analysis of substrate specificity showed that this alginate lyase had activity on both poly-alpha 1,4-L-guluronate and poly-beta 1,4-D-mannuronate in the alginate molecule.