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Physical Properties of Cd2GeSe4 and Cd2GeSe4:Co2+ Thin Films Grown by Thermal Evaporation (진공증착법에 의해 제작된 Cd2GeSe4와 Cd2GeSe4:Co2+ 박막의 물리적 특성)

  • Lee, Jeoung-Ju;Sung, Byeong-Hoon;Lee, Jong-Duk;Park, Chang-Young;Kim, Kun-Ho
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.459-467
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    • 2009
  • $Cd_2GeSe_4$ and $Cd_2GeSe_4:Co^{2+}$ films were prepared on indium-tin-oxide(ITO)-coated glass substrates by using thermal evaporation. The crystallization was achieved by annealing the as-deposited films in flowing nitrogen. X-ray diffraction spectra showed that the $Cd_2GeSe_4$ and the $Cd_2GeSe_4:Co^{2+}$ films were preferentially grown along the (113) orientation. The crystal structure was rhomohedral(hexagonal) with lattice constants of $a=7.405\;{\AA}$ and $c=36.240\;{\AA}$ for $Cd_2GeSe_4$ and $a=7.43\;{\AA}$ and $c=36.81\;{\AA}$ for $Cd_2GeSe_4:Co^{2+}$ films. From the scanning electron microscope images, the $Cd_2GeSe_4$ and $Cd_2GeSe_4:Co^{2+}$ films were plated, and the grain size increased with increasing annealing temperature. The optical energy band gap, measured at room temperature, of the as-deposited $Cd_2GeSe_4$ films was 1.70 eV and increased to about 1.74 eV and of the as-deposited $Cd_2GeSe_4:Co^{2+}$ films was 1.79 eV and decreased to about 1.74 eV upon annealing in flowing nitrogen at temperatures from $200^{\circ}C$ to $500^{\circ}C$. The dynamical behavior of the charge carriers in the $Cd_2GeSe_4$ and $Cd_2GeSe_4:Co^{2+}$ films were investigated by using the photoinduced discharge characteristics technique.

Time-relationship between Deformation and Growth of Metamorphic Minerals around the Shinbo Mine, Korea: the Relative Mineralization Time of Uranium Mineralized Zone (신보광산 주변지역에서 변성광물의 성장과 변형작용 사이의 상대적인 시간관계: 우라늄 광화대의 상대적인 광화시기)

  • Kang, Ji-Hoon;Lee, Deok-Seon
    • Economic and Environmental Geology
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    • v.45 no.4
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    • pp.385-396
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    • 2012
  • The geochemical high-grade uranium anormal zone has been reported in the Shinbo mine and its eastern areas, Jinan-gun, Jeollabuk-do located in the southwestern part of Ogcheon metamorphic zone, Korea. In this paper is reported the time-relationship between deformation and growth of metamorphic minerals in the eastern area of Shinbo mine, which consists of the Precambrian metasedimentary rocks (quartzite, metapelite, metapsammite) and the age-unknown pegmatite and Cretaceous porphyry which intrude them, and is considered the relative mineralization time on the basis of the previous research's result. The D1 deformation formed the straight-type Si internal foliation which is defined mainly as the arrangement of elongate quartz, biotite, opaque mineral in andalusite porphyroblast. The D2 deformation, which is defined by the microfolding of Si foliation, formed S2 crenulation cleavage. It can be divided into two sub-phases, early crenulation and late crenulation. The former occurs as the curvetype Si foliation in the mantle part of andalusite. The latter occurs as S1-2 composite foliation which warps around the andalusite. The andalusite porphyroblast began to grow under non-deformation condition after the formation of S1 foliation which corresponds to the straight-type Si foliation. It continued to grow before the late crenulation phase. The age-unknown pegmatite intruded after the D2 deformation and grew the fibrous sillimanite which random masks the S1-2 composite foliation. The D3 deformation formed F3 fold which folded the S1-2 composite foliation, D2 crenulation, fibrous sillimanite. It means that the intrusion of pegmatite related to the growth of the fibrous sillimanite took place during the inter-tectonic phase of D2 and D3 deformations. The retrograde metamorphism is recognized by the chloritization of biotite and two-way cleavage lamellae which is parallel to the S1-2 composite foliation and the F3 fold axial surface in the andalusite porphyroblast. It occurred during the D2 late crenulation phase and D3 deformation. In considering of the previous research's result inferring the most likely candidate for the uranium source rock as pegamatite, it indicates that the age-unknown pegmatite intruded during the inter-tectonic phase of D2 and D3 deformations, i.e. during the retrograde metamorphism related to the uplifting of crust, and formed the uranium ore zone around the Shinbo mine.

Identification of the Environmentally Problematic Input/Environmental Emissions and Selection of the Optimum End-of-pipe Treatment Technologies of the Cement Manufacturing Process (시멘트 제조공정의 환경적 취약 투입물/환경오염물 파악 및 최적종말처리 공정 선정)

  • Lee, Joo-Young;Kim, Yoon-Ha;Lee, Kun-Mo
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.449-455
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    • 2017
  • Process input data including material and energy, process output data including product, co-product and its environmental emissions of the reference and target processes were collected and analyzed to evaluate the process performance. Environmentally problematic input/environmental emissions of the manufacturing processes were identified using these data. Significant process inputs contributing to each of the environmental emissions were identified using multiple regression analysis between the process inputs and environmental emissions. Optimum combination of the end-of-pipe technologies for treating the environmental emissions considering economic aspects was made using the linear programming technique. The cement manufacturing processes in Korea and the EU producing same type of cement were chosen for the case study. Environmentally problematic input/environmental emissions of the domestic cement manufacturing processes include coal, dust, and $SO_x$. Multiple regression analysis among the process inputs and environmental emissions revealed that $CO_2$ emission was influenced most by coal, followed by the input raw materials and gypsum. $SO_x$ emission was influenced by coal, and dust emission by gypsum followed by raw material. Optimization of the end-of-pipe technologies treating dust showed that a combination of 100% of the electro precipitator and 2.4% of the fiber filter gives the lowest cost. The $SO_x$ case showed that a combination of 100% of the dry addition process and 25.88% of the wet scrubber gives the lowest cost. Salient feature of this research is that it proposed a method for identifying environmentally problematic input/environmental emissions of the manufacturing processes, in particular, cement manufacturing process. Another feature is that it showed a method for selecting the optimum combination of the end-of-pipe treatment technologies.

Effect of Demecolcine-Assisted Enucleation and Recipient Cell Cycle Stage on the Development of Nuclear Transfer Bovine Embryos (Demecolcine 처리에 의한 탈핵과 수핵란 세포질의 세포 주기가 소 핵이식란의 발육에 미치는 영향)

  • Back J. J.;Park C. K.;Yang B. K.;Kim C. I.;Cheong H. T.
    • Reproductive and Developmental Biology
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    • v.29 no.3
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    • pp.175-180
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    • 2005
  • This study was conducted to examine the effects of demecolcine-assisted enucleation and recipient cell cycle stage on the development of bovine somatic cell nuclear transfer (NT) embryos. In vitro cultured oocytes for $16\~20$ h were classified by first polar body (1st PB) extrusion and cell cycle stage (MI and MII) and treated $0.4\;{\mu}L/mL$ demecolcine for 40 min before enucleation. Enucleated oocytes were fused electrically with bovine ear skin cells, activated by Ca-ionophore+DMAP, and cultured in vitro. Most of eggs ($86.2\%$) treated with demecolcine protruded a chromosome mass and enucleated efficiently ($98.8\%$, (P<0.05). Demecolcine did not have a deteriorative effect on the development of NT embryos. Developmental rate of NT embryos reconstituted with oocytes extruded 1st PB significantly higher than that of NT embryos produced by oocytes without 1st PB ($18.2\%\;vs.\;4.6\%\cdot$, P<0.05). Cleavage and blastocyst formation rate of embryos reconstituted with MI oocytes ($69.4\%\;and\;5.9\%$, respectively) were significantly lower than those of embryos reconstituted with MII oocytes ($96.7\%\;and\;23.9\%$, respectively, P<0.05). From the present result, it is suggested that domecolcine is useful for the enucleation of recipient oocytes in bovine NT procedures, and MII oocytes rather than MI oocytes are more appropriate for recipient cytoplasm. Although, the potential to develop into blastocysts of NT embryos produced by 1st PB-nonextruded and MI oocytes was very low, these oorytes could be used for NT.

Effects of Selenium and Vitamin E Administration on the Semen Characteristics, Blood Chemical Values and Hormone in Hanwoo Sires II. Changes of Selenium and Vitamin E Concentrations of Blood in Hanwoo Sires after Selenium, Vitamin E and rBST Administration (Selenium 과 Vitamin E 투여가 한우 종모우의 정액성상, 혈액성분 및 호르몬 변화에 미치는 효과 II. Selenium, Vitamin E 및 rBST 투여가 한우 종모우의 혈중내 Selenium 과 Vitamin E 의 농도 변화에 미치는 효과)

  • 박동헌;양부근;김종복;전기준;정희태;박춘근;이성수;박노형;원유석
    • Korean Journal of Animal Reproduction
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    • v.23 no.3
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    • pp.205-212
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    • 1999
  • The present study was designed to examine the effects of selenium(Se), vitamin E(Vit. E) and recombinant Bovine Somatotropin(rBST) administration on the selenium and vitamin E concentrations of blood in Hanwoo sires Hanwoo sires were randomly assigned to five groups; 1. control, 2. rBST, 0.09mg/kg body weight (BW) 3. Vit E, 1,500IU/kg BW, 4. Se 0.lmg/kg BW, 5. Vit E, 1.500IU plus Se 0.1mg/kg BW. rBST, Vit. E and Se for each experimental group were given 6 times at 15 days interval by intramuscular injection. Blood samples were collected 10 times for experimental periods, separated the serum by centrifugation, and stored at -7$0^{\circ}C$. Se and Vito E concentrations in blood were measured by fluorophotometer and HPLC. Se concentrations of blood in control, rBST, Vito E, Se and Se plus Vito E groups were 64.55, 65.50, 68.15, 73.11 and 74.09 ppb/$m\ell$, respectively. Se concentration in Vit. E plus Se group was significantly higher than in control and rBST groups (P<0.05), but Vito E group was not significantly different in control and rBST groups(P>0.05). The Vit. E concentrations of blood in control, rBST, Vit. E, Se and Se plus Vit. E groups were 2.27, 2.32, 2.80, 2.58 and 2.75 ppm/$m\ell$, respectively. Vit. E and Vit. E plus Se groups were slightly higher than those of any other groups, but not significantly difference in 외 I experimental groups(P<0.05). These results indicate that Se and Vit. E concentrations of blood were slightly increased with the injection of Se and Vit. E in Hanwoo sires.

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Effects of Senenium and Vitamin E Administration on the Semen Characteristics, Blood Chemical Values and Hormone in Hanwoo Sires I. Effects of Selenium, Vitamin E and rBST Administration on the Semen Characteristics in Hanwoo Sires (Selenium 과 Vitamin E 투여가 한우 종모우의 정액성상, 혈액성분 및 호르몬 변화에 미치는 효과 I. Selenium, Vitamin E 및 rBST 투여가 한우 종모우의 정액성상에 미치는 효과)

  • 양부근;전기준;김종복;박동헌;김정익;박춘근;이성수;박노형;원유석
    • Korean Journal of Animal Reproduction
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    • v.23 no.3
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    • pp.191-203
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    • 1999
  • The objectives of this study were to investigate 1) the effects of Selenium(Se), Vitamin E (Vit. E) or recombinant Bovine Somatotropin(rBST) administration on fresh and frozen/thawed semen characteristics and 2) the effect of taurine on frozen/thawed semen characteristics in Hanwoo sires Hanwoo sires were randomly assigned to five groups (1. control, 2. rBST, 0.09mg/kg body weight (BW), 3. Vito E 1,500IU/kg BW, 4. Se 0.l mg/kg BW, 5. Vit. E 1,500IU plus Se 0.1 mg/kg BW). The administration of Se, Vit. E and rBST for each experimental group were given 6 times at 15 days interval by intramuscular injection. The administration of Se, Vit. E or rBST in Hanwoo sires didn't affect semen volume and pH values, but sperm viability was significantly increased comparing to the control group. Also, frozen/thawed semen analysis showed that the sperm viability increased, but any other effects were not found in total sperm :lumber, motility and abnormality among treatments. The addition of taurine in semen freezing extender had a beneficial effects on frozen/thawecl semen characteristics in all groups. The administrations of rBST, Vit. E and Se did not affect the sperm capacitation and acrosome reaction, either the ratio of F pattern(uncapacitated and acrosome intact sperm) or AR pattern(capacitated and acrosome-reacted sperm), but the ratio of B patten(capacitated and acrosome intact sperm) of treatment groups was significantly higher than that of control group, These results indicated that the viability, motility and quality of semen in Hanwoo sires were slightly increased by the injection of rBST, Vit. E and Se, and the addition of taurine in semen freezing extender were also increased the semen characteristics after thawing.

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A Survey of the Kumho River Pollution (금호강 오염의 종합적 조사)

  • Bae, Zun-Ung;Lee, Sang-Hak;Lee, Sung-Ho
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.54-66
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    • 2002
  • In order to study systematic survey of Kumho river pollution, water analysis for 24 items was conducted at 16 sites surrounding the Kumho river system for 3 times from May 2000 to February 2001. Analytical items for the study of water quality are as follows; water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol, T-P, ${PO_4}^{3-}-P$, T-N, $NH_3-N$, ${NO_2}^--N$, ${NO_3}^--N$, Cu, Zn, Cr, Cd, Mn, Fe, Pb and As. The mean values obtained for water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol T-P, T-N, Cu, Zn, Fe and Mn showed $17.84^{\circ}C$, 8.04, $2.54{\mu}g/mL$, $5.64{\mu}g/mL$, $7.07{\mu}g/mL$, $8.75{\mu}g/mL$, $600.4{\mu}S/cm$, $0.19{\mu}g/mL$, $0.015{\mu}g/mL$, $0.29{\mu}g/mL$, $0.21{\mu}g/mL$, $5.22{\mu}g/mL$, $0.005{\mu}g/mL$, $0.007{\mu}g/mL$, $0.044{\mu}g/mL$ and $0.001{\mu}g/mL$ respectively. As, Cd, Cr and Pb are not detected. The mean concentration of phenol, $NH_3-N$ and $NO_2-N$ were found to be increased compared to the prior study for 3 years from January 1997 to December 1999, that of BOD, COD, SS, oil & grease and ABS were found to be decreased and the others are nearly constant. The effect of Kumho river to the Nakdong river pollution are as follows. The mean concentration of BOD changed from $1.07{\mu}g/mL$ to $1.42{\mu}g/mL$ before and after of introducing of Kumho river water respectively. The mean concentration of COD, electrical conductivity, oil & grease, ABS, phenol, T-N and T-P changed from $1.99{\mu}g/mL$, $221{\mu}S/cm$, $0.15{\mu}g/mL$, $0.006{\mu}g/mL$, $0.06{\mu}g/mL$, $2.21{\mu}g/mL$ and $0.08{\mu}g/mL$ to $2.44{\mu}g/mL$, $392{\mu}S/cm$, $0.16{\mu}g/mL$, $0.015{\mu}g/mL$, $0.07{\mu}g/mL$, $2.81{\mu}g/mL$ and $0.19{\mu}g/mL$ respectively.

Correlated Relationships Between Vitamin A Concentration in Serum and Liver and Carcass Characteristics of Hanwoo Steers (거세한우의 혈청 및 간장내 비타민 A 농도와 도체형질간의 상관관계)

  • Chae, S.H.;Jung, K.K.;Choi, C.B.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.585-592
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    • 2003
  • The current study was conducted to determine the relationships of vitamin A on meat quality of Hanwoo as a basic study to manipulate vitamin A contents in feeds to produce high quality beef. Concentrations of vitamin A in serum and liver of Hanwoo steers(n=328) were analyzed and correlation coefficients with carcass properties were evaluated. Mean vitamin A concentration in the serum of Hanwoo steers in the early fattening period was 212.0$\pm$32.7 IU/dl, and that in the late fattening period was 117.56$\pm$43.15 IU/dl. Mean vitamin A concentration in the liver of Hanwoo steers in the late fattening period was 143.62$\pm$110 IU/g expressing large variations might be depended on animals, feeds and farms. There were negative correlations between serum vitamin A concentration and marbling degree(r=-0.24, P<0.01), fat contents in M. Logissimus dorsi (r=-0.21, P<0.01), and beef quality grade(r=-0.20, P<0.01). Vitamin A-palmitate in liver also expressed negative correlations with fat contents in M. Logissimus dorsi (r=-0.18, P<0.01) and beef quality grade(r=-0.16, P<0.05). From the results obtained in the current study, we concluded that it might be possible to produce high quality beef in Hanwoo by manipulating vitamin A contents in the feeds. Further detailed studies, however, are necessary to determine vitamin A contents in feeds, feeding levels, and feeding periods.

Estimation of Growth Curve for Evaluation of Growth Characteristics for Hanwoo cows (한우암소의 성장특성 평가를 위한 성장곡선의 추정)

  • Lee, C.W.;Choi, J.G.;Jeon, K.J.;Na, K.J.;Lee, C.;Yang, B.K.;Kim, J.B.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.509-516
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    • 2003
  • Growth curves were estimated for 1083 female Korean cattle raised in Daekwanryeong branch, National Livestock Research Institute (NLRI). Comparisons were made among various growth curve models for goodness of fit for the growth of the cows. Estimated growth curve functions were $W_t=370.2e^{-2.208e^{-0.00327t}$ for Gompertz model, for von Bertalanffy model, and $W_t=341.2(1+5.652e^{-0.00524t})^{-1}$ for Logistic model. Ages at inflection estimated from Gompertz model, von Bertalanffy model and Logistic model were 242.2 days, 191.5 days, and 330.5 days respectively, body weight at inflection were 136kg, 115kg, and 170kg, and daily gain at inflection were 0.445kg, 0.451kg, and 0.446kg. The predicted weights by ages from Gompertz model, von Bertalanffy model, and Logistic model were onsistently overestimated at birth weight and underestimated at 36 month weight. The von Bertalanffy model which had a variable point of inflection fit the data best.

Effects of Dietary Probiotic on Performance, Noxious Gas Emission and Microflora Population on the Cecum in Broiler (복합 생균제 첨가가 육계 생산성, 유해가스 발생량 및 맹장내 균총에 미치는 영향)

  • Ko, Y.D.;Sin, J.H.;Kim, S.C.;Kim, Y.M.;Park, K.D.;Kim, J.H.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.559-568
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    • 2003
  • This study was carried out to investigate the effect of probiotics on the performance, nutrients digestibility, noxious gas emission and microflora population on the cecum of broilers. A total of 120 broilers, consisted of 4 treatments X 3 replicates X 10 broilers per replicates, were fed the experimental diets containing 0, 0.1, 0.3 and 0.5% probiotics for 5 weeks. Broilers fed the diets containing 0.1 and 0.3% probiotic had higher (p<0.05) body weight gain and feed conversion than those of the others from the 3rd to 4th week. Broilers fed 0.3% probiotic had higher (p<0.05) body weight gain and feed conversion than those of the other levels from the 5th to 6th week. Broilers fed the diets containing 0.1% and 0.3% probiotic had higher (p<0.05) body weight gain and feed conversion than those of the others from the 2nd to 6th week. Dry matter digestibility was significantly (p<0.05) improved with 0.3% probiotic. Emission of ammonia and sulfate hydrogen gas was significantly (p<0.05) decreased at 6th week. However, there was no (p<0.05) difference at the levels of 0, 0.1, 0.3 and 0.5% at the 4th weeks. There was an increase in the lactobacillus sp, but there was a decrease in the microflora population of coliforms in the cecum of broiler with 0.1% and 0.3% probiotics. These results indicated that the compound probiotics of 0.1${\sim}$0.3% were effective in the body weight gain, feed conversion, nutrients digestibility, noxious gas emission and microflora population on the cecum in broilers.