• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.111-117
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• 2019

This study proposed the fabrication and deposition of high purity crystalline $core-TiO_2/shell-Al_2O_3$ nanoparticles. Morphological properties of $core-TiO_2$ and coated $shell-Al_2O_3$ were confirmed by transmission electron microscope (TEM) and transmission electron microscope - energy dispersive spectroscopy (TEM-EDS). The electrical properties of the prepared $core-TiO_2/shell-Al_2O_3$ nanoparticles were evaluated by applying them to a working electrode of a Dye-Sensitized Solar Cell (DSSC). The particle size, growth rate and the main crystal structure of $core-TiO_2$ were analyzed through dynamic light scattering system (DLS), scanning electron microscope (SEM) and X-ray diffraction (XRD). The $core-TiO_2$, which has a particle size of 17.1 nm, a thin film thickness of $20.1{\mu}m$ and a main crystal structure of anatase, shows higher electrical efficiency than the conventional paste-based dye-sensitized solar cell (DSSC). In addition, the energy conversion efficiency (6.28%) of the dye-sensitized solar cell (DSSC) using the $core-TiO_2/shell-Al_2O_3$ nanoparticles selectively controlled to the working electrode is 26.1% higher than the energy conversion efficiency (4.99%) of the dye-sensitized solar cell (DSSC) using the conventional paste method.

• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.65-72
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• 2019

In this study, heterogeneous ion exchange membranes were prepared by casting method with various mixing ratios of PPO ion-selective solution and ion exchange resin. Then heterogeneous bipolar membranes were prepared by using this. The water content of heterogeneous cation and anion exchange membranes were 60~80% respectively, the ion exchange capacity was 2.81~3.26 meq/g, 2.31~2.74 meq/g and electrical resistances were $1.65{\sim}1.45{\Omega}{\cdot}cm^2$ and $1.55{\sim}1.05{\Omega}{\cdot}cm^2$. The tensile strength of heterogeneous bipolar membrane was lower than that of PPO resin before functionalization ($700Kg_f/cm^2$). The tensile strength of heterogeneous bipolar membrane with catalyst layer was lower than that of non-catalytic heterogeneous bipolar membrane. The water splitting voltage of the heterogeneous bipolar membrane with catalyst layer was low and stable at a minimum of 1.7~1.8 V, maximum 3.9~4.0 V, and the water splitting voltage of the non-catalytic heterogeneous bipolar membrane was constant at 3.8~4.0 V.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.1
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• pp.259-267
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• 2019

The purpose of this study is to examine the inner side of those who raise the children, that is, the mothers, through the satisfaction with the parental roles and the child-rearing stress of them, with a view to emphasize the importance of an alternative for the mothers to cope with child-rearing stress and enhancing their satisfaction level with their role as a parent as well as the importance of social support in order to enhance the quality of rearing. For this purpose, the researcher conducted a survey with 312 mothers with preschool children of age 4 to 7 in Seoul and Gyeonggi Area from October 1, 2018 to October 15, 2018. To analyze the data, the researcher conducted frequency analysis, exploratory factor analysis, confirmatory factor analysis, confidence analysis, correlation analysis, structural equation model, and Sobet-test, using SPSS 22.0 and AMOS 22.0. The results of the analyses showed that social support and satisfaction with the parental role were significantly influenced by child-rearing stress, while social support influenced the satisfaction with the parental role significantly. Also, it turned out to have a mediating effect in the relationship between the mother's child-rearing stress and the satisfaction with the parental role. Based on these findings, the study highlights that the social network that is connected with the mothers may function to reduce the negative influence of child-rearing stress on the satisfaction with the parental role when the social network channels appropriate support, tangible assistance, appealing of difficulties, and encouragement.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.1
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• pp.224-235
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• 2019

The increase in the amount of energy used in the agricultural sector due to the expansion of agricultural machinery and greenhouse horticulture has caused a range of problems, such as an increase in the cost of input, such as heating costs and greenhouse gas emission. To overcome these problems, this study examined the current status of energy use in greenhouse horticulture as well as the change patterns of non-taxable oil and agricultural electricity, and reviewed the current status of the supply of renewable energy and energy saving facilities for agriculture. This study investigated the area of advanced and renewable energy and energy saving facilities implemented, applied the energy saving ratio of advanced and renewable energy and energy saving facilities, and determined the effects of renewable energy in the agricultural sector, such as increase in production, decrease in heating cost, reduction in Government financial expenditure, reduction in greenhouse gas emission, and oil substitution effect.

• Journal of the Korean Institute of Landscape Architecture
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• v.47 no.2
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• pp.133-145
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• 2019

This study was raised by the need to explain why the problems related to private parks have been sustained. In order to identify the fundamental cause, it is necessary to analyze the historical and institutional context of private parks. Therefore, the purpose of this study is to identify the direction of change in the private park system and to derive the characteristics of the system as it currently appears. The framework based on the historical institutionalism was divided into the Park Act (1967-1980), the former of Urban Park Act (1980-1993) and the late of Urban Park Act (1993-2005), and each was assessed using the analysis elements of the institutional environment and the outcomes of implementation. The analysis elements interpreted the path dependency, in which the inertia toward the choice of institution is maintained, despite the change in the environment. The institution took a special form of 'negative systeme' and secured profitability by expanding the types of park facilities while mitigating the criteria. Additionally, the designation of private park promoters as a landowner acted as a means of compensating those with property rights to unexecuted urban parks. The expectation effectiveness on urban park creation was insufficient and the environmental regulatory functions were weakened. Thus, historically, the private park system in Korea has experienced an 'institutional decoupling' as the purpose of the system and the results of actual outcomes are not consistent.

• Fire Science and Engineering
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• v.33 no.2
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• pp.114-123
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• 2019

The paper relates to a study on the changes in performance of insulation sheath resulting from accelerated degradation of IV and HIV insulated wire. To assume insulation degradation of IV and HIV insulated wire, accelerated life tests using Arrhenius equation were conducted among accelerated life test models, and experimental samples of 0 year, 10 years, 20 years, 30 years, and 40 years in equivalent life were produced. Whereas the maximum tensile load were increased as accelerated degradation of IV and HIV insulated wire progressed, elongation percentage, rupture time, and flexibility of insulated wires were found to be gradually reduced. According to the additional surface analysis results for the insulated wires per equivalent life using a scanning electron microscope, mechanical properties of the insulator were observed to be reduced as insulation degradation resulting from aging progressed since phenomena such as formation of crystalline structures and perforation, etc. occurred on the sample surface with progression of accelerated degradation. Consequently, institutional replacement of insulated wires and preparation of repair times considering performance degradation of the insulator installed inside buildings are considered necessary in order to prevent in advance the risks of electrical fire resulting from degradation in insulation performance.

• Journal of Climate Change Research
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• v.1 no.3
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• pp.205-210
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• 2010

LED light has various advantages such as an energy saving effect of over 80% compared to existing lighting and environmentally friendly characteristics; however, there has been no affordable market for LED lighting because of its expensive price. This study discussed the validity of the expansion of distribution of LED lighting through an assessment of economic efficiency concerning LED lightening in order to analyze its efficiency in terms of energy savings and maintenance and repair, which will be generated as a result of the change from existing incandescent bulbs to LED lighting in the public sector. As to the target of analysis, the paper reviewed the validity of change to LED lighting as a result of the elimination of existing incandescent bulbs, by referring to 'the current incandescent bulb use and elimination performance' published by the Ministry of Knowledge Economy based on the "Elimination management system" executed by Korea Energy Management Corporation. The paper considered expenses for change, annual power savings amount and electric charges savings amount, repair and maintenance cost, $CO_2$ reduction volume, and the profit from the sale of CER (certified emission reduction). As a result of analyzing economic efficiency, when the discount rate during the change of existing incandescent bulb lighting to LED lighting is 3.26%, the profit was 8,648,400,000 won. Accordingly, NPV was analyzed to have a 'positive (+)' value, which means that this change is profitable.

• Journal of Climate Change Research
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• v.4 no.2
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• pp.141-158
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• 2013

In this study, the projection of future heating and cooling degree days (HDDs and CDDs) has been conducted over South Korea for the period 1996~2005 with 2046~2055 and 2091~2100, using CCSM3 and MM5 simulations driven by the six IPCC SRES emission scenarios (A2, A1B, A1FI, A1T, B1, and B2). Annual mean surface air temperature increases by $1.2{\sim}3.4^{\circ}C$ at the end of the 21st century comparing to the present-day (1996~2005) in South Korea. HDDs decrease by 8~25% and CDDs increase up to 242~1,448% with corresponding changes in temperature. These increases and decreases also change the duration of HDDs and CDDs. HDDs duration decreases by 1 month, while the expansion of CDDs duration is much longer than 2 months. Thus, projected future HDDs and CDDs changes appear that cooling energy demand in summer season would increase and heating energy demand in winter would decrease in the future. Especially, these remarkable changes would be obvious at high mountain area, Gangwon-do and at south area, Jeju island. In the sense of future energy supply and policy, electrical energy for cooling in summer could be getting much more its importance rather than fossil energy used for heating in winter.

• Korean Journal of Materials Research
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• v.29 no.2
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• pp.92-96
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• 2019

Transition metal oxide is widely used as a water electrolysis catalyst to substitute for a noble metal catalyst such as $IrO_2$ and $RuO_2$. In this study, the sol-gel method is used to synthesize the $Cu_xCo_{3-x}O_4$ catalyst for the oxygen evolution reaction (OER),. The CuxCo3-xO4 is synthesized at various calcination temperatures from $250^{\circ}C$ to $400^{\circ}C$ for 4 h. The $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a perfect spinel structure without residues of the precursor and secondary phases, such as CuO. The particle size of $Cu_xCo_{3-x}O_4$ increases with an increase in calcination temperature. Amongst all the samples studied, $Cu_xCo_{3-x}O_4$, which is synthesized at 300?, has the highest activity for the OER. Its onset potential for the OER is 370 mV and the overpotential at $10mA/cm^2$ is 438 mV. The tafel slope of $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a low value of 58 mV/dec. These results are mainly explained by the increase in the available active surface area of the $Cu_xCo_{3-x}O_4$ catalyst.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.1
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• pp.5-14
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• 2019

The objective of this study was investigated the effect of organic fertilizer(OF) application on the grain yield, protein content, and soil chemical properties in rice cultivation to evaluate the replacement ratio of OF based on basal fertilization of inorganic(nitrogen) fertilizer, In case of soil 1 with optimum range of organic matter for rice growth, the grain yield of rice in 70% and 100% treatments of OF were higher than the other treatments. In soil 2 with higher than the optimum range of soil organic matter, the grain yield of rice of NPK, 30%, 70%, 100%, and 300% treatments of OF showed no significant difference. When the protein criteria of rice quality was below 7%, the treatment of 30%, 70%, and 100% using OF in soil 1 were satisfied with protein criteria of rice. In case of soil 1, ammonium nitrogen content, electrical conductivity, and the organic matter in 30%, 70%, 100%, 300% treatments of OF showed similar tendency to NPK treatment. These results suggested that the substitution ratio of OF 70~100% could be appropriate to increase the yield and commercial quality for rice.