• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.4
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• pp.306-317
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• 1995

Abstract Gallium arsenide crystal is usually grown from the melt by the horizontal Bridgman method. We constructed pseudo - steady - state model for crystal growth of GaAs which inclue melt, crystal and the free interface. Mathematical equations of the model were solved for flow, temperature, and concentration field in the melt and temperature field in the crystal. The location and shape of the interface were also solved simultaneously. In 2 - dimensional model, the shape of the interface is flat with adiabatic thermal boundary condition, but it becomes curved with completely conducting thermal boundary condition. In 3 - dimensional model, the interface is less curved than 2 - dimensional case and the flow intensity is similar to that of 2 - dimensional case. With the increase of flow intensity vertical segregation shows maximum value in both 2 - and 3 - D model. However, the maximum value occurs in lower flow intensity in 2 - D model because the interface is more curved for the same flow intensity.

• Journal of the Microelectronics and Packaging Society
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• v.15 no.1
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• pp.33-37
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• 2008

A noticeable amount of Kirkendall voids formed at the Sn-3.5Ag solder joint with electroplated Cu, and that became even more significant when an additive was added to Cu electroplating bath. With SPS, a large amount of voids formed at the $Cu/Cu_3Sn$ interface of the solder joint during thermal aging at $150^{\circ}C$. The in-situ AES analysis of fractured joints revealed S segregation on the void surface. Only Cu, Sn, and S peaks were detected at the fractured $Cu/Cu_3Sn$ interfaces, and the S peak decreased rapidly with AES depth profiling. The segregation of S at the $Cu/Cu_3Sn$ interface lowered interface energy and thereby reduced the free energy barrier for the Kirkendall void nucleation. The drop impact test revealed that the electrodeposited Cu film with SPS degraded drastically with aging time. Fracture occurred at the $Cu/Cu_3Sn$ interface where a lot of voids existed. Therefore, voids occupied at the $Cu/Cu_3Sn$ interface are shown to seriously degrade drop reliability of solder joints.

• Proceedings of the Optical Society of Korea Conference
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• 2000.02a
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• pp.236-237
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• 2000

용액인상법에 의하여 Cr$^{3+}$ 이온이 0.1-0.2% 주입된 Alexandrite (Cr$^{3+}$ :BeAl$_2$O$_4$) 단결정을 성장하고, 성장한 단결정을 이용하여 레이저 소자를 제조하였다. 고품질의 단결정을 성장할 수 있는 결정성장조건을 규명하고, Cr$^{3+}$ 이온의 유효편석 계수를 계산하였으며, 결정 결함 및 분광 물성을 조사하였다. 결정성장 실험 결과, 유속 3 1/min의 질소분위기, 이리듐 도가니 및 <001>방위의 Alexandrite 단결정을 종자결정으로 사용하여 결정을 성장하는 경우 최적의 결정성장 조건은 인상속도 0.5-1.0 mm/hr와 회전속도 20-25 rpm이었다. 육성된 결정은 (100)면이 넓게 발달되었으며, (120)과 (010)면이 측면에 발달되는 판상의 직팔각기둥의 형태로 성장되었다. 결정결함으로써 parasite crystal의 형성과 경계면의 균열, striation, inclusion 등이 검출되었다. Alexandrite 단결정 내에 분포하는 Cr$^{3+}$ 이온의 유효편석계수 k$_{eff}$는 2.8로 계산되었다. 분광물성으로써 실온에서의 $^4$A$_2$$\longrightarrow$$^4$T$_2$(689.6-489.3 nm), $^4$A$_2$$\longrightarrow$$^4$T$_1$(489.3-311.33m) 천이에 의한 흡수를 확인하고, $^4$T$_2$$\longrightarrow$$^4$A$_2$(650-800 nm), $^2$E$\longrightarrow$$^4$A$_2$에 의한 nophonon line R$_1$, R$_2$(680.4, 678.5 nm) 및 $^2$T$_1$$\longrightarrow$$^4$A$_2$(655.7, 649.3, 645.2 nm)의 형광방출 스펙트럼을 얻었으며, 형광수명은 0.264 ms로 조사되었다. 제조된 레이저 발진봉은 직경 6.3 m, 길이 45 nm이었다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.2
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• pp.169-177
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• 1994

Dilute Al-Cu and Al-Mg alloys were solidified unidirectionally upward by Bridgman method. It is necessary that solute concentration of initial melt is uniform to be able to control the concentration of crystal. When solute concentration is not uniform, it can cause unusual macro-segregation in grown solid. A non-steady state solidification was observed where the solute concentration in the grown solid decreased with the progress of solidification, when a dilute Al-Cu melt with positive axial temeprature gradient was solidified. This was caused by leaking out of Cu-rich melt into the gap between ingot and crucible during melt-down and its sedimentation after complete melting. In the case of Al-Mg alloy, the solute concentration has a minimum in the middle of grown specimen because Mg-rich melt flowed down the gap between ingot and crucible and floated after complete melting. Uniform initial melt concentration can be achieved by the homogenization of the ingot or by the absence of the gap between ingot and crucible.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.1
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• pp.162-171
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• 1993

This paper deals with the anisotropy of the mushy region during solidification process of a binary mixture. A theoretical model which specifies a permeability tensor in terms of pricipal values is proposed. Also, the governing equations are modified into convenient forms for the numerical analysis with the existing algorithm. Some test computations are performed for soeidification of aqueous ammonium chloride solution contained in a square cavity. Results show that not only the present model is capable of resolving fundamental characteristics of the tranport phenomena, but also the anisotropy significantly affects the interdendritic flow structure, i.e., double-diffusive convection and macrosegregation patterns.

• Analytical Science and Technology
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• v.5 no.2
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• pp.191-197
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• 1992

An ancient Korean bronze dagger excavated from Yongjai-ri, Iksan-kun, presumed to be manufactured in the pre-historical age, was examined by means of chemical analysis, energy dispersive spectrometry, optical and scanning electron microscopy. Also the measurement of lead isotope ratios was carried out in order to predict the site where raw materials were produced. The composition was identified as 75.3% Cu, 17.1% Sn and 6.8% Pb which was a typical composition of Korean bronze dagger. The microstructure was consisted of ${\alpha}$ and (${\alpha}+{\delta}$) eutectoid. The (${\alpha}+{\delta}$) eutectoid can be easily corroded in comparison with ${\alpha}$. The segregation was frequently observed in the interior of the sample. According to the lead isotopes ratios, raw materials have possibility to be from North China.

• Journal of the Korean Magnetics Society
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• v.5 no.2
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• pp.134-139
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• 1995

We produced $(Co_{93}Cr_{7})-P-Ni$ thin films for longitudinal magnetic recording media using OC magnetron sputtering system The variation of magnetic properties of $(Co_{93}Cr_{7})-P-Ni$ pseudo-ternary system with the composition was examined. We obtained the coercivity up to 1500 Oe. The coercivity iocrease could be ascribed to in-plane anisotropy enhaocement, grain size decrease, magnetic decoupling between particles. TEM micrographs showed that the grains were well-decoupled by the addition of phosphorous.

• Transactions of Materials Processing
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• v.12 no.2
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• pp.94-101
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• 2003

For the optimal net shape forging of S semi-solid materials (SSM), it is important to predict the deformation behavior and defects of materials. Among these defects, liquid segregation is detrimental to produce products with good mechanical properties. Moreover, to apply a numerical method to thixoforging, it is very important to prevent a liquid segregation during forming process. The liquid segregation phenomena in deformation behavior of semi-solid material with variation of test specimen size were studied. The SSM compression tests were performed by dynamic material test system with a furnace. Stress-strain curves and microstructures of SSM were investigated, and Porosities were analyzed to evaluate the effects of experiment parameters on liquid segregation.

• Transactions of Materials Processing
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• v.14 no.4 s.76
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• pp.338-350
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• 2005

Recently, in the field of automobile industry, to solve the problem of reducing the weight of automobile for the improvement of fuel efficiency and the protection of environment, the aluminum alloy parts have been substituted for the steel parts. However, the aluminum alloy does not have as good mechanical property as the steel part. To improve the mechanical property, the semi-solid die casting process is performed to make automobile parts. In the fabrication of semisolid material the control of the liquid segregation is very important to improve the material properties of aluminum alloy. In the present paper we examine the influence of the liquid segregation by the injection conditions in the semi-solid die casting has been investigated.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.3
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• pp.445-456
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• 1997

Continuous casting process is numerically analyzed using the continuum model in a non-orthogonal coordinate system. Flow damping in the mush is modeled by combining the viscosity dependence on liquid fraction in dilute mush and the permeability dependence on liquid fraction in concentrated mush. The effect of turbulence is indirectly considered by effective diffusivity determined elsewhere by experiment. The main objective is to investigate the effects of casting parameters such as casting speed and tundish superheat on the distribution of surface temperature, shell thickness, metallurgical length and centerline segregation. Some of the computed results are compared with available experiments, and reasonable agreements are obtained.