• Title/Summary/Keyword: η-factor

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Novel Extended π-Conjugated Dendritic Zn(II)-porphyrin Derivatives for Dye-sensitized Solar Cell Based on Solid Polymeric Electrolyte: Synthesis and Characterization

  • Kang, Min-Soo;Oh, Jae-Buem;Roh, Soo-Gyun;Kim, Mi-Ra;Lee, Jin-Kook;Jin, Sung-Ho;Kim, Hwan-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.28 no.1
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    • pp.33-40
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    • 2007
  • We have designed and synthesized three Zn(II)-porphyrin derivatives, such as Zn(II) porphyrin ([G-0]Zn-P1) and aryl ether-typed dendron substituted Zn(II)-porphyrin derivatives ([G-1]Zn-P1 and [G-1]Zn-P-CN1). Their chemical structures were characterized by 1H-NMR, FT-IR, UV-vis absorption, EI-mass, and MALDI-TOF mass spectroscopies. Their electrochemical properties were studied by cyclic voltammetry measurement. These Zn(II)-porphyrin derivatives have been used to fabricate dye-sensitized solar cells (DSSCs) based on solid polymeric electrolytes as dye sensitizers and their device performances were evaluated by comparing with that of a standard Ru(II) complex dye. [G-1]Zn-P-CN1 showed the enhanced power conversion efficiency than those of other porphyrin derivatives, as expected. Short-circuit photocurrent density (Jsc), open-circuit voltage (Voc), fill factor (FF), and power conversion efficiency (η) of solid-typed DSSC for [G-1]Zn-P-CN1 were evaluated to be Jsc = 11.67 mA/cm2, Voc = 0.51 V, FF = 0.46, and η = 2.76%, respectively.

Behavior of the Flexural Vibration Damping of a Sandwich Beam System with a Partially Inserted Viscoelastic Layer (점탄성층이 부분적으로 삽입된 샌드위치보의 횡진동 감쇠특성)

  • Park, Jin-Taek;Yu, Hyeong-Won;Jang, Seok-Won;Choe, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.2
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    • pp.225-233
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    • 2002
  • The flexural vibration characteristics of a sandwich beam system with a partially inserted viscoelastic layer have been quantitatively studied using a finite element analysis in combination with a sine-sweep test. Antisymmetric mode shapes of the flexural vibration were visualized by the holographic interferometry and agreed with those calculated by the finite element simulation. Effects of the beam thickness as well as the length and thickness of partial viscoelastic layers on the system loss factor(η$\_$s/) and resonant frequency($\omega$$\_$r/) were significantly large fur the symmetric and antisymmetric modes of the beam system.

A study for improvement of Recognition velocity of Korean Character using Neural Oscillator (신경 진동자를 이용한 한글 문자의 인식 속도의 개선에 관한 연구)

  • Kwon, Yong-Bum;Lee, Joon-Tark
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2004.04a
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    • pp.491-494
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    • 2004
  • Neural Oscillator can be applied to oscillatory systems such as the image recognition, the voice recognition, estimate of the weather fluctuation and analysis of geological fluctuation etc in nature and principally, it is used often to pattern recoglition of image information. Conventional BPL(Back-Propagation Learning) and MLNN(Multi Layer Neural Network) are not proper for oscillatory systems because these algorithm complicate Learning structure, have tedious procedures and sluggish convergence problem. However, these problems can be easily solved by using a synchrony characteristic of neural oscillator with PLL(phase-Locked Loop) function and by using a simple Hebbian learning rule. And also, Recognition velocity of Korean Character can be improved by using a Neural Oscillator's learning accelerator factor η$\_$ij/

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A Study on the Fatigue Strength Evaluation in Rail-type Expansion Joint Weldment of Bridge (레일형 교량신축이음장치 용접부의 피로강도 평가에 관한 연구)

  • 이용복
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1998.10a
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    • pp.115-120
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    • 1998
  • This paper is especially concerned with the weldment between support beam and square bar that plays important roles in control box of Expansion Joint as a bridge structure. Fatigue strength of the weldment is dependent on notch radius from welding defects and material properties. From which, tensile strength($\sigma$ult) and fatigue notch factor(Kf) become important factors to predict fatigue life. The fatigue notch sensitivity(η) for metals can be divided into two types : high and low notch sensitivity. In this work, the Expansion Joint weldment was found to have low notch sensitivity. Fatigue test of real structure was performed up to 106cycles to be compared with predicted endurance limit.

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Flexural Vibration Analysis of a Sandwich Beam Specimen with a Partially Inserted Viscoelastic Layer

  • Park, Jin-Tack;Park, Nak-Sam
    • Journal of Mechanical Science and Technology
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    • v.18 no.3
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    • pp.347-356
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    • 2004
  • The flexural vibration characteristics of a sandwich beam system with a partially inserted viscoelastic layer were quantitatively studied using the finite element analysis in combination with the sine-sweep experiment. Asymmetric mode shapes of the flexural vibration were visualized by holographic interferometry, which agreed with those obtained by the finite element simulation. Effects of the length and the thickness of the partial viscoelastic layer on the system loss factor (η$\_$s/) and resonant frequency (f$\_$r/) were significantly large for both the symmetric and asymmetric modes of the beam system.

Synthesis of Novel Organic Dyes Containing Coumarin Moiety for Solar Cell

  • Choi, Hyun-Bong;Baik, Chul;Kim, Hyun-Jun;Kim, Jeum-Jong;Song, Ki-Hyung;Kang, Sang-Ook;Ko, Jae-Jung
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1973-1979
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    • 2007
  • Novel organic dyes, JK-34, JK-35 and JK-36 containing bis-dimethylfluorenyl amino coumarin unit are designed and synthesized. Nanocrystalline TiO2 dye-sensitized solar cells were fabricated using these dyes. Under standard global AM 1.5 solar condition, the JK-34 sensitized cell gave a short circuit photocurrent density of 10.05 mA cm?2, open circuit voltage of 0.65 V, and a fill factor of 0.68, corresponding to an overall conversion efficiency η of 4.54%. We found that the power conversion efficiency was shown to be quite sensitive to the structural modifications of bridging thiophene moiety.

Electrical Properties of ITO/TiO$_2$/Se Solar Cell (ITO/TiO$_2$/Se 태양전지의 전기적특성에 관한 연구)

  • 문수경;박현빈;구할본;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.114-116
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    • 1992
  • ITO/TiO$_2$/Se solar cell were fabricated by vacuum deposition method, the Se and TiO$_2$were deposited on the ITO/Glass. Prior to the electrical properties of film, the provide Te between the ITO and the Se film were deposited by substrate temperature 20[$^{\circ}C$] and evaporation time 15[min], next time TiO$_2$ were treated by rf-magnetron sputtering in substrate temperature 250[$^{\circ}C$]. Fabricated ITO/TiO$_2$/Se solar cell were as follows : Open Voltage V$\_$oc/=848[mV], Short Circuit Current I$\_$sc/=10.79[mA/$\textrm{cm}^2$]. Fill Factor FF=0.518, energy conversion efficiency η=4.74[%] under the illumination of AM 1.

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Effect of p-type a-SiO:H buffer layer at the interface of TCO and p-type layer in hydrogenated amorphous silicon solar cells

  • Kim, Youngkuk;Iftiquar, S.M.;Park, Jinjoo;Lee, Jeongchul;Yi, Junsin
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.336-340
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    • 2012
  • Wide band gap p-type hydrogenated amorphous silicon oxide (a-SiO:H) buffer layer has been used at the interface of transparent conductive oxide (TCO) and hydrogenated amorphous silicon (a-Si:H) p-type layer of a p-i-n type a-Si:H solar cell. Introduction of 5 nm thick buffer layer improves in blue response of the cell along with 0.5% enhancement of photovoltaic conversion efficiency (η). The cells with buffer layer show higher open circuit voltage (Voc), fill factor (FF), short circuit current density (Jsc) and improved blue response with respect to the cell without buffer layer.

On Reliability and Comparison of $J_{Rice}$-Resistance considering Optimal Strength Ratio and $J_{\delta}$-Resistance Curves converted from CTOD using Appropriate Strength chosen according to Strain Hardening Level (강도비를 적용한 Rice-저항곡선과 변형경화를 고려한 $J_{\delta}$-저항곡선과의 비교)

  • 장석기
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.59-67
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    • 2002
  • The comparison of $J_{Rice}$-resistance considering a few strength ratio in Rice J-integral formula and $J_{\delta}$-resistance curves converted from experimental CTOD using appropriate strength chosen according to strain hardening level, n=10.6 (A533B steel) and n=8.1 (BS4360 steel) is carried out. The optimal dimensionless strength ratio like the factor of revision, (see full text)reflecting strain hardening level in Rice\`s experimental formula is found out and the reliability of appropriate reference strength chosen according to strain hardening level in different materials is investigated through doing that CTOD is transformed from $J_{\delta}$-integral using relationship between J-integral and CTOD. The results are as follows; 1) The optimal factor of revision is when m equals to 3 in (see full text) for Rice's and the above optimal factor of revision multiplies by coefficient, η in Rice's experimental formula instead of n=2, 2) and the pertinent reference strength for high strain hardening material like BS4360 steel is ultimate strength, $\sigma_{u}$ and for material like A533B steel is ultimate-flow strength, $\sigma_{u-f}$. The incompatible of the behavior of both experimental J-resistance curves using Rice's formula and CTOD-resistance curves for A533B and BS4360 steel by Gordon, et al., could be corrected using the optimal factor of revision in Rice\`s and the pertinent reference strength in J=$m_{j}$${\times}$$\sigma_{i}$${\times}$CTOD.

A Single-Stage LED Tube Lamp Driver with Input-Current Shaping for Energy-Efficient Indoor Lighting Applications

  • Cheng, Chun-An;Chang, Chien-Hsuan;Cheng, Hung-Liang;Chung, Tsung-Yuan;Tseng, Ching-Hsien;Tseng, Kuo-Ching
    • Journal of Power Electronics
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    • v.16 no.4
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    • pp.1288-1297
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    • 2016
  • This study proposes a single-stage light-emitting diode (LED) tube lamp driver with input-current shaping for T8/T10-type fluorescent lamp replacements. The proposed AC-DC LED driver integrates a dual-boost converter with coupled inductors and a half-bridge series-resonant converter with a bridge rectifier into a single-stage power conversion topology. This paper presents the operational principles and design considerations for one T8-type 18 W-rated LED tube lamp with line input voltages ranging from 100 V rms to 120 V rms. Experimental results for the prototype driver show that the highest power factor (PF = 0.988), lowest input current total harmonic distortion (THD = 7.22%), and highest circuit efficiency (η = 92.42%) are obtained at an input voltage of 120 V. Hence, the proposed driver is feasible for use in energy-efficient indoor lighting applications.