• Title/Summary/Keyword: α-Hydroxy phosphonates

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Sulphamic Acid: an Efficient Catalyst for the Synthesis of α-HydroxyPhosphonates Using Ultrasound Irradiation (술팜산: 초음파 조사를 이용한 α-히드록시 인산염 합성의 효과적인 촉매)

  • Sadaphal, Sandip A.;Sonar, Swapnil S.;Pokalwar, Rajkumar U.;Shitole, Nanasaheb V.;Shingare, Murlidhar S.
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.536-541
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    • 2009
  • Sulphamic acid has been exploited as a cost-effective catalyst and green alternative for conventional acidic materials to synthesize $\alpha$-hydroxy phosphonates under solvent-free condition. The reaction carried out using ultrasound irradiation with better yields and shorter reaction time.

Neat Synthesis and Anti-oxidant Activity of α-Hydroxyphosphonates

  • Rao, K. Uma Maheswara;Sundar, Ch. Syama;Prasad, S. Siva;Rani, C. Radha;Reddy, C. Suresh
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3343-3347
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    • 2011
  • A simple efficient and neat synthesis of ${\alpha}$-hydroxy phosphonates has been accomplished from aromatic/heterocyclic aldehydes and diethyl phosphite using $KHSO_4$ as a catalyst under solvent-free conditions at ambient temperature. These compounds are characterized by spectral and analytical data and tested for their anti-oxidant activity.