• Title/Summary/Keyword: ] $SO_{4}$

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$CaSO_4$ Decomposition and Desulfurization in In-Furnace Desulfurization for Oxy-Fuel Combustion Using DTF (DTF를 이용한 순산소연소 조건에서 탈황반응과 $CaSO_4$ 분해 특성)

  • Choi, Wook;Jo, Hang-Dae;Choi, Won-Kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.420-425
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    • 2011
  • In general, the decomposition of $CaSO_4$ formed by sulfation reaction in the in-furnace desulfurization process using limestone has strong effect on the desulfurization reaction under the oxy-fuel combustion condition. In this study, the conversion rates were measured and reaction rates were calculated in order to investigate the effects of the experimental variables such as temperature and the concentrations of $CO_2$, $O_2$, $SO_2$, on the $CaSO_4$ decomposition reaction using DTF (Drop Tube Furnace) in the desulfurization reaction. The conversion rate and the reaction rate of $CaSO_4$ decomposition reaction were increased with reaction temperature. $CO_2$ concentration has little effect on $CaSO_4$ decomposition reaction in the presence of $O_2$. Under the same experimental conditions, the decomposition rate of $CaSO_4$ was enhanced with the decreasing the $O_2$ concentration, but vice versa with the increasing of $SO_2$ concentration.

Sulfur Cycle in the Rehabilitated Forest Catchment in Tanakami Mountain, Kansai District, Japan (일본 칸사이 지방 타나카미 산지의 황폐지 복구 산림유역 내 황(黃)순환에 관한 연구)

  • Kim, Su-Jin;Ohte, Nobuhito;Park, Jong-Kwan
    • Journal of the Korean Geographical Society
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    • v.44 no.4
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    • pp.429-446
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    • 2009
  • To understand the sulfur flux and cycle in the forest catchment, the hydrological processes and chemical variation of soil solution, groundwater and stream water were analyzed at the Matsuzawa catchment located in the Kiryu Experimental Basin, Shiga Prefecture, central Japan. Unsaturated soil layer at the upper slope of catchment was the source area of ${SO_4}^{2-}$, and deep soil layer and groundwater were the sink zone of ${SO_4}^{2-}$. The vertical distribution of ${SO_4}^{2-}$ concentrations in groundwater affected seasonal variation of ${SO_4}^{2-}$ concentrations in stream water, as groundwater level changed. It is reasonable to assume that each hydrological processes in the forest catchment play an important roles in the retention and discharge of ${SO_4}^{2-}$.

The Adsorption and Desorption of SO4-2 in the Garlic Field (마늘 재배지토양(栽培地土壤) 중 SO4-2의 흡(吸), 탈착(脫着))

  • Chang, Gi-Chul;Chang, Sang-Moon;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.327-332
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    • 1987
  • Soil samples were collected from the paddy soils growing two crops of rice and garlic in Kyung-pook province. To obtain the basic information on the application of S-fertilizer in the garlic field, the adsorption and release amount of $SO_4{^{-2}}$ in subsoil samples were determined. The ranges of $SO_4{^{-2}}$ contents in surface and sub-soil were 59-117 and 34-102 ppm, respectively. The amount of $SO_4{^{-2}}$ adsorbed by soil samples was found to be more at lower pH and higher concentration of $SO_4{^{-2}}$. The $SO_4{^{-2}}$ adsorption constants in Freundlich equation tended to be higher at lower pH. It is apparent that most of $SO_4{^{-2}}$ was released in the first extraction. However, the lower the pH of extracted solution, the more the $SO_4{^{-2}}$ contents was released by distilled water.

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Effects of Posttraumatic MgSO4 Injection and Hypothermia an Animal Model of Traumatic Brain Injury(TBI) (실험적 외상성 뇌손상모델에서 외상 후 저체온과 MgSO4의 효과)

  • Han, Seong Rok;Hyun, Dong Keun;Park, Chong Oon;Ha, Young Soo;Kim, Joon Mee
    • Journal of Korean Neurosurgical Society
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    • v.29 no.10
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    • pp.1296-1302
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    • 2000
  • Objective : Traumatic brain injury including diffuse axonal injury has been shown to result in a decrease in brainfree magnesium concentration, an endogenous inhibitor of calcium entry into neuron, that is associated with the development of neurological motor deficits. The goal of this study is to establish the therapeutic window during which the therapy with $MgSO_4$ and/or hypothermia improve damaged neurons by TUNEL stain. Method : Moderate brain injury was induced in 64 adult Sprague-Dawley rats, weighing 350 to 450gm each, by using a simple weight-drop device(Marmarou model). The animals were randomly assigned to four groups(sixteen rats each, a control group, a group treated with $MgSO_4$, a group treated with hypothermia, and a group treated with $MgSO_4$ and hypothermia) and the rats in each group were sacrificed and studied after 12 hrs, 24 hrs, 1 wk, and 2 wks after insult. In hypothermic group, these rats were subjected to hypothermia after injury, with their rectal temperatures maintained at $32^{\circ}C$ for 1 hour. After 1-hour period of hypothermia, rewarming to normothermic level was accomplished over 30-minute period. In the groups treated $MgSO_4$, hypothermia and $MgSO_4$ were subsequently treated with $MgSO_4$($750{\mu}moles/kg$) infused intra-muscularly at 30 minutes after trauma. Result : In all treated groups, a significant reduction in TUNEL positive cells was found in comparison with the control group each time(p<0.001). Between treatment groups, No differnce was seen 12hrs, 24hrs, and 1wk. However, hypothermic group treated with or without $MgSO_4$ showed more significant reduction in apoptotic cells than group treated with $MgSO_4$ 2 weeks after trauma(p<0.05). However, hypothermic group treated with $MgSO_4$ showed no significant reduction in apoptotic cells compared with hypothermic group(p>0.05). Conclusion : These findings suggest that both hypothermia and $MgSO_4$ significantly improve pathological changes. Otherwise simultaneously $MgSO_4$ and hypothermia treatment groups is failed to provide additional neuroprotection. These results may be relevant to the design of future clinical trials of therapeutic hypothermia and $MgSO_4$ for traumatic brain injury.

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Study on the Change of Strength and Water Vapour Diffusion Resistant of Stone by Soluble Salt (수용성 염에 의한 암석의 강도와 수증기확산저항도 변화에 관한 연구)

  • Lim, Kwon-Woong;Do, Jin-Young
    • Journal of Conservation Science
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    • v.25 no.2
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    • pp.147-154
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    • 2009
  • The change of strength and water vapour diffusion resistant by soluble salts was investigated in the tuff and granite used in many stone monuments of Gyeongju area. With $Na_2SO_4$ and $CaSO_4{\cdot}2H_2O$ were treated the rock samples to understand the difference of solubility. The densities of the tested rocks were increased by the impregnation of $CaSO_4{\cdot}2H_2O$ and $Na_2SO_4$. The flexural strength was increased in the tuff samples but decreased in the granite as the salts increased in the pore. In the tuff, the uniaxial compressive strength was increased by $CaSO_4{\cdot}2H_2O$, but decreased by $Na_2SO_4$. In the granite, it was decreased slightly by $CaSO_4{\cdot}2H_2O$, but increased by $Na_2SO_4$. The water vapour diffusion resistant was increased by the salts in both rocks. As results, it was cleared that the mechanical strength colud be increased in early stage of weathering by the accumulation of salt and water vapour diffusion resistant.

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Reflectance and Flexural Modulus of ABS/TiO2 Composite Sheets (ABS/TiO2 복합체 쉬트의 반사율과 굴곡 탄성률)

  • Kim, Jun Hong;Yoon, Kwan Han
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.103-107
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    • 2014
  • Poly(acrylonitrile-butadiene-styrene) (ABS) composite sheets containing titanium dioxide ($TiO_2$), barium sulfate ($BaSO_4$), calcium carbonate ($CaCO_3$) were prepared by using a co-rotating twin screw extruder, and the reflectance and flexural modulus of the composite sheets were measured. The fillers were well dispersed in ABS matrix. The reflectance of composite sheet was increased with increasing $TiO_2$ and $BaSO_4$ content. Sheet having $TiO_2$ 20 wt% composition, with 5~20 wt% $BaSO_4$ resulted in more than 95% of reflectance. The flexural modulus of composite sheet was increased from 1864 MPa for $ABS/TiO_2/BaSO_4$ 85/10/5 (w/w/w) to 3134 MPa for $ABS/TiO_2/BaSO_4$ 55/20/25 (w/w/w).

The Medium Optimization through Continuous Culture of an Methanol Utilizing Bacterium for SCP Production (SCP 생산용 메탄올 자화균주의 연속배양에 의한 배지 최적화)

  • 김창호;김태진홍석인
    • KSBB Journal
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    • v.5 no.4
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    • pp.355-363
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    • 1990
  • Methanol-utilizing bacterium isolated from sewage samples in Seoul showed optimal temperature and pH of $33^{\circ}C$ and 7.1 for growth, respectively. The maximum specific growth rate was $0.42hr^{-1}$. The minimum medium composition was reconstituted depending on the surplus and the deficit of each component in the basal medium at steady state. The optimal composition was given as(g/l); Methanol 40, $(NH_4)_2\;SO_42, \;KH_2PO_4\;1.5, \;K_2HPO_4\;0.2, \;H_3PO_4\;0.79, \;Na_2HPO_4{\cdot}12H_2O\;0.15, \;MgSO_4{\cdot}7H_2O\;1.5, \;FeSO_4{\cdot}7H_2O\;0.034, \;MnSO_4{\cdot}4H_2O\;0.005, \;CuSO_4{\cdot}5H_2O\;0.0027, \;CaCl_2{\cdot}2H_2O\;0.25, \;ZnSO_4{\cdot}7H_2O\;0.007, \;(NH_4)_6\;Mo_7O_{24}{\cdot}4H_2O\;0.00048, \;H_3BO_3\;0.00068, \;CoCl_2\; 0.00024$ Under the continuous culture with optimum medium the maximum cell productivity was 3.8g/1/hr at dilution rate $0.23hr^{-1}$. Maximum cell concentration and its protein content were 19.5g/l and 70% at dilution rate of $0.1hr^{-1}$, respectively.

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[ $SO_2/O_2$ ] Separation with [DMIm]$MeSO_4$ in IS Cycle (IS cycle에서의 [DMIm]$MeSO_4$를 이용한 $SO_2/O_2$ 분리)

  • Lee, Ki-Yong;Song, Kwang-Ho;Yoo, Kye-Sang;Kim, Hong-Gon;Jeong, Kwang-Deog;Kim, Chang-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.1
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    • pp.49-55
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    • 2008
  • The feasibility of ionic liquid as a novel absorbent of $SO_2$ for the separation of $SO_2$ from $SO_2/O_2$ mixture in the thermochemical IS(Iodine-Sulfur) cycle was investigated. 1,3-dimethylimidazolium methylsulfate ([DMIm]$MeSO_4$) had shown twenty five times higher solubility of $SO_2$ than that of $O_2$. The dependence of $SO_2$ solubility by [DMIm]$MeSO_4$ on temperature and $SO_2$ partial pressure was examined, which confirmed the possibility of temperature and pressure swing for the separation process. Through cyclic absorption and desorption with temperature swing the stability of [DMIm]$MeSO_4$ in the separation process was also demonstrated. As a result of the experiments carried out, $SO_2$ separation from $SO_2/O_2$ mixture with ionic liquid([DMIm]$MeSO_4$) can be applied to the thermochemical IS cycle.

An Implementation AXI4 Bus for Verification of SoC Platform Using Verilator and C/C++ (Verilator와 C/C++를 이용한 SoC 플랫폼 검증을 위한 AXI4 BUS 구현)

  • Lee, Jung-Yong;Lee, Kwang-Yeob
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.05a
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    • pp.364-367
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    • 2012
  • In this paper, AXI4 BUS was implemented using Verilator and C/C++ for verification of SoC platform H/W IP which is based on AXI4 BUS. In this paper we proposed a method to verify the AXI4 BUS based SoC platform H / W IP by implemented AXI4 BUS on PC using Verilator and C/C++. The result shows AXI4 BUS based H/W IP that is verified by implemented AXI4 BUS is to perform the same behavior on FPGA environment.

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Effect of Manganese Sulfate Concentration in Media on Production Speed of Insecticidal Crystal by Bacillus thuringiensis (배지 중 Manganese sulfate 농도가 Bacillus thuringiensis의 곤충독소 생성 시간에 미치는 영향)

  • Ro-Un Lee;Do Gyung Oh;Eun-Sun Jeong;Jung-Beom Kim
    • Journal of Food Hygiene and Safety
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    • v.38 no.3
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    • pp.170-175
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    • 2023
  • In this study, the effect of MnSO4 on the insecticidal crystal (IC) produced by Bacillus thuringiensis for a rapid detection medium was analyzed. The strains used included one B. thuringiensis reference (KCTC 1511) and nine wild-type strains. The IC in B. thuringiensis was detected following the method published by the Ministry of Food and Drug Safety in Korea. In the nutrient agar to which 0.005% MnSO4 was added, IC was observed on two of the three plates after 48 hours of incubation and on all three plates after 120 hours. In AK agar, IC was observed on one and two of the three plates after 48 and 96 hours of incubation, respectively. These results indicated that 0.005% MnSO4 nutrient agar is more appropriate than AK agar for production of IC in B. thuringiensis. The effect of various MnSO4 concentrations on IC production was studied after 24 hours of incubation. IC was produced on 1 of the 10 plates with 0.000% MnSO4 nutrient agar, 2 of the 10 plates with 0.001% MnSO4 nutrient agar, and 3 of the 10 plates with 0.002% MnSO4 nutrient agar. IC was not observed for the other nutrient agars containing 0.003%-0.009% MnSO4. These results indicated that nutrient agar with 0.002% MnSO4 led to the most rapid production of IC by B. thuringiensis after 24 hours of incubation. However, the conditions for IC production by B. thuringiensis depended on the incubation conditions and strain activity. Therefore, further studies are needed to verify the effects of 0.002% MnSO4 on the production of IC by various Bacillus thuringiensis strains.