• Title/Summary/Keyword: \gamma,\

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Investigation of Co- and Pr-doped yttria-stabilized cubic zirconia (YSZ) single crystal grown by skull melting method (스컬용융법에 의해 성장시킨 Co와 Pr이 첨가된 이트리아안정화큐빅지르코니아(YSZ) 단결정의 연구)

  • Moon, So-I;Seok, Jeong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.4
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    • pp.140-144
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    • 2014
  • Co-(0.7 wt%) and Pr-(2.0, 3.5 or 5.0 wt%) doped cubic zirconia ($ZrO_2:Y_2O_3=50:50wt%$) single crystals grown by a skull melting method were heat-treated in $N_2$ at $1150^{\circ}C$ for 5 hrs. The brown colored as-grown single crystals were changed into either dark brownish green, greenish blue and light green color after the heat treatment. Before and after the heat treatment, the YSZ (yttria-stabilized zirconia) single crystals were cut for wafer form (${\phi}7.5mm{\times}t3mm$). The optical and structural properties were examined by UV-VIS spectrophotometer and X-ray diffraction. Absorption by $Co^{2+}$(${\fallingdotseq}589nm$: ${\Gamma}_8[^4A_2(^4F)]{\rightarrow}{\Gamma}_8+{\Gamma}_7[^4T_1(^4F)]$, ${\fallingdotseq}610nm$: ${\Gamma}_8[^4A_2(^4F)]{\rightarrow}{\Gamma}_8[^4T_1(^4F)]$], ${\fallingdotseq}661nm$: ${\Gamma}_8[^4A_2(^4F)]{\rightarrow}{\Gamma}_6[^4T_1(^4F)]$]) and $Pr^{3+}$(${\fallingdotseq}450nm$: ${^3}H{_4}-{^3}P{_2}$, ${\fallingdotseq}473nm$: ${^3}H{_4}{\rightarrow}{^3}P{_1}$, ${\fallingdotseq}484nm$: ${^3}H{_4}{\rightarrow}{^3}P{_0}$), change of ionization energy and lattice parameter were confirmed.

Preparation of Fiber-Reinforced $\gamma-LiAlO_2$ Matrixes by the Tape Casting Method (테이프캐스팅법에 의한 화이버 강화 $\gamma-LiAlO_2$ 메트릭스의 제조)

  • 현상훈;백계현;홍성안
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.303-313
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    • 1997
  • To enhance the strength and formability of MCFC matrixes, alumina/${\gamma}$-LiAlO2 fiber-reinforced ${\gamma}$-LiAlO2 ma-trixes have been investigated. The MCFC matrixes with the thickness of 500~600 ${\mu}{\textrm}{m}$ were prepared by tape-casting of the slurry containing 10~30wt% fibers, followed by heat-treating up to $650^{\circ}C$. The porosity of fi-ber-reinforced matrixes decreased with the content of fibers, while the appropriate porosity(50~60%) for MCFC matrixes could be attained by adding larger ${\gamma}$-LiAlO2 particles with the diameter of about 50${\mu}{\textrm}{m}$ up to 50 wt%. The optimum length and content of the alumina fiber, both in the alignment of fibers and the enhancement of the strength, were found to be below 250${\mu}{\textrm}{m}$ and 20 wt%, respectively. On the other hand, the strength(156 gf/$\textrm{mm}^2$) of the ${\gamma}$-LiAlO2 matrix reinforced with ${\gamma}$-LiAlO2 fibers prepared in this study was improved by 20~40% in comparison with the alumina-fiber-reinforced matrix. It was also found that the alu-mina-fiber-reinforced matrix was completely corroded in molten carbonates but the ${\gamma}$-LiAlO2 was not.

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Effects of low dose ${\gamma}$ radiation on the uptake of mineral nutrients in chinese cabbage and radish (저선량 ${\gamma}$ 선 조사가 배추와 무 종자의 발아와 양분흡수에 미치는 영향)

  • Yoon, Young-Man;Kim, Nam-Bum;Kim, Jae-Sung;Kim, Jeong-Gyu
    • Korean Journal of Environmental Agriculture
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    • v.18 no.4
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    • pp.344-348
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    • 1999
  • To investigate hormetic effect of low dose ${\gamma}$-ray on the uptake of mineral nutrients in Chinese cabbage (Brassica campestris var. Hekjinju var. Surim and) and radish (Raphanus sativas var. Chung-un), seeds of these plants were irradiated with the dose of 1 to 10 Gy. Germination rate and dry weight were examined at pot experiment in greenhouse. Samples for analysis of mineral nutrient were harvested at 17 days and at 59 days after seedling and were analyzed by ICP. Brassica campestris varieties showed higher germination rate and dry weight production with increasing ${\gamma}$ ray dose. Dry weight of Hekjinju Surim and were 143% and 138% at 10Gy dose. respectively. There was no tendency in germination rate and dry weight production for Raphanus sativas var. Chung-un with ${\gamma}$-ray irradiation. The pattern of mineral nutrient content of these plants showed ${\gamma}$ or ${\delta}$ type of dose-reaction curve with no siginificant. This investigation suggests that the more results can be required to understand the hormetic effect of low dose ${\gamma}$ ray on the uptake of mineral nutrient for these plants.

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Combined Removal of n-heptane and CO using Plasma-catalytic Process (플라즈마/촉매 공정을 이용한 n-헵테인과 일산화탄소 동시제거)

  • Lee, Sang Baek;Jo, Jin Oh;Mok, Young Sun
    • Journal of the Korean Institute of Gas
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    • v.20 no.2
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    • pp.1-9
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    • 2016
  • Combined removal of n-heptane and carbon monoxide (CO) using a plasma-catalytic process was investigated. The performance of the plasma-catalytic process was compared with that of the catalyst-alone process to characterize the decomposition of n-heptane and CO with the operation parameters such as the type of catalyst, reaction temperature, and discharge power. From several sets of experiments, it was found that the decomposition efficiency of n-heptane mainly depended on the specific input energy rather than the reactor temperature, whereas the oxidation of CO on both the energy density and the reaction temperature. The results conducted over several metal oxide catalysts exhibited that the decomposition efficiency of n-heptane was in the order: $Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3{\approx}Ag/{\gamma}-Al_2O_3$. Especially, $Pd/{\gamma}-Al_2O_3$ catalyst did hardly generate CO as a byproduct during the decomposition of n-heptane under an appropriate condition, revealing $CO_2$ selectivity of nearly 100%. The CO oxidation efficiency was largely affected by the type of catalyst ($Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$). At temperatures below $180^{\circ}C$, the plasma-catalytic process was more effective in the oxidation of CO, while above $180^{\circ}C$, the catalytic process resulted in slightly higher CO oxidation efficiency.

Fc ${\gamma}R$ genetic polymorphisms of periodontal disease in Korean population (한국인 치주질환 환자에서 Fc ${\gamma}R$ 유전자다형성에 관한 연구)

  • Shin, Seung-Yun;Kim, Kyoung-Hwa;Park, Ok-Jin;Lee, Yong-Moo;Rhyu, In-Chul;Kim, Kack-Kyun;Ku, Young;Yoshie, Hiromasa;Han, Soo-Boo;Chung, Chong-Pyoung
    • Journal of Periodontal and Implant Science
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    • v.34 no.3
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    • pp.671-681
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    • 2004
  • Genomic Project 이후로 다양한 질환에 있어서 유전적인 영향에 관한 연구가 진행되고 있다. 이 연구의 목적은 한국인 치주질환 환자에서 Fc ${\gamma}R$ 유전자의 유전자다형성과 치주질환 특성과의 관련성을 알아보는 것이다. 치주적으로 건강한 한국인 90명(대조군, 남자64명, 여자26명), 중도 만성 치주염환자 40명(severe chronic periodontitis patients; severe CP, 남자 24명, 여자 16명)을 대상으로 임상지수(치주낭 깊이, 입상부착소실, 치은지수, 치태지수, 탐침 후 출혈지수, 치조골소실)를 측정하였다. 또한 이들의 정맥혈에서 추출한 DNA를 PCR(Polymerase Chain Reaction)법, 전기영동법 등을 이용하여 Fc ${\gamma}RIIIa$ , Fc ${\gamma}RIIIb$의 대립유전자의 존재여부를 확인하였다. 이를 바탕으로 각 유전자의 다형성 및 Fc ${\gamma}R$ 복합유전자형 (Fc ${\gamma}R$ composite genotype)을 확인하여, 각 군 간을 비교하였다. 치주질환의 특성과 유전자 다형성과의 관련성을 알아보기 위하여 Fc ${\gamma}R$ 유전자에 대한 유전자다형성을 조사한 결과 다음과 같은 결과를 얻을 수 있었다. 1. Fc ${\gamma}RIIla$에 대한 유전자다형성 연구결과 대조군과 severe CP, AgP군 사이에서, severe CP와 AgP군 사이에서는 대립유전자분포가 서로 유의성 있는 차이를 나타내었지만(p<0.05), Fc ${\gamma}RIIlb$에서는 유의성 있는 차이를 보이지 않았다(p>0.05). 2. Fc ${\gamma}R$ 복합유전자형간의 비교에서 유의성 있는 차이를 발견할 수 없었다(p>0.05). 이와 같은 결과를 종합하여 볼 때 실험대상 한국인 치주염환자에서 Fc ${\gamma}R$ 유전자에 대한 다형성분석에서 Fc ${\gamma}RIIIa$ 대립유전자가 치주염에 대한 감수성과 관련되어 있다고 생각된다. 이 연구의 결과는 유전자의 차이가 치주질환의 감수성 판단의 자료로 활용할 수 있는 가능성을 보여주고 있다.

Gamma-ray Exposure Rate Monitoring by Energy Spectra of NaI(Tl) Scintillation detectors

  • Lee, Mo Sung
    • Journal of Radiation Protection and Research
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    • v.42 no.3
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    • pp.158-165
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    • 2017
  • Background: Nuclear facilities in South Korea have generally adopted pressurized ion chambers to measure ambient gamma ray exposure rates for monitoring the impact of radiation on the surrounding environment. The rates assessed with pressurized ion chambers do not distinguish between natural and man-made radiation, so a further step is needed to identify the cause of abnormal variation. In contrast, using NaI(Tl) scintillation detectors to detect gamma energy rates can allow an immediate assessment of the cause of variation through an analysis of the energy spectra. Against this backdrop, this study was conducted to propose a more effective way to monitor ambient gamma exposure rates. Materials and Methods: The following methods were used to analyze gamma energy spectra measured from January to November 2016 with NaI detectors installed at the Korea Atomic Energy Research Institute (KAERI) dormitory and Hanbat University. 1) Correlations of the variation of rates measured at the two locations were determined. 2) The dates, intervals, duration, and weather conditions were identified when rates increased by $5nSv{\cdot}h^{-1}$ or more. 3) Differences in the NaI spectra on normal days and days where rates spiked by $5nSv{\cdot}h^{-1}$ or more were studied. 4) An algorithm was derived for automatically calculating the net variation of the rates. Results and Discussion: The rates measured at KAERI and Hanbat University, located 12 kilometers apart, did not show a strong correlation (coefficient of determination = 0.577). Time gaps between spikes in the rates and rainfall were factors that affected the correlation. The weather conditions on days where rates went up by $5nSv{\cdot}h^{-1}$ or more featured rainfall, snowfall, or overcast, as well as an increase in peaks of the gamma rays emitted from the radon decay products of $^{214}Pb$ and $^{214}Bi$ in the spectrum. This study assumed that $^{214}Pb$ and $^{214}Bi$ exist at a radioactive equilibrium, since both have relatively short half-lives of under 30 minutes. Provided that this assumption is true and that the gamma peaks of the 352 keV and 1,764 keV gamma rays emitted from the radionuclides have proportional count rates, no man-made radiation should be present between the two energy levels. This study proved that this assumption was true by demonstrating a linear correlation between the count rates of these two gamma peaks. In conclusion, if the count rates of these two peaks detected in the gamma energy spectrum at a certain time maintain the ratio measured at a normal time, such variation can be confirmed to be caused by natural radiation. Conclusion: This study confirmed that both $^{214}Pb$ and $^{214}Bi$ have relatively short half-lives of under 30 minutes, thereby existing in a radioactive equilibrium in the atmosphere. If the gamma peaks of the 352 keV and 1,764 keV gamma rays emitted from these radionuclides have proportional count rates, no man-made radiation should exist between the two energy levels.

Binding Model of Amentoflavone to Peroxisome Proliferator-Activated Receptor &#x03B3;

  • Lee, Jee-Young;Kim, Jin-Kyoung;Lee, So-Jung;Lee, Eun-Jung;Shin, So-Young;Jin, Qinglong;Yoon, Do-Young;Woo, Eun-Rhan;Kim, Yang-Mee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1475-1479
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    • 2012
  • Human peroxisome proliferator-activated receptor gamma ($hPPAR{\gamma}$) has been implicated in numerous pathologies, including obesity, diabetes, and cancer. In this study, we verified that amentoflavone is an agonist of $hPPAR{\gamma}$ and probed the molecular basis of its action. It was demonstrated that amentoflavone bound $hPPAR{\gamma}$ with high (picomolar) affinity and increased the binding between $hPPAR{\gamma}$ and steroid receptor coactivator-1 (SRC-1) by approximately 4-fold. Based on a docking study, for the first time, we propose a model of amentoflavone and $hPPAR{\gamma}$ binding in which amentoflavone forms three hydrogen bonds with the side chains of His323, Tyr327, and Arg280 in $hPPAR{\gamma}$ and participates in two hydrophobic interactions.

A Study on the Strength Characteristics of $L1_{2}-Ni_{3}Al$ Intermetallic Compound ($L1_{2}-Ni_{3}Al$ 금속간화합물의 강도특성에 관한 연구)

  • Han, Chang-Suk;Chun, Chang-Hwan;Han, Seung-Oh
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.1
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    • pp.8-15
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    • 2009
  • Structural studies have been performed on precipitation hardening found in $Ni_{3}Al$ based ordered alloys using transmission electron microscopy (TEM). Tilt experiments by the weak-beam method were made to obtain some information concerning the cross slip mechanism of the superlattice dislocation. The strength of ${\gamma}'-Ni_3$(Al,Ti) increases over the temperature range of experiment by the precipitation of fine $\gamma$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature. Over the whole temperature range, the interaction between dislocation and $\gamma$ precipitates is attractive. On the temperature range of 773 K to 973 K, the dislocations in ${\gamma}'$ matrix move on (111) primary slip plane. When the applied stress is removed, the dislocations make cross slip into (010) plane, while those in $\gamma$ precipitates remain on the (111) primary slip plane. The increase of high temperature strength in ${\gamma}'-Ni_3$(Al,Ti) containing $\gamma$ precipitates is due to the restraint of cross slip of dislocations from (111) to (010) by the dispersion of disordered $\gamma$ particles.

The SH3 Domain of Phospholipase C-${\gamma}1$ Associates with Shc

  • Kim, Myung-Jong;Hwang, Jong-Ik;Chang, Jong-Soo;Ryu, Sung-Ho;Suh, Pann-Ghill
    • BMB Reports
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    • v.32 no.2
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    • pp.119-126
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    • 1999
  • The SH3 domain of PLC-${\gamma}1$ has been known to induce DNA synthesis. However, little is known about the putative effector proteins that associate with the domain. In this report, we provide evidence that the SH3 domain of PLC-${\gamma}1$ associates with Shc, which has been implicated in the activation of p21Ras in response to many growth factors. The association between Shc and PLC-${\gamma}1$ is enhanced either by v-Src-induced transformation or EGF-stimulation in vivo and in vitro. Furthermore, from transient expression studies with COS-7 cells, we show that the SH3 domain of PLC-${\gamma}1$ is required for association with Shc in vivo, whereas tyrosyl phosphorylation of PLC-${\gamma}1$ is not. Taken together, we suggest that Shc might be involved in the PLC-${\gamma}1$-mediated signaling pathway.

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Singular Representation and Finite Element Methods

  • 김석찬
    • Proceedings of the Korean Society of Computational and Applied Mathematics Conference
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    • 2003.09a
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    • pp.9-9
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    • 2003
  • Let $\Omega$ be a bounded, open, and polygonal domain in $R^2$ with re-entrant corners. We consider the following Partial Differential Equations: $$(I-\nabla\nabla\cdot+\nabla^{\bot}\nabla\times)u\;=\;f\;in\;\Omega$$, $$n\cdotu\;0\;0\;on\;{\Gamma}_{N}$$, $${\nabla}{\times}u\;=\;0\;on\;{\Gamma}_{N}$$, $$\tau{\cdot}u\;=\;0\;on\;{\Gamma}_{D}$$, $$\nabla{\cdot}u\;=\;0\;on\;{\Gamma}_{D}$$ where the symbol $\nabla\cdot$ and $\nabla$ stand for the divergence and gradient operators, respectively; $f{\in}L^2(\Omega)^2$ is a given vector function, $\partial\Omega=\Gamma_{D}\cup\Gamma_{N}$ is the partition of the boundary of $\Omega$; nis the outward unit vector normal to the boundary and $\tau$represents the unit vector tangent to the boundary oriented counterclockwise. For simplicity, assume that both $\Gamma_{D}$ and $\Gamma_{N}$ are nonempty. Denote the curl operator in $R^2$ by $$\nabla\times\;=\;(-{\partial}_2,{\partial}_1$$ and its formal adjoint by $${\nabla}^{\bot}\;=\;({-{\partial}_1}^{{\partial}_2}$$ Consider a weak formulation(WF): Find $u\;\in\;V$ such that $$a(u,v):=(u,v)+(\nabla{\cdot}u,\nabla{\cdot}v)+(\nabla{\times}u,\nabla{\times}V)=(f,v),\;A\;v{\in}V$$. (2) We assume there is only one singular corner. There are many methods to deal with the domain singularities. We introduce them shortly and we suggest a new Finite Element Methods by using Singular representation for the solution.

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